MEGUIAR'S G120 User Manual

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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
27-4184-1
Version number:
4.00
Revision date:
28/04/2014
Supersedes date:
18/10/2013
Transportation version number: 1.00 (15/06/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G120, Hot Shine Tyre Spray (21-71B): G12024, G12032
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Aspiration Hazard, Category 1 - Asp. Tox. 1; H304 Specific Target Organ Toxicity-Single Exposure, Category 3 - STOT SE 3; H336
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Harmful; Xn; R65 R66 R67
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For full text of R phrases, see Section 16.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
DANGER!
Symbols:
GHS07 (Exclamation mark) | GHS08 (Health Hazard) |
Pictograms
Ingredient CAS Nbr % by Wt Distillates (petroleum), hydrotreated light 64742-47-8 60 - 80
HAZARD STATEMENTS:
H304 May be fatal if swallowed and enters airways. H336 May cause drowsiness or dizziness.
PRECAUTIONARY STATEMENTS General:
P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand.
Prevention:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response:
P331 Do NOT induce vomiting. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH066 Repeated exposure may cause skin dryness or cracking.
Contains 100% of components with unknown hazards to the aquatic environment.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
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Symbol(s)
Harmful
Contains:
Distillates (petroleum), hydrotreated light
Risk phrases
R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Safety phrases
S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
S2 Keep out of the reach of children.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Distillates (petroleum), hydrotreated light 64742-47-8 EINECS 265-
149-8
60 - 80 Xn:R65 - Nota 4 (EU)
R10; R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP) Flam. Liq. 3, H226; STOT SE 3, H336; EUH066 (Self Classified)
Siloxanes and silicones, di-Me 63148-62-9 15 - 40 Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
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If swallowed
Do not induce vomiting. Get immediate medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Avoid breathing
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dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Store away from heat. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene.
Respiratory protection
In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
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9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Very slight chemical odour; Clear liquid
Odour threshold
No data available.
pH
Not applicable.
Boiling point/boiling range
232.2 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Flash point > 93 °C (200 °F)
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.823 - 0.857 [Ref Std:WATER=1]
Water solubility
No data available.
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
< 1
Vapour density
> 1
Decomposition temperature
No data available.
Viscosity
0.045 Pa-s - 0.055 Pa-s
Density
0.823 - 0.857 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.00 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
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Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Chemical (aspiration) pneumonitis: Signs/symptoms may include coughing, gasping, choking, burning of the mouth, difficulty breathing, bluish coloured skin (cyanosis), and may be fatal. Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Target Organ Effects:
Single exposure may cause:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Distillates (petroleum), hydrotreated light Dermal Rabbit LD50 > 3,160 mg/kg Distillates (petroleum), hydrotreated light Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 3.0 mg/l
Distillates (petroleum), hydrotreated light Ingestion Rat LD50 > 5,000 mg/kg Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Distillates (petroleum), hydrotreated light Rabbit Mild irritant
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Siloxanes and silicones, di-Me Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Distillates (petroleum), hydrotreated light Rabbit Mild irritant Siloxanes and silicones, di-Me Rabbit No significant irritation
Skin Sensitisation
Name Species Value
Distillates (petroleum), hydrotreated light Guinea
pig
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Distillates (petroleum), hydrotreated light In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
Distillates (petroleum), hydrotreated light Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Distillates (petroleum), hydrotreated light
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL Not
available Distillates (petroleum), hydrotreated light
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Aspiration Hazard
Name Value
Distillates (petroleum), hydrotreated light Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be
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reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Distillates (petroleum), hydrotreated light
64742-47-8 Data not
available or insufficient for
classification Siloxanes and silicones, di­Me
63148-62-9 Data not
available or
insufficient for
classification
12.2. Persistence and degradability
No test data available.
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Distillates (petroleum), hydrotreated light
64742-47-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
No test data available.
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Distillates (petroleum), hydrotreated light
64742-47-8 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
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13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R10 Flammable. R65 Harmful: May cause lung damage if swallowed.
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R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 12: Persistence and Degradability information information was modified. Section 1: Address information was modified. Copyright information was modified. Section 11: Aspiration Hazard Table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Section 11: Target Organs - Single Table information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: CLP Percent Unknown information was added. Label: Graphic information was added. Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added. Label: CLP Precautionary - Disposal information was added. Label: CLP Precautionary - Disposal - Header information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: CLP Precautionary - Prevention information was added. Label: CLP Precautionary - Prevention - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: CLP Precautionary - Storage information was added. Label: CLP Precautionary - Storage - Header information was added. Label: Precautionary Statement - Header information was added. CLP: Ingredient table information was added. Label: CLP Supplemental Hazard Statements information was added. Label: CLP Supplemental Hazard Statements - Header information was added. Label: CLP Supplemental Information - Header information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Label: CLP Ingredients table Ingredient heading information was added. Label: CLP Ingredients table CAS No heading information was added. Label: CLP Ingredients table Percent by Wt heading information was added. Section 2: H phrase reference information was added. Section 11: Disclosed components not in tables text information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV information was added. Section 11: Respiratory Sensitization Table information was deleted. Section 11: Reproductive Toxicity Table information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to
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satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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