MEGUIAR'S G103 User Manual

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Safety Data Sheet
Copyright, 2013, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
27-6195-5
Version number:
2.00
Revision date:
11/02/2013
Supersedes date:
07/07/2012
Transportation version number: 1.00 (05/08/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G103, Scratch X 2.0 (20-191B): G10307
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
R66
For full text of R phrases, see Section 16.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
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None.
Contains:
No ingredients are assigned to the label.
Risk phrases
R66 Repeated exposure may cause skin dryness or cracking.
Safety phrases
S46 If swallowed, seek medical advice immediately and show this container or label. S2 Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota N applied to CASRN 64742-46-7. For containers <125mL, label with S46-2. (Consumer)
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 60 - 90 Solvent naphtha (petroleum), medium aliphatic
64742-88-7 EINECS 265-
191-7
7 - 13 Xn:R65 - Nota 4 (EU)
R10; R66; R67 (Self Classified)
Asp. Tox. 1, H304 (CLP) Flam. Liq. 3, H226; STOT SE 3, H336; EUH066 (Self Classified)
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
7 - 13 Nota N (EU)
Xn:R20-65; R66 (Self Classified)
Nota N (CLP) Acute Tox. 4, H332; Asp. Tox. 1, H304; STOT SE 3, H336; EUH066 (Self Classified)
Aluminium oxide 1344-28-1 EINECS 215-
691-6
5 - 10
Glycerin 56-81-5 EINECS 200-
289-5
0.5 - 1.5
Triethanolamine 102-71-6 EINECS 203-
049-8
0.5 - 1.5
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
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Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion. Oxides of nitrogen. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible.
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Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep container tightly closed. Store away from heat. Store away from acids. Store away from strong bases.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Aluminium oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable dust):4 mg/m³
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
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a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet hydrocarbon odoUr; White, creamy, viscous lotion
Odour threshold
No data available.
pH
8 - 8.8
Boiling point/boiling range
No data available.
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
>= 93.3 ºC [Test Method:Pensky-Martens Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
1.18 [Ref Std:WATER=1]
Water solubility
Moderate
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
22,000 - 28 Pa-s
Density
1.18 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
11.00 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
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10.5 Incompatible materials
Strong acids. Strong bases.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Target Organ Effects:
Single exposure may cause:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg Solvent naphtha (petroleum), medium aliphatic
Dermal Rabbit LD50 > 3,000 mg/kg
Distillates (petroleum), hydrotreated middle
Dermal Rabbit LD50 > 2,000 mg/kg
Solvent naphtha (petroleum), medium aliphatic
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20 - 50 mg/l
Solvent naphtha (petroleum), Ingestion Rat LD50 > 5,000 mg/kg
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medium aliphatic Distillates (petroleum), hydrotreated middle
Inhalation-Dust/Mist (4 hours)
Rat LC50 4.6 mg/l
Distillates (petroleum), hydrotreated middle
Ingestion Rat LD50 > 5,000 mg/kg
Aluminium oxide Inhalation-Dust/Mist
(4 hours)
Rabbit LC50 > 1.9 mg/l
Aluminium oxide Ingestion Rat LD50 > 5,000 mg/kg Triethanolamine Dermal Rabbit LD50 > 2,000 mg/kg Triethanolamine Ingestion Rat LD50 9,000 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Solvent naphtha (petroleum), medium aliphatic Mild irritant Distillates (petroleum), hydrotreated middle Rabbit Minimal irritation Aluminium oxide No data available Triethanolamine Rabbit Minimal irritation Glycerin Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Solvent naphtha (petroleum), medium aliphatic Mild irritant Distillates (petroleum), hydrotreated middle Not available Mild irritant Aluminium oxide No data available Triethanolamine Rabbit Mild irritant Glycerin Rabbit No significant irritation
Skin Sensitisation
Name Species Value
Solvent naphtha (petroleum), medium aliphatic Not sensitizing Distillates (petroleum), hydrotreated middle No data available Aluminium oxide No data available Triethanolamine Human Some positive data exist, but the data are not
sufficient for classification
Glycerin Guinea pig Not sensitizing
Respiratory Sensitisation
Name Species Value
Solvent naphtha (petroleum), medium aliphatic No data available Distillates (petroleum), hydrotreated middle No data available Aluminium oxide No data available Triethanolamine No data available Glycerin No data available
Germ Cell Mutagenicity
Name Route Value
Solvent naphtha (petroleum), medium aliphatic Inhalation Not mutagenic Solvent naphtha (petroleum), medium aliphatic In Vitro Some positive data exist, but the data are not
sufficient for classification
Distillates (petroleum), hydrotreated middle In Vitro Some positive data exist, but the data are not
sufficient for classification Aluminium oxide In Vitro Not mutagenic Triethanolamine In Vitro Not mutagenic Triethanolamine In vivo Not mutagenic Glycerin No data available
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Carcinogenicity
Name Route Species Value
Solvent naphtha (petroleum), medium aliphatic
Dermal Some positive data exist, but the data
are not sufficient for classification Solvent naphtha (petroleum), medium aliphatic
Inhalation Some positive data exist, but the data
are not sufficient for classification Distillates (petroleum), hydrotreated middle
Dermal Mouse Some positive data exist, but the data
are not sufficient for classification Aluminium oxide Inhalation Not carcinogenic Triethanolamine Dermal Multiple animal
species
Not carcinogenic
Triethanolamine Ingestion Mouse Some positive data exist, but the data
are not sufficient for classification Glycerin Ingestion Mouse Some positive data exist, but the data
are not sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Solvent naphtha (petroleum), medium aliphatic
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Distillates (petroleum), hydrotreated middle
No data available
Aluminium oxide No data available Triethanolamine Ingestion Not toxic to
development
Mouse NOAEL
1,125 mg/kg/day
during organogenesis
Glycerin Ingestion Not toxic to female
reproduction
Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to male
reproduction
Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to
development
Rat NOAEL
2,000 mg/kg/day
2 generation
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Solvent naphtha (petroleum), medium aliphatic
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Distillates (petroleum), hydrotreated middle
Inhalation central nervous
system depression | respiratory irritation
Some positive data exist, but the data are not sufficient for classification
Not available NOAEL NA
Solvent naphtha (petroleum), medium aliphatic
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
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Solvent naphtha (petroleum), medium aliphatic
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation heart All data are
negative
NOAEL 2.5 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation liver | kidney
and/or bladder
All data are negative
NOAEL 0.610 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation muscles All data are
negative
NOAEL 0.61 mg/l
Distillates (petroleum), hydrotreated middle
Ingestion central nervous
system depression
May cause drowsiness or dizziness
Not available NOAEL NA
Aluminium oxide
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Triethanolami ne
No data available
Glycerin No data available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Solvent naphtha (petroleum), medium aliphatic
Dermal nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 691 mg/kg
Solvent naphtha (petroleum), medium aliphatic
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 4.580 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 0.619 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation endocrine
system | muscles
Some positive data exist, but the data are not sufficient for classification
LOEL 0.616 mg/l
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Solvent naphtha (petroleum), medium aliphatic
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
LOEL 0.57 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are negative
NOAEL 5.62 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation heart All data are
negative
NOAEL 1.271 mg/l
Solvent naphtha (petroleum), medium aliphatic
Inhalation immune system All data are
negative
NOAEL 0.616 mg/l
Distillates (petroleum), hydrotreated middle
No data available
Aluminium oxide
Inhalation pneumoconiosis May cause
damage to organs though prolonged or repeated exposure
NOAEL N/A
Aluminium oxide
Inhalation pulmonary
fibrosis
Some positive data exist, but the data are not sufficient for classification
NOAEL N/A
TriethanolamineDermal kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Multiple animal species
NOAEL 2,000 mg/kg/day
2 years
TriethanolamineDermal liver Some positive
data exist, but the data are not sufficient for classification
Mouse NOAEL 4,000
mg/kg/day
13 weeks
TriethanolamineIngestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 1,000
mg/kg/day
2 years
TriethanolamineIngestion liver Some positive
data exist, but the data are not sufficient for classification
Guinea pig NOAEL 1,600
mg/kg/day
24 weeks
Glycerin Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 3.91
mg/l
14 days
Glycerin Inhalation heart | liver |
kidney and/or
All data are negative
Rat NOAEL 3.91
mg/l
14 days
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bladder
Glycerin Ingestion endocrine
system | hematopoietic system | liver | kidney and/or bladder
All data are negative
Rat NOAEL 10,000
mg/kg/day
2 years
Aspiration Hazard
Name Value
Solvent naphtha (petroleum), medium aliphatic Aspiration hazard Distillates (petroleum), hydrotreated middle Aspiration hazard Aluminium oxide Not an aspiration hazard Triethanolamine Not an aspiration hazard Glycerin Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
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13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR: Not restricted for transport. IMDG: Not restricted for transport. IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Triethanolamine 102-71-6 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness.
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List of relevant R-phrases
R10 Flammable. R20 Harmful by inhalation. R65 Harmful: May cause lung damage if swallowed. R65 is not required on the label due to the product's viscosity.
R65 is not required on the label due to the product's viscosity.
R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Safety phrase was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 13: EU waste code (product as sold) information was modified. Section 9: Flammability (solid, gas) information was modified. Section 2: Label remarks was modified. Copyright was modified. Section 8: Occupational exposure limit table was modified. Section 11: Acute Toxicity table was modified. Section 5: Fire - Extinguishing media information was modified. Section 6: Accidental release clean-up information was modified. Section 7: Precautions safe handling information was modified. Section 7: Conditions safe storage was modified. Section 13: Standard Phrase Category Waste GHS was modified. Section 2: Indication of danger heading was added. Section 2: Indication of danger information was added. Section 9: Odour Threshold was added. Section 9: Solubility (non-water) was added. Section 09: Decomposition Temperature was added. Section 11: Single exposure may cause: heading was added. Section 11: Single exposure may cause standard phrases was added. Section 2: R phrase reference was added. Label: Graphic was added. Section 02: Graphic information was added. Section 9: Flammability (solid, gas) information was added. Section 2: Symbols heading was deleted. Section 15: Symbol information was deleted. Section 11: Health Effects - Other information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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