MEGUIAR'S G1016 User Manual

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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
30-2532-7
Version number:
3.00
Revision date:
11/08/2014
Supersedes date:
02/09/2013
Transportation version number: 1.00 (23/01/2012)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
G11, Smooth Surface Clay Bar: G11EU
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification, labelling, and packaging of substances and mixtures.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
Not applicable
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Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Not applicable
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Calcium Carbonate 471-34-1 EINECS 207-
439-9
40 - 60
Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene)
9003-29-6 NLP 500-004-7 20 - 40
NUC - Silica 7631-86-9 EINECS 231-
545-4
10 - 30
Talc 14807-96-6 EINECS 238-
877-9
10 30
Pigments Trade Secret < 5 Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
No need for first aid is anticipated.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Material will not burn. Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
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None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion.
5.3. Advice for fire-fighters
No special protective actions for fire-fighters are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
Store in a dry place.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Talc 14807-96-6 Health and
Safety Comm. (UK)
TWA(as respirable dust):1 mg/m³
Limestone 471-34-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m3;TWA(as respirable dust):4 mg/m3;TWA(Inhalable):10 mg/m3;TWA(respirable):4 mg/m3
Silicon dioxide 7631-86-9 Health and TWA(as inhalable dust):6
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Safety Comm. (UK)
mg/m3;TWA(as respirable dust):2.4 mg/m3
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Not applicable.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Solid.
Specific Physical Form:
Clay
Appearance/Odour
Typical odour; white
Odour threshold
No data available.
pH
Not applicable.
Boiling point/boiling range
Not applicable.
Melting point
No data available.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
No flash point
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
Not applicable.
Relative density
2 [Ref Std:WATER=1]
Water solubility
Nil
Solubility- non-water
No data available.
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Partition coefficient: n-octanol/water
No data available.
Evaporation rate
Not applicable.
Vapour density
Not applicable.
Decomposition temperature
No data available.
Viscosity
Not applicable.
Density
2 g/ml
9.2. Other information
Volatile organic compounds (VOC)
0 %
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from 3M assessments.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
No health effects are expected.
Skin contact
Prolonged or repeated exposure may cause:
Dermal Defatting: Signs/symptoms may include localised redness, itching, drying and cracking of skin.
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Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Calcium Carbonate Dermal Rat LD50 > 2,000 mg/kg Calcium Carbonate Inhalation-
Dust/Mist (4 hours)
Rat LC50 3.0 mg/l
Calcium Carbonate Ingestion Rat LD50 6,450 mg/kg Butene, homopolymer (products derived from either/or But-1­ene/But-2-ene)
Dermal Rat LD50 > 10,250 mg/kg
Butene, homopolymer (products derived from either/or But-1­ene/But-2-ene)
Ingestion Rat LD50 > 34,600 mg/kg
Talc Dermal LD50 Not available Talc Ingestion LD50 Not available NUC - Silica Dermal Rabbit LD50 > 5,000 mg/kg NUC - Silica Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 0.691 mg/l
NUC - Silica Ingestion Rat LD50 > 5,110 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Calcium Carbonate Rabbit No significant irritation Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) Rabbit Minimal irritation NUC - Silica Rabbit No significant irritation Talc Rabbit No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Calcium Carbonate Rabbit No significant irritation Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) Rabbit Mild irritant NUC - Silica Rabbit No significant irritation Talc Rabbit No significant irritation
Skin Sensitisation
Name Species Value
NUC - Silica Human
and animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Talc Human Not sensitizing
Germ Cell Mutagenicity
Name Route Value
NUC - Silica In Vitro Not mutagenic Talc In Vitro Not mutagenic Talc In vivo Not mutagenic
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Carcinogenicity
Name Route Species Value
NUC - Silica Not
specified.
Mouse Some positive data exist, but the data are not
sufficient for classification
Talc Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Calcium Carbonate Ingestion Not toxic to development Rat NOAEL 625
mg/kg/day
premating & during gestation
NUC - Silica Ingestion Not toxic to female reproduction Rat NOAEL 509
mg/kg/day
1 generation
NUC - Silica Ingestion Not toxic to male reproduction Rat NOAEL 497
mg/kg/day
1 generation
NUC - Silica Ingestion Not toxic to development Rat NOAEL
1,350 mg/kg/day
during organogenesis
Talc Ingestion Not toxic to development Rat NOAEL
1,600 mg/kg
during organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Calcium Carbonate Inhalation respiratory system All data are negative Rat NOAEL
0.812 mg/l
90 minutes
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Calcium Carbonate Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Human NOAEL Not
available
occupational exposure
Butene, homopolymer (products derived from either/or But-1-ene/But-2­ene)
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 0.07
mg/l
2 weeks
Butene, homopolymer (products derived from either/or But-1-ene/But-2­ene)
Inhalation liver Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 0.7
mg/l
2 weeks
Talc Inhalation pneumoconiosis Causes damage to organs through
prolonged or repeated exposure
Human NOAEL Not
available
occupational exposure
Talc Inhalation pulmonary fibrosis |
respiratory system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 18
mg/m3
113 weeks
NUC - Silica Inhalation respiratory system |
silicosis
All data are negative Human NOAEL Not
available
occupational exposure
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
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The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from 3M assessments.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Butene, homopolymer (products derived from either/or But-1­ene/But-2-ene)
9003-29-6 Data not
available or insufficient for classification
NUC - Silica 7631-86-9 Data not
available or insufficient for
classification Calcium Carbonate
471-34-1 Rainbow trout Experimental 21 days NOEC >100 mg/l
Calcium Carbonate
471-34-1 Western
Mosquitofish
Experimental 96 hours LC50 >100 mg/l
Talc 14807-96-6 Data not
available or
insufficient for
classification
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Butene, homopolymer (products derived from either/or But-1­ene/But-2-ene)
9003-29-6 Estimated
Biodegradation
28 days CO2 evolution <6.5 % weight OECD 301B -
Modified sturm or CO2
NUC - Silica 7631-86-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Calcium Carbonate
471-34-1 Data not
available or insufficient for classification
N/A N/A N/A N/A
Talc 14807-96-6 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Butene, 9003-29-6 Estimated Bioaccumulati <83 Estimated:
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homopolymer (products derived from either/or But-1­ene/But-2-ene)
Bioconcentrati on
on factor Bioconcentration factor
NUC - Silica 7631-86-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
Calcium Carbonate
471-34-1 Data not
available or insufficient for classification
N/A N/A N/A N/A
Talc 14807-96-6 Data not
available or insufficient for classification
N/A N/A N/A N/A
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility. If no other disposal options are available, waste product may be placed in a landfill properly designed for industrial waste.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
120199 Wastes not otherwise specified
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
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Ingredient CAS Nbr Classification Regulation
NUC - Silica 7631-86-9 Gr. 3: Not classifiable International Agency
for Research on Cancer
Talc 14807-96-6 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
Revision information:
Revision Changes: Section 15: Carcinogenicity information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 12: Component ecotoxicity information information was modified. Section 12: Persistence and Degradability information information was modified. Section 12:Bioccumulative potential information information was modified. Section 1: Address information was modified. Copyright information was modified. Section 8: Occupational exposure limit table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Section 11: Respiratory Sensitization Table information was modified. Section 11: Reproductive Toxicity Table information was modified. Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 11: Target Organs - Single Table information was modified. Section 5: Fire - Extinguishing media information information was modified. Section 5: Fire - Advice for fire fighters information information was modified. Section 8: Personal Protection - Eye information information was modified. Section 8: Personal Protection - Skin/hand information information was modified. Section 13: 13.1. Waste disposal note information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Not applicable information was added. Not applicable information was added.
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Section 11: Disclosed components not in tables text information was added. Section 12: Classification Warning information was added. Section 11: Classification disclaimer information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV information was added. Section 8: Eye/face protection text information was deleted. Section 8: Skin protection - protective clothing text information was deleted. Section 2: Contains heading information was deleted. Section 2: Safety phrases heading information was deleted. Section 2: Risk phrases heading information was deleted. Section 15: Symbol information information was deleted. Section 2: Label ingredient information information was deleted. Section 8: mg/m³ key information was deleted. Section 8: ppm key information was deleted. Section 11: Aspiration Hazard Table information was deleted. Section 11: Classification disclaimer information was deleted. Section 12: Classification Warning information was deleted. Risk phrase - None information was deleted. Label: Graphic information was deleted. Section 02: Graphic information information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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