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D300
User Manual
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MEGUIAR'S D300 User Manual

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Page 1
D300, DA Microfiber Correction Compound (21-49D): D30001, D30016, D30032
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-6680-4
Version number:
3.00
Revision date:
22/04/2014
Supersedes date:
31/07/2012
Transportation version number: 1.00 (29/06/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
D300, DA Microfiber Correction Compound (21-49D): D30001, D30016, D30032
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Specific Target Organ Toxicity-Repeated Exposure, Category 1 - STOT RE 1; H372
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Harmful; Xn; R48/20
For full text of R phrases, see Section 16.
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2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
DANGER!
Symbols:
GHS07 (Exclamation mark) | GHS08 (Health Hazard) |
Pictograms
Ingredient CAS Nbr % by Wt Solvent naphtha (petroleum), medium aliphatic 64742-88-7 7 - 13
HAZARD STATEMENTS:
H315 Causes skin irritation.
H372 Causes damage to organs through prolonged or repeated exposure: nervous system
PRECAUTIONARY STATEMENTS General:
P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children.
Prevention:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
Response:
P332 + P313 If skin irritation occurs: Get medical advice/attention.
Disposal:
P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
Contains 16% of components with unknown hazards to the aquatic environment.
Notes on labelling
H304 is not required on the label due to the product's viscosity
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
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Harmful
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
S23A Do not breathe vapour. S46 If swallowed, seek medical advice immediately and show this container or label. S2 Keep out of the reach of children.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 50 - 70 Aluminium Oxide 1344-28-1 EINECS 215-
691-6
10 - 30
Solvent naphtha (petroleum), medium aliphatic
64742-88-7 EINECS 265-
191-7
7 - 13 Xn:R48/20; Xn:R65 (EU)
Xi:R38; R10 (Self Classified)
Asp. Tox. 1, H304; STOT RE 1, H372 (CLP) Flam. Liq. 3, H226; Skin Irrit. 2, H315 (Self Classified)
White mineral oil (petroleum) 8042-47-5 EINECS 232-
455-8
5 - 10 Xn:R65 (Self Classified)
Asp. Tox. 1, H304 (Self
Classified) Conditioners None < 5 Siloxanes and silicones, di-Me 63148-62-9 1 - 5 Glycerin 56-81-5 EINECS 200-
289-5
1 - 5
Triethanolamine 102-71-6 EINECS 203-
049-8
0.5 - 1.5
PEG Stearate 9004-99-3 <= 0.5 N:R50 (Self Classified)
Aquatic Acute 1, H400,M=1;
Aquatic Chronic 3, H412 (Self
Classified) Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
55965-84-9 < 0.0015 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)
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Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons. During combustion. Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
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to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Vapours may travel long distances along the ground or floor to an ignition source and flash back.
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from strong bases. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Aluminium Oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable dust):4 mg/m³
Glycerin 56-81-5 Health and
Safety Comm. (UK)
TWA(as mist):10 mg/m3
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
8.2. Exposure controls
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8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile rubber.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Sweet odour; Red, creamy, viscous lotion
Odour threshold
No data available.
pH
8.2 - 8.8
Boiling point/boiling range
193.3 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
>= 93.3 ºC [Test Method:Pensky-Martens Closed Cup] [Details:D93-90]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
1.18 [Ref Std:WATER=1]
Water solubility
Moderate
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
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Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
28 Pa-s - 35 Pa-s
Density
1.18 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
11.00 % weight
VOC less H2O & exempt solvents
572.47 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
Strong acids. Strong bases. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.
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Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Aluminium Oxide Dermal LD50 estimated to be > 5,000 mg/kg Aluminium Oxide Inhalation-
Dust/Mist (4 hours)
Rat LC50 > 2.3 mg/l
Aluminium Oxide Ingestion Rat LD50 > 5,000 mg/kg Solvent naphtha (petroleum), medium aliphatic Inhalation-
Vapor
LC50 estimated to be 20 - 50 mg/l
Solvent naphtha (petroleum), medium aliphatic Dermal Rabbit LD50 > 3,000 mg/kg Solvent naphtha (petroleum), medium aliphatic Ingestion Rat LD50 > 5,000 mg/kg White mineral oil (petroleum) Dermal Rabbit LD50 > 2,000 mg/kg White mineral oil (petroleum) Ingestion Rat LD50 > 5,000 mg/kg Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg Triethanolamine Dermal Rabbit LD50 > 2,000 mg/kg Triethanolamine Ingestion Rat LD50 9,000 mg/kg Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Inhalation­Dust/Mist (4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Aluminium Oxide Rabbit No significant irritation Solvent naphtha (petroleum), medium aliphatic Rabbit Irritant White mineral oil (petroleum) Rabbit No significant irritation Siloxanes and silicones, di-Me Rabbit No significant irritation Glycerin Rabbit No significant irritation Triethanolamine Rabbit Minimal irritation Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Aluminium Oxide Rabbit No significant irritation Solvent naphtha (petroleum), medium aliphatic Rabbit No significant irritation White mineral oil (petroleum) Rabbit Mild irritant Siloxanes and silicones, di-Me Rabbit No significant irritation Glycerin Rabbit No significant irritation Triethanolamine Rabbit Mild irritant
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Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Solvent naphtha (petroleum), medium aliphatic Guinea
pig
Not sensitizing
White mineral oil (petroleum) Guinea
pig
Not sensitizing
Glycerin Guinea
pig
Not sensitizing
Triethanolamine Human Some positive data exist, but the data are not
sufficient for classification Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Sensitising
Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Aluminium Oxide In Vitro Not mutagenic Solvent naphtha (petroleum), medium aliphatic In vivo Not mutagenic Solvent naphtha (petroleum), medium aliphatic In Vitro Some positive data exist, but the data are not
sufficient for classification White mineral oil (petroleum) In Vitro Not mutagenic Triethanolamine In Vitro Not mutagenic Triethanolamine In vivo Not mutagenic Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Aluminium Oxide Inhalation Rat Not carcinogenic Solvent naphtha (petroleum), medium aliphatic Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Solvent naphtha (petroleum), medium aliphatic Inhalation Human
and animal
Some positive data exist, but the data are not sufficient for classification
White mineral oil (petroleum) Dermal Mouse Not carcinogenic White mineral oil (petroleum) Inhalation Multiple
animal species
Not carcinogenic
Glycerin Ingestion Mouse Some positive data exist, but the data are not
sufficient for classification
Triethanolamine Dermal Multiple
animal species
Not carcinogenic
Triethanolamine Ingestion Mouse Some positive data exist, but the data are not
sufficient for classification Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
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Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Solvent naphtha (petroleum), medium aliphatic
Inhalation Not toxic to development Rat NOAEL 2.4
mg/l
during
organogenesis
White mineral oil (petroleum) Ingestion Not toxic to female reproduction Rat NOAEL
4,350 mg/kg/day
13 weeks
White mineral oil (petroleum) Ingestion Not toxic to male reproduction Rat NOAEL
4,350 mg/kg/day
13 weeks
White mineral oil (petroleum) Ingestion Not toxic to development Rat NOAEL
4,350 mg/kg/day
during
gestation
Glycerin Ingestion Not toxic to female reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to male reproduction Rat NOAEL
2,000 mg/kg/day
2 generation
Glycerin Ingestion Not toxic to development Rat NOAEL
2,000 mg/kg/day
2 generation
Triethanolamine Ingestion Not toxic to development Mouse NOAEL
1,125 mg/kg/day
during
organogenesis
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Solvent naphtha (petroleum), medium aliphatic
Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human and animal
NOAEL Not available
Solvent naphtha (petroleum), medium aliphatic
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
NOAEL Not available
Solvent naphtha (petroleum), medium aliphatic
Inhalation nervous system Some positive data exist, but the
data are not sufficient for classification
Dog NOAEL 6.5
mg/l
4 hours
Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
similar health hazards
NOAEL Not available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Aluminium Oxide Inhalation pneumoconiosis |
pulmonary fibrosis
Some positive data exist, but the data are not sufficient for classification
Human NOAEL Not
available
occupational exposure
Solvent naphtha (petroleum), medium
Inhalation nervous system Some positive data exist, but the
data are not sufficient for
Rat LOAEL 4.6
mg/l
6 months
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aliphatic classification Solvent naphtha (petroleum), medium aliphatic
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 1.9
mg/l
13 weeks
Solvent naphtha (petroleum), medium aliphatic
Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Multiple animal species
NOAEL 0.6 mg/l
90 days
Solvent naphtha (petroleum), medium aliphatic
Inhalation bone, teeth, nails,
and/or hair | blood | liver | muscles
All data are negative Rat NOAEL 5.6
mg/l
12 weeks
Solvent naphtha (petroleum), medium aliphatic
Inhalation heart All data are negative Multiple
animal species
NOAEL 1.3 mg/l
90 days
White mineral oil (petroleum)
Ingestion hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
1,381 mg/kg/day
90 days
White mineral oil (petroleum)
Ingestion liver | immune
system
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL
1,336 mg/kg/day
90 days
Glycerin Inhalation respiratory system Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 3.91
mg/l
14 days
Glycerin Inhalation heart | liver | kidney
and/or bladder
All data are negative Rat NOAEL 3.91
mg/l
14 days
Glycerin Ingestion endocrine system |
hematopoietic system | liver | kidney and/or bladder
All data are negative Rat NOAEL
10,000 mg/kg/day
2 years
Triethanolamine Dermal kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Multiple animal species
NOAEL 2,000 mg/kg/day
2 years
Triethanolamine Dermal liver Some positive data exist, but the
data are not sufficient for classification
Mouse NOAEL
4,000 mg/kg/day
13 weeks
Triethanolamine Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL
1,000 mg/kg/day
2 years
Triethanolamine Ingestion liver Some positive data exist, but the
data are not sufficient for classification
Guinea pig
NOAEL 1,600 mg/kg/day
24 weeks
Aspiration Hazard
Name Value
Solvent naphtha (petroleum), medium aliphatic Aspiration hazard White mineral oil (petroleum) Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
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Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l
Glycerin 56-81-5 Water flea Experimental 24 hours EC50 >10,000 mg/l Glycerin 56-81-5 Goldfish Experimental 24 hours LC50 >5,000 mg/l Solvent naphtha (petroleum), medium aliphatic
64742-88-7 Data not
available or insufficient for classification
Aluminium Oxide
1344-28-1 Green algae Experimental 72 hours NOEC >100 mg/l
Aluminium Oxide
1344-28-1 Fish Experimental 96 hours LC50 >100 mg/l
Aluminium Oxide
1344-28-1 Green algae Experimental 72 hours EC50 >100 mg/l
Aluminium Oxide
1344-28-1 Water flea Experimental 48 hours EC50 >100 mg/l
PEG Stearate 9004-99-3 Green algae Estimated 72 hours NOEC 0.25 mg/l PEG Stearate 9004-99-3 Water flea Estimated 48 hours EC50 0.72 mg/l PEG Stearate 9004-99-3 Zebra Fish Estimated 96 hours LC50 0.65 mg/l PEG Stearate 9004-99-3 Green algae Estimated 72 hours EC50 0.64 mg/l Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
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Triethanolamine102-71-6 Water flea Experimental 21 days NOEC 16 mg/l
Triethanolamine102-71-6 Goldfish Experimental 24 hours LC50 5,000 mg/l
Triethanolamine102-71-6 Water flea Experimental 48 hours EC50 609.98 mg/l
Triethanolamine102-71-6 Green algae Experimental 72 hours EC50 216 mg/l
White mineral oil (petroleum)
8042-47-5 Water flea Experimental 21 days NOEC >100 mg/l
White mineral oil (petroleum)
8042-47-5 Bluegill Experimental 96 hours Lethal Level
50%
>100 mg/l
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
PEG Stearate 9004-99-3 Estimated
Biodegradation
28 days CO2 evolution 85.3 % weight OECD 301B -
Modified sturm or CO2
Glycerin 56-81-5 Experimental
Biodegradation
14 days BOD 63 % weight OECD 301C - MITI
test (I) Solvent naphtha (petroleum), medium aliphatic
64742-88-7 Data not
available or insufficient for classification
N/A N/A N/A N/A
Aluminium Oxide
1344-28-1 Data not
available or insufficient for classification
N/A N/A N/A N/A
White mineral oil (petroleum)
8042-47-5 Experimental
Biodegradation
28 days CO2 evolution 0 % weight OECD 301B -
Modified sturm or CO2 Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Experimental
Biodegradation
28 days CO2 evolution 48 % weight Other methods
Triethanolamine102-71-6 Experimental
Biodegradation
19 days Dissolv.
Organic Carbon Deplet
96 % weight 40CFR 796.3240-Mod.
OECD Scree
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and silicones, di­Me
63148-62-9 Data not
available or insufficient for classification
N/A N/A N/A N/A
PEG Stearate 9004-99-3 Estimated Bioaccumulati 5.5 Estimated:
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Bioconcentrati on
on factor Bioconcentration factor
Glycerin 56-81-5 Experimental
Bioconcentrati on
Log Kow -1.76 Other methods
Solvent naphtha (petroleum), medium aliphatic
64742-88-7 Data not
available or insufficient for classification
N/A N/A N/A N/A
Aluminium Oxide
1344-28-1 Data not
available or insufficient for classification
N/A N/A N/A N/A
White mineral oil (petroleum)
8042-47-5 Data not
available or insufficient for classification
N/A N/A N/A N/A
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Estimated
Bioconcentrati on
Log Kow 0.5 Other methods
Triethanolamine102-71-6 Experimental
Bioaccumulati on
Log Kow -2.3 Estimated: Octanol-
water partition
coefficient
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
Ingredient CAS Nbr PBT/vPvB status White mineral oil (petroleum) 8042-47-5 Meets REACH PBT criteria
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC -
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2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 13* Solvents
SECTION 14: Transportation information
ADR / IMDG / IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Triethanolamine 102-71-6 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H226 Flammable liquid and vapour. H301 Toxic if swallowed. H304 May be fatal if swallowed and enters airways. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects.
List of relevant R-phrases
R10 Flammable. R23 Toxic by inhalation.
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R24 Toxic in contact with skin. R25 Toxic if swallowed. R34 Causes burns. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. R65 Harmful: May cause lung damage if swallowed.
Revision information:
Revision Changes: Section 1: Product name information was modified. Section 8: Respiratory protection - recommended respirators information information was modified. Page Heading: Product name information was modified. Section 16: List of relevant R phrase information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 13: EU waste code (product as sold) information information was modified. Section 9: Flammability (solid, gas) information information was modified. Section 16: Regulations - Inventories - EU ONLY information was modified. Section 1: Address information was modified. Copyright information was modified. Section 8: Occupational exposure limit table information was modified. Section 11: Aspiration Hazard Table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Photosensitisation Table information was modified. Section 11: Reproductive Toxicity Table information was modified. Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 11: Target Organs - Single Table information was modified. Section 11: Health Effects - Skin information information was modified. Section 11: Health Effects - Inhalation information information was modified. Section 5: Fire - Extinguishing media information information was modified. Section 6: Accidental release environmental information information was modified. Section 6: Accidental release clean-up information information was modified. Section 7: Precautions safe handling information information was modified. Section 8: Personal Protection - Eye information information was modified. Section 8: Personal Protection - Skin/hand information information was modified. Section 8: Personal Protection - Respiratory Information information was modified. Section 13: 13.1. Waste disposal note information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Section 4: First aid for skin contact information information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Section 8: Skin protection - recommended gloves information information was added. Risk phrase information was added. Safety phrase information was added. Section 2: Indication of danger heading information was added. Section 8: Skin protection - recommended gloves text information was added. Section 2: Indication of danger information information was added. Section 12: Component ecotoxicity information information was added. Section 12: Persistence and Degradability information information was added.
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Section 12:Bioccumulative potential information information was added. Section 12: Component Ecotoxicity table Material column header information was added. Section 12: Component Ecotoxicity table CAS No column header information was added. Section 12: Component Ecotoxicity table Organism column header information was added. Section 12: Component Ecotoxicity table Type column header information was added. Section 12: Component Ecotoxicity table Exposure column header information was added. Section 12: Component Ecotoxicity table End point column header information was added. Section 12: Component Ecotoxicity table Result column header information was added. Section 12: Persistence and degradability table Material column header information was added. Section 12: Persistence and degradability table CAS No column header information was added. Section 12: Persistence and degradability table Test Type column header information was added. Section 12: Persistence and degradability table Duration column header information was added. Section 12: Persistence and degradability table Test Result column header information was added. Section 12: Persistence and degradability table Protocol column header information was added. Section 12:Bioccumulative potential table Material column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table Test Result column header information was added. Section 12:Bioccumulative potential table Protocol column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: CLP Percent Unknown information was added. Label: Graphic information was added. Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added. Label: CLP Precautionary - Disposal information was added. Label: CLP Precautionary - Disposal - Header information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: CLP Precautionary - Prevention information was added. Label: CLP Precautionary - Prevention - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: Precautionary Statement - Header information was added. CLP: Ingredient table information was added. Label: CLP Supplemental Hazard Statements - Header information was added. Label: CLP Supplemental Information - Header information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Section 2: Notes on labelling heading information was added. CLP Remark(phrase) information was added. Section 12: PBT/vPvB table CAS No. column heading information was added. Section 12: PBT/vPvB table CAS No. column heading information was added. Section 12: PBT/vPvB table PBT/vPvB Status column heading information was added. Section 12: PBT/vPvB table row information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Label: CLP Ingredients table Ingredient heading information was added. Label: CLP Ingredients table CAS No heading information was added. Label: CLP Ingredients table Percent by Wt heading information was added.
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Section 12: Persistence and degradability table Study Type column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Section 9: Odour Threshold information was added. Section 9: Solubility (non-water) information was added. Section 09: Decomposition Temperature information was added. Section 2: H phrase reference information was added. Section 10: Hazardous decomposition products during combustion text information was added. Label: CLP Target Organ Hazard Statement Heading information was added. Label: CLP Target Organ Hazard Statement information was added. Section 11: Disclosed components not in tables text information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV information was added. Section 2: R phrase reference information was added. Label: Graphic information was added. List of sensitizers information was added. Label: Graphic Text information was added. Section 9: Flammability (solid, gas) information information was added. Section 8: Eye/face protection text information was deleted. Section 8: Respiratory protection - recommended respirators information was deleted. Section 2: Contains heading information was deleted. Section 2: Safety phrases heading information was deleted. Section 2: Risk phrases heading information was deleted. Section 2: Symbols heading information was deleted. Section 15: Symbol information information was deleted. Section 15: Symbol information information was deleted. Section 2: Label ingredient information information was deleted. Section 12: Acute aquatic hazard information information was deleted. Section 12: Chronic aquatic hazard heading information was deleted. Section 12: Acute aquatic hazard heading information was deleted. Section 12: Chronic aquatic hazard information information was deleted. Section 2: Special provisions concerning the labelling of certain substances heading information was deleted. Section 2: Label remarks information was deleted. Prints No Data if Component ecotoxicity information is not present information was deleted. Prints No Data if Persistence and Degradability information is not present information was deleted. Prints No Data if Bioccumulative potential information is not present information was deleted. Section 2: Additional label requirements phrase information was deleted. Section 8: mg/m³ key information was deleted. Section 8: ppm key information was deleted. Section 11: Respiratory Sensitization Table information was deleted. Section 12: No PBT/vPvB information available warning information was deleted. Section 2.1: Classification information information was deleted. Risk phrase - None information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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