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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
Document group:
28-7579-7
Version number:
3.00
Revision date:
21/02/2014
Supersedes date:
13/09/2013
Transportation version number: 1.00 (17/08/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
G185, Leather Cleaner (24-01C): G18516
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319
Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Indication of danger
Irritant; Xi; R36/37/38
For full text of R phrases, see Section 16.
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2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
WARNING!
Symbols:
GHS07 (Exclamation mark) |
Pictograms
HAZARD STATEMENTS:
H319 Causes serious eye irritation.
H315 Causes skin irritation.
PRECAUTIONARY STATEMENTS
General:
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P332 + P313 If skin irritation occurs: Get medical advice/attention.
Notes on labelling
Ingredients required per 648/2004: <5%: Anionic surfactant. Contains: Perfumes, hexyl cinnam-aldehyde.
Test data showed no corrosivity, so H314 not applied.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
Irritant
Contains:
No ingredients are assigned to the label.
Risk phrases
R36/37/38 Irritating to eyes, respiratory system and skin.
Safety phrases
S23C Do not breathe vapour or spray.
S51 Use only in well ventilated areas.
S46 If swallowed, seek medical advice immediately and show this container or label.
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S2 Keep out of the reach of children.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: <5%: Anionic surfactant. Contains: Perfumes, hexyl cinnam-aldehyde.
Test data showed no corrosivity, so R35 not assigned.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 89 - 99
2-(Propyloxy)ethanol 2807-30-9 EINECS 220-
548-6
0.1 - 1.0 Xn:R21; Xi:R36 (EU)
Acute Tox. 4, H312; Eye Irrit. 2,
H319 (CLP)
Sodium Metasilicate 6834-92-0 EINECS 229-
912-9
0.1 - 1.0 C:R34; Xi:R37 (EU)
Skin Corr. 1B, H314; STOT SE
3, H335 (CLP)
Met. Corr. 1, H290 (Self
Classified)
Sulphonic acids, C14-16-alkane hydroxy
and C14-16-alkene, sodium salts
68439-57-6 EINECS 270-
407-8
0.1 - 1.0 Xn:R22; Xi:R41; R52 (Self
Classified)
Acute Tox. 4, H302; Eye Dam.
1, H318; Aquatic Chronic 3,
H412 (Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
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See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Material will not burn. Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and
health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the
container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on
clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising
agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.
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SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure
assessment. The following eye/face protection(s) are recommended:
Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl rubber.
Respiratory protection
Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment.
Consult with your respirator manufacturer for selection of appropriate types of respirators.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet odour; Clear liquid
Odour threshold
No data available.
pH
11.5 - 12.4
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Not applicable.
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.0 [Ref Std:WATER=1] [Details:approximately]
Water solubility
Complete
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Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.35 %
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
Strong acids.
Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
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Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Sodium Metasilicate Dermal Rabbit LD50 > 4,640 mg/kg
Sodium Metasilicate Ingestion Rat LD50 500 mg/kg
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene,
sodium salts
Dermal Rat LD50 > 2,000 mg/kg
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene,
sodium salts
Ingestion Rat LD50 578 mg/kg
2-(Propyloxy)ethanol Dermal Rabbit LD50 1,337 mg/kg
2-(Propyloxy)ethanol Inhalation-
Vapor (4
hours)
Rat LC50 > 11.1 mg/l
2-(Propyloxy)ethanol Ingestion Rat LD50 3,089 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Sodium Metasilicate Rabbit Corrosive
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts Rabbit Mild irritant
Serious Eye Damage/Irritation
Name Species Value
Sodium Metasilicate Rabbit Corrosive
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts Rabbit Corrosive
Skin Sensitisation
Name Species Value
Sodium Metasilicate Mouse Not sensitizing
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts Guinea
pig
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Sodium Metasilicate In Vitro Not mutagenic
Sodium Metasilicate In vivo Not mutagenic
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts In Vitro Not mutagenic
Carcinogenicity
Name Route Species Value
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene,
sodium salts
Dermal Rat Not carcinogenic
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene,
sodium salts
Ingestion Rat Not carcinogenic
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Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Sodium Metasilicate Ingestion Some positive developmental data exist,
but the data are not sufficient for
classification
Mouse NOAEL 200
mg/kg/day
during
gestation
Sulphonic acids, C14-16-alkane hydroxy
and C14-16-alkene, sodium salts
Ingestion Not toxic to female reproduction Rat NOAEL 871
mg/kg
2 generation
Sulphonic acids, C14-16-alkane hydroxy
and C14-16-alkene, sodium salts
Ingestion Not toxic to male reproduction Rat NOAEL 891
mg/kg
2 generation
Sulphonic acids, C14-16-alkane hydroxy
and C14-16-alkene, sodium salts
Ingestion Some positive developmental data exist,
but the data are not sufficient for
classification
Rabbit NOAEL 600
mg/kg
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Sodium Metasilicate Inhalation respiratory irritation May cause respiratory irritation official
classifica
tion
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Sodium Metasilicate Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Dog LOAEL
2,400
mg/kg/day
4 weeks
Sodium Metasilicate Ingestion endocrine system Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 804
mg/kg/day
3 months
Sulphonic acids, C14-16alkane hydroxy and C1416-alkene, sodium salts
Ingestion liver Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 500
mg/kg/day
6 months
Sulphonic acids, C14-16alkane hydroxy and C1416-alkene, sodium salts
Ingestion kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 500
mg/kg
6 months
Sodium Metasilicate Ingestion blood All data are negative Rat NOAEL 804
mg/kg/day
3 months
Sodium Metasilicate Ingestion heart | liver All data are negative Rat NOAEL
1,259
mg/kg/day
8 weeks
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.
12.1. Toxicity
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No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
2(Propyloxy)eth
anol
2807-30-9 Green Algae Estimated 72 hours NOEC 130 mg/l
2(Propyloxy)eth
anol
2807-30-9 Crustacea Estimated 96 hours EC50 89.4 mg/l
2(Propyloxy)eth
anol
2807-30-9 Green Algae Estimated 72 hours EC50 >1,000 mg/l
2(Propyloxy)eth
anol
2807-30-9 Rainbow trout Estimated 96 hours LC50 1,474 mg/l
2(Propyloxy)eth
anol
2807-30-9 Water flea Estimated 48 hours EC50 1,550 mg/l
2(Propyloxy)eth
anol
2807-30-9 Water flea Estimated 21 days NOEC 100 mg/l
Sodium
Metasilicate
6834-92-0 Rainbow trout Estimated 96 hours LC50 281 mg/l
Sodium
Metasilicate
6834-92-0 Water flea Estimated 48 hours EC50 1,700 mg/l
Sulphonic
acids, C14-16alkane hydroxy
and C14-16alkene, sodium
salts
68439-57-6 Data not
available or
insufficient for
classification
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Sulphonic
acids, C14-16alkane hydroxy
and C14-16alkene, sodium
salts
68439-57-6 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
2(Propyloxy)eth
anol
2807-30-9 Experimental
Biodegradation
20 days BOD 100 % weight Other methods
Sodium
Metasilicate
6834-92-0 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Sodium
Metasilicate
6834-92-0 Data not
available or
N/A N/A N/A N/A
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insufficient for
classification
Sulphonic
acids, C14-16alkane hydroxy
and C14-16alkene, sodium
salts
68439-57-6 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
2(Propyloxy)eth
anol
2807-30-9 Estimated
Bioconcentrati
on
Log Kow 0.08 Estimated: Octanol-
water partition
coefficient
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and
handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable
regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable
waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal
facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC 2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR / IMDG / IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on
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Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for
additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical
Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this
material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment
Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components
of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may
apply. Contact the selling division for additional information. The components of this material are in compliance with the
provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional
information. The components of this product are in compliance with the new substance notification requirements of CEPA.
The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.
List of relevant R-phrases
R21 Harmful in contact with skin.
R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.
R41 Risk of serious damage to eyes.
R52 Harmful to aquatic organisms.
Revision information:
Revision Changes:
Section 16: List of relevant R phrase information information was modified.
Section 3: Composition/ Information of ingredients table information was modified.
Section 9: Relative density information information was modified.
Section 12: Persistence and Degradability information information was modified.
Copyright information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.
Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 5: Fire - Extinguishing media information information was modified.
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Section 8: Personal Protection - Eye information information was modified.
Section 13: 13.1. Waste disposal note information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. information was modified.
Label: Signal Word - Header information was added.
Label: Signal Word information was added.
Label: CLP Classification - Header information was added.
Label: CLP Classification information was added.
Label: CLP Classification information was added.
Label: CLP Classification - Header information was added.
Label: Graphic information was added.
Label: Graphic information was added.
Label: Symbol information was added.
Label: Symbol information was added.
Label: CLP Precautionary - General information was added.
Label: CLP Precautionary - General - Header information was added.
Label: CLP Precautionary - Response information was added.
Label: CLP Precautionary - Response - Header information was added.
Label: Precautionary Statement - Header information was added.
Section 2: Notes on labelling heading information was added.
Section 15: Label remarks and EU Detergent information was added.
Section 2: 2.2 & 2.3. CLP REGULATION heading information was added.
Section 8: Personal Protection - Skin/hand information information was added.
Section 2: H phrase reference information was added.
Section 11: Disclosed components not in tables text information was added.
Section 8: Eye/face protection text information was deleted.
Section 8: Skin protection - protective clothing text information was deleted.
Section 11: Aspiration Hazard Table information was deleted.
Section 11: Respiratory Sensitization Table information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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