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D156
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MEGUIAR'S D156 User Manual

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D156, Express Spray Wax (DX-93B)
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
28-4535-2
Version number:
3.00
Revision date:
01/05/2014
Supersedes date:
01/05/2014
Transportation version number: 1.00 (29/06/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
D156, Express Spray Wax (DX-93B)
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification, labelling, and packaging of substances and mixtures.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
Not applicable
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SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Not applicable
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 79 - 99 Conditioners Trade Secret < 5 Triethoxyoctylsilane 2943-75-1 EINECS 220-
941-2
<= 0.2
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox. 3, H311; Acute Tox. 3, H301; Skin Corr. 1B, H314; Skin Sens. 1A, H317; Aquatic Acute 1, H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP) Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you are concerned, get medical advice.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
If swallowed
No need for first aid is anticipated.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
D156, Express Spray Wax (DX-93B)
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4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Non-combustible. Use a fire fighting agent suitable for surrounding fire.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
Biological limit values
No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.
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8.2. Exposure controls
8.2.1. Engineering controls
Not applicable.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Eye protection not required.
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Moderately sweet odour; Light, milky liquid
Odour threshold
No data available.
pH
6.95 - 7.85
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Not applicable.
Flash point
Flash point > 93 °C (200 °F)
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Complete
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.0 % weight
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SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
Carbon monoxide. Not specified. Carbon dioxide. Not specified. Irritant vapours or gases. Not specified.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
No health effects are expected.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
No health effects are expected.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
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Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Inhalation­Dust/Mist (4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Sensitising
Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
Human and animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H-
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
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isothiazol-3-one Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
similar health hazards
NOAEL Not available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l
Mixture of 5- 55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l
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chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l
Triethoxyoctyl silane
2943-75-1 Data not
available or insufficient for classification
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Triethoxyoctyl silane
2943-75-1 Estimated
Hydrolysis
Hydrolytic half-life
28-
504 minutes
(t 1/2)
Other methods
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Experimental
Biodegradation
28 days CO2 evolution 48 % weight Other methods
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Triethoxyoctyl silane
2943-75-1 Estimated
Bioconcentrati on
Log Kow 4.24 Estimated: Octanol-
water partition
coefficient Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one
55965-84-9 Estimated
Bioconcentrati on
Log Kow 0.5 Other methods
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
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12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
This product has been classified as a non-hazardous waste. Prior to disposal, consult all applicable authorities and regulations to insure proper classification. Dispose of waste product in a permitted industrial waste facility. Empty and clean product containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to determine available options and requirements.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 30 Detergents other than those mentioned in 20 01 29.
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H301 Toxic if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects.
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List of relevant R-phrases
R23 Toxic by inhalation. R24 Toxic in contact with skin. R25 Toxic if swallowed. R34 Causes burns. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Revision information:
Revision Changes: Section 3: Composition/ Information of ingredients table information was modified. Section 12: Component ecotoxicity information information was modified. Section 12: Persistence and Degradability information information was modified. Section 12:Bioccumulative potential information information was modified. Section 8: Eye/face protection information information was deleted. Section 8: Eye/face protection text information was deleted. Section 2: Contains heading information was deleted. Section 2: Safety phrases heading information was deleted. Section 16: List of relevant R-phrases information was added. Section 16: List of relevant R phrase information information was added. Section 3: Composition/ Information of ingredients table information was modified. Section 2: Risk phrases heading information was deleted. Section 2: Symbols heading information was deleted. Section 15: Symbol information information was deleted. Section 15: Symbol information information was deleted. Section 2: Label ingredient information information was deleted. Section 12: Acute aquatic hazard information information was deleted. Section 12: Chronic aquatic hazard heading information was deleted. Section 12: Acute aquatic hazard heading information was deleted. Section 12: Chronic aquatic hazard information information was deleted. Section 12: Component ecotoxicity information information was added. Section 12: Persistence and Degradability information information was added. Section 12:Bioccumulative potential information information was added. Section 9: Flammability (solid, gas) information information was modified. Section 12: Component Ecotoxicity table Material column header information was added. Section 12: Component Ecotoxicity table CAS No column header information was added. Section 12: Component Ecotoxicity table Organism column header information was added. Section 12: Component Ecotoxicity table Type column header information was added. Section 12: Component Ecotoxicity table Exposure column header information was added. Section 12: Component Ecotoxicity table End point column header information was added. Section 12: Component Ecotoxicity table Result column header information was added. Section 12: Persistence and degradability table Material column header information was added. Section 12: Persistence and degradability table CAS No column header information was added. Section 12: Persistence and degradability table Test Type column header information was added. Section 12: Persistence and degradability table Duration column header information was added. Section 12: Persistence and degradability table Test Result column header information was added. Section 12: Persistence and degradability table Protocol column header information was added. Section 12:Bioccumulative potential table Material column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table CAS No column header information was added. Section 12:Bioccumulative potential table Test Result column header information was added. Section 12:Bioccumulative potential table Protocol column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Section 16: Regulations - Inventories - EU ONLY information was modified. Section 1: Address information was modified. Copyright information was modified.
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Section 9: Flash point information information was modified. Prints No Data if Component ecotoxicity information is not present information was deleted. Prints No Data if Persistence and Degradability information is not present information was deleted. Prints No Data if Bioccumulative potential information is not present information was deleted. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Supplemental Hazard Statements - Header information was added. Label: CLP Supplemental Information - Header information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Contains statement for sensitizers information was added. Section 11: Aspiration Hazard Table information was deleted. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Section 11: Respiratory Sensitization Table information was deleted. Section 11: Photosensitisation table - Name heading information was added. Section 11: Photosensitisation table heading information was added. Photosensitisation Table information was added. Section 11: Reproductive Toxicity Table information was modified. Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Photosensitisation table - Species heading information was added. Section 11: Target Organs - Repeated Table information was deleted. Section 11: Target Organs - Single Table information was modified. Section 11: UN GHS Classification table heading information was deleted. Section 11: Photosensitisation table - Value heading information was added. Section 11: Health Effects - Eye information information was modified. Section 11: Health Effects - Inhalation information information was modified. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Section 5: Fire - Extinguishing media information information was modified. Section 6: Accidental release personal information information was modified. Section 6: Accidental release clean-up information information was modified. Section 7: Precautions safe handling information information was modified. Section 8: Personal Protection - Eye information information was added. Section 8: Personal Protection - Skin/hand information information was modified. Section 10: Hazardous decomposition or by-products table information was modified. Section 13: 13.1. Waste disposal note information was modified. Section 13: Standard Phrase Category Waste GHS information was modified. Section 4: First aid for inhalation information information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was added. Section 16: List of relevant H statements heading information was added. Section 12: Persistence and degradability table Study Type column header information was added. Section 12:Bioccumulative potential table Test Type column header information was added. Risk phrase - None information was deleted. Section 9: Odour Threshold information was added. Section 9: Solubility (non-water) information was added. Section 09: Decomposition Temperature information was added. Not applicable information was added. Not applicable information was added. Section 11: Disclosed components not in tables text information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV information was added. List of sensitizers information was added.
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Section 9: Flammability (solid, gas) information information was added.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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