MEGUIAR'S D151 User Manual

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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
26-6704-6
Version number:
1.02
Revision date:
20/04/2012
Supersedes date:
28/11/2011
Transportation version number: 1.00 (26/09/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
D151, Paint Reconditioning Cream (20-147D): D15101
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
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No ingredients are assigned to the label.
Risk phrases None. Safety phrases
S23A Do not breathe vapour. S24 Avoid contact with skin. S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
Notes on labelling
R65 is not required on the label due to the product's viscosity.
Nota P applied to CASRN 64742-48-9. Nota N applied to CASRN 64742-46-7.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non hazardous ingredient Mixture 50 - 70 Naphtha (petroleum), hydrotreated heavy 64742-48-9 EINECS 265-
150-3
10 - 30 Xn:R65 - Nota 4,P (EU)
R66; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P (CLP) STOT SE 3, H336; EUH066
(Self Classified) Aluminium oxide (REACH Reg. No.:01­2119529248-35)
1344-28-1 EINECS 215-
691-6
3 - 7
Distillates (petroleum), hydrotreated middle 64742-46-7 EINECS 265-
148-2
1 - 5 Nota N (EU)
Xn:R20-65; R66 (Self
Classified)
Nota N (CLP)
Acute Tox. 4, H332; Asp. Tox.
1, H304; STOT SE 3, H336;
EUH066 (Self Classified) Siloxanes and silicones, di-Me 63148-62-9 1 - 5 Ceramic materials and wares, chemicals 66402-68-4 EINECS 266-
340-9
1 - 5
Conditioners Trade Secret 0.5 - 1.5 Quartz 14808-60-7 EINECS 238-
878-4
<= 0.04 Xn:R48/20 (Vendor)
STOT RE 1, H372 (Self
Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
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Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Formaldehyde During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation by appropriate authorities.
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Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not get in eyes, on skin, or on clothing. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not use in a confined area or areas with little or no air movement. Use personal protective equipment (eg. gloves, respirators…) as required. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from heat. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Aluminium oxide 1344-28-1 Health and
Safety Comm. (UK)
TWA(as inhalable dust):10 mg/m³;TWA(as respirable
dust):4 mg/m³ Silica, crystalline (airborne particles of respirable size)
14808-60-7 Health and
Safety Comm. (UK)
TWA(respirable):0.1 mg/m3
Naphtha (petroleum), hydrotreated heavy
64742-48-9 Manufacturer
determined
TWA:100 ppm
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
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Gloves made from the following material(s) are recommended: Polymer laminate
Respiratory protection
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Sweet odour; Pink, viscous lotion
pH
8 - 8.8
Boiling point/boiling range
193.3 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
93.3 ºC [Test Method:Pensky-Martens Closed Cup] [Details:D93-90]
Autoignition temperature
No data available.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
0.98 [Ref Std:WATER=1]
Water solubility
Moderate
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
40 - 50 Pa-s
Density
0.98 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
14.54 % weight
VOC less H2O & exempt solvents
463.89 g/l
SECTION 10: Stability and reactivity
10.1 Reactivity
This material is considered to be non reactive under normal use conditions
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
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Heat.
10.5 Incompatible materials
Strong acids. Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Dust created by cutting, grinding, sanding, or machining may cause eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin contact
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation
Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain. May cause target organ effects after inhalation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Target Organ Effects:
Prolonged or repeated exposure may cause:
Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg
Naphtha (petroleum), hydrotreated Dermal Rabbit LD50 > 3,000 mg/kg
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heavy Naphtha (petroleum), hydrotreated heavy
Inhalation-Vapor (4 hours)
Rat LC50 estimated to be 20 - 50 mg/l
Naphtha (petroleum), hydrotreated heavy
Ingestion Rat LD50 > 5,000 mg/kg
Aluminium oxide Inhalation-Dust/Mist
(4 hours)
Rabbit LC50 > 1.9 mg/l
Aluminium oxide Ingestion Rat LD50 > 5,000 mg/kg Siloxanes and silicones, di-Me Dermal LD50 > 2,000 mg/kg Siloxanes and silicones, di-Me Ingestion LD50 > 17,000 mg/kg Ceramic materials and wares, chemicals
Dermal LD50 estimated to be > 5,000 mg/kg
Ceramic materials and wares, chemicals
Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg
Distillates (petroleum), hydrotreated middle
No data available
Conditioners Ingestion LD50 estimated to be > 5,000 mg/kg Quartz Ingestion LD50 estimated to be > 5,000 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Mild irritant Aluminium oxide No data available Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals No data available Distillates (petroleum), hydrotreated middle No data available Conditioners Minimal irritation Quartz No significant irritation
Serious Eye Damage/Irritation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Mild irritant Aluminium oxide No data available Siloxanes and silicones, di-Me Mild irritant Ceramic materials and wares, chemicals No data available Distillates (petroleum), hydrotreated middle No data available Conditioners Mild irritant Quartz No data available
Skin Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy Not sensitizing Aluminium oxide No data available Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals No data available Distillates (petroleum), hydrotreated middle No data available Conditioners Some positive data exist, but the data are not
sufficient for classification
Quartz No data available
Respiratory Sensitisation
Name Species Value
Naphtha (petroleum), hydrotreated heavy No data available Aluminium oxide No data available Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals No data available Distillates (petroleum), hydrotreated middle No data available Conditioners No data available
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Quartz No data available
Germ Cell Mutagenicity
Name Route Value
Naphtha (petroleum), hydrotreated heavy Inhalation Not mutagenic Naphtha (petroleum), hydrotreated heavy In Vitro Some positive data exist, but the data are not
sufficient for classification Aluminium oxide In Vitro Not mutagenic Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals In Vitro Some positive data exist, but the data are not
sufficient for classification Distillates (petroleum), hydrotreated middle No data available Conditioners In Vitro Not mutagenic Conditioners In vivo Not mutagenic Quartz In vivo Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Naphtha (petroleum), hydrotreated heavy
Dermal Some positive data exist, but the data
are not sufficient for classification Naphtha (petroleum), hydrotreated heavy
Inhalation Some positive data exist, but the data
are not sufficient for classification Aluminium oxide Inhalation Not carcinogenic Siloxanes and silicones, di-Me No data available Ceramic materials and wares, chemicals
Inhalation Carcinogenic.
Distillates (petroleum), hydrotreated middle
No data available
Conditioners No data available Quartz Inhalation Carcinogenic.
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation Not toxic to
reproduction and/or development
NOAEL
2.356 mg/l
Aluminium oxide No data available Siloxanes and silicones, di-Me
No data available
Ceramic materials and wares, chemicals
No data available
Distillates (petroleum), hydrotreated middle
No data available
Conditioners Ingestion Some positive
reproductive/develop mental data exist, but the data are not sufficient for classification
NOEL 248 mg/kg/day
Quartz No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Value Species Test result Exposure
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Organ(s) Duration
Naphtha (petroleum), hydrotreated heavy
Inhalation central nervous
system depression
May cause drowsiness or dizziness
NOAEL N/A
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
NOEL 6.5 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 2.4 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 2.5 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation liver All data are
negative
NOAEL 0.610 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation muscles All data are
negative
NOAEL 0.61 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
All data are negative
NOAEL 0.610 mg/l
Aluminium oxide
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Siloxanes and silicones, di­Me
No data available
Ceramic materials and wares, chemicals
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Distillates (petroleum), hydrotreated middle
No data available
Conditioners No data available Quartz Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
Irritation Positive
Specific Target Organ Toxicity - repeated exposure
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Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Naphtha (petroleum), hydrotreated heavy
Dermal nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 691 mg/kg
Naphtha (petroleum), hydrotreated heavy
Inhalation endocrine
system | muscles
Some positive data exist, but the data are not sufficient for classification
LOEL 0.616 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation nervous system Some positive
data exist, but the data are not sufficient for classification
LOEL 4.580 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
LOEL 0.57 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL 0.619 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation heart All data are
negative
NOAEL 1.271 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation bone, teeth,
nails, and/or hair | blood | liver
All data are negative
NOAEL 5.62 mg/l
Naphtha (petroleum), hydrotreated heavy
Inhalation immune system All data are
negative
NOAEL 0.616 mg/l
Aluminium oxide
Inhalation pneumoconiosis May cause
damage to organs though prolonged or repeated exposure
NOAEL N/A
Aluminium oxide
Inhalation pulmonary
fibrosis
Some positive data exist, but the data are not sufficient for classification
NOAEL N/A
Ceramic materials and wares, chemicals
Inhalation pulmonary
fibrosis
May cause damage to organs though prolonged or repeated exposure
NOAEL N/A
Ceramic materials and wares, chemicals
Inhalation respiratory
system
Some positive data exist, but the data are not sufficient for classification
NOEL N/A
Distillates (petroleum),
No data available
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hydrotreated middle Conditioners Ingestion heart Some positive
data exist, but the data are not sufficient for classification
LOEL 248 mg/kg/day
Conditioners Ingestion hematopoietic
system
Some positive data exist, but the data are not sufficient for classification
LOEL 300 mg/kg/day
Conditioners Ingestion liver Some positive
data exist, but the data are not sufficient for classification
NOEL 2,000 mg/kg/day
Conditioners Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
NOEL 3,000 mg/kg/day
Quartz Inhalation silicosis Causes damage to
organs through prolonged or repeated exposure
NOAEL N/A
Aspiration Hazard
Name Value
Naphtha (petroleum), hydrotreated heavy Aspiration hazard Aluminium oxide Not an aspiration hazard Siloxanes and silicones, di-Me Not an aspiration hazard Ceramic materials and wares, chemicals Not an aspiration hazard Distillates (petroleum), hydrotreated middle Not an aspiration hazard Conditioners Not an aspiration hazard Quartz Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
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12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances 20 01 27* Paint, inks, adhesives and resins containing dangerous substances
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
Quartz 14808-60-7 Grp. 1: Carcinogenic to
humans
International Agency for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
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List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking. H304 May be fatal if swallowed and enters airways. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H372 Causes damage to organs through prolonged or repeated exposure.
List of relevant R-phrases
R20 Harmful by inhalation. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R65 Harmful: May cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Section 2: Label remarks was modified. Copyright was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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