MEGUIAR'S D120 User Manual

D120, Glass Cleaner Concentrate (22-134A): D12001, D12005, D12025
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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
26-8367-0
Version number:
4.00
Revision date:
06/05/2014
Supersedes date:
25/07/2013
Transportation version number: 1.00 (20/09/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
D120, Glass Cleaner Concentrate (22-134A): D12001, D12005, D12025
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
Flammable Liquid, Category 3 - Flam. Liq. 3; H226 Acute Toxicity, Category 4 - Acute Tox. 4; H332 Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315
For full text of H phrases, see Section 16.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Flammable; R10
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Irritant; Xi; R36 R67
For full text of R phrases, see Section 16.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
SIGNAL WORD
WARNING!
Symbols:
GHS02 (Flame) |GHS07 (Exclamation mark) |
Pictograms
Ingredient CAS Nbr % by Wt 2-Butoxyethanol 111-76-2 10 - 30
HAZARD STATEMENTS:
H226 Flammable liquid and vapour. H332 Harmful if inhaled. H319 Causes serious eye irritation. H315 Causes skin irritation.
PRECAUTIONARY STATEMENTS General:
P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand.
Prevention:
P210A Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P271 Use only outdoors or in a well-ventilated area.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. P332 + P313 If skin irritation occurs: Get medical advice/attention. P370 + P378G In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry
chemical or carbon dioxide to extinguish.
Disposal:
P501 Dispose of contents/container in accordance with applicable local/regional/national/international
regulations.
Notes on labelling
Updated per Regulation (EC) No. 648/2004 on detergents. Ingredients required per 648/2004 (not required on industrial label): <5%: Anionic surfactant. Contains: Perfumes, d­Limonene.
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Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
Irritant
Contains:
No ingredients are assigned to the label.
Risk phrases
R10 Flammable. R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness.
Safety phrases
S23C Do not breathe vapour or spray. S51 Use only in well ventilated areas. S46 If swallowed, seek medical advice immediately and show this container or label. S2 Keep out of the reach of children.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents. Ingredients required per 648/2004 (not required on industrial label): <5%: Anionic surfactant. Contains: Perfumes, d­Limonene.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 40 - 70 2-Butoxyethanol 111-76-2 EINECS 203-
905-0
10 - 30 Xn:R20-21-22; Xi:R36-38 (EU)
R52 (Self Classified)
Acute Tox. 3, H331; Acute Tox. 3, H311; Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2, H319 (CLP)
Propan-2-ol 67-63-0 EINECS 200-
661-7
10 - 30 F:R11; Xi:R36; R67 (EU)
Flam. Liq. 2, H225; Eye Irrit. 2,
H319; STOT SE 3, H336 (CLP) Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
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4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids and solids such as dry chemical or carbon dioxide to extinguish.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
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Contain spill. Cover spill area with a fire-extinguishing foam designed for use on solvents, such as alcohols and acetone, that can dissolve in water. An AR-AFFF type foam is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
2-Butoxyethanol 111-76-2 Health and
Safety Comm. (UK)
TWA:123 mg/m3(25 ppm);STEL:246 mg/m3(50 ppm)
Skin Notation
Propan-2-ol 67-63-0 Health and
Safety Comm. (UK)
TWA:999 mg/m³(400 ppm);STEL:1250 mg/m³(500 ppm)
Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling
Biological limit values
Ingredient CAS
Nbr
Agency Determinant Biological
Specimen
Sampling Time
Value Additional
comments
2-Butoxyethanol 111-76-2UK EH40
BMGVs
Butoxyacetic acid
Creatinine in urine
EOS 240 mmol/mol
UK EH40 BMGVs : UK. EH40 Biological Monitoring Guidance Values (BMGVs) EOS: End of shift.
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8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect vented goggles.
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl rubber. Fluoroelastomer
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet chemical odour; Dark blue liquid
Odour threshold
No data available.
pH
7.2 - 7.8
Boiling point/boiling range
82.2 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
29.4 ºC [Test Method:Pensky-Martens Closed Cup]
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
0.77 [Ref Std:WATER=1]
Water solubility
Complete
Solubility- non-water
No data available.
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Partition coefficient: n-octanol/water
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
0.77 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
32.4 % weight
VOC less H2O & exempt solvents
No data available.
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Sparks and/or flames. Heat.
10.5 Incompatible materials
Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
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Harmful if inhaled. Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation.
Skin contact
May be harmful in contact with skin. Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision.
Ingestion
May be harmful if swallowed. Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion.
Target Organ Effects:
Single exposure may cause:
Central nervous system (CNS) depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure may cause:
Blood effects: Signs/symptoms may include generalised weakness and fatigue, skin pallor, changes in blood clotting time, internal bleeding, and hemoglobinemia.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE2,000 - 5,000
mg/kg
Overall product Inhalation-
Vapor(4 hr)
No data available; calculated ATE10 - 20 mg/l
Overall product Ingestion No data available; calculated ATE2,000 - 5,000
mg/kg Propan-2-ol Dermal Rabbit LD50 12,870 mg/kg Propan-2-ol Inhalation-
Vapor (4 hours)
Rat LC50 72.6 mg/l
Propan-2-ol Ingestion Rat LD50 4,710 mg/kg 2-Butoxyethanol Dermal Rabbit LD50 400 mg/kg 2-Butoxyethanol Inhalation-
Vapor (4 hours)
Rat LC50 2.2 mg/l
2-Butoxyethanol Ingestion Rat LD50 560 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Propan-2-ol Multiple
animal species
No significant irritation
2-Butoxyethanol Rabbit Irritant
Serious Eye Damage/Irritation
Name Species Value
Propan-2-ol Rabbit Severe irritant
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2-Butoxyethanol Rabbit Severe irritant
Skin Sensitisation
Name Species Value
Propan-2-ol Guinea
pig
Not sensitizing
2-Butoxyethanol Guinea
pig
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
Propan-2-ol In Vitro Not mutagenic Propan-2-ol In vivo Not mutagenic 2-Butoxyethanol In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Propan-2-ol Inhalation Rat Some positive data exist, but the data are not
sufficient for classification 2-Butoxyethanol Inhalation Multiple
animal species
Some positive data exist, but the data are not
sufficient for classification
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
Propan-2-ol Ingestion Some positive developmental data exist,
but the data are not sufficient for classification
Rat NOAEL 400
mg/kg/day
during
organogenesis
Propan-2-ol Inhalation Some positive developmental data exist,
but the data are not sufficient for classification
Rat LOAEL 9
mg/l
during
gestation
2-Butoxyethanol Dermal Not toxic to development Rat NOAEL
1,760 mg/kg/day
during
gestation
2-Butoxyethanol Ingestion Some positive developmental data exist,
but the data are not sufficient for classification
Rat NOAEL 100
mg/kg/day
during
organogenesis
2-Butoxyethanol Inhalation Some positive developmental data exist,
but the data are not sufficient for classification
Multiple animal species
NOAEL 0.48 mg/l
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Propan-2-ol Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
Propan-2-ol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
Human NOAEL Not
available
Propan-2-ol Inhalation auditory system Some positive data exist, but the
data are not sufficient for classification
Guinea pig
NOAEL 13.4 mg/l
24 hours
Propan-2-ol Ingestion central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
poisoning and/or abuse
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2-Butoxyethanol Dermal endocrine system Some positive data exist, but the
data are not sufficient for classification
Rabbit NOAEL 902
mg/kg
6 hours
2-Butoxyethanol Dermal liver Some positive data exist, but the
data are not sufficient for classification
Rabbit LOAEL 72
mg/kg
not available
2-Butoxyethanol Dermal kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rabbit LOAEL 451
mg/kg
6 hours
2-Butoxyethanol Dermal blood Some positive data exist, but the
data are not sufficient for classification
Multiple animal species
NOAEL Not available
not available
2-Butoxyethanol Inhalation blood May cause damage to organs Multiple
animal species
NOAEL Not available
not available
2-Butoxyethanol Inhalation central nervous
system depression
May cause drowsiness or dizziness
Human NOAEL Not
available
2-Butoxyethanol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for classification
Human NOAEL Not
available
2-Butoxyethanol Ingestion blood Causes damage to organs Human NOAEL Not
available
poisoning and/or abuse
2-Butoxyethanol Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Human NOAEL Not
available
poisoning and/or abuse
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
Propan-2-ol Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 12.3
mg/l
24 months
Propan-2-ol Inhalation nervous system All data are negative Rat NOAEL 12
mg/l
13 weeks
Propan-2-ol Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 400
mg/kg/day
12 weeks
2-Butoxyethanol Dermal blood Some positive data exist, but the
data are not sufficient for classification
Multiple animal species
NOAEL Not available
not available
2-Butoxyethanol Dermal endocrine system All data are negative Rabbit NOAEL 150
mg/kg/day
90 days
2-Butoxyethanol Inhalation blood May cause damage to organs
though prolonged or repeated exposure
Rat NOAEL 0.12
mg/l
90 days
2-Butoxyethanol Inhalation liver Some positive data exist, but the
data are not sufficient for classification
Rat NOAEL 2.4
mg/l
14 weeks
2-Butoxyethanol Inhalation kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat NOAEL 0.15
mg/l
14 weeks
2-Butoxyethanol Inhalation endocrine system Some positive data exist, but the
data are not sufficient for classification
Dog LOAEL 1.9
mg/l
8 days
2-Butoxyethanol Ingestion blood Causes damage to organs through
prolonged or repeated exposure
Multiple animal species
NOAEL Not available
not available
2-Butoxyethanol Ingestion kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Multiple animal species
NOAEL Not available
not available
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
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on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
2­Butoxyethanol
111-76-2 Green Algae Experimental 72 hours EC50 >1,000 mg/l
2­Butoxyethanol
111-76-2 Rainbow trout Experimental 96 hours LC50 1,474 mg/l
2­Butoxyethanol
111-76-2 Water flea Experimental 48 hours EC50 1,550 mg/l
2­Butoxyethanol
111-76-2 Crustacea Experimental 96 hours EC50 89.4 mg/l
Propan-2-ol 67-63-0 Fathead
minnow
Experimental 96 hours LC50 6,120 mg/l
Propan-2-ol 67-63-0 Crustacea Experimental 48 hours EC50 1,400 mg/l Propan-2-ol 67-63-0 Algae Experimental 24 hours EC50 >1,000 mg/l 2­Butoxyethanol
111-76-2 Water flea Experimental 21 days NOEC 100 mg/l
2­Butoxyethanol
111-76-2 Green Algae Experimental 72 hours NOEC 130 mg/l
Propan-2-ol 67-63-0 Water flea Experimental 21 days NOEC 30 mg/l
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Non­Hazardous Ingredients
Mixture Data not
available or insufficient for classification
N/A N/A N/A N/A
2­Butoxyethanol
111-76-2 Experimental
Biodegradation
14 days BOD 96 % weight OECD 301C - MITI
test (I)
Propan-2-ol 67-63-0 Experimental
Photolysis
Photolytic half­life (in air)
6.3 days (t 1/2) Other methods
Propan-2-ol 67-63-0 Experimental
Biodegradation
14 days BOD 86 % weight OECD 301C - MITI
test (I)
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Non­Hazardous Ingredients
Mixture Data not
available or insufficient for classification
N/A N/A N/A N/A
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2­Butoxyethanol
111-76-2 Experimental
Bioconcentrati on
Log Kow 0.83 Other methods
Propan-2-ol 67-63-0 Experimental
Bioconcentrati on
Log Kow 0.05 Other methods
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Incinerate in a permitted waste incineration facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR: UN1993 Flammable liquid, N.O.S. (Propan-2-ol); 3; III; (D/E); F1 IMDG: UN1993 Flammable liquid, N.O.S. (Propan-2-ol); 3; III; EmS: F-E, S-E IATA: UN1993 Flammable liquid, N.O.S. (Propan-2-ol); 3; III
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
2-Butoxyethanol 111-76-2 Gr. 3: Not classifiable International Agency
for Research on Cancer
Global inventory status
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Contact manufacturer for more information The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness.
List of relevant R-phrases
R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R21 Harmful in contact with skin. R22 Harmful if swallowed. R36 Irritating to eyes. R38 Irritating to skin. R52 Harmful to aquatic organisms. R67 Vapours may cause drowsiness and dizziness.
Revision information:
Revision Changes: Section 8: Skin protection - recommended gloves information information was modified. Section 15: Carcinogenicity information information was modified. Section 16: List of relevant R phrase information information was modified. Section 3: Composition/ Information of ingredients table information was modified. Section 12: Component ecotoxicity information information was modified. Section 12: Persistence and Degradability information information was modified. Section 12:Bioccumulative potential information information was modified. Section 16: Regulations - Inventories - EU ONLY information was modified. Section 1: Address information was modified. Copyright information was modified. Section 8: Occupational exposure limit table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Skin Sensitization Table information was modified. Section 11: Reproductive Toxicity Table information was modified. Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 11: Target Organs - Single Table information was modified. Section 11: Health Effects - Skin information information was modified.
D120, Glass Cleaner Concentrate (22-134A): D12001, D12005, D12025
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Section 11: Health Effects - Inhalation information information was modified. Section 7: Precautions safe handling information information was modified. Section 7: Conditions safe storage information was modified. Section 8: Personal Protection - Eye information information was modified. Section 8: Personal Protection - Skin/hand information information was modified. Section 8: Personal Protection - Respiratory Information information was modified. Section 13: 13.1. Waste disposal note information was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. information was modified. Label: Signal Word - Header information was added. Label: Signal Word information was added. Label: CLP Classification - Header information was added. Label: CLP Classification information was added. Label: CLP Classification information was added. Label: CLP Classification - Header information was added. Label: Graphic information was added. Label: Graphic information was added. Label: Symbol information was added. Label: Symbol information was added. Label: CLP Precautionary - Disposal information was added. Label: CLP Precautionary - Disposal - Header information was added. Label: CLP Precautionary - General information was added. Label: CLP Precautionary - General - Header information was added. Label: CLP Precautionary - Prevention information was added. Label: CLP Precautionary - Prevention - Header information was added. Label: CLP Precautionary - Response information was added. Label: CLP Precautionary - Response - Header information was added. Label: Precautionary Statement - Header information was added. CLP: Ingredient table information was added. Section 2: Notes on labelling heading information was added. Section 15: Label remarks and EU Detergent information was added. CLP Remark(phrase) information was added. Section 2: 2.2 & 2.3. CLP REGULATION heading information was added. Label: CLP Ingredients table Ingredient heading information was added. Label: CLP Ingredients table CAS No heading information was added. Label: CLP Ingredients table Percent by Wt heading information was added. Section 2: H phrase reference information was added. Legend description information was added. BLV Reg Agency Desc information was added. Section 10: Hazardous decomposition products during combustion text information was added. Section 11: Disclosed components not in tables text information was added. Section 8: 8.1.1 Biological limit values table heading information was added. Section 8: BLV table information was added. Section 8: BLV table ingredient column heading information was added. Section 8: BLV table cas nbr column heading information was added. Section 8: BLV table agency column heading information was added. Section 8: BLV table cas nbr column heading information was added. Section 8: BLV table biological specimen Column heading information was added. Section 8: BLV table sampling time Column heading information was added. Section 8: BLV table value Column heading information was added. Section 8: BLV table additional comments Column heading information was added. Section 8: Eye/face protection text information was deleted. Section 8: Respiratory protection - recommended respirators information was deleted. Section 8: Skin protection - protective clothing text information was deleted. Section 8: mg/m³ key information was deleted. Section 8: ppm key information was deleted.
D120, Glass Cleaner Concentrate (22-134A): D12001, D12005, D12025
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Section 11: Aspiration Hazard Table information was deleted. Section 11: Respiratory Sensitization Table information was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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