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Safety Data Sheet
Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
Document group:
29-6439-3
Version number:
1.00
Revision date:
28/05/2014
Supersedes date:
Initial issue.
Transportation version number: 1.00 (28/05/2014)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
D115, Rinse Free Express Wash N’Wax (24-97C): D11501, D11505
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
CLP REGULATION (EC) No 1272/2008
CLASSIFICATION:
This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification,
labelling, and packaging of substances and mixtures.
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
CLP REGULATION (EC) No 1272/2008
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SUPPLEMENTAL INFORMATION
Supplemental Hazard Statements:
EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-
isothiazol-3-one. May produce an allergic reaction.
Notes on labelling
Updated per Regulation (EC) No. 648/2004 on detergents.
Ingredients required per 648/2004 (not required on industrial label): Contains: Perfumes, mixture of:
methylchloroisothiazolinone and methylisothiazolinone (3:1).Ingredients required per 648/2004 (not required on industrial
label): Contains: Perfumes, mixture of: methylchloroisothiazolinone and methylisothiazolinone (3:1).
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbol(s)
None.
Contains:
No ingredients are assigned to the label.
Risk phrases None.
Safety phrases None.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004 (not required on industrial label): Contains: Perfumes, mixture of:
methylchloroisothiazolinone and methylisothiazolinone (3:1).Ingredients required per 648/2004 (not required on industrial
label): Contains: Perfumes, mixture of: methylchloroisothiazolinone and methylisothiazolinone (3:1).
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-Hazardous Ingredients Mixture 75 - 95
Conditioners Trade Secret < 5
Siloxanes and silicones, di-Me 63148-62-9 1 - 5
1-propoxypropan-2-ol 1569-01-3 EINECS 216-
372-4
1 - 5 Xi:R36; R10; R66; R67 (Self
Classified)
Flam. Liq. 3, H226; Eye Irrit. 2,
H319; STOT SE 3, H336;
EUH066 (Self Classified)
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;
R43 (EU)
Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
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H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air. Observe precautions from other sections.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or
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bodies of water.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the
container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using
this product. Wash thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Eye protection not required.
Skin/hand protection
No chemical protective gloves are required.
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
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For questions about suitability for a specific application, consult with your respirator manufacturer.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet odour; greenish-blue
Odour threshold
No data available.
pH
3.2 - 4
Boiling point/boiling range
100 ºC
Melting point
No data available.
Flammability (solid, gas)
Not applicable.
Explosive properties
Not classified
Oxidising properties
Not classified
Flash point
Flash point > 93 °C (200 °F)
Autoignition temperature
No data available.
Flammable Limits(LEL)
No data available.
Flammable Limits(UEL)
No data available.
Vapour pressure
No data available.
Relative density
1 [Ref Std:WATER=1]
Water solubility
Complete
Solubility- non-water
No data available.
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Decomposition temperature
No data available.
Viscosity
No data available.
Density
1 g/ml
9.2. Other information
Volatile organic compounds (VOC)
1.4 % [Test Method:calculated per CARB title 2]
Volatile organic compounds (VOC)
25 g/l [Test Method:calculated SCAQMD rule 443.1]
VOC less H2O & exempt solvents
444 g/l [Test Method:calculated SCAQMD rule 443.1]
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
None known.
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10.5 Incompatible materials
Strong acids.
Strong oxidising agents.
10.6 Hazardous decomposition products
Substance Condition
None known.
Refer to section 5.2 for hazardous decomposition products during combustion.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Skin contact
Contact with the skin during product use is not expected to result in significant irritation.
Eye contact
Contact with the eyes during product use is not expected to result in significant irritation.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Additional information:
This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the
International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human consumption
of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the foreseeable use of this
product is not expected to cause cancer, developmental toxicity, or liver toxicity.
Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.
Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
Siloxanes and silicones, di-Me Dermal Rabbit LD50 > 19,400 mg/kg
Siloxanes and silicones, di-Me Ingestion Rat LD50 > 17,000 mg/kg
1-propoxypropan-2-ol Dermal Rabbit LD50 2,805 mg/kg
1-propoxypropan-2-ol Inhalation-
Dust/Mist
Rat LC50 > 11.8 mg/l
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(4 hours)
1-propoxypropan-2-ol Ingestion Rat LD50 2,500 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Dermal Rabbit LD50 87 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Inhalation-
Dust/Mist
(4 hours)
Rat LC50 0.33 mg/l
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Ingestion Rat LD50 40 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Siloxanes and silicones, di-Me Rabbit No significant irritation
1-propoxypropan-2-ol Rabbit Minimal irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Rabbit Corrosive
Serious Eye Damage/Irritation
Name Species Value
Siloxanes and silicones, di-Me Rabbit No significant irritation
1-propoxypropan-2-ol Rabbit Severe irritant
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Rabbit Corrosive
Skin Sensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Human
and
animal
Sensitising
Photosensitisation
Name Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
Human
and
animal
Not sensitizing
Respiratory Sensitisation
Name Species Value
Germ Cell Mutagenicity
Name Route Value
1-propoxypropan-2-ol In Vitro Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3one
In Vitro Some positive data exist, but the data are not
sufficient for classification
Carcinogenicity
Name Route Species Value
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Dermal Mouse Not carcinogenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl2H-isothiazol-3-one
Ingestion Rat Not carcinogenic
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure
Duration
1-propoxypropan-2-ol Inhalation Some positive developmental data exist, Rat NOAEL 3.6 during
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but the data are not sufficient for
classification
mg/l organogenesis
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to female reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to male reproduction Rat NOAEL 10
mg/kg/day
2 generation
Mixture of 5-chloro-2-methyl-2Hisothiazol-3-one and 2-methyl-2Hisothiazol-3-one
Ingestion Not toxic to development Rat NOAEL 15
mg/kg/day
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
1-propoxypropan-2-ol Inhalation central nervous
system depression
May cause drowsiness or
dizziness
Multiple
animal
species
LOAEL 10.8
mg/l
6 hours
1-propoxypropan-2-ol Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
NOAEL Not
available
1-propoxypropan-2-ol Ingestion central nervous
system depression
May cause drowsiness or
dizziness
Rat LOAEL
1,770 mg/kg
not applicable
Mixture of 5-chloro-2methyl-2H-isothiazol-3one and 2-methyl-2Hisothiazol-3-one
Inhalation respiratory irritation Some positive data exist, but the
data are not sufficient for
classification
similar
health
hazards
NOAEL Not
available
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test result Exposure
Duration
1-propoxypropan-2-ol Inhalation liver | kidney and/or
bladder
Some positive data exist, but the
data are not sufficient for
classification
Rat NOAEL 9.5
mg/l
11 days
Aspiration Hazard
Name Value
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.
12.1. Toxicity
No product test data available.
Material CAS Nbr Organism Type Exposure Test endpoint Test result
Siloxanes and
silicones, diMe
63148-62-9 Data not
available or
insufficient for
classification
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1propoxypropan
-2-ol
1569-01-3 Green algae Experimental 96 hours EC50 1,466 mg/l
1propoxypropan
-2-ol
1569-01-3 Water flea Experimental 48 hours EC50 >100 mg/l
1propoxypropan
-2-ol
1569-01-3 Rainbow trout Experimental 96 hours LC50 >100 mg/l
12.2. Persistence and degradability
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and
silicones, diMe
63148-62-9 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
1propoxypropan
-2-ol
1569-01-3 Experimental
Biodegradation
20 days BOD 64 % weight Other methods
12.3 : Bioaccumulative potential
Material CAS Nbr Test type Duration Study Type Test result Protocol
Siloxanes and
silicones, diMe
63148-62-9 Data not
available or
insufficient for
classification
N/A N/A N/A N/A
1propoxypropan
-2-ol
1569-01-3 Estimated
Bioconcentrati
on
Bioaccumulati
on factor
3 Estimated:
Bioconcentration factor
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
See Section 11.1 Information on toxicological effects
Dispose of waste product in a permitted industrial waste facility. Empty and clean product containers may be disposed as
non-hazardous waste. Consult your specific regulations and service providers to determine available options and
requirements.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
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manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC 2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
EUH066 Repeated exposure may cause skin dryness or cracking.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R10 Flammable.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
Revision information:
No revision information is available.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
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(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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