D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
Document group:
26-7909-0
Version number:
1.04
Revision date:
14/08/2012
Supersedes date:
22/03/2012
Transportation version number: 1.00 (07/09/2010)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
This product is not classified as hazardous according to EU Directive 1999/45/EC.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols None.
Contains:
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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No ingredients are assigned to the label.
Risk phrases None.
Safety phrases None.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004: 5-15%: Anionic surfactants. Contains: Perfumes, amyl cinnamal,
methylchloroisothiazolinone, methylisothiazolinone.
Based on the results of toxicity testing, following specific concentration limits are applied for CAS# 68439-57-6:
Xi; R41 if c >= 40%
Xi; R36 if 20% >= c < 40%
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Non-hazardous ingredients Mixture 70 - 90
Sulphonic acids, C14-16-alkane hydroxy
and C14-16-alkene, sodium salts
68439-57-6 EINECS 270-
407-8
5 - 10 Xn:R22; Xi:R41 (Self
Classified)
Acute Tox. 4, H302; Eye Dam.
1, H318 (Self Classified)
Alkanolamide Trade Secret 1 - 5
Anionic surfactant Trade Secret 1 - 5
Sodium Chloride 7647-14-5 EINECS 231-
598-3
1 - 5
Diethyl Phthalate 84-66-2 EINECS 201-
550-6
< 0.11 R52 (Self Classified)
2,4-Dihydroxybenzophenone 131-56-6 EINECS 205-
029-4
< 0.11 N:R50/53 (Self Classified)
Aquatic Acute 1, H400,M=1;
Aquatic Chronic 1, H410,M=1
(Self Classified)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.
Skin contact
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.
Inhalation
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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Remove person to fresh air. If you are concerned, get medical advice.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Material will not burn.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Ventilate the area with fresh air.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible.
Seal the container.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. Keep out of reach of children. Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Use personal protective equipment (eg. gloves, respirators…) as
required.
7.2. Conditions for safe storage including any incompatibilities
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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No special storage requirements.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient CAS Nbr Agency Limit type Additional comments
Diethyl Phthalate 84-66-2 Health and
Safety Comm.
(UK)
TWA:5 mg/m3;STEL:10
mg/m3
Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
ppm: parts per million
mg/m³: milligrams per cubic metre
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
The following eye protection(s) are recommended: Safety glasses with side shields.
Skin/hand protection
Wear protective gloves.
Gloves made from the following material(s) are recommended: Neoprene.
Nitrile rubber.
Respiratory protection
None required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state
Liquid.
Appearance/Odour
Sweet odour; Blue, pourable gel
pH
8.6 - 9.5
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
Oxidising properties
Not classified
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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Flash point
Not applicable.
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Vapour pressure
No data available.
Relative density
1.00 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Vapour density
No data available.
Viscosity
0.45 - 0.8 Pa-s
Density
1 kg/cm3
9.2. Other information
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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Eye contact
Moderate eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin contact
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Inhalation
No health effects are expected.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE
>5,000 mg/kg
Sulphonic acids, C14-16-alkane
hydroxy and C14-16-alkene, sodium
salts
Ingestion Rat LD50 578 mg/kg
Sodium Chloride No data available
2,4-Dihydroxybenzophenone No data available
Diethyl Phthalate No data available
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Sulphonic acids, C14-16-alkane hydroxy and C1416-alkene, sodium salts
Rabbit Mild irritant
Sodium Chloride No data available
2,4-Dihydroxybenzophenone No data available
Diethyl Phthalate No data available
Serious Eye Damage/Irritation
Name Species Value
Sulphonic acids, C14-16-alkane hydroxy and C1416-alkene, sodium salts
Rabbit Corrosive
Sodium Chloride No data available
2,4-Dihydroxybenzophenone No data available
Diethyl Phthalate No data available
Skin Sensitisation
Name Species Value
Sulphonic acids, C14-16-alkane hydroxy and C1416-alkene, sodium salts
No data available
Sodium Chloride No data available
2,4-Dihydroxybenzophenone No data available
Diethyl Phthalate No data available
Respiratory Sensitisation
Name Species Value
Sulphonic acids, C14-16-alkane hydroxy and C14- No data available
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16-alkene, sodium salts
Sodium Chloride No data available
2,4-Dihydroxybenzophenone No data available
Diethyl Phthalate No data available
Germ Cell Mutagenicity
Name Route Value
Sulphonic acids, C14-16-alkane hydroxy and C1416-alkene, sodium salts
No data available
Sodium Chloride No data available
2,4-Dihydroxybenzophenone No data available
Diethyl Phthalate No data available
Carcinogenicity
Name Route Species Value
Sulphonic acids, C14-16-alkane
hydroxy and C14-16-alkene, sodium
salts
No data available
Sodium Chloride No data available
2,4-Dihydroxybenzophenone No data available
Diethyl Phthalate No data available
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Sulphonic acids,
C14-16-alkane
hydroxy and C14-16alkene, sodium salts
No data available
Sodium Chloride No data available
2,4Dihydroxybenzophen
one
No data available
Diethyl Phthalate No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Sulphonic
acids, C1416-alkane
hydroxy and
C14-16alkene,
sodium salts
No data available
Sodium
Chloride
No data available
2,4Dihydroxyben
zophenone
No data available
Diethyl
Phthalate
No data available
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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Sulphonic
acids, C1416-alkane
hydroxy and
C14-16alkene,
sodium salts
No data available
Sodium
Chloride
No data available
2,4Dihydroxyben
zophenone
No data available
Diethyl
Phthalate
No data available
Aspiration Hazard
Name Value
Sulphonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts Not an aspiration hazard
Sodium Chloride Not an aspiration hazard
2,4-Dihydroxybenzophenone Not an aspiration hazard
Diethyl Phthalate Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available.
No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
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12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC)
No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities. Incinerate in a permitted waste incineration
facility. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of
additional fuel during incineration processes.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC 2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 30 Detergents other than those mentioned in 20 01 29.
SECTION 14: Transportation information
ADR: Not restricted for transport.
IMDG: Not restricted for transport.
IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua
Sodium C14-16 olefin sulfonate
Alkanolamide
Anionic surfactant
Sodium chloride
Sodium sulfate
Perfumes
Benzophenone-1
Tetrasodium EDTA
Formaldehyde
Magnesium nitrate
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Polyethylene glycol
Diethanolamine
Sodium glycolate
Sodium hydroxide
Trisodium NTA
Colorant
Methylchloroisothiazolinone
Magnesium chloride
Methylisothiazolinone
Citric acid
Potassium sorbate
Sodium benzoate
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
List of relevant R-phrases
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R52 Harmful to aquatic organisms.
Revision information:
Revision Changes:
Section 16: List of relevant R phrase information was modified.
Section 3: Composition/ Information of ingredients table was modified.
Aspiration Hazard Table was modified.
Section 11: Acute Toxicity table was modified.
Carcinogenicity Table was modified.
Serious Eye Damage/Irritation Table was modified.
Germ Cell Mutagenicity Table was modified.
Skin Sensitisation Table was modified.
Respiratory Sensitisation Table was modified.
Reproductive Toxicity Table was modified.
Skin Corrosion/Irritation Table was modified.
Target Organs - Repeated Table was modified.
Target Organs - Single Table was modified.
Section 6: Accidental release clean-up information was modified.
Section 13: Standard Phrase Category Waste GHS was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
material. was modified.
Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
D111, Shampoo Plus (DX-59B): D11101, D11105, D11155
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product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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