MEGUIAR'S D110 User Manual

D110, Detailer Hyper Wash (DX-61B): D11001, D11005
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Safety Data Sheet
Copyright, 2012, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.
26-7822-5
Version number:
1.02
Revision date:
17/07/2012
Supersedes date:
26/03/2012
Transportation version number: 1.00 (26/09/2011)
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
D110, Detailer Hyper Wash (DX-61B): D11001, D11005
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture Address:
Meguiars United Kingdon Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF
Telephone:
+44 (0)870 241 6696
E Mail:
info@meguiars.co.uk
Website:
www.meguiars.co.uk
1.4. Emergency telephone number
+44 (0)870 241 6696
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger
Irritant.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols
Xi Irritant.
Contains:
D110, Detailer Hyper Wash (DX-61B): D11001, D11005
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No ingredients are assigned to the label.
Risk phrases
R36 Irritating to eyes.
Safety phrases
S46 If swallowed, seek medical advice immediately and show this container or label.
Notes on labelling
Updated per Regulation (EC) 648/2004 on detergents.
CAS 68439-57-6 is manufacturer classified as Xi; R41 with following specific concentration limits: Xi; R41 : concentration >= 40%; Xi; R36 : 20% <= concentration < 40%.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient CAS Nbr EU Inventory % by Wt Classification
Water 7732-18-5 EINECS 231-
791-2
50 - 70
Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts
68439-57-6 EINECS 270-
407-8
10 - 30 Xn:R22; Xi:R41 (Self
Classified)
Acute Tox. 4, H302; Eye Dam.
1, H318 (Self Classified) Alkanolamide Trade Secret 5 - 10 Anionic surfactant Trade Secret 5 - 10 2,2'-iminodiethanol 111-42-2 EINECS 203-
868-0
0.5 - 1.5 Xn:R22-48/22; Xi:R38-41 (EU)
Acute Tox. 4, H302; Skin Irrit.
2, H315; Eye Dam. 1, H318;
STOT RE 2, H373 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
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If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
5.1. Extinguishing media
Material will not burn.
5.2. Special hazards arising from the substance or mixture
None inherent in this product.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide. During combustion. Carbon dioxide. During combustion. Irritant vapours or gases. During combustion.
5.3. Advice for fire-fighters
No unusual fire or explosion hazards are anticipated.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water.
6.3. Methods and material for containment and cleaning up
Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. For industrial or professional use only. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not
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get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Use personal protective equipment (eg. gloves, respirators…) as required.
7.2. Conditions for safe storage including any incompatibilities
No special storage requirements.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
No occupational exposure limit values exist for any of the components listed in Section 3 of this Safety Data Sheet.
8.2. Exposure controls
8.2.1. Engineering controls
Not applicable. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Wear eye/face protection. The following eye protection(s) are recommended: Indirect vented goggles.
Skin/hand protection
Wear protective gloves. Gloves made from the following material(s) are recommended: Neoprene. Nitrile rubber.
The following protective clothing material(s) are recommended:Neoprene apron.
Respiratory protection
Respiratory protection is not required.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties Physical state
Liquid.
Appearance/Odour
Sweet, clean odour; Bright orange, pourable gel
pH
9 - 9.8
Boiling point/boiling range
100 ºC
Melting point
Not applicable.
Flammability (solid, gas)
Not classified
Explosive properties
Not classified
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Oxidising properties
Not classified
Flash point
Not applicable.
Autoignition temperature
Not applicable.
Flammable Limits(LEL)
Not applicable.
Flammable Limits(UEL)
Not applicable.
Relative density
1.0 [Ref Std:WATER=1]
Water solubility
Complete
Partition coefficient: n-octanol/water
No data available.
Evaporation rate
No data available.
Vapour density
No data available.
Viscosity
400 - 0.95 Pa-s
Density
1 g/cm3
9.2. Other information
Volatile organic compounds (VOC)
0.0 % weight
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Temperatures above the boiling point.
10.5 Incompatible materials
None known.
10.6 Hazardous decomposition products
Substance Condition
None known.
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.
11.1 Information on Toxicological effects
Signs and Symptoms of Exposure
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Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision.
Skin contact
May cause target organ effects after skin contact. Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation
No health effects are expected.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May be harmful if swallowed. May cause target organ effects after ingestion.
Target Organ Effects:
Hematopoietic effects: Signs/symptoms may include generalised weakness, fatigue and alterations in numbers of circulating blood cells. Kidney/Bladder effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Allergic Skin Reaction (non-photo induced) in sensitive people: Signs/symptoms may include redness, swelling, blistering, and itching.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Toxicological Data
Acute Toxicity
Name Route Species Value
Overall product Ingestion No test data available; calculated ATE2,957
mg/kg Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts
Ingestion Rat LD50 578 mg/kg
2,2'-iminodiethanol Ingestion Rat LD50 1,410 mg/kg
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name Species Value
Sulfonic acids, C14-16-alkane hydroxy and C14-16­alkene, sodium salts
Rabbit Mild irritant
2,2'-iminodiethanol Rabbit Mild irritant
Serious Eye Damage/Irritation
Name Species Value
Sulfonic acids, C14-16-alkane hydroxy and C14­16-alkene, sodium salts
Rabbit Corrosive
2,2'-iminodiethanol Rabbit Severe irritant
Skin Sensitisation
Name Species Value
Sulfonic acids, C14-16-alkane hydroxy and C14-16­alkene, sodium salts
No data available
2,2'-iminodiethanol No data available
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Respiratory Sensitisation
Name Species Value
Sulfonic acids, C14-16-alkane hydroxy and C14­16-alkene, sodium salts
No data available
2,2'-iminodiethanol No data available
Germ Cell Mutagenicity
Name Route Value
Sulfonic acids, C14-16-alkane hydroxy and C14-16­alkene, sodium salts
No data available
2,2'-iminodiethanol No data available
Carcinogenicity
Name Route Species Value
Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts
No data available
2,2'-iminodiethanol Dermal Mouse Carcinogenic.
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name Route Value Species Test result Exposure Duration
Sulfonic acids, C14­16-alkane hydroxy and C14-16-alkene, sodium salts
No data available
2,2'-iminodiethanol No data available
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
Sulfonic acids, C14­16-alkane hydroxy and C14-16­alkene, sodium salts
No data available
2,2'­iminodiethano l
Inhalation respiratory
irritation
Some positive data exist, but the data are not sufficient for classification
NOAEL not available
2,2'­iminodiethano l
Ingestion kidney and/or
bladder
May cause damage to organs
Rat NOAEL 200
mg/kg
not applicable
2,2'­iminodiethano l
Ingestion central nervous
system depression
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 200
mg/kg
not applicable
Specific Target Organ Toxicity - repeated exposure
Name Route Target
Organ(s)
Value Species Test result Exposure
Duration
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Sulfonic acids, C14­16-alkane hydroxy and C14-16­alkene, sodium salts
No data available
2,2'­iminodiethano l
Dermal hematopoietic
system
May cause damage to organs though prolonged or repeated exposure
Rat LOAEL 32
mg/kg/day
13 weeks
2,2'­iminodiethano l
Dermal kidney and/or
bladder
Some positive data exist, but the data are not sufficient for classification
Rat LOAEL 8
mg/kg/day
2 years
2,2'­iminodiethano l
Ingestion hematopoietic
system
May cause damage to organs though prolonged or repeated exposure
Rat NOAEL 14
mg/kg/day
13 weeks
2,2'­iminodiethano l
Ingestion nervous system Some positive
data exist, but the data are not sufficient for classification
Rat NOAEL 57
mg/kg/day
13 weeks
Aspiration Hazard
Name Value
Sulfonic acids, C14-16-alkane hydroxy and C14-16-alkene, sodium salts Not an aspiration hazard 2,2'-iminodiethanol Not an aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available. No component test data available.
12.2. Persistence and degradability
No test data available.
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12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor
EU waste code (product as sold)
20 01 29* Detergents containing dangerous substances
SECTION 14: Transportation information
ADR/IMDG/IATA: Not restricted for transport.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Carcinogenicity
Ingredient CAS Nbr Classification Regulation
2,2'-iminodiethanol 111-42-2 Grp. 2B: Possible human
carc.
International Agency for Research on Cancer
Global inventory status
Contact manufacturer for more information The components of this product are in compliance with the chemical notification requirements of TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
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The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Aqua Sodium C14-16 olefin sulfonate Alkanolamide Anionic surfactant Sodium sulfate Sodium chloride Perfumes Tetrasodium EDTA Hexyl cinnam-aldehyde Citronellol Diethanolamine Magnesium nitrate Sodium glycolate Sodium hydroxide Trisodium NTA Colorant Methylchloroisothiazolinone Magnesium chloride Copper-based stabilizers Methylisothiazolinone
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure.
List of relevant R-phrases
R22 Harmful if swallowed. R38 Irritating to skin. R41 Risk of serious damage to eyes. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
Revision information:
Revision Changes: Section 16: List of relevant R phrase information was modified. Section 3: Composition/ Information of ingredients table was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Respiratory Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified.
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Target Organs - Single Table was modified. Section 6: Accidental release personal information was modified. Section 6: Accidental release environmental information was modified. Section 6: Accidental release clean-up information was modified. Section 13: Standard Phrase Category Waste GHS was modified. Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given material. was modified. Section 15: Carcinogenicity heading was added. Section 15: Carcinogenicity information was added. Section 15: Carcinogenicity table Regulation column heading was added. Section 15: Carcinogenicity table Ingredient column heading was added. Section 15: Carcinogenicity table CAS No column heading was added. Section 15: Carcinogenicity table Classification column heading was added. Section 11: UN GHS Classification table heading was deleted.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications.
Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk
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