MEGUIAR'S A33 User Manual

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Safety Data Sheet

Copyright, 2014, Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes
unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

Document group:

27-6190-6

Version number:

4.00

Revision date:

15/09/2014

Supersedes date:

04/02/2014

Transportation version number: 1.00 (22/08/2011)

This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

1.1. Product identifier

A33, Quik Detailer (19-187B): A3316, A3332

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses

Automotive.

1.3. Details of the supplier of the substance or mixture
Address:

Meguiars United Kingdom Limited, 3 Lamport Court, Heartlands, Daventry, Northants, NN11 8UF

Telephone:

[phone]

E Mail:

[e-mail]

Website:

www.meguiars.co.uk

1.4. Emergency telephone number

[phone]

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

CLP REGULATION (EC) No 1272/2008

CLASSIFICATION:

This material is not classified as hazardous according to Regulation (EC) No. 1272/2008, as amended, on classification,
labelling, and packaging of substances and mixtures.

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

This product is not classified as hazardous according to EU Directive 1999/45/EC.

2.2. Label elements

CLP REGULATION (EC) No 1272/2008

Not applicable

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SUPPLEMENTAL INFORMATION

Supplemental Hazard Statements:

EUH208 Contains Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-

isothiazol-3-one. May produce an allergic reaction.

Notes on labelling

Updated per Regulation (EC) No. 648/2004 on detergents.
Ingredients required per 648/2004 (not required for industrial label): Contains: Perfumes, Mixture of
methylchloroisothiazolinone and methylisothiazolinone (3:1).

Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive

Not applicable

Notes on labelling

Updated per Regulation (EC) 648/2004 on detergents.
Ingredients required per 648/2004 (not required for industrial label): Contains: Perfumes, Mixture of
methylchloroisothiazolinone and methylisothiazolinone (3:1).

2.3. Other hazards

None known.

SECTION 3: Composition/information on ingredients

Ingredient CAS Nbr EU Inventory % by Wt Classification

Non-Hazardous Ingredients Mixture 90 - 98
1-propoxypropan-2-ol 1569-01-3 EINECS 216-

372-4

0.5 - 1.5 Xi:R36; R10; R66; R67 (Self
Classified)

Flam. Liq. 3, H226; Eye Irrit. 2,
H319; STOT SE 3, H336;
EUH066 (Self Classified)

Propane-1,2-diol 57-55-6 EINECS 200-

338-0

0.5 - 1.5

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

55965-84-9 < 0.001 T:R23-24-25; C:R34; N:R50/53;

R43 (EU)

Acute Tox. 3, H331; Acute Tox.
3, H311; Acute Tox. 3, H301;
Skin Corr. 1B, H314; Skin Sens.
1A, H317; Aquatic Acute 1,
H400,M=10; Aquatic Chronic 1,
H410,M=10 (CLP)

Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components

For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation

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Remove person to fresh air. If you feel unwell, get medical attention.

Skin contact

Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye contact

Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If swallowed

Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

See Section 11.1 Information on toxicological effects

4.3. Indication of any immediate medical attention and special treatment required

Not applicable

SECTION 5: Fire-fighting measures

5.1. Extinguishing media

Material will not burn. Use a fire fighting agent suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

None inherent in this product.

Hazardous Decomposition or By-Products

Substance Condition

Aldehydes. During combustion.
Carbon monoxide. During combustion.
Carbon dioxide. During combustion.
Irritant vapours or gases. During combustion.

5.3. Advice for fire-fighters

No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Ventilate the area with fresh air.

6.2. Environmental precautions

Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled
material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with
water. Seal the container. Dispose of collected material as soon as possible.

6.4. Reference to other sections

Refer to Section 8 and Section 13 for more information

SECTION 7: Handling and storage

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7.1. Precautions for safe handling

Do not use in a confined area with minimal air exchange. Keep out of reach of children. Avoid breathing
dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.)

7.2. Conditions for safe storage including any incompatibilities

Store away from acids. Store away from oxidising agents.

7.3. Specific end use(s)

See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational exposure limits

If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.

Ingredient CAS Nbr Agency Limit type Additional comments

Propane-1,2-diol 57-55-6 Health and

Safety Comm.
(UK)

TWA(as particulate):10
mg/m3;TWA(as total vapour
and particulates):474
mg/m3(150 ppm)

Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

Biological limit values

No biological limit values exist for any of the components listed in Section 3 of this safety data sheet.

8.2. Exposure controls

8.2.1. Engineering controls

Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Safety glasses with side shields.

Skin/hand protection

No chemical protective gloves are required.

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:

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Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state

Liquid.

Appearance/Odour

Pleasant odour; Light milky blue, watery liquid

Odour threshold

No data available.

pH

7.5 - 8.5

Boiling point/boiling range

100 ºC

Melting point

Not applicable.

Flammability (solid, gas)

Not applicable.

Explosive properties

Not classified

Oxidising properties

Not classified

Flash point

No flash point

Autoignition temperature

Not applicable.

Flammable Limits(LEL)

Not applicable.

Flammable Limits(UEL)

Not applicable.

Relative density

1.0 [Ref Std:WATER=1]

Water solubility

Complete

Solubility- non-water

No data available.

Partition coefficient: n-octanol/water

No data available.

Evaporation rate

No data available.

Vapour density

No data available.

Decomposition temperature

No data available.

Viscosity

No data available.

Density

1 g/cm3

9.2. Other information

Volatile organic compounds (VOC)

1.32 % weight

SECTION 10: Stability and reactivity

10.1 Reactivity

This material may be reactive with certain agents under certain conditions - see the remaining headings in this section

10.2 Chemical stability

Stable.

10.3 Possibility of hazardous reactions

Hazardous polymerisation will not occur.

10.4 Conditions to avoid

None known.

10.5 Incompatible materials

Strong acids.
Strong oxidising agents.

10.6 Hazardous decomposition products

Substance Condition

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None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from
3M assessments.

11.1 Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation

Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin contact

Contact with the skin during product use is not expected to result in significant irritation.

Eye contact

Sprayed material may cause eye irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy
vision.

Ingestion

Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.

Toxicological Data

If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity

Name Route Species Value

Overall product Ingestion No data available; calculated ATE >5,000 mg/kg
1-propoxypropan-2-ol Dermal Rabbit LD50 2,805 mg/kg
1-propoxypropan-2-ol Inhalation-

Dust/Mist
(4 hours)

Rat LC50 > 11.8 mg/l

1-propoxypropan-2-ol Ingestion Rat LD50 2,500 mg/kg
Propane-1,2-diol Dermal Rabbit LD50 20,800 mg/kg
Propane-1,2-diol Ingestion Rat LD50 22,000 mg/kg
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Rabbit LD50 87 mg/kg

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Inhalation­Dust/Mist
(4 hours)

Rat LC50 0.33 mg/l

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat LD50 40 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

1-propoxypropan-2-ol Rabbit Minimal irritation
Propane-1,2-diol Rabbit No significant irritation

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Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Serious Eye Damage/Irritation

Name Species Value

1-propoxypropan-2-ol Rabbit Severe irritant
Propane-1,2-diol Rabbit No significant irritation
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Rabbit Corrosive

Skin Sensitisation

Name Species Value

Propane-1,2-diol Human Some positive data exist, but the data are not

sufficient for classification
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Sensitising

Photosensitisation

Name Species Value

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

Human
and
animal

Not sensitizing

Respiratory Sensitisation

Name Species Value

Germ Cell Mutagenicity

Name Route Value

1-propoxypropan-2-ol In Vitro Not mutagenic
Propane-1,2-diol In Vitro Not mutagenic
Propane-1,2-diol In vivo Not mutagenic
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In vivo Not mutagenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3­one

In Vitro Some positive data exist, but the data are not

sufficient for classification

Carcinogenicity

Name Route Species Value

Propane-1,2-diol Dermal Mouse Not carcinogenic
Propane-1,2-diol Ingestion Multiple

animal
species

Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Dermal Mouse Not carcinogenic

Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl­2H-isothiazol-3-one

Ingestion Rat Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects

Name Route Value Species Test result Exposure

Duration

1-propoxypropan-2-ol Inhalation Some positive developmental data exist,

but the data are not sufficient for
classification

Rat NOAEL 3.6

mg/l

during

organogenesis

Propane-1,2-diol Ingestion Not toxic to female reproduction Mouse NOAEL

10,100
mg/kg/day

2 generation

Propane-1,2-diol Ingestion Not toxic to male reproduction Mouse NOAEL

10,100
mg/kg/day

2 generation

Propane-1,2-diol Ingestion Not toxic to development Multiple NOAEL during

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animal
species

1,230
mg/kg/day

organogenesis

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to female reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to male reproduction Rat NOAEL 10

mg/kg/day

2 generation

Mixture of 5-chloro-2-methyl-2H­isothiazol-3-one and 2-methyl-2H­isothiazol-3-one

Ingestion Not toxic to development Rat NOAEL 15

mg/kg/day

during

organogenesis

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

1-propoxypropan-2-ol Inhalation central nervous

system depression

May cause drowsiness or
dizziness

Multiple
animal
species

LOAEL 10.8
mg/l

6 hours

1-propoxypropan-2-ol Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

NOAEL Not
available

1-propoxypropan-2-ol Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Rat LOAEL

1,770 mg/kg

not applicable

Propane-1,2-diol Ingestion central nervous

system depression

May cause drowsiness or
dizziness

Human NOAEL Not

available

poisoning

and/or abuse
Mixture of 5-chloro-2­methyl-2H-isothiazol-3­one and 2-methyl-2H­isothiazol-3-one

Inhalation respiratory irritation Some positive data exist, but the

data are not sufficient for
classification

similar
health
hazards

NOAEL Not
available

Specific Target Organ Toxicity - repeated exposure

Name Route Target Organ(s) Value Species Test result Exposure

Duration

1-propoxypropan-2-ol Inhalation liver | kidney and/or

bladder

Some positive data exist, but the
data are not sufficient for
classification

Rat NOAEL 9.5

mg/l

11 days

Propane-1,2-diol Ingestion hematopoietic

system

Some positive data exist, but the
data are not sufficient for
classification

Multiple
animal
species

NOAEL
1,370
mg/kg/day

117 days

Propane-1,2-diol Ingestion kidney and/or

bladder

All data are negative Dog NOAEL

5,000
mg/kg/day

104 weeks

Aspiration Hazard

Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information

The information below may not agree with the EU material classification in Section 2 and/or the ingredient
classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition,
statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from
3M assessments.

12.1. Toxicity

No product test data available.

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Material CAS Nbr Organism Type Exposure Test endpoint Test result

1­propoxypropan

-2-ol

1569-01-3 Water flea Experimental 48 hours EC50 >100 mg/l

1­propoxypropan

-2-ol

1569-01-3 Rainbow trout Experimental 96 hours LC50 >100 mg/l

1­propoxypropan

-2-ol

1569-01-3 Green algae Experimental 96 hours EC50 1,466 mg/l

Propane-1,2­diol

57-55-6 Green algae Experimental 96 hours EC50 19,000 mg/l

Propane-1,2­diol

57-55-6 Water flea Experimental 48 hours LC50 4,919 mg/l

Propane-1,2­diol

57-55-6 Fathead

minnow

Experimental 96 hours LC50 710 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 21 days NOEC 0.172 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Rainbow trout Experimental 96 hours LC50 0.07 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Water flea Experimental 48 hours EC50 0.18 mg/l

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Green algae Experimental 96 hours EC50 0.062 mg/l

12.2. Persistence and degradability

Material CAS Nbr Test type Duration Study Type Test result Protocol

1­propoxypropan

-2-ol

1569-01-3 Experimental

Biodegradation

20 days BOD 64 % weight Other methods

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Propane-1,2­diol

57-55-6 Experimental

Biodegradation

28 days BOD 90 % weight OECD 301C - MITI

test (I)
Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Experimental

Biodegradation

28 days CO2 evolution 48 % weight Other methods

12.3 : Bioaccumulative potential

Material CAS Nbr Test type Duration Study Type Test result Protocol

1­propoxypropan

-2-ol

1569-01-3 Estimated

Bioconcentrati
on

Bioaccumulati
on factor

3 Estimated:

Bioconcentration factor

Propane-1,2­diol

57-55-6 Experimental

Bioaccumulati
on

Log Kow -0.92 Other methods

Mixture of 5­chloro-2­methyl-2H­isothiazol-3­one and 2­methyl-2H­isothiazol-3­one

55965-84-9 Estimated

Bioconcentrati
on

Log Kow 0.5 Other methods

12.4. Mobility in soil

Please contact manufacturer for more details

12.5. Results of the PBT and vPvB assessment

No information available at this time, contact manufacturer for more details

12.6. Other adverse effects

No information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

See Section 11.1 Information on toxicological effects

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty and
clean product containers may be disposed as non-hazardous waste. Consult your specific regulations and service providers to
determine available options and requirements.

The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of the
manufacturer, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC ­2000/532/CE and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional
regulations are complied with and always use a licensed waste contractor

EU waste code (product as sold)

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20 01 30 Detergents other than those mentioned in 20 01 29.

SECTION 14: Transportation information

ADR / IMDG / IATA: Not restricted for transport.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Global inventory status

Contact manufacturer for more information The components of this product are in compliance with the chemical notification
requirements of TSCA.

15.2. Chemical Safety Assessment

Not applicable

SECTION 16: Other information

List of relevant H statements

EUH066 Repeated exposure may cause skin dryness or cracking.
H226 Flammable liquid and vapour.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H336 May cause drowsiness or dizziness.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.

List of relevant R-phrases

R10 Flammable.
R23 Toxic by inhalation.
R24 Toxic in contact with skin.
R25 Toxic if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

Revision information:

Revision Changes:
Section 3: Composition/ Information of ingredients table information was modified.
Section 12: Component ecotoxicity information information was modified.
Section 12: Persistence and Degradability information information was modified.
Section 12:Bioccumulative potential information information was modified.
Section 1: Address information was modified.
Section 11: Acute Toxicity table information was modified.
Section 11: Carcinogenicity Table information was modified.

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Section 11: Serious Eye Damage/Irritation Table information was modified.
Section 11: Germ Cell Mutagenicity Table information was modified.
Section 11: Skin Sensitization Table information was modified.
Photosensitisation Table information was modified.
Section 11: Reproductive Toxicity Table information was modified.
Section 11: Skin Corrosion/Irritation Table information was modified.
Section 11: Target Organs - Repeated Table information was modified.
Section 11: Target Organs - Single Table information was modified.
Section 11: Health Effects - Eye information information was modified.
Section 5: Fire - Extinguishing media information information was modified.
Section 5: Fire - Advice for fire fighters information information was modified.
Section 13: Standard Phrase Category Waste GHS information was modified.
List of sensitizers information was modified.
Section 8: Occupational exposure limit table information was added.
Not applicable information was added.
Not applicable information was added.
Section 12: Classification Warning information was added.
Section 11: Classification disclaimer information was added.
Section 8: 8.1.1 Biological limit values table heading information was added.
Section 8: BLV information was added.
Section 2: Contains heading information was deleted.
Section 2: Safety phrases heading information was deleted.
Section 2: Risk phrases heading information was deleted.
Section 15: Symbol information information was deleted.
Section 2: Label ingredient information information was deleted.
Section 11: Aspiration Hazard Table information was deleted.
Section 11: Classification disclaimer information was deleted.
Section 11: Respiratory Sensitization Table information was deleted.
Section 12: Classification Warning information was deleted.
Risk phrase - None information was deleted.
Label: Graphic information was deleted.
Section 02: Graphic information information was deleted.

DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.

Meguiar's, Inc. United Kingdom MSDSs are available at www.meguiars.co.uk