The coolingmeans keeping theroom temperaturelower than outsidetemperature.AS
shown Fig.1-1,operate tocarry the heat from the room with a lower temperature(28”C,
82”F)to the open air with a higher temperatureis required.
heat cannotmove from alowtemperaturesidetoahightemperatureside.So, to
transmittheheatasoppposed tothislaw(principle),some way(apparatus)is
necessary.
That is, a heat pump(chiller) isused topumpout thehear fromlow
temperature one asifawater pump isused todraw upthewater from adeep well.
But, in the nature,the
IUl~CAI I-IUGU-I-U
COOLING LOAD
(82 “F)(90 ‘F)
AIR CONDITIONER
FIG .1-1 HEAT FLOW
+
HEAT FLOW
–2–
The typicalc+illerusing an electricas a operation
curry the heatin Fig.1-2is an electricturbo chiller
heatenergyis an absorptionchiller.
power source as a conveyerto
and the typicalchillerusing a
Chilled wateris made by using the latent hear released byaliquid asitevaporates.
We can find this principlethrough our experiencein a daily life.
having aninjection,afterapplyingas alcoholfor disinfectionon the arm, we feel
thepartofarmcool..
heat from thearmwhen itevaporates.
we sweatin a hot dayorbytaking exercise.
automaticallycontrolledby theevaporationof sweat which takes theheat fromthe
absorbingthe vaporized solution.To recover
concentratingProcess of theabsorbentis required.
naturalgas, steam or hot water.
A chilleralso uses an latentheat of evaporation
chiller.
absorbent decrease
Because. the alcoholis heated by body's temperature.took the
And another sampleis that we feel cool when
Because, thebody temperature
But in a chiller,itis
theabsorption power whenitbecomes dilutedsolutionby
the absorptionpower, the heatingand
Asheat sourceitisused by
For example, when
For thispurpose,the
n
:&KOWEIJ:PERATIRESIDE
I
A GRAINOF HEAT
FIG .1-2HEAT FLOW AT CJ30UNG
iv
HIGHERTEt4PERATuRE
ENERGY
SIDE
–3–
(2) TI-E PRlNCIPLEOF ABSORPTION
Installheattransfertubesin a closedvessel and put a dry silicagel(Silicagelis
high qualityabsorbent material)initas shown Fig.l -3.
vessel tomakeavacuum
with the pressure
of approx. 6.5mmHg (1/4inchHg).Drops of
water are allowed to fall on the heat transfertubes (Evaporator).
vacuum vessel evaporatesat5-C (41 ‘F) .
refrigerantvapor,itisdilutedand decreases
chilled water can not be obtained.
in continuously.
At thisstage,thedilutedsolutionisheated bydrivingheat
to fall(Absorber)insidethe vessel.The LiBr
But, when the absorbent once absorbs the
abilitytoabsorb.Resultinginthe
This means that concentratedsolutionmust befed
source (natural gas, steam orhot water:Generator). The heat causes thesolution to
releasetheabsorbedrefrigerantand also
reconcentratesthesolution.
The refrigerantvapor which is relasedfrom the solutionwhen heatedis cooledin a
seperate vessel (Condenser) tobecome
liquid refrigemnt.
Drops of thiswaterare
again introducedinto the vacuum vessel and recyled.This is shown Fig.l -5.
COOLIN
WATER
e~R;ING
FIG.1-5
Put@
C=
SOUCE
(3]SINGLE EFFECT TYPE(BASICCYCLE)
AS *Fig.l -6.
absorption chiller.
shows an evaporator
Cooling water flows
condenser—cools the
cooling waterin the absorber absorbs the heat when the refrigerantvaporis absorbed
by theabsorbent.
The generator0heatsthedilutedsolutionby drivingheatsource.
solutionreleasesthe refrigerantvapor and becomes theconcentratedsolution.
Atthe condenser (2),the refrierant vapor which came from thegenerator condensed by
coolingwater.
The condensed refrigerant drops onthe heat transfer tubes ofevaporator(3).Drops
of the refrigerantevaporate on the tubes.
of evaporatoris cooled by thelatentheatof vaporized refrigerant.
f--=--n
,—. .
The waterThrough the heat transfertubes
The diluted
/?h@
COWING1-,-
c=-&-=s/.””-w
WATE
~.\
I*-=
d
‘----’’--”=44 ~
CHILLED
WATER
WATER
(“~>”‘“‘WATER
COOLING
FIG.1-6
—7–
(4) DOU8LEEFFECT TYPE
In case of the singleeffecttype absorptionchillermentioned above
heat when the refrigerantvapor coming from generatoris cooled and
allcondensation
condensed at the
condenser,is releasedin the coolingwater.
The double effecttypeabsorptionchillerisused
The generatorsectionisdividedintoahigh
temperaturegenerator.
The refrigerantvapor
generatoris used to heat the LiBr solutionin the
temperaturegeneratorandalow
producedbythehightemperature
low temperaturegeneratorin which
heateffectively.
the pressure(hence the boilingpoint)islower.
As mentionedin thesingleeffecttype,the refrigerantvaporproduced by thelow
temperature generator issent tothe condenser
to become liquidrefrigerant.On the
otherhand, the refrigerantvapor produced by the high temperature generatorturnsto
water as itreleasedheat to theintermediateLiBr solutitn.
heat transfertubes in the low temperaturegenerator.
The refrigerantvapor produced
This occursinsidethe
by both low and high temperaturegeneratorsturnstoliquidrefrigerantand mixes in
thecondenser beforereturningtotheevaporator.
In thisstep,the dilutedsolutionis heated by drivingheat sourceby thelatent
heatintherefrigerantvaporwhich otherwisewould be releasedintothecooling
water.
This combinatiom means a lower energy consumption of drivingheatsource.
Moreover, lessheatbeingdiscardedintothecedingwatertranslatesintoa small
cooling tower.As shown Fig.1-7.
‘~‘-\aGENERATCR
LDW TEMPERATL8?E
@-x~‘-
DRIVING
HEAT
–8–
(5) COOLIKWATER
Cooling water flows through an absorber and a condenser.
The cooling water takes the heat which the LiBr solutionabsobsthe refrigerantvapor
at absorber.
This means the aborbentis cooled by cooling water.
The refrigerantvapor from the generatoris cooled by cooling water.
The lower temperateof cooling water
a)
The absorptionpower ofLiBr solutionisstrongatthelowertemperature
coolingwater.
condensed temperatureofrefrigerantdowns.
low.
AS the boilingtemperature(generatortemperature)of the LiBr solutiondowns
temperature lower then 42C (108F) with concentration of60%
lower than 17C (63°F).
Chiller has some problems when cooling watertemperaturebecomes too high
c)
When the temperatureof the coolingwaterbecomes high,the absorptionpower ofthe
LiBrsolutiondecreases.
temperatureand wastesmuch fuel.
The chillercannotgetthenormalchilledwater
Therefore.topreventthis,themaintenancefor
cooling water system (equipmentand control)and water treatmentarerequired.
ofthe
islow.
becomes
lhatis,the
atthetemperature
d)
Water treatmentof
cooling water
The water treatmentof the cooling wateris an important factorfor the chiller.If
the water qualityis no good, scale adheres to theinside of the heattransfertubes,
resultingin the decreasestransferheat effectand waste fuel.
Astheheattransfer
tubes may become corroded,itisrequiredto fully take careof the watertreatment.
ltis experiencedin a daiily lifethatthe wateris boiled(evaporated)at100C
(212”F)in theatmosphericpressure.
pressure
between the pressure
Ihe
Therefore,theinsidethe chillershould be always keptin high vacuum.
refrigerantis evaporated at 5C (41 oF) to get the chilledwater of 7C (45F)by an
absorptionchiller,
6.54mmHg(1/4inchHg) in the evaporator.
(
wateris evaporated atlower temperature,when the pressure
When explainingthe vacuum
vacuum), the water boiled below 100C (210”F).Table 1-1 shows the relation
and the evaporationtemperature.
itisrequiredto keep a high-vacuum conditionwith
Table 1-1
Gauge
pressurepressure
kgh’e
(psig)
Absolute
mldk
(inchM)
for the absorptionchiller.itis requiredto
and the
When the pressure
Thispressure
less than atmospheric pressure
evaporationt.emperature o thewater.
is lower than the atmospheric
iscalledatmospheric
is called
islower and lower.
Sinesthe
Pressure
of
10(142)
8(114)
Atmospheric
pressure1(14.2)
u
1 ata.
n
Yacmm
5( 71)
0.5 ( 7.2)
o(o)760(29. 9)
Driving pressurefor double effecttype
Driving pressurefor singleeffecttype
Atwpheric pressure
525.9 (2&3/4)
61.0 ( 2-3/8)Pressurein the condenser
9.2 (3/8)
6.54(1/4)Pressurein the waporator
I
I
–lo–
(7)LITYIUMBROMIDE (LiBr: ABSORBENT)
Lithium bromide (LiBr)is a medicine made from lithium obtained from lithiumore and
bromide obtained from the sea water.
with sodiumchloride(NaCl) .
Because lithium(Li)and sodium (Na) are alkaliwhile
brumide (Br) and chlorine(Cl)are halcgen.
The lithium bromide has the same characteristic
the sodium chloride(Ml)is salt.It
is well known that when saltis leftin a high-humidityatmosphere. it becomes sticky.
This means it absorbs moisturein the atmosphere.
Thelithium bromide has the same
characteristicsand itsabsorptionpower is Stronger than thatof salt.
itsconcentrationand the lower itstemperatureof liquid. thestrongerthe absorption
power.
Fig.1-8shows the lithium bromide equilibrium diagram.
Fig.1-9shows the lithiumbromide concentration diagram.
Fig.1-l0shows the lithium bromide DUhring diagram.
This chartis convenient to show
theconditionof the coolingcycleof lithiumbromide solution.
Fig.1-l1shows the lithiumbromide enthalpy diagram.
Ihe higher
Lithium bromide has corrosiveactionto a metal under existingoxygen.
absorption chilleris a vacuum vessel, almost no oxygen is in a vessel.
But, as the
However, to
make more complete,corrosioninhibitorisaddedintheabsorbentandfurther
alkalinityis adjusted.
So, attention shouldbe taken to handle the absorbentand it
isnecessaryto keep the amount of inhibitorby performingthe chemicalanalysisfor
theabsorbent.
Chemical formula : Li13r
Molecular weight : 86.856
Component
: Li= 7.99%
Br=92.01%
Specific gravity: 3.464 at25C(77”F)
Melting
Boilingpoint : 1,265C
point :
549C( 1,020.2”F)
(2,309Φ)
–11–
(“F)
2!2
200
(“c)
I 00
17!5
150
125
10C
5(
x
80
60
40 ‘
20
0
-20
-lo
-2!
-4(
-5’
-7
-40
-60
-80
10
20
CONCENTRATION(X)
FIG.1-8LIBR
30
EOILIBRI~DIAGRAM
40
50
60
–12–
TEMPERATURE
1.90°
1.85
1.80
1.75
1.70
3250
10
-
75
I
I
100
I
125
I
150
I
2030405060708090
II
175
I
1
200212(”FI
I
1OO(”C)
I
67
66
65
64
63
62
61
60
I
1.65
1.60
1.55
1.50
1.45
1.401
59
58
m
57
56
l=+
1
I
55
54
53
52
-1
51
50
49
48
47
46
45
0
102030405060708090
100[”CI
325075
FIG.
100125150
TEt@ERATURE
1-9CDNCENTRATICNDIAGRAM
–13–
175
200212(”F)
;::
500
400
300
200
160
!cm
f30
50
40
30
‘z
J21
20
10
8
5
0
32 40
102030405060708090
60
80
100
120140160
TEMPERATURE
FIG.1-10
180200
DUHRINGDIAGRAM
100110120
220
240
260
130
280
140
150
160
300320
170(”C)
338(°F)
150
140
130
120
110
—160
100
90
k-.
80
70
60
170
50
40
40
4550
FIG.1-11ENTHALPY DIAGRAM
55
CONCENTRATION(%)
–15–
60
65
70
r
(8) COOLING CYCLE
An example for the actualdrivingcycleof double effecttype is explainedusingthe
Duhringdiagram.
ABshows theabsorption processin theabsorber.
a)
The absorbent withconcen-
trationof 63.6% at point A absorbs the refrigerantvapor from the evaporatoras itis
cooleduntil36.3-C (97.3”F)by coolingwater,thenbecomes dilutedsolutionwith
concentrationof 58.1% atpointB.
The pressure of thispointis 6.31mmHg(torr) which is equalto the saturationvapor
pressure of water at 4.3C(39.7°F)(crosspointon
the chilledwater at 7C (44.6°F)can be produced in
Therefore,thehigherthetemperatureof the cooling
internalpressure(equaltotheevaporatorinternal
evaporationtemperatureofrefrigerantbecomes high
the saturationliquidline) , so,
the evaporator.
water,the highertheabsorber
pressure) .
As a result,the
and chilledwatercannotbe
obtained.
B+C+D”shows the temperaturerise
b)
process under the fixed concentrationwhen
the dilutedsolutionpass through thelow
D’+D+E showstheheatingand concentratingprocess inthehigh temperature
c)
generator..
The dilutedsolutionat pointD’ is heated untilpointD.
therefrigerantvaporand
isconcentrated.Then itbecomes theintermediate
It releases
solution of61.1% at pointE and finishesthe firststage of concentrating.
The pressure at point E becomes approx. 707.lmmHg(torr).
thepressureof55.7mmHg(torr)inthecondenser
temperatureofcoolingwater.
Thatis,thepressureinsidethelow temperature
determiningitaccordingtothe
(This pressure
depends on
generatorhas to be performed atthe temperaturehigherthan 91.1C(196”F)of the
concentratedsolutionobtainedfrom thecrosspointwiththeconcentratedsolution
of 63.6%.Whensetting to 97.9C(208.2“F) by making this as AT 6.8C(12.2”F), the
pressure of the high temperaturegeneratorbecomes 707.lmmHg(torr).
d)
--16–
e
absorbentwith 61.1% atpointF’is heated by the refrigerantvapor from the
temperaturegenerator.
concentrationrises,and itbecomes the concentratedsolutionof 63.6%.thus
second stageof theconcentration isfinished.
As aresult.
therefrigerantvaporisgenerated.
F+F+Gshows the
The
high
the
the
conce
The pressure at point G is determinedby the temperatureof the cooling water.
the condensation temperatureof 40.2C(104.4”F).the
Asdescribedabove,itcanbeunderstoodthatthecycleof the absorptioncooling
system depends onthe temperaturecondition (partiallydertermination element from the
takingout temperatureof the chilledwater).
With
pressureis thesaturatedvapor
thecoolingwater,thenstartstoabsorbthe refrigerant
–17–
w
-1
cl
z
-1
t-
ti
-.—
v,
m“
.,
CfJ
u
e
C6
u
—18—
.-,
m
It+
HEATING CYCLE
(9)
The dilutedsolutionisheatedin the high temperaturegenerator.
The refrigerant
vaporisreleasedfrom absorbent.
The refrigerantvaporflowstoabsorberthroughthechangeovervalve.
refrigerantvapor
condenses on the heat transfertubes of evaporator.The condensed