Marsh 30400, 30395, 30394 User Manual
SAFETY DATA SHEET
1. Product and Company Identification
Product identifier
Other means of identification
Marsh Spray Stencil Ink
30394 (Tan Markover), 30395 (Black), 30396 (Blue), 30397 (Green), 30398 (Orange), 30399
(Red), 30400 (White), 30401 (Yellow), 5XT12 (Tan Markover), 5XT13 (Black), 5XT14 (White)
Not available
Spray Ink
None known.
MSSC, LLC
926 McDonough Lake Road, Unit E
Collinsville, IL 62234 US
Phone: (618) 343-1006
Fax: (618) 343-1016
Emergency Phone: 1-800-535-5053 (Infotrac)
Emergency Phone: 352-323-3500 (Int'l Collect)
See above.
Synonyms
Recommended use
Recommended restrictions
Manufacturer information
Supplier
2. Hazards Identification
Physical hazards
Flammable aerosols
Gases under pressure
Skin corrosion/irritation
Serious eye damage/eye irritation
Specific target organ toxicity, single exposure
Aspiration hazard
Not classified.
Not classified
Category 1
Liquefied gas
Category 2
Category 2
Category 3 narcotic effects
Category 1
Health hazards
Environmental hazards
WHMIS 2015 defined hazards
Label elements
Signal word
Hazard statement
Danger
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways.
Precautionary statement
Prevention
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use.
Avoid breathing mist or vapor.
Use only outdoors or in a well-ventilated area.
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse. Specific treatment (see information on
this label).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Response
Storage
Disposal
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WHMIS 2015: Health Hazard(s)
not otherwise classified
(HHNOC)
WHMIS 2015: Physical
Hazard(s) not otherwise
classified (PHNOC)
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
None known
None known
None known.
None.
3. Composition/Information on Ingredients
Mixture
Chemical name
Common name and synonyms
CAS number
%
Acetone
67-64-1
28 - 38
Petroleum gases, liquefied,
sweetened
68476-86-8
15 - 18
Propane
74-98-6
15 - 18
Solvent naptha (petroleum), light
aliphatic
64742-89-8
9 -11
Hydrous magnesium silicate
14807-96-6
2 - 6
Limestone
1317-65-3
2 - 4
2-Pentanone, 4-hydroxy-4-methyl-
123-42-2
0.2 - 5
Titanium oxide
13463-67-7
0 - 4
Solvent naphtha (petroleum), light
aromatic
64742-95-6
0.8 - 3
2-Propanol, 1-methoxy-, acetate
108-65-6
1.4 - 1.9
Quaternary ammonium compounds,
bis(hydrogenated tallow alkyl)
dimethyl, salts with bentonite
68953-58-2
0.8 - 1.2
Carbon black
1333-86-4
0 - .91
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First Aid Measures
Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take
off contaminated clothing and wash it before reuse. Specific treatment (see information on this
label).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce
vomiting.
Aspiration may cause pulmonary edema and pneumonitis.
May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Causes serious eye irritation. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision.
Skin irritation. May cause redness and pain.
Symptoms may be delayed.
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance. Avoid contact with eyes and skin. Keep out of reach of children.
5. Fire Fighting Measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Water fog. Alcohol resistant foam. Carbon dioxide.
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
During fire, gases hazardous to health may be formed.
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Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Specific methods
General fire hazards
Hazardous combustion
products
Not available.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
risk. Containers should be cooled with water to prevent vapor pressure build up.
Use standard firefighting procedures and consider the hazards of other involved materials.
Extremely flammable aerosol.
May include and are not limited to: Oxides of carbon.
6. Accidental Release Measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Avoid
breathing mist or vapor. Ventilate closed spaces before entering them. Emergency personnel need
self-contained breathing equipment. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is
irreparable. Isolate area until gas has dispersed. Eliminate all ignition sources (no smoking, flares,
sparks, or flames in immediate area). Dike the spilled material, where this is possible. Cover with
plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into
containers. Following product recovery, flush area with water. Clean surface thoroughly to remove
residual contamination. For waste disposal, see section 13 of the SDS.
Do not discharge into lakes, streams, ponds or public waters.
Methods and materials for
containment and cleaning up
Environmental precautions
7. Handling and Storage
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
All equipment used when handling the product must be grounded.
Avoid contact with eyes, skin, and clothing.
Wear appropriate personal protective equipment.
Use only in well-ventilated areas.
Avoid breathing mist or vapor.
Observe good industrial hygiene practices.
Wash thoroughly after handling.
When handling, do not eat, drink or smoke.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F.
Keep away from heat, sparks and open flame.
Store in a well-ventilated place.
Store away from incompatible materials (see Section 10 of the SDS).
Keep out of reach of children.
Store locked up.
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
8. Exposure Controls/Personal Protection
Occupational exposure limits
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
TWA
238 mg/m3
50 ppm
1800 mg/m3
750 ppm
1200 mg/m3
500 ppm
3.5 mg/m3
Acetone (CAS 67-64-1)
STEL
TWA
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
TWA
TWA
2 mg/m3
Respirable particles.
TWA
TWA
TWA
10 mg/m3
1000 ppm
1590 mg/m3
400 ppm
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Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Form
Components
Type
Value
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
TWA
1590 mg/m3
400 ppm
10 mg/m3
Titanium oxide (CAS
13463-67-7)
TWA
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
2-Propanol, 1-methoxy-,
acetate (CAS 108-65-6)
TWA
50 ppm
STEL
75 ppm
TWA
STEL
TWA
TWA
50 ppm
500 ppm
250 ppm
3 mg/m3
Acetone (CAS 67-64-1)
Carbon black (CAS
1333-86-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Inhalable
TWA
2 mg/m3
Respirable.
STEL
TWA
20 mg/m3
3 mg/m3
10 mg/m3
1000 ppm
3 mg/m3
Total dust.
Respirable fraction.
Total dust.
Propane (CAS 74-98-6)
Titanium oxide (CAS
13463-67-7)
TWA
TWA
Respirable fraction.
10 mg/m3
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
Total dust.
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
Acetone (CAS 67-64-1)
TWA
50 ppm
STEL
TWA
TWA
500 ppm
250 ppm
3 mg/m3
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Titanium oxide (CAS
13463-67-7)
Inhalable fraction.
TWA
2 mg/m3
Respirable fraction.
TWA
10 mg/m3
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
2-Propanol, 1-methoxy-,
acetate (CAS 108-65-6)
TWA
50 ppm
TWA
270 mg/m3
50 ppm
750 ppm
500 ppm
3 mg/m3
Acetone (CAS 67-64-1)
STEL
TWA
TWA
Carbon black (CAS
1333-86-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Inhalable fraction.
TWA
2 fibers/ml
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Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components
Type
Value
Form
2 mg/m3
1000 ppm
10 mg/m3
Respirable fraction.
Propane (CAS 74-98-6)
Titanium oxide (CAS
13463-67-7)
TWA
TWA
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components
Type
Value
Form
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
TWA
238 mg/m3
50 ppm
2380 mg/m3
1000 ppm
1190 mg/m3
500 ppm
3.5 mg/m3
Acetone (CAS 67-64-1)
STEL
TWA
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
TWA
TWA
3 mg/m3
Respirable dust.
TWA
TWA
10 mg/m3
1800 mg/m3
1000 ppm
1590 mg/m3
Total dust.
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
TWA
400 ppm
1590 mg/m3
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
TWA
400 ppm
10 mg/m3
Titanium oxide (CAS
13463-67-7)
TWA
Total dust.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
PEL
240 mg/m3
50 ppm
2400 mg/m3
1000 ppm
3.5 mg/m3
Acetone (CAS 67-64-1)
PEL
Carbon black (CAS 133386-4)
Limestone (CAS 1317-65-3)
PEL
PEL
5 mg/m3
15 mg/m3
1800 mg/m3
1000 ppm
400 mg/m3
Respirable fraction.
Total dust.
Propane (CAS 74-98-6)
PEL
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
PEL
100 ppm
400 mg/m3
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
PEL
100 ppm
15 mg/m3
Titanium oxide (CAS
13463-67-7)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
PEL
Total dust.
Form
Type
Value
Hydrous magnesium
silicate (CAS 14807-96-6)
TWA
0.1 mg/m3
Respirable.
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US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
Type
Value
Form
20 mppcf
2.4 mppcf
5 mg/m3
Respirable.
Respirable fraction.
Titanium oxide (CAS
13463-67-7)
TWA
15 mg/m3
50 mppcf
15 mppcf
Total dust.
Total dust.
Respirable fraction.
US. ACGIH Threshold Limit Values
Components
Form
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
Acetone (CAS 67-64-1)
TWA
50 ppm
STEL
TWA
TWA
500 ppm
250 ppm
3 mg/m3
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Titanium oxide (CAS
13463-67-7)
Inhalable fraction.
TWA
2 mg/m3
Respirable fraction.
TWA
10 mg/m3
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
Form
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
TWA
240 mg/m3
50 ppm
590 mg/m3
250 ppm
0.1 mg/m3
Acetone (CAS 67-64-1)
TWA
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
TWA
TWA
2 mg/m3
Respirable.
TWA
5 mg/m3
10 mg/m3
1800 mg/m3
1000 ppm
400 mg/m3
Respirable.
Total
Propane (CAS 74-98-6)
TWA
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
TWA
100 ppm
400 mg/m3
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
TWA
100 ppm
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
Components
Type
Value
2-Propanol, 1-methoxy-,
acetate (CAS 108-65-6)
Biological limit values
ACGIH Biological Exposure Indices
TWA
50 ppm
Components
Value
Determinant
Specimen
Sampling Time
Acetone (CAS 67-64-1)
25 mg/L
Acetone
Urine
*
* - For sampling details, please see the source document.
Appropriate engineering
controls
Ensure adequate ventilation.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
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