SAFETY DATA SHEET
1. Product and Company Identification
Product identifier
Other means of identification
Marsh Spray Stencil Ink
30394 (Tan Markover), 30395 (Black), 30396 (Blue), 30397 (Green), 30398 (Orange), 30399
(Red), 30400 (White), 30401 (Yellow), 5XT12 (Tan Markover), 5XT13 (Black), 5XT14 (White)
Not available
Spray Ink
None known.
MSSC, LLC
926 McDonough Lake Road, Unit E
Collinsville, IL 62234 US
Phone: (618) 343-1006
Fax: (618) 343-1016
Emergency Phone: 1-800-535-5053 (Infotrac)
Emergency Phone: 352-323-3500 (Int'l Collect)
See above.
Synonyms
Recommended use
Recommended restrictions
Manufacturer information
Supplier
2. Hazards Identification
Physical hazards
Flammable aerosols
Gases under pressure
Skin corrosion/irritation
Serious eye damage/eye irritation
Specific target organ toxicity, single exposure
Aspiration hazard
Not classified.
Not classified
Category 1
Liquefied gas
Category 2
Category 2
Category 3 narcotic effects
Category 1
Health hazards
Environmental hazards
WHMIS 2015 defined hazards
Label elements
Signal word
Hazard statement
Danger
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes skin irritation.
Causes serious eye irritation.
May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways.
Precautionary statement
Prevention
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use.
Avoid breathing mist or vapor.
Use only outdoors or in a well-ventilated area.
Wash thoroughly after handling.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse. Specific treatment (see information on
this label).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Response
Storage
Disposal
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WHMIS 2015: Health Hazard(s)
not otherwise classified
(HHNOC)
WHMIS 2015: Physical
Hazard(s) not otherwise
classified (PHNOC)
Hazard(s) not otherwise
classified (HNOC)
Supplemental information
None known
None known
None known.
None.
3. Composition/Information on Ingredients
Mixture
Chemical name
Common name and synonyms
CAS number
%
Acetone
67-64-1
28 - 38
Petroleum gases, liquefied,
sweetened
68476-86-8
15 - 18
Propane
74-98-6
15 - 18
Solvent naptha (petroleum), light
aliphatic
64742-89-8
9 -11
Hydrous magnesium silicate
14807-96-6
2 - 6
Limestone
1317-65-3
2 - 4
2-Pentanone, 4-hydroxy-4-methyl-
123-42-2
0.2 - 5
Titanium oxide
13463-67-7
0 - 4
Solvent naphtha (petroleum), light
aromatic
64742-95-6
0.8 - 3
2-Propanol, 1-methoxy-, acetate
108-65-6
1.4 - 1.9
Quaternary ammonium compounds,
bis(hydrogenated tallow alkyl)
dimethyl, salts with bentonite
68953-58-2
0.8 - 1.2
Carbon black
1333-86-4
0 - .91
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First Aid Measures
Inhalation
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take
off contaminated clothing and wash it before reuse. Specific treatment (see information on this
label).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce
vomiting.
Aspiration may cause pulmonary edema and pneumonitis.
May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Causes serious eye irritation. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision.
Skin irritation. May cause redness and pain.
Symptoms may be delayed.
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
General information
IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance. Avoid contact with eyes and skin. Keep out of reach of children.
5. Fire Fighting Measures
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Water fog. Alcohol resistant foam. Carbon dioxide.
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame.
During fire, gases hazardous to health may be formed.
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Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Specific methods
General fire hazards
Hazardous combustion
products
Not available.
In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without
risk. Containers should be cooled with water to prevent vapor pressure build up.
Use standard firefighting procedures and consider the hazards of other involved materials.
Extremely flammable aerosol.
May include and are not limited to: Oxides of carbon.
6. Accidental Release Measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Avoid
breathing mist or vapor. Ventilate closed spaces before entering them. Emergency personnel need
self-contained breathing equipment. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is
irreparable. Isolate area until gas has dispersed. Eliminate all ignition sources (no smoking, flares,
sparks, or flames in immediate area). Dike the spilled material, where this is possible. Cover with
plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into
containers. Following product recovery, flush area with water. Clean surface thoroughly to remove
residual contamination. For waste disposal, see section 13 of the SDS.
Do not discharge into lakes, streams, ponds or public waters.
Methods and materials for
containment and cleaning up
Environmental precautions
7. Handling and Storage
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
All equipment used when handling the product must be grounded.
Avoid contact with eyes, skin, and clothing.
Wear appropriate personal protective equipment.
Use only in well-ventilated areas.
Avoid breathing mist or vapor.
Observe good industrial hygiene practices.
Wash thoroughly after handling.
When handling, do not eat, drink or smoke.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F.
Keep away from heat, sparks and open flame.
Store in a well-ventilated place.
Store away from incompatible materials (see Section 10 of the SDS).
Keep out of reach of children.
Store locked up.
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
8. Exposure Controls/Personal Protection
Occupational exposure limits
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
TWA
238 mg/m3
50 ppm
1800 mg/m3
750 ppm
1200 mg/m3
500 ppm
3.5 mg/m3
Acetone (CAS 67-64-1)
STEL
TWA
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
TWA
TWA
2 mg/m3
Respirable particles.
TWA
TWA
TWA
10 mg/m3
1000 ppm
1590 mg/m3
400 ppm
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Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Form
Components
Type
Value
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
TWA
1590 mg/m3
400 ppm
10 mg/m3
Titanium oxide (CAS
13463-67-7)
TWA
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
2-Propanol, 1-methoxy-,
acetate (CAS 108-65-6)
TWA
50 ppm
STEL
75 ppm
TWA
STEL
TWA
TWA
50 ppm
500 ppm
250 ppm
3 mg/m3
Acetone (CAS 67-64-1)
Carbon black (CAS
1333-86-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Inhalable
TWA
2 mg/m3
Respirable.
STEL
TWA
20 mg/m3
3 mg/m3
10 mg/m3
1000 ppm
3 mg/m3
Total dust.
Respirable fraction.
Total dust.
Propane (CAS 74-98-6)
Titanium oxide (CAS
13463-67-7)
TWA
TWA
Respirable fraction.
10 mg/m3
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
Total dust.
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
Acetone (CAS 67-64-1)
TWA
50 ppm
STEL
TWA
TWA
500 ppm
250 ppm
3 mg/m3
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Titanium oxide (CAS
13463-67-7)
Inhalable fraction.
TWA
2 mg/m3
Respirable fraction.
TWA
10 mg/m3
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
2-Propanol, 1-methoxy-,
acetate (CAS 108-65-6)
TWA
50 ppm
TWA
270 mg/m3
50 ppm
750 ppm
500 ppm
3 mg/m3
Acetone (CAS 67-64-1)
STEL
TWA
TWA
Carbon black (CAS
1333-86-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Inhalable fraction.
TWA
2 fibers/ml
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Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components
Type
Value
Form
2 mg/m3
1000 ppm
10 mg/m3
Respirable fraction.
Propane (CAS 74-98-6)
Titanium oxide (CAS
13463-67-7)
TWA
TWA
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components
Type
Value
Form
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
TWA
238 mg/m3
50 ppm
2380 mg/m3
1000 ppm
1190 mg/m3
500 ppm
3.5 mg/m3
Acetone (CAS 67-64-1)
STEL
TWA
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
TWA
TWA
3 mg/m3
Respirable dust.
TWA
TWA
10 mg/m3
1800 mg/m3
1000 ppm
1590 mg/m3
Total dust.
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
TWA
400 ppm
1590 mg/m3
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
TWA
400 ppm
10 mg/m3
Titanium oxide (CAS
13463-67-7)
TWA
Total dust.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Form
Components
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
PEL
240 mg/m3
50 ppm
2400 mg/m3
1000 ppm
3.5 mg/m3
Acetone (CAS 67-64-1)
PEL
Carbon black (CAS 133386-4)
Limestone (CAS 1317-65-3)
PEL
PEL
5 mg/m3
15 mg/m3
1800 mg/m3
1000 ppm
400 mg/m3
Respirable fraction.
Total dust.
Propane (CAS 74-98-6)
PEL
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
PEL
100 ppm
400 mg/m3
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
PEL
100 ppm
15 mg/m3
Titanium oxide (CAS
13463-67-7)
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
PEL
Total dust.
Form
Type
Value
Hydrous magnesium
silicate (CAS 14807-96-6)
TWA
0.1 mg/m3
Respirable.
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US. OSHA Table Z-3 (29 CFR 1910.1000)
Components
Type
Value
Form
20 mppcf
2.4 mppcf
5 mg/m3
Respirable.
Respirable fraction.
Titanium oxide (CAS
13463-67-7)
TWA
15 mg/m3
50 mppcf
15 mppcf
Total dust.
Total dust.
Respirable fraction.
US. ACGIH Threshold Limit Values
Components
Form
Type
Value
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
Acetone (CAS 67-64-1)
TWA
50 ppm
STEL
TWA
TWA
500 ppm
250 ppm
3 mg/m3
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Titanium oxide (CAS
13463-67-7)
Inhalable fraction.
TWA
2 mg/m3
Respirable fraction.
TWA
10 mg/m3
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
Form
2-Pentanone,
4-hydroxy-4-methyl- (CAS
123-42-2)
TWA
240 mg/m3
50 ppm
590 mg/m3
250 ppm
0.1 mg/m3
Acetone (CAS 67-64-1)
TWA
Carbon black (CAS 133386-4)
Hydrous magnesium
silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
TWA
TWA
2 mg/m3
Respirable.
TWA
5 mg/m3
10 mg/m3
1800 mg/m3
1000 ppm
400 mg/m3
Respirable.
Total
Propane (CAS 74-98-6)
TWA
Solvent naphtha
(petroleum), light aromatic
(CAS 64742-95-6)
TWA
100 ppm
400 mg/m3
Solvent naptha (petroleum),
light aliphatic (CAS
64742-89-8)
TWA
100 ppm
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
Components
Type
Value
2-Propanol, 1-methoxy-,
acetate (CAS 108-65-6)
Biological limit values
ACGIH Biological Exposure Indices
TWA
50 ppm
Components
Value
Determinant
Specimen
Sampling Time
Acetone (CAS 67-64-1)
25 mg/L
Acetone
Urine
*
* - For sampling details, please see the source document.
Appropriate engineering
controls
Ensure adequate ventilation.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
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Skin protection
Hand protection
Other
Respiratory protection
Wear appropriate chemical resistant gloves. Confirm with a reputable supplier first.
Wear appropriate chemical resistant clothing. As required by employer code.
Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Respirator should be selected by and used under the direction of a trained health and safety
professional following requirements found in OSHA's respirator standard (29 CFR 1910.134),
CAN/CSA-Z94.4 and ANSI's standard for respiratory protection (Z88.2).
Not applicable.
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks
and immediately after handling the product. When using, do not eat, drink or smoke.
Thermal hazards
General hygiene
considerations
9. Physical and Chemical Properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
pH
Melting point/freezing point
Initial boiling point and boiling
range
Pour point
Specific gravity
Partition coefficient
(n-octanol/water)
Flash point
Evaporation rate
Flammability (solid, gas)
Aerosol
Liquid.
Liquid
Not available.
Not available.
Not available.
Not available.
Not available.
-44 - 410 °F (-42.22 - 210 °C)
Not available.
0.72
Not available.
-248.8 °F (-156.0 °C) Pensky-Martens Closed Cup
> 1 (BuAc=1)
Not applicable.
Upper/lower flammability or explosive limits
> 1
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Explosive limit - lower (%)
Explosive limit - upper (%)
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Auto-ignition temperature
Decomposition temperature
Viscosity
Other information
Explosive properties
Oxidizing properties
< 12.8
Not available.
Not available.
Not available.
Not available.
Not available.
Partial
Not available.
Not available.
Not available.
Not explosive.
Not oxidizing.
10. Stability and Reactivity
May react with incompatible materials.
Hazardous polymerization does not occur.
Reactivity
Possibility of hazardous
reactions
Chemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Material is stable under normal conditions.
Do not mix with other chemicals. Heat.
Acids. Strong oxidizing agents.
May include and are not limited to: Oxides of carbon.
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11. Toxicological Information
Routes of exposure
Eye, Skin contact, Inhalation, Ingestion.
Information on likely routes of exposure
May cause stomach distress, nausea or vomiting. Droplets of the product aspirated into the lungs
through ingestion or vomiting may cause a serious chemical pneumonia.
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be
harmful.
Causes skin irritation.
Causes serious eye irritation.
Aspiration may cause pulmonary edema and pneumonitis.
May cause drowsiness and dizziness. Headache. Nausea, vomiting.
Causes serious eye irritation. Symptoms may include stinging, tearing, redness, swelling, and
blurred vision.
Skin irritation. May cause redness and pain.
Ingestion
Inhalation
Skin contact
Eye contact
Symptoms related to the
physical, chemical and
toxicological characteristics
Information on toxicological effects
May be fatal if swallowed and enters airways. Narcotic effects.
Acute toxicity
Components
Species
Test Results
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Acute
Dermal
LD50
Rabbit
13500 mg/kg, Sigma Aldrich
14.5 ml/kg, 24 Hours, ECHA
> 1875 mg/kg, 24 Hours, ECHA
Rat
Inhalation
LC50
Oral
LD50
Rat
10 mg/L, 4 h, Sigma Aldrich
Rat
3002 mg/kg
2520 mg/kg, Sigma Aldrich
4 g/kg, Spectrum Chemical
2-Propanol, 1-methoxy-, acetate (CAS 108-65-6)
Acute
Dermal
LD50
Rabbit
Rat
> 5000 mg/kg
> 2000 mg/kg, 24 Hours
Inhalation
LC50
Oral
LD50
Rat
> 5320 ppm, 4 hours
Rat
> 5000 mg/kg
> 14.1 ml
8532 mg/kg
Acetone (CAS 67-64-1)
Acute
Dermal
LD50
Guinea pig
> 7426 mg/kg, 24 Hours, ECHA
> 9.4 ml/kg, 24 Hours, ECHA
> 15800 mg/kg, 24 Hours, ECHA
> 7426 mg/kg, 24 Hours, ECHA
> 20 ml/kg, 24 Hours, ECHA
> 9.4 ml/kg, 24 Hours, ECHA
Rabbit
Inhalation
LC50
Rat
55700 ppm, 3 Hours, ECHA
50100 mg/m3, 8 hours, American Industrial
Hygiene Association Journal
132 mg/L, 3 Hours, ECHA
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Components
Species
Test Results
76 mg/L, 4 Hours, ECHA/HSDB
50.1 mg/L, 4 Hours, ECHA
50.1 mg/L, 8 Hours
Oral
LD50
Mouse
3000 mg/kg, Pharmaceutical Chemistry
Journal
5800 mg/kg, Journal of Toxicology and
Environmental Health
9.1 ml/kg, ECHA
8.5 ml/kg, ECHA
5.6 ml/kg, ECHA
2.2 ml/kg, ECHA
Rat
Carbon black (CAS 1333-86-4)
Acute
Dermal
LD50
Inhalation
LC50
Oral
LD50
Rabbit
> 3000 mg/kg
Not available
Rat
> 15400 mg/kg
> 10000 mg/kg, ECHA
> 8000 mg/kg, ECHA/HSDB
Hydrous magnesium silicate (CAS 14807-96-6)
Acute
Dermal
LD50
Inhalation
LC50
Oral
LD50
Limestone (CAS 1317-65-3)
Acute
Dermal
LD50
Inhalation
LC50
Oral
LD50
Rat
> 2000 mg/kg, ECHA
Rat
> 2.1 mg/L, 4 h, ECHA
Rat
> 5000 mg/kg, ECHA
Not available
Not available
Rat
6450 mg/kg, SPI Pharma
Petroleum gases, liquefied, sweetened (CAS 68476-86-8)
Acute
Dermal
LD50
Inhalation
LC50
Not available
Mouse
539600 ppm, 120 Minutes, ECHA
520400 ppm, 120 Minutes, ECHA
1237 mg/L, 120 Minutes, ECHA
57 %, 120 Minutes, ECHA
52 %, 120 Minutes, ECHA
> 800000 ppm, 10 Minutes, ECHA
1442738 mg/m3, 10 Minutes, ECHA
1354944 mg/m3, 10 Minutes, ECHA
570000 ppm, 10 Minutes, ECHA
Rat
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Components
Species
Test Results
1443 mg/L, 10 Minutes, ECHA
1355 mg/L, 10 Minutes, ECHA
Oral
LD50
Propane (CAS 74-98-6)
Acute
Dermal
LD50
Inhalation
LC50
Not available
Not available
Mouse
539600 ppm, 120 Minutes, ECHA
520400 ppm, 120 Minutes, ECHA
1237 mg/L, 120 Minutes
57 %, 120 Minutes, ECHA
52 %, 120 Minutes
> 12000000 ppm, 4 hours
> 800000 ppm, 10 Minutes, ECHA
> 1464 mg/L, 15 Minutes, HSDB
1442738 mg/m3, 10 Minutes, ECHA
1354944 mg/m3, 10 Minutes, ECHA
570000 ppm, 10 Minutes, ECHA
1355 mg/L, 10 Minutes
Rat
Oral
LD50
Not available
Quaternary ammonium compounds, bis(hydrogenated tallow alkyl) dimethyl, salts with bentonite (CAS 68953-58-2)
Acute
Dermal
LD50
Inhalation
LC50
Rat
> 2000 mg/kg, BYK Additives Inc.
Rat
> 200 mg/L, BYK Additives Inc.
12.6 mg/l/4h, SCBT
Oral
LD50
Rat
5000 mg/kg, SCBT
Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6)
Acute
Dermal
LD50
Rabbit
> 1900 mg/kg, 24 Hours
3000 mg/kg
Inhalation
LC50
Rat
> 4980 mg/m3, 4 Hours
> 5 mg/L, 4 Hours
5.2 mg/l/4h
Oral
LD50
Rat
> 25 ml/kg
4820 mg/kg
4700 mg/kg
Solvent naptha (petroleum), light aliphatic (CAS 64742-89-8)
Acute
Dermal
LD50
Rabbit
> 6000 mg/kg, 24 Hours, ECHA
> 3750 mg/kg, 24 Hours, ECHA
> 3000 mg/kg, 24 Hours, ECHA
> 2000 mg/kg, ECHA
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Components
Species
Test Results
> 2000 mg/kg, 24 Hours, ECHA
> 1900 mg/kg, 24 Hours, ECHA
Inhalation
LC50
Rat
> 8530 mg/m3, 4 Hours, ECHA
> 7970 mg/m3, 4 Hours, ECHA
> 7630 mg/m3, 4 Hours, ECHA
> 7300 mg/m3, 4 Hours, ECHA
> 5830 mg/m3, 4 Hours, ECHA
> 5740 mg/m3, 4 Hours, ECHA
> 5610 mg/m3, 4 Hours, ECHA
> 5470 mg/m3, 4 Hours, ECHA
> 5300 mg/m3, 4 Hours, ECHA
> 5280 mg/m3, 4 Hours, ECHA
> 5260 mg/m3, 4 Hours, ECHA
> 5250 mg/m3, 4 Hours, ECHA
> 5240 mg/m3, 4 Hours, ECHA
> 5220 mg/m3, 4 Hours, ECHA
> 5200 mg/m3, 4 Hours, ECHA
> 5170 mg/m3, 4 Hours, ECHA
> 5160 mg/m3, 4 Hours, ECHA
> 5100 mg/m3, 4 Hours, ECHA
> 5080 mg/m3, 4 Hours, ECHA
> 5050 mg/m3, 4 Hours, ECHA
> 5040 mg/m3, 4 Hours, ECHA
> 5020 mg/m3, 4 Hours, ECHA
> 5000 mg/m3, 4 Hours, ECHA
> 4980 mg/m3, 4 Hours, ECHA
> 4970 mg/m3, 4 Hours, ECHA
> 4420 mg/m3, 4 Hours, ECHA
> 5.4 mg/L, 4 Hours, ECHA
> 5.1 mg/L, 4 Hours, ECHA
> 5.1 mg/L, 4 Hours, ECHA
> 5 mg/L, 4 Hours, ECHA
> 5 mg/L, 4 Hours, ECHA
>= 5060 mg/m3, 4 Hours, ECHA
Oral
LD50
Rat
> 7000 mg/kg, ECHA
> 6000 mg/kg, ECHA
> 5570 mg/kg, ECHA
> 5200 mg/kg, ECHA
> 5000 mg/kg, ECHA
> 4800 mg/kg, ECHA
> 4500 mg/kg, ECHA
> 25 ml/kg, HSDB
14063 mg/kg, ECHA
6620 mg/kg, ECHA
5800 mg/kg, ECHA
5390 mg/kg, ECHA
4820 mg/kg, ECHA
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Components
Species
Test Results
Titanium oxide (CAS 13463-67-7)
Acute
Dermal
LD50
Inhalation
LC50
Not available
Rat
> 6.8 mg/L, 4 Hours, ECHA
> 3.6 mg/l/4h, ECHA
> 3.6 mg/L, 4 Hours, ECHA
> 2.3 mg/L, 4 Hours, ECHA
5.1 mg/L, 4 Hours, ECHA
3.4 mg/L, 4 Hours, ECHA
Oral
LD50
Mouse
Rat
> 5000 mg/kg, ECHA
> 25000 mg/kg, ECHA
> 11000 mg/kg, ECHA
> 5000 mg/kg, ECHA
> 2000 mg/kg, ECHA
Causes skin irritation.
Not available.
Not available.
Not available.
Causes serious eye irritation.
Skin corrosion/irritation
Exposure minutes
Erythema value
Oedema value
Serious eye damage/eye
irritation
Corneal opacity value
Iris lesion value
Conjunctival reddening
value
Conjunctival oedema value
Recover days
Respiratory or skin sensitization
Not available.
Not available.
Not available.
Not available.
Not available.
Canada - Alberta OELs: Irritant
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Limestone (CAS 1317-65-3)
Titanium oxide (CAS 13463-67-7)
Irritant
Irritant
Irritant
Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.
Not classified.
Not classified. Contains < 3% (w/w) DMSO-extract
Respiratory sensitization
Skin sensitization
Mutagenicity
Carcinogenicity
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
This product is not expected to cause reproductive or developmental effects.
Not available.
May cause drowsiness and dizziness.
Reproductive toxicity
Teratogenicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Not classified.
May be fatal if swallowed and enters airways.
Prolonged exposure may cause chronic effects.
12. Ecological Information
See below
Ecotoxicity
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Ecotoxicological data
Components
Species
Test Results
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Aquatic
Fish
LC50
Bluegill (Lepomis macrochirus)
420 mg/L, 96 hours
2-Propanol, 1-methoxy-, acetate (CAS 108-65-6)
Crustacea
Acetone (CAS 67-64-1)
Crustacea
Aquatic
Crustacea
Fish
EC50
Daphnia
500 mg/L, 48 Hours
EC50
Daphnia
13999 mg/L, 48 Hours
EC50
LC50
Water flea (Daphnia magna)
Rainbow trout,donaldson trout
(Oncorhynchus mykiss)
10294 - 17704 mg/L, 48 hours
4740 - 6330 mg/L, 96 hours
Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6)
Crustacea
Aquatic
Crustacea
Fish
EC50
Daphnia
6.14 mg/L, 48 Hours
EC50
LC50
Water flea (Daphnia pulex)
Rainbow trout,donaldson trout
(Oncorhynchus mykiss)
2.7 - 5.1 mg/L, 48 hours
8.8 mg/L, 96 hours
8.8 mg/L, 96 hours
Solvent naptha (petroleum), light aliphatic (CAS 64742-89-8)
Algae
Aquatic
Crustacea
Fish
IC50
Algae
4700 mg/L, 72 Hours
EC50
LC50
Water flea (Daphnia pulex)
Rainbow trout,donaldson trout
(Oncorhynchus mykiss)
2.7 - 5.1 mg/L, 48 hours
8.8 mg/L, 96 hours
8.8 mg/L, 96 hours
Titanium oxide (CAS 13463-67-7)
Aquatic
Crustacea
Fish
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Mobility in general
Other adverse effects
EC50
LC50
Water flea (Daphnia magna)
Mummichog (Fundulus heteroclitus)
> 1000 mg/L, 48 hours
> 1000 mg/L, 96 hours
No data is available on the degradability of this product.
No data available.
Not available.
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
13. Disposal Considerations
Dispose of contents/container in accordance with local/regional/national/international regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe manner (see: Disposal instructions).
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.
Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
14. Transport Information
Transport of Dangerous Goods
(TDG) Proof of Classification
In accordance with Part 2.2.1 (SOR/2014-152) of the Transportation of Dangerous Goods
Regulations, we certify that the classification of this product is correct as of the SDS date of issue.
U.S. Department of Transportation (DOT)
Basic shipping requirements:
UN number
Proper shipping name
Hazard class
UN1950
Aerosols, flammable
2.1
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Issue date 11-December-2017
Special provisions
Packaging exceptions
N82
Limited Quantity 1L
Transportation of Dangerous Goods (TDG - Canada)
Basic shipping requirements:
UN number
Proper shipping name
Hazard class
Special provisions
Packaging exceptions
DOT
UN1950
AEROSOLS, flammable
2.1
80, 107
Limited Quantity 1L
TDG
15. Regulatory Information
Canadian federal regulations
This product has been classified in accordance with the hazard criteria of the HPR and the SDS
contains all the information required by the HPR.
Canada CEPA Schedule I: Listed substance
Hydrous magnesium silicate (CAS 14807-96-6)
Titanium oxide (CAS 13463-67-7)
Canada DSL Challenge Substances: Listed substance
Carbon black (CAS 1333-86-4)
Listed.
Listed.
Listed.
Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/Identification Number
2-Propanol, 1-methoxy-, acetate (CAS 108-65-6)
Propane (CAS 74-98-6)
Solvent naphtha (petroleum), light aromatic (CAS
64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS
64742-89-8)
1 TONNES
1 TONNES
1 TONNES
1 TONNES
Canada Priority Substances List (Second List): Listed substance
Hydrous magnesium silicate (CAS 14807-96-6)
Titanium oxide (CAS 13463-67-7)
Export Control List (CEPA 1999, Schedule 3)
Not listed.
Greenhouse Gases
Not listed.
Precursor Control Regulations
Acetone (CAS 67-64-1)
Listed.
Listed.
Class B
Not applicable
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
WHMIS 2015 Exemptions
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Acetone (CAS 67-64-1)
Propane (CAS 74-98-6)
Listed.
Listed.
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US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
No
Hazard categories
SARA 302 Extremely
hazardous substance
SARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Chemical name
No
CAS number
% by wt.
Solvent naptha (petroleum), light aliphatic
Other federal regulations
64742-89-8
9 -11
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Propane (CAS 74-98-6)
US state regulations
See below
US - California Hazardous Substances (Director's): Listed substance
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Acetone (CAS 67-64-1)
Carbon black (CAS 1333-86-4)
Hydrous magnesium silicate (CAS 14807-96-6)
Solvent naphtha (petroleum), light aromatic (CAS
64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS
64742-89-8)
US - Illinois Chemical Safety Act: Listed substance
Acetone (CAS 67-64-1)
Propane (CAS 74-98-6)
US - Louisiana Spill Reporting: Listed substance
Acetone (CAS 67-64-1)
Propane (CAS 74-98-6)
US - Minnesota Haz Subs: Listed substance
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Acetone (CAS 67-64-1)
Carbon black (CAS 1333-86-4)
Hydrous magnesium silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Solvent naphtha (petroleum), light aromatic (CAS
64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS
64742-89-8)
Titanium oxide (CAS 13463-67-7)
US - New Jersey RTK - Substances: Listed substance
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Acetone (CAS 67-64-1)
Carbon black (CAS 1333-86-4)
Hydrous magnesium silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS 64742-89-8)
Titanium oxide (CAS 13463-67-7)
US - Texas Effects Screening Levels Hazard Data: Simple asphyxiant
Propane (CAS 74-98-6)
US - Texas Effects Screening Levels: Listed substance
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
2-Propanol, 1-methoxy-, acetate (CAS 108-65-6)
Acetone (CAS 67-64-1)
Carbon black (CAS 1333-86-4)
Listed.
Listed.
Listed.
Listed.
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Hydrous magnesium silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Quaternary ammonium compounds,
bis(hydrogenated tallow alkyl) dimethyl, salts with
bentonite (CAS 68953-58-2)
Solvent naphtha (petroleum), light aromatic (CAS
64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS
64742-89-8)
Titanium oxide (CAS 13463-67-7)
US. Massachusetts RTK - Substance List
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Acetone (CAS 67-64-1)
Carbon black (CAS 1333-86-4)
Hydrous magnesium silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Listed.
Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS 64742-89-8)
Titanium oxide (CAS 13463-67-7)
US. New Jersey Worker and Community Right-to-Know Act
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Acetone (CAS 67-64-1)
Carbon black (CAS 1333-86-4)
Hydrous magnesium silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS 64742-89-8)
Titanium oxide (CAS 13463-67-7)
US. Rhode Island RTK
2-Pentanone, 4-hydroxy-4-methyl- (CAS 123-42-2)
Acetone (CAS 67-64-1)
Carbon black (CAS 1333-86-4)
Hydrous magnesium silicate (CAS 14807-96-6)
Limestone (CAS 1317-65-3)
Propane (CAS 74-98-6)
Solvent naphtha (petroleum), light aromatic (CAS 64742-95-6)
Solvent naptha (petroleum), light aliphatic (CAS 64742-89-8)
Titanium oxide (CAS 13463-67-7)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Inventory status
Country(s) or region
Canada
Canada
United States & Puerto Rico
Inventory name
Domestic Substances List (DSL)
Non-Domestic Substances List (NDSL)
Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)*
No
Yes
Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
16. Other Information
/
2
HEALTH
4
4
FLAMMABILITY
2
1
1
PHYSICAL HAZARD
PERSONAL
PROTECTION
X
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LEGEND
Severe 4
Serious 3
Moderate 2
Slight 1
Minimal 0
Disclaimer
Information contained herein was obtained from sources considered technically accurate and
reliable. While every effort has been made to ensure full disclosure of product hazards, in some
cases data is not available and is so stated. Since conditions of actual product use are beyond
control of the supplier, it is assumed that users of this material have been fully trained according to
the requirements of all applicable legislation and regulatory instruments. No warranty, expressed
or implied, is made and supplier will not be liable for any losses, injuries or consequential damages
which may result from the use of or reliance on any information contained in this document.
11-December-2017
01
11-December-2017
Dell Tech Laboratories Ltd. Phone: (519) 858-5021
For an updated SDS, please contact the supplier/manufacturer listed on the first page of the
document.
Issue date
Version #
Effective date
Prepared by
Other information
#25254
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