Issuing Date 23-Jun-2015Revision Date 09-Aug-2018Revision Number 4
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Code(s)
Product Name
Component
Other means of identification
Document
R-BK
Rolmark Black Stencil Ink
Part Codes: 20887,20903,5A132,20928,20929,33564,4HY29
Other Information
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
Marsh Shipping Supply Co., LLC
926 McDonough Lake Road - Unit E
Collinsville, IL 62234
USA
Emergency telephone number
24 Hour Emergency Phone Number
This Safety Data Sheet complies with the requirements of the OSHA Hazard
Communication Standard 2012 Final Rule. This product is intended for use by properly
trained and qualified professionals after having familiarized themselves with this SDS and
understand all hazards to themselves and the environment through a comprehensive
training program according to the Hazard Communication Standard 29 CFR 1910.1200,
and the Occupational Safety and Health adoption of the Global Harmonization Standard
(GHS). Use of this product may present additional hazards, and no guarantee is implied
that the hazards and necessary precautions listed in this document are the only ones
present. Customers using this product are responsible for determining proper personal
protection equipment according to the specific conditions, PPE listed are a minimum
standard. This product is not intended for general public use.
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Wear protective gloves/protective clothing/eye protection/face protection
Wash face, hands and any exposed skin thoroughly after handling
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ non-sparking/ equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Precautionary Statements - Response
IF exposed: Call a POISON CENTER or doctor/physician
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
In case of fire: Use CO2, dry chemical, or foam to extinguish
Precautionary Statements - Storage
Store locked up
Store in a well-ventilated place. Keep cool
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
May be harmful if swallowed
Unknown acute toxicity
0 % of the mixture consists of ingredient(s) of unknown toxicity
3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Chemical NameCAS No.Weight-%
4-hydroxy-4-methylpentan-2-one123-42-282
Carbon black1333-86-45.5
4. FIRST AID MEASURES
Description of first aid measures
General advice
Show this safety data sheet to the doctor in attendance. Call 911 or emergency medical
service. Immediately call a POISON CENTER or doctor/physician. Use first aid treatment
according to the nature of the injury.
Inhalation
Eye contact
Skin contact
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Remove to fresh air. Administer oxygen if breathing is difficult. IF INHALED: Remove to
fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a
physician. Unconscious persons should be moved to an uncontaminated area and, as
necessary, given artificial resuscitation and supplemental oxygen.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. In
case of contact with substance, immediately flush skin or eyes with running water for at
least 20 minutes. Get medical attention if symptoms occur.
Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Remove material from skin immediately. Wash off immediately with
soap and plenty of water for at least 15 minutes. Do not use solvents or thinners to dissolve
the material. Take off contaminated clothing and wash before reuse. Get medical attention
immediately if symptoms occur. Allergic symptoms may be delayed.
Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician. Call a physician or
poison control center immediately. Do not induce vomiting without medical advice.
Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination. Use
personal protective equipment as required. See section 8 for more information. Avoid
contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).
Burning sensation. Symptoms may include headache, dizziness, thirst, cramping, coughing,
and nausea. These symptoms may be delayed. Repeated or prolonged exposure may
cause kidney, liver, neurological, central nervous system, eye and skin disorders. See
Section 11 for additional Toxicological Information. Symptoms of allergic reaction may
include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness,
lightheadedness, chest pain, muscle pain, or flushing. Vapors may cause drowsiness and
dizziness.
Indication of any immediate medical attention and special treatment needed
Note to physicians
Treat symptomatically. Effects of exposure (inhalation, ingestion or skin contact) to
substance may be delayed. May cause sensitization in susceptible persons.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Unsuitable extinguishing media
Specific hazards arising from the
Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam. Dry chemical,
CO2, alcohol-resistant foam or water spray. Use water spray or fog; do not use straight
streams. Dry sand. Use extinguishing measures that are appropriate to local circumstances
and the surrounding environment.
CAUTION: Use of water spray when fighting fire may be inefficient.
Risk of ignition. Keep product and empty container away from heat and sources of ignition.
In the event of fire, cool tanks with water spray. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations. May be
ignited by heat, sparks or flames. Vapors may form explosive mixture with air. Vapors may
travel to source of ignition and flash back. In the event of fire and/or explosion do not
breathe fumes. Containers may explode when heated. Vapors may accumulate in confined
areas (basement, tanks, hopper/tank cars, etc.). Collect contaminated fire extinguishing
water separately. This must not be discharged into drains. Fire may produce irritating,
corrosive and/or toxic gases.
R-BK - Rolmark Black Stencil InkRevision Date 09-Aug-2018
_____________________________________________________________________________________________
Hazardous combustion products
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear. Use only non-sparking tools.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Other Information
Environmental precautions
Evacuate personnel to safe areas. Use personal protective equipment as required. See
section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take
precautionary measures against static discharges. All equipment used when handling the
product must be grounded. Do not touch or walk through spilled material. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Full
encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.
Wear protective gloves/protective clothing and eye/face protection.
Ventilate the area. Refer to protective measures listed in Sections 7 and 8. Water spray
may reduce vapor; but may not prevent ignition in closed spaces.
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevention of secondary hazards
Reference to other sections
Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so. Prevent product from entering drains. See Section 12 for additional
Ecological Information. Dispose of this material and its container to hazardous or special
waste collection point. Prevent entry into waterways, sewers, basements or confined areas.
Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor
suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff
water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other
non-combustible material and transfer to containers for later disposal. Prevent further
leakage or spillage if safe to do so. Absorb spill with inert material (e.g. dry sand or earth),
then place in a chemical waste container. Dike to collect large liquid spills.
Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers. Place in appropriate
chemical waste container. Use a non-combustible material like vermiculite, sand or earth to
soak up the product and place into a container for later disposal. Use clean non-sparking
tools to collect absorbed material. Use personal protective equipment as required.
Clean contaminated objects and areas thoroughly observing environmental regulations.
See section 8 for more information. See section 13 for more information.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Use personal protection equipment. Avoid contact with skin and eyes. Avoid breathing
vapors or mists. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use
grounding and bonding connection when transferring this material to prevent static
discharge, fire or explosion. Use with local exhaust ventilation. Use spark-proof tools and
explosion-proof equipment. Keep in an area equipped with sprinklers. Use according to
package label instructions. Handle in accordance with good industrial hygiene and safety
practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using
this product. Ensure adequate ventilation. Wash thoroughly after handling. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical
assistance. Ground and bond all lines and equipment associated with product system. All
equipment should be non-sparking and explosion proof. Remove all sources of ignition.
Remove contaminated clothing and shoes.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Packaging materials
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Limits
Chemical NameACGIH TLVOSHA PELNIOSH IDLH
4-hydroxy-4-methylpentan-2-on
e
123-42-2
Carbon black
1333-86-4
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep in properly labeled containers. Do not store near combustible materials.
Keep in an area equipped with sprinklers. Store in accordance with the particular national
regulations. Store in accordance with local regulations. Keep/store only in original
container. Keep away from open flames, hot surfaces and sources of ignition. Keep out of
the reach of children. Store locked up.
use only with original package - do not repackage.
.
TWA: 50 ppmTWA: 50 ppm
TWA: 240 mg/m
(vacated) TWA: 50 ppm
(vacated) TWA: 240 mg/m
TWA: 3 mg/m3 inhalable
fraction
TWA: 3.5 mg/m
(vacated) TWA: 3.5 mg/m
3
3
3
3
IDLH: 1800 ppm
TWA: 50 ppm
TWA: 240 mg/m
IDLH: 1750 mg/m
TWA: 3.5 mg/m
TWA: 0.1 mg/m3 Carbon black
in presence of Polycyclic
aromatic hydrocarbons PAH
3
3
3
Other Information
This product may also contain pigments that are otherwise non hazardous according to the
US GHS: REFER TO ACGIH TLV NUISANCE PARTICULATE GUIDANCE OF 10mg/m3 ,
3 mg/m3 respirable fraction; OSHA PEL 15mg/m3 total dust, 5mg/m3 respirable fraction.
Individual protection measures, such as personal protective equipment
Eye/face protection
Hand Protection
Tight sealing safety goggles.
Wear suitable gloves. Impervious gloves. Wear nitrile or natural rubber gloves to protect
hands from contact. Butyl gloves are best for prolonged contact.
Skin and body protection
Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron.
Antistatic boots. Impervious clothing such as Tyvek(R) coveralls for light protection or
Saranex(R) 23-P for moderate protection.
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations. Adequate ventilation should be used
as the first measure to ensure airborne thresholds listed in section 8 of this SDS are not
exceeded. If respirators are used, they should be used in accordance with the Hazard
Communication Standard.
Do not eat, drink or smoke when using this product. Contaminated work clothing should not
be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes or clothing. Wear suitable gloves and eye/face protection.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Color
Odor threshold
Property Values Remarks • Method
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability
limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
liquid
Paint
Alcohol
black
No information available
7
No data availableNone known
150 °C / 302 °F
58 °C / 136 °F
No data availableNone known
No data availableNone known
No data available
No data availableNone known
No data availableNone known
No data availableNone known
No data availableNone known
No data availableNone known
No data availableNone known
No data availableNone known
No data availableNone known
No data availableNone known
No data availableNone known
No information available
No information available
None known
None known
Lower
flammability
limit:
No data available
Other Information
Softening point
Molecular weight
Specific gravity
Non-Volatile (%)
VOC Content (g/l)
Density
Bulk density
No information available
No information available
.98
18 %
809
No information available.
Stable under normal conditions.
R-BK - Rolmark Black Stencil InkRevision Date 09-Aug-2018
_____________________________________________________________________________________________
Possibility of hazardous reactions
Hazardous polymerization
Conditions to avoid
Incompatible materials
Hazardous decomposition products
None under normal processing.
None under normal processing.
Heat, flames and sparks.
Strong acids. Strong bases. Do not store together with acids, oxidizing substances, strong
alkalis, or heavy-metal compounds.
Carbon oxides. Nitrogen oxides (NOx). Thermal decomposition can lead to release of
irritating and toxic gases and vapors.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye contact
Skin contact
Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Specific test data for the substance or mixture is not available. Causes serious eye irritation.
(based on components). May cause redness, itching, and pain.
Specific test data for the substance or mixture is not available. May cause irritation.
Prolonged contact may cause redness and irritation.
Ingestion
Chemical NameAcute toxicity - OralOral LD50Acute toxicity -
4-hydroxy-4-methylpentan-2-on
e
123-42-2
Carbon black
1333-86-4
Chemical Name Physical state Acute toxicity
4-hydroxy-4-methylp
entan-2-one
123-42-2
Carbon black
1333-86-4
Chemical NameAcute aquatic toxicityM-FactorChronic aquatic toxicityM-Factor
4-hydroxy-4-methylpenta
n-2-one
123-42-2
Chemical NameEyesRespiratory
4-hydroxy-4-methylpenta
n-2-one
123-42-2
liquid---
solid---
Category 2
Specific test data for the substance or mixture is not available. Ingestion may cause
gastrointestinal irritation, nausea, vomiting and diarrhea.
Information on toxicological effects
Symptoms
Numerical measures of toxicity
Acute toxicity
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
Unknown acute toxicity
Component Information
Chemical NameOral LD50LD50/dermal/rat - mg/kgInhalation LC50
4-hydroxy-4-methylpentan-2-on
e
123-42-2
Carbon black
1333-86-4
eyes,CNS,respirator
y system,liver,skin
eyes,respiratory
system lymphatic
cancer in presence
of PAHs
May cause redness and tearing of the eyes.
4,697.00 mg/kg
16,463.00 mg/kg
0 % of the mixture consists of ingredient(s) of unknown toxicity
= 4 g/kg ( Rat )= 13500 mg/kg ( Rabbit )-
> 15400 mg/kg ( Rat )> 3 g/kg ( Rabbit )-
STOT - single
exposure
Target Organ
Systemic Toxicant
- Repeated
exposure
Aspiration toxicityOzone
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory or skin sensitization
Germ cell mutagenicity
Carcinogenicity
The table below indicates whether each agency has listed any ingredient as a carcinogen.
Chemical NameACGIHIARCNTPOSHA
Carbon black
1333-86-4
Legend
ACGIH (American Conference of Governmental Industrial Hygienists)
IARC (International Agency for Research on Cancer)
NTP (National Toxicology Program)
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
May cause skin irritation.
Classification based on data available for ingredients. Irritating to eyes.
No information available.
No information available.
Classification based on data available for ingredients. Contains a known or suspected
Reproductive toxicity
STOT - single exposure
Target Organ Systemic Toxicant -
Repeated exposure
Target organ effects
Aspiration hazard
No information available.
No information available.
No information available.
liver, Respiratory system, Eyes, Skin, Central nervous system, Lymphatic System.
No information available.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical NameAlgae/aquatic plantsFishToxicity to
4-hydroxy-4-methylpenta
n-2-one
123-42-2
Carbon black
1333-86-4
Persistence and degradability
Bioaccumulation
.
microorganisms
-420: 96 h Lepomis
macrochirus mg/L LC50
static 420: 96 h Lepomis
macrochirus mg/L LC50
---5600: 24 h Daphnia
No information available.
There is no data for this product.
Crustacea
-8750: 24 h Daphnia
magna mg/L EC50
magna mg/L EC50
Component Information
Chemical NamePartition coefficientDOT Marine PollutantDOT Severe Marine pollutant
4-hydroxy-4-methylpentan-2-one
123-42-2
Other adverse effects
Waste treatment methods
Waste from residues/unused
products
Contaminated packaging
US EPA Waste Number
1.03
No information available.
13. DISPOSAL CONSIDERATIONS
Should not be released into the environment. Dispose of in accordance with local
regulations. Dispose of waste in accordance with environmental legislation.
Empty containers pose a potential fire and explosion hazard. Do not cut, puncture of weld
containers.
Proper shipping name
Hazard Class
Packing Group
Classification code
Special Provisions
Description
Hazard label(s)
Limited quantity (LQ)
Ventilation
3
PRINTING INK
3
III
F1
163, 640E
UN1210, PRINTING INK, 3, III
3
5 L
VE01
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
Complies
Complies
Complies
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CAA (Clean Air Act)
The following component(s) are listed in the Clean Air Act.
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42).
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level
pertaining to releases of this material.
This product can expose you to chemicals including those listed below, which is [are] known to the State of California to cause cancer, birth defects
or other reproductive harm. For more information go to www.P65Warnings.ca.gov
Chemical NameCalifornia Proposition 65
Carbon black - 1333-86-4Carcinogen
U.S. State Right-to-Know Regulations
US State Regulations
Chemical NameNew JerseyMassachusettsPennsylvania
4-hydroxy-4-methylpentan-2-one
123-42-2
Carbon black
1333-86-4
XXX
XXX
U.S. EPA Label Information
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION
NFPA Health hazards 2Flammability 2Instability 0Physical and chemical
properties -
HMIS Health hazards 2 *Flammability 2Physical hazards 0
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. No express or implied warranty of merchantability or fitness for a
particular purpose or use, with respect to the product information provided herein is given. The manufacturer disclosed
in section 1 shall under no circumstance be liable for incidental or consequential damage nor makes any representation
as to the information's accuracy or sufficiency. All suitability of use and safe handleing of this product is upon the user.
This product is not to be repackaged. Any re-sale or repackaging of this product is a violation of the original terms of
sale, and the manufacturer shall not be held responsible whatsoever for the product or use thereof.