Marsh 20903 User Manual

SAFETY DATA SHEET

Issuing Date 23-Jun-2015 Revision Date 09-Aug-2018 Revision Number 4

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

Product identifier
Product Code(s)
Product Name

Component
Other means of identification

Document

R-BK
Rolmark Black Stencil Ink

Part Codes: 20887,20903,5A132,20928,20929,33564,4HY29

Other Information

Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against

Details of the supplier of the safety data sheet
Manufacturer Address

Marsh Shipping Supply Co., LLC
926 McDonough Lake Road - Unit E
Collinsville, IL 62234
USA

Emergency telephone number
24 Hour Emergency Phone Number

This Safety Data Sheet complies with the requirements of the OSHA Hazard
Communication Standard 2012 Final Rule. This product is intended for use by properly
trained and qualified professionals after having familiarized themselves with this SDS and
understand all hazards to themselves and the environment through a comprehensive
training program according to the Hazard Communication Standard 29 CFR 1910.1200,
and the Occupational Safety and Health adoption of the Global Harmonization Standard
(GHS). Use of this product may present additional hazards, and no guarantee is implied
that the hazards and necessary precautions listed in this document are the only ones
present. Customers using this product are responsible for determining proper personal
protection equipment according to the specific conditions, PPE listed are a minimum
standard. This product is not intended for general public use.

Coatings.
Restricted to professional users

Infotrac: 1-800-535-5053
International: call collect 352-323-3500

2. HAZARDS IDENTIFICATION

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2A
Carcinogenicity Category 2
Flammable liquids

Label elements

Warning
Hazard statements

Causes serious eye irritation
Suspected of causing cancer
Flammable liquid and vapor

Category 3

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Appearance Paint Physical state liquid Odor Alcohol

Precautionary Statements

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Wear protective gloves/protective clothing/eye protection/face protection
Wash face, hands and any exposed skin thoroughly after handling
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ ventilating / lighting/ non-sparking/ equipment
Use only non-sparking tools
Take precautionary measures against static discharge

Precautionary Statements - Response

IF exposed: Call a POISON CENTER or doctor/physician
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower
In case of fire: Use CO2, dry chemical, or foam to extinguish

Precautionary Statements - Storage

Store locked up
Store in a well-ventilated place. Keep cool

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Other Information

May be harmful if swallowed

Unknown acute toxicity

0 % of the mixture consists of ingredient(s) of unknown toxicity

3. COMPOSITION/INFORMATION ON INGREDIENTS

Mixture

Chemical Name CAS No. Weight-%

4-hydroxy-4-methylpentan-2-one 123-42-2 82

Carbon black 1333-86-4 5.5

4. FIRST AID MEASURES

Description of first aid measures
General advice

Show this safety data sheet to the doctor in attendance. Call 911 or emergency medical

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service. Immediately call a POISON CENTER or doctor/physician. Use first aid treatment
according to the nature of the injury.

Inhalation

Eye contact

Skin contact

Ingestion

Self-protection of the first aider

Most important symptoms and effects, both acute and delayed
Symptoms

Remove to fresh air. Administer oxygen if breathing is difficult. IF INHALED: Remove to
fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a
physician. Unconscious persons should be moved to an uncontaminated area and, as
necessary, given artificial resuscitation and supplemental oxygen.

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. In
case of contact with substance, immediately flush skin or eyes with running water for at
least 20 minutes. Get medical attention if symptoms occur.

Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Remove material from skin immediately. Wash off immediately with
soap and plenty of water for at least 15 minutes. Do not use solvents or thinners to dissolve
the material. Take off contaminated clothing and wash before reuse. Get medical attention
immediately if symptoms occur. Allergic symptoms may be delayed.

Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician. Call a physician or
poison control center immediately. Do not induce vomiting without medical advice.

Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, take precautions to protect themselves and prevent spread of contamination. Use
personal protective equipment as required. See section 8 for more information. Avoid
contact with skin, eyes or clothing. Wear personal protective clothing (see section 8).

Burning sensation. Symptoms may include headache, dizziness, thirst, cramping, coughing,
and nausea. These symptoms may be delayed. Repeated or prolonged exposure may
cause kidney, liver, neurological, central nervous system, eye and skin disorders. See
Section 11 for additional Toxicological Information. Symptoms of allergic reaction may
include rash, itching, swelling, trouble breathing, tingling of the hands and feet, dizziness,
lightheadedness, chest pain, muscle pain, or flushing. Vapors may cause drowsiness and
dizziness.

Indication of any immediate medical attention and special treatment needed
Note to physicians

Treat symptomatically. Effects of exposure (inhalation, ingestion or skin contact) to
substance may be delayed. May cause sensitization in susceptible persons.

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Unsuitable extinguishing media
Specific hazards arising from the

chemical

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Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam. Dry chemical,
CO2, alcohol-resistant foam or water spray. Use water spray or fog; do not use straight
streams. Dry sand. Use extinguishing measures that are appropriate to local circumstances
and the surrounding environment.

CAUTION: Use of water spray when fighting fire may be inefficient.
Risk of ignition. Keep product and empty container away from heat and sources of ignition.

In the event of fire, cool tanks with water spray. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations. May be
ignited by heat, sparks or flames. Vapors may form explosive mixture with air. Vapors may
travel to source of ignition and flash back. In the event of fire and/or explosion do not
breathe fumes. Containers may explode when heated. Vapors may accumulate in confined
areas (basement, tanks, hopper/tank cars, etc.). Collect contaminated fire extinguishing
water separately. This must not be discharged into drains. Fire may produce irritating,
corrosive and/or toxic gases.

R-BK - Rolmark Black Stencil Ink Revision Date 09-Aug-2018
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Hazardous combustion products
Explosion data

Sensitivity to Mechanical Impact
Sensitivity to Static Discharge

Special protective equipment for
fire-fighters

Carbon monoxide. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx).

None.
Yes.

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear. Use only non-sparking tools.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal precautions

Other Information

Environmental precautions

Evacuate personnel to safe areas. Use personal protective equipment as required. See
section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take
precautionary measures against static discharges. All equipment used when handling the
product must be grounded. Do not touch or walk through spilled material. Do not breathe
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Full
encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.
Wear protective gloves/protective clothing and eye/face protection.

Ventilate the area. Refer to protective measures listed in Sections 7 and 8. Water spray
may reduce vapor; but may not prevent ignition in closed spaces.

Environmental precautions

Methods and material for containment and cleaning up
Methods for containment

Methods for cleaning up

Prevention of secondary hazards
Reference to other sections

Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so. Prevent product from entering drains. See Section 12 for additional
Ecological Information. Dispose of this material and its container to hazardous or special
waste collection point. Prevent entry into waterways, sewers, basements or confined areas.

Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor
suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff
water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other
non-combustible material and transfer to containers for later disposal. Prevent further
leakage or spillage if safe to do so. Absorb spill with inert material (e.g. dry sand or earth),
then place in a chemical waste container. Dike to collect large liquid spills.

Take precautionary measures against static discharges. Dam up. Soak up with inert
absorbent material. Pick up and transfer to properly labeled containers. Place in appropriate
chemical waste container. Use a non-combustible material like vermiculite, sand or earth to
soak up the product and place into a container for later disposal. Use clean non-sparking
tools to collect absorbed material. Use personal protective equipment as required.

Clean contaminated objects and areas thoroughly observing environmental regulations.
See section 8 for more information. See section 13 for more information.

7. HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling

Use personal protection equipment. Avoid contact with skin and eyes. Avoid breathing
vapors or mists. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use
grounding and bonding connection when transferring this material to prevent static

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