Safety Data Sheet
GHS product identifier
:
INTERPON 600
Product code
:
Other means of
:
Not available.
identification
Product type
:
Powder.
Section 1. Identification
Relevant identified uses of the substance or mixture and uses advised against
Electrostatic coating for use in industrial plants
Supplier's details : AkzoNobel (China) Investment Co., Ltd. 22F, Eco City, No. 1788 West
Nan Jing Road, Shanghai, 200040, P.R. China Tel: +86 21 22205535
Emergency telephone : +86 532 83889090 (24 hour) – For Mandarin only
number (with hours of
operation)
Section 2. Hazards identification
Classification of the : ACUTE TOXICITY: ORAL - Category 5 SKIN
substance or mixture CORROSION/IRRITATION - Category 3
GHS label elements
Signal word : Warning
Hazard statements : May be harmful if swallowed.
Causes mild skin irritation.
Precautionary statements
Prevention : Not applicable.
Response : IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. If skin
Storage : Not applicable.
Disposal : Not applicable.
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 1 / 11
irritation occurs: Get medical attention.
Other hazards which do not : Fine dust clouds may form explosive mixtures with air. Handling and/or processing
Substance/mixture
:
Mixture
Other means of
:
Not available.
identification
Ingredient name
%
CAS number
titanium dioxide
10 - 20
13463-67-7
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
2.5 - 10
2451-62-9
Eye contact
:
Immediately flush eyes with plenty of water, occasionally lifting the upper and
lower eyelids. Check for and remove any contact lenses. Continue to rinse for
at least 10 minutes. If irritation persists, get medical attention.
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention
if adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation
of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact
:
Flush contaminated skin with plenty of water. Remove contaminated clothing
and shoes. Continue to rinse for at least 10 minutes. Get medical attention if
adverse health effects persist or are severe. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Ingestion
:
Wash out mouth with water. Remove dentures if any. Remove victim to fresh
air and keep at rest in a position comfortable for breathing. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do
not induce vomiting unless directed to do so by medical personnel. If
result in classification of this material may generate a dust which can cause mechanical irritation of the eyes, skin,
nose and throat.
Section 3. Composition/information on ingredients
CAS number/other identifiers
CAS number : Not applicable.
EC number : Mixture.
Product code : Not available.
There are no additional ingredients present which, within the current knowledge of the
supplier and in the concentrations applicable, are classified as hazardous to health or the
environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First-aid measures
Description of necessary first aid measures
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 2 / 11
vomiting occurs, the head should be kept low so that vomit does not enter the
Eye contact
:
Causes eye irritation.
Inhalation
:
Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the nose, throat and lungs. Exposure to
decomposition products may cause a health hazard. Serious effects may be
delayed following exposure.
Skin contact
:
Causes mild skin irritation.
Ingestion
:
May be harmful if swallowed. Irritating to mouth, throat and stomach.
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation
:
Adverse symptoms may include the following:
respiratory tract irritation coughing
Skin contact
:
Adverse symptoms may include the following:
irritation
redness
Ingestion
:
No specific data.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be
delayed. The exposed person may need to be kept under medical surveillance for
48 hours.
Specific treatments
:
No specific treatment.
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. it
may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation.
Extinguishing media
Suitable extinguishing
media
Unsuitable extinguishing
media
:
:
Use dry chemical powder.
Do not use water jet.
Specific hazards arising
from the chemical
:
Fine dust clouds may form explosive mixtures with air.
lungs. Get medical attention if adverse health effects persist or are severe. If
necessary, call a poison center or physician. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a
collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed Potential acute health effects
Over-exposure signs/symptoms
Indication of immediate medical attention and special treatment needed, if necessary
See toxicological information (Section 11)
Section 5. Fire-fighting measures
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Hazardous thermal : Decomposition products may include the following materials:
Small spill
:
Move containers from spill area. Use spark-proof tools and explosion-proof
equipment. Avoid dust generation. Using a vacuum with HEPA filter will
reduce dust dispersal. Place spilled material in a designated, labeled waste
container. Dispose of via a licensed waste disposal contractor.
Large spill
:
Move containers from spill area. Use spark-proof tools and explosion-proof
equipment. Approach the release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Avoid dust generation. Do not
dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a
closed, labeled waste container. Avoid creating dusty conditions and prevent
wind dispersal. Dispose of via a licensed waste disposal contractor. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the
for fire-fighters incident if there is a fire. No action shall be taken involving any personal risk
or without suitable training. Move containers from fire area if this can be
done without risk. Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable
personnel training. Evacuate surrounding areas. Keep unnecessary and unprotected
personnel from entering. Do not touch or walk through spilt material. Shut
off all ignition sources. No flares, smoking or flames in hazard area. Avoid
breathing dust. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal
protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also
the information in "For non-emergency personnel".
Environmental precautions : Avoid dispersal of spilt material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 4 / 11
Section 7. Handling and storage
Ingredient name
Exposure limits
titanium dioxide
1,3,5-tris(oxiranylmethyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
GBZ-2 (China, 4/2007). PC-TWA: 8
mg/m³ 8 hours. Form: dust ACGIH TLV
(United States, 3/2012). TWA: 0.05
mg/m³ 8 hours.
Appropriate engineering
controls
:
Use only with adequate ventilation. If user operations generate dust, fumes, gas,
vapour or mist, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep
gas, vapour or dust concentrations below any lower explosive limits. Use
explosion-proof ventilation equipment.
Environmental
exposure
Controls
:
Emissions from ventilation or work process equipment should be checked to
ensure they comply with the requirements of environmental protection legislation.
In some cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid breathing dust. Avoid the creation
of dust when handling and avoid all possible sources of ignition (spark or flame).
Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Electrical equipment and lighting should be protected to appropriate standards to
prevent dust coming into contact with hot surfaces, sparks or other ignition sources.
Take precautionary measures against electrostatic discharges. To avoid fire or
explosion, dissipate static electricity during transfer by earthing and bonding containers
and equipment before transferring material. Empty containers retain product residue
and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
Conditions for safe : Store in accordance with local regulations. Store in a segregated and approved area.
storage, including any Store in original container protected from direct sunlight in a dry, cool and
incompatibilities well-ventilated area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store
in unlabelled containers. Use appropriate containment to avoid environmental
contamination.
Section 8. Exposure controls/personal protection
Control parameters Occupational exposure limits
Individual protection measures
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 5 / 11
Hygiene measures
:
Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated
clothing. Wash contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Eye/face protection
:
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles. If operating conditions cause high dust concentrations to be produced,
use dust goggles.
Skin protection
Hand protection
:
Chemical-resistant, impervious gloves complying with an approved standard
should be worn at all times when handling chemical products if a risk assessment
indicates this is necessary. Considering the parameters specified by the glove
manufacturer, check during use that the gloves are still retaining their protective
properties. It should be noted that the time to breakthrough for any glove material
may be different for different glove manufacturers. In the case of mixtures,
consisting of several substances, the protection time of the gloves cannot be
accurately estimated.
Body protection
:
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection
:
Use a properly fitted, particulate filter respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection
must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator.
Appearance
Physical state
:
Solid. [Powder.]
Colour
:
Various
Odour
:
Odourless.
pH
:
Not applicable.
Flash point
:
Closed cup: Not applicable.
Lower and upper
explosive
:
20 - 70 g/m3
(flammable) limits
Vapour density
:
Not available.
Relative density
:
1.2 to 1.9 [ISO 8130-2/-3]
Solubility
:
Insoluble in the following materials: cold water and hot
water.
Solubility in water
:
Not available.
Auto-ignition temperature
:
450 to 600°C (842 to 1112°F)
Section 9. Physical and chemical properties
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 6 / 11
Section 10. Stability and reactivity
Reactivity
:
No specific test data related to reactivity available for this product or its
ingredients.
Chemical stability
:
The product is stable.
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid
:
Avoid the creation of dust when handling and avoid all possible sources of
ignition (spark or flame). Take precautionary measures against electrostatic
discharges. To avoid fire or explosion, dissipate static electricity during transfer
by earthing and bonding containers and equipment before transferring material.
Prevent dust accumulation.
Incompatible materials
:
Reactive or incompatible with the following materials: oxidizing materials
Hazardous
decomposition products
:
Under normal conditions of storage and use, hazardous decomposition products
should not be produced.
Product/ingredient name
Result
Species
Dose
Exposure
titanium dioxide
LC50 Inhalation Dusts and
mists
Rat
>5 mg/l
4 hours
LD50 Dermal
Rabbit
>5000
mg/kg
-
LD50 Oral
Rat
>5000
mg/kg
-
1,3,5-tris(oxiranylmethyl)-1,3,
LD50 Dermal
Rabbit
>2000
mg/kg
-
5-triazine-2,4,6(1H,3H,5H)
trione
LD50 Oral
Rat
188 mg/kg
-
Irritation/Corrosion
Product/ingredient name
Result
Species
Score
Exposure
Observation
titanium dioxide
Skin - Mild
irritant
Human
-
72 hours
300
-
Micrograms
Intermittent
1,3,5-tris(oxiranylmethyl)-1,3,
Eyes Severe
irritant
Rabbit
-
100
5-triazine-2,4,6(1H,3H,5H)
milligrams
trione
Sensitisation
Not available.
Section 11. Toxicological information
Information on toxicological effects Acute toxicity
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 7 / 11
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Information on the likely
:
Not available.
routes of exposure
Potential acute health
effects
Eye contact
:
Causes eye irritation.
Inhalation
:
Exposure to airborne concentrations above statutory or recommended exposure
limits may cause irritation of the nose, throat and lungs. Exposure to
decomposition products may cause a health hazard. Serious effects may be
delayed following exposure.
Skin contact
:
Causes mild skin irritation.
Ingestion
:
May be harmful if swallowed. Irritating to mouth, throat and stomach.
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation
:
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact
:
Adverse symptoms may include the following:
irritation
redness
Ingestion
:
No specific data.
Short term exposure
Potential immediate
:
Not available.
effects
Potential delayed effects
:
Not available.
Long term exposure
Potential immediate
:
Not available.
effects
Potential delayed effects
:
Not available.
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Symptoms related to the physical, chemical and toxicological characteristics
Delayed and immediate effects and also chronic effects from short and long term exposure
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 8 / 11
Potential chronic health effects
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
No known significant effects or critical hazards.
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Route
ATE value
Oral
4476.2 mg/kg
Dermal
59523.8 mg/kg
Product/ingredient name
Result
Species
Exposure
1,3,5-tris(oxiranylmethyl)-1,3,
5-triazine-2,4,6(1H,3H,5H)trione
Acute EC50 29 mg/l Fresh
water
Algae
72 hours
Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
1,3,5-tris(oxiranylmethyl)-1,3,
5-triazine-2,4,6(1H,3H,5H)trione
- - Not readily
Bioaccumulative potential
Not available.
Mobility in soil
Soil/water partition
coefficient (KOC)
:
Not available.
Other adverse effects
:
No known significant effects or critical
hazards.
Not available.
General : Repeated or prolonged inhalation of dust may lead to chronic respiratory irritation.
Numerical measures of toxicity Acute toxicity estimates
Section 12. Ecological information
Toxicity
Persistence/degradability
Not available.
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 9 / 11
Section 13. Disposal considerations
China
UN
IMDG
IATA
UN number
Not regulated.
Not regulated.
Not regulated.
Not regulated.
UN proper
shipping name
Not regulated.
Not regulated.
Not regulated.
Not regulated.
Transport
hazard class(es)
Not regulated.
Not regulated.
Not regulated.
Not regulated.
Packing group
- - -
-
Environmental
hazards
No.
No.
No.
No.
Additional
information
- - -
-
Safety, health and
:
No known specific national and/or regional regulations applicable to this product
environmental
regulations
(including its ingredients).
specific for the product
China inventory (IECSC)
:
Not determined.
Disposal methods : The generation of waste should be avoided or minimised wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Avoid dispersal of spilt material and runoff
and contact with soil, waterways, drains and sewers.
Section 14. Transport information
Special precautions for user : Transport within user’s premises: always transport in closed
containers that are upright and secure. Ensure that persons
transporting the product know what to do in the event of an
accident or spillage.
Section 15. Regulatory information
List of Goods banned for Importing
None of the components are listed.
List of Goods banned for Exporting
None of the components are listed.
List of Toxic Chemicals Severely Restricted for Importing & Exporting by China
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 10 / 11
None of the components are listed.
History
Date of printing
:
26/3/2014.
Date of issue/Date of
:
26/3/2014
revision
Date of previous issue
:
26/3/2014.
Version
:
2
Key to abbreviations
:
ADN = European Provisions concerning the International Carriage of Dangerous
Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
RID = The Regulations concerning the International Carriage of Dangerous
Goods
by Rail
UN = United Nations
References
:
Not available.
Section 16. Other information
Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither
the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for
the accuracy or completeness of the information contained herein. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.
Version : 2 Date of issue/Date of revision : 3 / 26 / 2014 page 11 / 11
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