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SAFETY DATA SHEET
Issuing Date January 5, 2015
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product identifier
Product Name Clorox Commercial Solutions® Heavy Duty Liquid-Plum
Other means of identification
Synonyms
Recommended use of the chemical and restrictions on use
Recommended use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Address
Clorox Professional Products Company
1221 Broadway
Oakland, CA 94612
Phone: 1-510-271-7000
Emergency telephone number
Emergency Phone Numbers
None
Drain cleaner/opener
No information available
For Medical Emergencies, call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
Revision Date July 5, 2015
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2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
GHS Label elements, including precautionary statements
Emergency Overview
Signal word Danger
Hazard Statements
Causes severe skin burns and eye damage
Causes serious eye damage
Appearance Clear, pale yellow
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling.
Wear protective gloves, protective clothing, face protection, and eye protection such as safety glasses.
Precautionary Statements - Response
Immediately call a poison center or doctor.
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water.
Wash contaminated clothing before reuse.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Specific treatment (see supplemental first aid instructions on this label).
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Precautionary Statements - Storage
Store locked up.
Precautionary Statements - Disposal
Dispose of contents in accordance with all applicable federal, state, and local regulations.
Hazards not otherwise classified (HNOC)
lthough not expected, heart conditions or chronic respiratory problems such as asthma, chronic bronchitis, or obstructive lun g
disease may be aggravated by exposure to high concentrations of vapor or mist.
Physical State Viscous liquid
Odor Bleach
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Unknown Toxicity
Not applicable.
Other information
Very toxic to aquatic life with long lasting effects.
Keep children away from basins containing this product.
Do not use with a plunger or in toilets.
Interactions with Other Chemicals
Reacts with other household chemicals such as ammonia, toilet bowl clea ners, acids, and non-Liqu id-Plumr® drain openers to produce
hazardous gases, such a s chlo rine and other chlorinated compounds.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight % Trade Secret
Sodium hypochlorite 7681-52-9 3 - 7 *
Sodium hydroxide 1310-73-2 1 - 2.5 *
* The exact percentage (concentration) of composition has been withheld as a trade secr et.
4. FIRST AID MEASURES
First aid measures
General Advice
Eye Contact
Skin Contact
Inhalation
Ingestion
Protection of First-aiders
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Effects
Indication of any immediate medical attention and special treatment need ed
Notes to Physician
Show this safety data sheet to the doctor in attendance.
Flush immediately with water for at least 15 minutes. If wearing contact lenses, remove afte
first 5 minutes. Call a doctor or poison control center immediately.
Remove contaminated clothing. Wash immediately with water. Call a doctor or poison
control center immediately.
Move to fresh air. If breathing is affected, call a doctor.
Drink a glassful of water. DO NOT induce vomiting unless told to do so by a poison control
center or doctor. Call a doctor or poison control center immediately.
void contact with skin, eyes, and clothing. Use personal protective equipment as required.
Wear personal protective clothing (see section 8).
Burning of eyes and skin.
Treat symptomatically. Use of gastric lavage or emesis is contraindicated.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
This product causes burns to eyes, skin, and mucous membranes. Thermal decomposition can release sodium chlorate and
irritating gases and vapors.
Explosion Data
Sensitivity to Mechanical Impact
None.
Sensitivity to Static Discharge
None.
Protective equipment and precautions for firefighters
s in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective
gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
void contact with eyes, skin, and clothing. Ensure adequate ventilation. Use personal
protective equipment as required. For spi lls o f multiple produ cts, responders should evaluate
the MSDSs of the products for incompatibility with sodium hypochlorite. Breathing protection
should be worn in enclose d and/or poorly-ventilated areas until hazard assessment is
complete.
Other Information
Refer to protective measures listed in Sections 7 and 8.
Environmental precautions
Environmental Precautions
See Section 12 for ecological Information.
Methods and material for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up
bsorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Conditions for safe storage, including any incompatibilities
Storage
Incompatible Products
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes, and clothing. Do not eat, drink, or smoke when using this product.
Keep containers tightly closed in a dry, cool, and well-ventilated place.
mmonia, toilet bowl cleane rs, acids, and non-Liquid-Plumr® drain openers.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Sodium hypochlorite
7681-52-9
Sodium hydroxide
1310-73-2
GIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health
dministration - Permissible Exposure Limits. NI OSH IDLH: Immediately Dangerous to Life or Health.
Appropriate engineering controls
None None None
3
Ceiling: 2 mg/m
3
TWA: 2 mg/m3
IDLH: 10 mg/m
Ceiling: 2 mg/m
3
Engineering Measures
Individual protection measures, such as personal protective equipment
Showers
Eyewash stations
Ventilation systems
Eye/Face Protection
If splashes are likely to occur: Wear safety glasses with side shields (or goggles) or face
shield.
Skin and Body Protection
Wear rubber or neoprene gloves and protective clothing such as long-sle eved shirt.
Respiratory Protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
Hygiene Measures
Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged
periods. Remove and wash contaminated clothing before re-use. Do not eat, drink, or
smoke when using this product.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Physical and Chemical Properties
Physical State
Appearance
Color
Viscous liquid
Clear
Pale yellow
Odor
Odor Threshold
Bleach
No information available
Property
pH
Melting/freezing point
Boiling point / boiling range
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
Upper flammability limit
Lower flammability limit
apor pressure
apor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive Properties
Oxidizing Properties
alues
~13
No data available
No data available
Not flammable
No data available
No data available
No data available
No data available
No data available
No data available
~1.1
Soluble in water
No data available
No data available
No data available
No data available
No data available
No data available
Not explosive
No data available
Remarks/ Method
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
None known
Other Information
Softening Point
OC Content (%)
Particle Size
Particle Size Distribution
No data available
No data available
No data available
No data available
10. STABILITY AND REACTIVITY
Reactivity
Reacts with other household chemicals such as ammonia, toile t bowl cleaners, acids, and non-Liquid -Plumr® drain openers to produce
hazardous gases, such a s chlo rine and other chlorinated compounds.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
None known based on information supplied.
Incompatible materials
mmonia, toilet bowl cleane rs, acids, and non-Liquid-Plumr® drain openers.
Hazardous Decomposition Products
None known based on information supplied.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye Contact
Skin Contact
Ingestion
Component Information
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Sodium hypochlorite
7681-52-9
Sodium hydroxide
1310-73-2
Information on toxicological effects
Symptoms
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
Sodium hypochlorite
7681-52-9
IARC (International Agency for Research on Cancer)
Group 3 - Not Classifiable as to Carcinogenicity in Humans
Reproductive Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
Target Organ Effects
Aspiration Hazard
.
Exposure to vapor or mist may irritate respiratory tract and cause coughing. Inhalation o
high concentrations may cause pulmonary edema.
Corrosive. May cause severe damage to eyes.
May cause severe irritation to skin. Prolonged contact may cause burns to skin.
Ingestion may cause burns to gastrointestinal tract and respiratory tract, nausea, vomiting,
and diarrhea.
8200 mg/kg (Rat) >10000 mg/kg (Rabbit) -
- 1350 mg/kg (Rabbit) -
May cause redness and tearing of the eyes. May cause burns to eyes. May cause redness
or burns to skin. Inhalation may cause coughing.
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
- Group 3 - -
No information available.
No information available.
No information available.
Carcinogenic potential is unknown.
Respiratory system, eyes, skin, gastrointestinal tract (GI).
No information available.
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Numerical measures of toxicity - Product Information
The following values are calculated based on chapter 3.1 of the GHS document
ATEmix (oral)
45 g/kg
ATEmix (dermal)
77 g/kg (ATE)
ATEmix (inhalation-dust/mist)
33 mg/L
12. ECOLOGICAL INFORMATION
Ecotoxicity
Very toxic to aquatic life with long lasting effects.
Persistence and Degradability
No information available.
Bioaccumulation
No information available.
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Disposal methods
Dispose of in accordance with all applicable federal, state, and local regulations.
Contaminated Packaging
Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local re gulations.
14. TRANSPORT INFORMATION
DOT
Not restricted.
TDG
ICAO
IAT
IMDG/IMO
Not restricted for road or rail.
Not restricted, as per Special Provision A197, Environmentally Hazardous Substance
exception.
Not restricted, as per Special Provision A197, Environmentally Hazardous Substance
exception.
Not restricted, as per IMDG Code 2.10.2.7, Marine Pollutant exception.
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15. REGULATORY INFORMATION
Chemical Inventories
TSCA
DSL/NDSL
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and
40 CFR 122.42)
Chemical Name
Sodium hypochlorite
7681-52-9
Sodium hydroxide
1310-73-2
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
CWA - Reportable
Chemical Name Hazardous Substances RQs
Sodium hypochlorite
7681-52-9
Sodium hydroxide
1310-73-2
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Sodium hypochlorite
7681-52-9
Sodium hydroxide
1310-73-2
ll components of this product are either on the TSCA 8(b) Inventory or otherwise exempt
from listing.
ll components are on the DSL or NDSL.
Yes
No
No
No
No
Quantities
100 lb
1000 lb
100 lb
1000 lb
CWA - Toxic Pollutants CWA - Priority Pollutants
Extremely Hazardous Substances
RQs
-
-
CWA - Hazardous
Substances
RQ
RQ 100 lb final RQ
RQ 45.4 kg final RQ
RQ 1000 lb final RQ
RQ 454 kg final RQ
X X X X
X X X X
X
X
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International Regulations
Canada
WHMIS Hazard Class
E - Corrosive material
16. OTHER INFORMATION
NFPA
HMIS
Prepared By
Revision Date
Revision Note
Reference
General Disclaime
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The in formation given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal, and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Health Hazard 3 Flammability 0
Health Hazard 3 Flammability 0
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
July 5, 2015
Revision Section 14.
1086638/51620001.002
End of Safety Data Sheet
Instability 0
Physical Hazard 0 Personal Protection B
Physical and Chemical Hazards -
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