Datasheet LTC1325 Datasheet (LINEAR TECHNOLOGY)

Application Note 64
Using the LTC1325 Battery Management IC
Anthony Ng, Peter Schwartz, Robert Reay, Richard Markell
INTRODUCTION
August 1996
For a variety of reasons, it is desirable to charge batteries as rapidly as possible. At the same time, overcharging must be limited to prolong battery life. Such limitation of overcharging depends on factors such as the choice of charge termination technique and the use of multi-rate/ multi-stage charging schemes. The majority of battery charger ICs available today lock the user into one fixed charging regimen, with at best a limited number of customization options to suit a variety of application needs or battery types. The LTC®1325 addresses these short­comings by providing the user with all the functional blocks needed to implement a simple but highly flexible battery charger (see Figure 1) which not only addresses the issue of charging batteries but also those of battery conditioning and capacity monitoring. A microprocessor interacts with the LTC1325 through a serial interface to control the operation of its functional blocks, allowing software to expand the scope and flexibility of the charger circuit.
MPU
(e.g. 8051)
p1.4
p1.3 p1.2
REG D
OUT
D
IN
CS
R1 10k 1%
C
REG
+
NOTE 1: THERMISTORS 1 AND 2 ARE PANASONIC ERT-D2FHL103S NTC THERMISTORS OR EQUIVALENT. NOTE 2: V NOTE 3: CHOOSE FOR C/20 TRICKLE CHARGE RATE. NOTE 4: 2.0k AND 47µF FOR COMPATIBILITY WITH LITHIUM-ION AND LEAD-ACID
4.7µF TANT 25V
R2 10k 1%
R3 10k 1%
= 160mV, R
REF
CLK LTF MCV HTF GND
SENSE
VDD
PGATE
DIS
LTC1325
V
BAT
T
BAT
T
AMB
V
IN
SENSE
FILTER
+
= 1 FOR C/3 CHARGE RATE (160mA).
C 1µF
F
R4
7.5k 1%
THERM 2 10k NOTE 1
+ +
This Application Note was written with the following objectives in mind :
• Provide users with an insight into the architecture and operation of the LTC1325.
• Outline basic techniques for charging various battery types.
• Present a variety of useful, tried and tested charging circuits.
• Give an overview of the most common battery types and their characteristics.
• Clarify specialized and application-specific terminol­ogy. Definitions are provided in the text, as well as in Appendix C.
, LTC and LT are registered trademarks of Linear Technology Corporation.
V
DC
16V MAX
C2
+
R
AN64 F01
10µF TANT 25V
500pF
3.3µF (NOTE 4)
COILTRONICS
R5
7.5k 1%
100(NOTE 4)
THERM 1 10k NOTE 1
100
CTX100-1-52
100µH
V
BAT
8 CELLS
500mA HR
C/3 RATE
P1 IRF9531
L1
D1
1N5818
IRF510
R
SENSE
1
TRK
NOTE 3
R
DIS
N1
Figure 1. Complete LTC1325 Battery Management System
AN64-1
Application Note 64
LTC1325 PRIMER
The main features of the LTC1325 may be summarized as follows:
• It has all the functional blocks needed to build a charger: a 10-bit Analog-to-Digital Converter (ADC), fault detec­tion circuitry, a switching regulator controller with a MOSFET driver, a programmable timer, a precision
3.072V regulator for powering external temperature sensors, and a programmable battery voltage divider.
• The functional blocks are placed under the control of an external microprocessor for ready adaptability to different charging algorithms, battery chemistries, or charge rates.
• Communication with the microprocessor is via a simple serial interface, configurable for 3-wire or 4-wire opera­tion.
• It has autonomous fault detection circuitry to protect the battery against temperature or voltage extremes.
• In addition to charging, the part can discharge batteries for battery conditioning purposes.
• It includes on-chip circuitry for an accurate battery capacity monitor (Gas Gauge).
• It charges batteries using a switching buck regulator for highest efficiency and lowest power dissipation.
• The wide supply voltage range (VDD) of 4.5V to 16V allows the battery charger to be powered from the charging supply while charging batteries of up to 8 cells in series.
• It can charge batteries which require charging voltages greater than VDD.
Charging Circuit
Unlike most other charger ICs which employ a linear regulator, the LTC1325 charges batteries using a switch­ing buck regulator. This approach simultaneously maxi­mizes efficiency and minimizes power dissipation. The only external power components needed are an inductor, a P-channel MOSFET switch, a sense resistor and a catch diode (see Figure 1). An internal, programmable battery voltage divider which accommodates 1 to 16 cells re­moves the need for an external resistive divider (for batteries with voltages below the maximum VDD of 16V). All the circuits needed for controlling the loop are inte­grated on-chip and no external ICs are required. The LTC1325 operates from 4.5V to 16V so that it can be powered directly from the charging supply. The wide supply range makes it possible to charge up to 8 cells without the need for an external regulator to drop the charging supply down to the supply range of the LTC1325. These features make the LTC1325 easy to use. When charging is completed and the charging supply is re­moved, the chip does not load down other system sup­plies. If the LTC1325 is powered from a system supply, the microprocessor can program it into shutdown mode in which the quiescent current drops to 30µA. In shutdown mode the digital inputs stay alive to await the wake-up signal from the microprocessor.
The buck regulator control circuit maintains the average voltage across the sense resistor (R
SENSE
) at V
DAC
(see Figure 2). In addition, a programmable duty cycle can modulate the P-channel MOSFET driver output (PGATE) to reduce average charging current. The average charging current is given by:
I
CHRG
= V
(duty cycle)/Rsense
DAC
• It can charge batteries from charging supplies greater than VDD.
• A shutdown mode drops the supply current to 30µA.
AN64-2
The microprocessor can set V
to one of four values,
DAC
and the duty cycle to one of five values, giving 20 possible I
values with a single R
CHRG
SENSE
resistor.
Application Note 64
V
DD
16V
111kHz
OSCILLATOR
TO ADC MUX
3
QS
R
CHARGE
DUTY RATIO GENERATOR
ONE SHOT
PGATE
DISCHARGE
GG
R1
S1
C1
S2
+
A2
16pF
+
500k
CL
S3 S4
R2
125k
R
F
1k
A1
+
V
DAC
REG
3.072V
DAC
DIS
SENSE
FILTER
BATTERY
100
500pF
+
CF
1µF
P1 IRF9531
L1
R
SENSE
1
D1 1N5818
NOTE 2
R
TRK
R
DIS
C
10µF
SPLY
AN64 F02
+
2
V
GAS GAUGE (GG)
R0, VR1
Figure 2. LTC1325 Charge, Discharge and Gas Gauge Circuit
Charge Termination
Virtually any known charge termination technique can be implemented with the LTC1325. The most common of these are based on battery temperature (T (V
), time (t), ambient temperature (T
CELL
), cell voltage
BAT
), or a com-
AMB
BAT
, T
AMB
and V
. By keeping track of
CELL
elapsed time, the microprocessor has the means to calcu­late all existing termination techniques (including dT dt and d2V
/dt2), and perform averaging to reduce the
BAT
BAT
/
CHIP BOUNDARY
that a single circuit can charge Nickel-Cadmium, Nickel­Metal Hydride, Sealed Lead-Acid, and Lithium-Ion batter­ies. The LTC1325 has an on-chip 10-bit successive ap­proximation ADC with a 5-channel input multiplexer. Three channels are dedicated to T
BAT
, V
and the Gas Gauge
CELL
AMB
or another external sensor. The LTC1325 can be pro­grammed into Idle mode in which the charge loop is turned off. This permits measurements to be made without the switching noise that is present across the battery during charging.
AN64-3
Application Note 64
Fault Protection
The LTC1325 monitors battery temperature, cell voltage and elapsed time for faults and prevents the initiation or the continuation of charging should a fault arise. The fault detection circuit (see Figure 3) consists of comparators which monitor T
BAT
and V
to detect low temperature
CELL
faults (LTF), high temperature faults (HTF), low cell volt­ages (BATR, EDV) and high cell voltages (MCV). The LTF, HTF and MCV thresholds are set by an external resistor divider (R1 to R4) to maximize flexibility. The LTC1325 also includes a timer that permits the microprocessor to set charging time before a timer fault occurs to one of eight values: 5, 10, 20, 40, 80, 160, 320 minutes or no time-out. Selecting “no time-out” disables timer faults (the time-out period is in effect set to infinity).
V
DD
+
BATP
MCV
1.6V
+
C1
BATTERY
+
C2
DIVIDER
3.072V
LINEAR
REGULATOR
REG
Battery Conditioning
Under some operating or storage conditions, certain bat­tery types (most notably NiCd) lose their full capacity. It is often necessary to subject such batteries to deep dis­charge and charge cycles to restore the lost capacity. The LTC1325 can be programmed into Discharge mode in which it automatically discharges each cell to 0.9V. This voltage is defined as the End-of-Discharge Voltage (EDV). Fault protection remains active in Discharge mode to protect the battery against temperature extremes (LTF, HTF) and to detect the EDV discharge termination point.
V
DD
R
REG
V
BAT
MCV
TRK
R1
R2
SENSE
+
C3EDV
900mV
+
C4BATR
100mV
C5HTF
+
T
HTF
BAT
+
C6LTF
LTF
Figure 3. LTC1325 Fault Detection Circuitry
AN64 • F03
R3 R
R4 R
L
T
AN64-4
Application Note 64
Capacity Monitoring
and ground so that the load
BAT
current passes through the sense resistor, producing a negative voltage at the Sense pin. The Sense pin voltage is filtered by a 1k × CF lowpass filter and multiplied by a gain of –4 via amplifier A1. The output of A1 is converted by the ADC whenever the gas gauge channel is selected by the microprocessor. By accumulating gas gauge mea­surements over time, the microprocessor can determine how much charge has left the battery and what capacity remains.
APPLICATIONS CIRCUITS
Charging Nickel Cadmium and Nickel Metal Hydride Batteries
It is desirable to charge batteries as fully and rapidly as possible. At the same time it is necessary to limit over­charging, which can adversely affect battery life. To meet these requirements, multi-stage charging algorithms are recommended for NiCd and NiMH batteries. Multi-stage charging algorithms consist of 2 or 3 stages:
2-Stage: Fast Charge
Trickle Charge
3-Stage: Fast Charge
Top-Off Charge Trickle Charge
During Fast Charge, the battery is charged at the maximum permitted rate to near full capacity. In Top-Off the battery is charged at a lower rate to bring it to full capacity thus minimizing overcharge. Finally, during Trickle Charge, the battery is charged at a rate that just compensates for self-
discharge to maintain it at full capacity. Recommenda­tions of the battery manufacturer determine which algo­rithm to use. In general, the best way to limit overcharge is to use a primary charge termination technique and several secondary techniques for redundancy. Regardless of the algorithm, the basic circuit to charge up to 8 NiCd or NiMH cells is shown in Figure 1.
Examples of Charging Algorithms
2-Stage NiCd
Fast Charge C/1 rate, –V (15mV) primary termination
Time-out secondary termination (80 minutes)
Trickle Charge C/10 rate, no termination needed
2-Stage NiCd
Fast Charge C/1 rate, TCO (45°C) primary termination
Time-out secondary termination (80 minutes)
Trickle Charge C/10 rate, no termination needed.
3-Stage NiMH
Fast Charge C/1 rate, TCO (10°C) primary termination
Top-Off Charge C/10 until secondary termination at
180 minutes (160 min + 20 min)
Trickle Charge C/40 rate, no termination
3-Stage NiMH
Quick Charge C/3 rate, 120 minute (80 min + 40 min) to
160 minute time-out TCO (40°C) secondary termination
Top-Off Charge C/10 rate until V
Trickle Charge C/40 rate, no termination
CELL
= 1.5V
All these algorithms may be realized with the circuit in Figure 1. Only the software and perhaps some component values change.
AN64-5
Application Note 64
Conditioning Batteries
When overcharged for extended periods of time, some NiCd batteries exhibit what is commonly called the “memory effect,” The voltage per cell drops 150mV which may lead the user to conclude that the battery is at the end of its discharge curve. This condition may be reversed by deeply discharging and recharging the battery. The LTC1325 can be programmed to discharge a battery until its per cell voltage falls below 0.9V (EDV). As shown in Figure 1, the external N-channel MOSFET N1 is turned on to discharge the battery. R current, V
BAT/RDIS
is selected such that the discharge
DIS
, is within the allowable limits set by the battery manufacturer. Discharge currents can be large with high capacity batteries. The power rating of R should be greater than I be terminated to the top of R ground. The former is preferred since the V
DIS
2
× R
. The source of N1 may
DIS
(as in Figure 1) or to
SENSE
BAT
pin moni-
DIS
tors the battery voltage for EDV and not the battery voltage plus the drop across R
. If desired it is possible to
SENSE
adjust the EDV voltage via the internal battery divider setting as outlined in the next section.
Using the End-of-Discharge Voltage Fail-Safe
The LTC1325, when commanded to do so, will discharge a battery until its cell voltage goes below 900mV nominal, at which point an EDV fail-safe occurs and the DIS pin is taken low to stop discharge. This function of the IC is most commonly used for the protection and conditioning of NiCd and NiMH batteries, but may also be used to condi­tion a Lead-Acid battery or to reset the Gas Guage to a known point (remaining battery capacity equals zero) for any battery type. Immediately following discharge, the voltage per cell for NiCd and NiMH batteries will typically “rebound” by 100mV to 200mV. The controlling software will need to take this rebound into account to prevent a possible oscillation in which the ADC would be read, the EDV and fail-safe bits reset, and the battery discharged for a few more seconds before again indicating EDV and stopping the discharge.
If desired, the battery divider can be programmed to divide by a factor that is less than the number of cells in the battery. For example, if the divider is programmed to divide-by-5 when the number of cells in the battery is six, the EDV fault occurs at (5 × 0.9)/6 or 0.75V. Similarly,
programming the divider to divide-by-6 with a three-cell Lead-Acid battery would give an EDV of (6 × 0.9)/3 = 1.8V per cell at termination of discharge.
Operating from Charging Power Supplies of Above 16V
The LTC1325 has a maximum VDD range of 16V. To operate from a higher supply voltage, it is necessary to do two things: add a regulator to drop the higher supply (VDC) down to the supply range of the LTC1325 and add a level shifter between the PGATE pin and the gate of the external P-channel MOSFET. The level shifter ensures that the P-channel MOSFET can be switched off completely. Figure 4 shows a low cost circuit that will charge up to 8 cells from a 25V supply at 160mA. For 2A charge current, L1 and R tively. V
should be changed to 15µH and 0.08 respec-
SENSE
is set to 160mV in both cases for best
DAC
accuracy. The number of cells that can be charged is affected by any series resistance in the charge path. At high charging currents low resistance inter-cell connec­tions such as solder tabs are recommended.
The zener diode D3 is used to drop the 25V VDC down to 16V to serve as VDD supply to the LTC1325. R7 should not be greater than 220. Alternatively, a 3-terminal regulator (such as the LT®1086-12 or LT1085-12) may replace D3, C1 and R7. The regulator output voltage (VDD) fixes the number of cells that can be charged with the circuit to about VDD/VEC where VEC is the maximum cell voltage expected.
When the battery is removed, R towards VDC. D4 acts as a clamp to prevent V
pulls the V
TRK
BAT
BAT
pin
from rising above the VDD supply voltage. D2, C2 and R11 form a simple level shifter. During charging, D2 clamps the voltage at the gate of P1 between V
– VZ and V
DC
+ 0.7V,
DC
where VZ is the reverse breakdown voltage of D2. VZ is selected to limit the VGS of P1 to within its maximum rating. For logic-level P-channel MOSFETs with a maxi­mum VGS of ± 8V, D2 may be a 3.9V zener such as the 1N4730A. For standard MOSFETs (± 20V VGS rating), a 1N4740A 10V zener may be used. When power (VDC) is first applied, VDD takes a finite time to charge up to 16V so that the voltage on the PGATE pin is initially 0 and P1 is turned on. D2 breaks down, charging C2 quickly to one zener drop below VDC. Then as PGATE rises, D2 forward
AN64-6
MPU
(e.g. 8051)
p1.4
p1.3 p1.2
R7
220
1/2W
+
C1
1µF
35V
REG D
OUT
D
IN
CS
R1 10k 1%
C
+
REG
R2
4.7µF
10k
35V
1% R3
10k 1%
NOTE 1: THERMISTORS ARE PANASONIC ERT-D2FHL103S NTC THERMISTORS OR EQUIVALENT.
CLK LTF MCV HTF GND
LTC1325
D3 16V 1N4745A
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V
SENSE
FILTER
   
IN
+ +
C 1µF CER
F
R4
7.5k 1%
10k THERM 2 NOTE 1
3.3µF
500pF
+
D2 10V 1N4740A
C2
0.1µF 35V
R5
7.5k 1%
10k THERM 1 NOTE 1
Application Note 64
V
DC
25V
R11 100k
P1
100µH
COILTRONICS
CTX100-1-52
100
100
IRF9531
D5 1N5818
L1
D1
1N5818
V
BAT
8 CELLS 500mA HR C/3 RATE
R
SENSE
1 1%
R
TRK
487 C/20 TRICKLE
D4 16V 1N4745A
+
AN64 F04
C
SPLY
10µF
Figure 4. Charging from a 25V Supply
biases and the gate of P1 rises to one diode drop above V and P1 shuts off. R11 serves to hold P1 off if the V
DC
DD
supply should go away for some reason. In this situation, it takes several milliseconds for R11 to shut P1 off com­pletely which means that P1, L1 and R to withstand a brief current pulse of (V R is the total of the R
DS(ON)
of P1, R
must be able
SENSE
– V
DC
BAT
and inductor
SENSE
)/R, where
winding resistance. Diode D5 prevents battery discharge if the VDC supply is removed.
Charging “Tall” Batteries (> 8 cells)
To charge more than 8 cells, the charging supply (VDC) must be greater than 16V (assuming 2V per cell at the end of charge). Since VDC is above 16V, a regulator and level shifter are required, as explained in the previous applica­tion. Figure 5 shows a circuit that will charge batteries with more than 8 cells in series. In addition, an external battery divider is added to limit the voltage seen at the V
BAT
pin to below VDD. The values of R8, R9 and R10 are selected such that R10/(R8 + R9 + R10) is the number of cells in the
battery. The battery divider in the LTC1325 is programmed to divide by one. V the charging current is 160mV/R charges the 10 cell 500mA Hr stack at a C/3 rate. R
is programmed for 160mV so that
DAC
or 160mA. This
SENSE
TRK
is selected to trickle charge the battery at C/20. The same circuit will charge batteries at 2A if L1 and R
SENSE
are
changed to 15µH and 0.08 respectively. Without R11 to R14, P2 and A1 in Figure 5, the BATP status
flag will always be high regardless of whether the battery is present or not. It is therefore possible to start the charge loop when the battery is not present. The current through the charge loop will be low (typically in the milliampere range). If this is undesirable, R11 to R14, P2 and A1 may be added to ensure proper operation of the BATP flag. R11 and R12 are selected such that R12/(R11+R12) is the number of cells in the battery. Op amp A1 compares the cell voltage against a threshold set by R13 and R14. When the battery is absent, A1 trips to turn on P2 which then pulls V
up to VDD. This causes the BATP flag to go low
BAT
to indicate the absence of the battery.
AN64-7
Application Note 64
V 25V
DC
MPU
(e.g. 8051)
p1.4
p1.3 p1.2
C
REG
4.7µF
R7
220
C2
1µF 35V
REG D D CS
R1 10k 1%
+
R2 10k 1%
R3 10k 1%
NOTE 1: PANASONIC ERT-D2FHL103S NTC THERMISTORS OR EQUIVALENT.
CLK LTF MCV HTF GND
+
OUT
IN
LTC1325
D4 16V 1N4745A
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V
SENSE
FILTER
1µF
R4
   
IN
C
F
7.5k 1%
THERM 2 NOTE 1
+
R13 10k
R14
5.1k
+
Figure 5. Charging More Than 8 Cells
32V
2
500pF
+
LT1006
A1
P2 BS250
7
4
100
6
3.3µF
+
+
D3 10V 1N4740A
C2
0.1µF 35V
R5
7.5k 1%
THERM 1 NOTE 1
R16 100k
COILTRONICS
CTX100-1-52
100µH
100
P1 IRF9531
D2 1N5818
L1
D1
1N5818
V
BAT
10 CELLS 500mA HR C/3 RATE
R
SENSE
1 
C/20 TRICKLE
R8
11.3k 1%
R9
78.7k 1%
R10 10k 1%
R
TRK
200
1/4W
R11 91k
R12 10k
C
SPLY
10µF
AN64 F05
+
Hardwired Charge Termination Using Thermistors Termination Using Positive Temperature Coefficient
(PTC) Thermistors: The resistance of a PTC thermistor
increases sharply when its temperature rises above a specified setpoint (TS). This rapid change may be ex­ploited to implement hardwired TCO charge termination. In Figure 6, fixed resistor R4 is connected from REG to the T
input, and the PTC thermistor R5 is connected
BAT
between the T
input and Sense. Hence R5 is the
BAT
controlling element of a temperature-dependent voltage divider. The PTC is mounted on the battery to sense its temperature. R4 is selected such that when the battery temperature is below TS, the divider output voltage is between the voltages at the LTF and HTF pins. When the battery temperature rises above TS, the rapid increase in the resistance of the PTC device causes the divider output
(i.e. the voltage at the T
pin) to rise above the voltage
BAT
set by R1, R2 and R3 at the LTF pin. The LTC1325 detects a temperature fail-safe (LTF = 1, FS = 1) and stops charging by taking the PGATE pin to VDD. A typical value for TCO is 45°C. TS and R
THERM1
have typical tolerances of ±5°C and ±40% respectively. The PTC shown in Figure 6 has a TS of 50°C ±5°C, so charging will terminate when the battery temperature reaches a value between 45°C and 55°C. The series resistance of PTC thermistor and R4 should be in the k range to minimize loading on the REG pin of the LTC1325.
In principle, it is possible to implement hardwired TCO termination by replacing R4 with another PTC with a resistance vs temperature characteristic that matches that of R5 as shown in Figure 7. If both PTCs match closely, the divider output will now respond to the difference between
AN64-8
Application Note 64
battery and ambient temperature. In practice, matched PTCs are not generally available as standard items from thermistor manufacturers and are therefore not recom­mended for such use. If hardware TCO termination is desired, standard NTCs such as those matched over a
MPU
(e.g. 8051)
p1.4
p1.3 p1.2
REG D
OUT
R1 
R2
+
C
REG
4.7µF
R3 
R4
D
IN
CS CLK LTF MCV HTF GND
LTC1325
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V SENSE FILTER
   
IN
+ +
C 1µF
F
specified temperature range may be used. With NTCs, the divider output will drop as the battery heats up and when the voltage drops below the voltage at the HTF pin, the LTC1325 will detect a temperature fail-safe (HTF = 1, FS = 1) and terminate charging.
V
DC
16V MAX
P1
D1
R
TRK
AN64 F06
+
C
SPLY
10µF
500pF
R4
100
+
3.3µF
PTC
THERM 1
100
L1
V 8 CELLS MAX
R
SENSE
BAT
MPU
(e.g. 8051)
p1.4
p1.3 p1.2
Figure 6. Hardwired TCO Termination
V
DC
12V
P1
D1
R
TRK
AN64 F07
+
C
SPLY
10µF
LTC1325
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V
SENSE
FILTER
   
IN
+ +
C 1µF
THERM 1
100
+
F
500pF
3.3µF
THERM 2
100
L1
V
BAT
8 CELLS MAX
R
SENSE
REG D
OUT
R1 
R2
+
C
REG
4.7µF
R3 
R4
D
IN
CS CLK LTF MCV HTF GND
Figure 7. Hardwired TCO Termination
AN64-9
Application Note 64
Termination Using Negative Temperature Coefficient (NTC) Thermistor: It is common for the thermistor in the
battery pack to be terminated at the negative terminal of the battery. During charging, the Sense pin will exhibit a switching waveform with peaks of 200mV to 300mV when V
is programmed for 160mV. This waveform appears
DAC
on the T
pin when the thermistor is terminated at the
BAT
negative terminal of the battery. The thermistor slope is typically –30mV/°C, so the switching noise can cause premature fail-safes when the battery temperature is within 10°C of the LTF or HTF trip points. An RC filter (with time constant much greater than the clock period of 10µ s) can be inserted between the T
pin and the output of the
BAT
battery thermistor circuit to prevent false fail-safes.
Disabling Fail-Safes
pin is tied to the
BAT
top of resistor R3. The LTC1325 is made to think that the battery temperature is constant and within the limits set by
the LTF and HTF pins. Similarly, V
may be tied to the
BAT
AMB
and V
IN
channels of the ADC. An external divider (R7, R8) replaces the internal divider connected to the V
channel.
BAT
Gated P-Channel MOSFET Controller
When an external current-limited voltage source is avail­able, and charging currents are low enough that efficiency and heat dissipation are not major concerns, the LTC1325 can be used to turn on a P-channel MOSFET to gate the current into the battery. This circuit makes an inexpensive and effective combination. The battery’s current limit during charging is set by the current limit of the charging power supply VDC . The maximum available current should therefore not exceed the permissible charge rate of the battery. With the LTC1325 V
programmed to the
DAC
160mV setting, and the voltage at the Sense pin below this value, the LTC1325 will hold MOSFET P1 on until charge
MPU
(e.g. 8051)
p1.4
p1.3 p1.2 p1.5
LTC1325
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V
SENSE
FILTER
   
IN
+ +
C 1µF
F
REG D
OUT
D
IN
CS
R1 10k
REG
1%
R2
4.99k 1%
R3
4.99k 1%
R4 10k 1%
+
C
4.7µF 25V
NOTE 1: PANASONIC ERT-D2FHL103S NTC THERMISTOR OR EQUIVALENT. NOTE 2: CHOOSE FOR C/20 TRICKLE CHARGE RATE.
CLK LTF MCV HTF GND
100
500pF
R7
30.1k 1%
R8 10k 1%
Q1 VN2222LL
100µH
COILTRONICS
CTX100-1-52
R9
7.5k 1%
THERM 1 NOTE 1
V
DC
16V MAX
L1
R 1
P1 IRF9531
D1
1N5818
V
BAT
500mA HR
SENSE
R
TRK
NOTE 2
AN64 F08
+
C
SPLY
10µF
AN64-10
Figure 8. Charger with T
BAT
and V
Fail-Safes Disabled
BAT
MPU
(e.g. 8051)
p1.4
p1.3 p1.2
LTC1325
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V
SENSE
FILTER
R4
7.5k 1%
   
IN
+
NTC
THERM 1
NOTE 1
C
F
1µF
REG D
OUT
D
IN
CS
R1 10k
C
REG
4.7µF
1% R2
10k 1%
R3 10k 1%
+
NOTE 1: PANASONIC ERT-D2FHL103S NTC THERMISTOR OR EQUIVALENT. NOTE 2: CHOOSE FOR C/20 TRICKLE CHARGE.
CLK LTF MCV HTF GND
Application Note 64
V
DC
16V MAX
P1 IRF9531
R
TRK
NOTE 2
V
BAT
4 CELLS 500mA HR
R
SENSE
1
AN64 F09
Figure 9. LTC1325 Charger Using an External Constant-Current Supply
is terminated by the microprocessor, or a fail-safe occurs. As shown in Figure 9, the inductor and catch diode that are normally connected to the positive terminal of the battery are not required, as no PWM switching action occurs at the drain of MOSFET P1.
With the wall adapter connected, the current into the battery will always be (I
ADAPTER
– I
EQUIPMENT
). The use of one additional operational amplifier, such as the LT1077, allows monitoring this charging current by integrating the voltage across R
during the charging interval. The
SENSE
result of this integration can then be measured using the LTC1325’s auxiliary ADC input VIN. Combined with the built-in gas gauge function during the discharge interval (via the Sense input), the state of charge of the battery may be reliably determined at any time.
If the battery pack is heavily depleted or is damaged, the wall adapter can still be used to operate the equipment by putting the LTC1325 into Idle mode. Under these condi­tions the battery will receive no charging current (except through the trickle charging resistor, if one is provided). If the gas gauge is not needed, R
can be removed and
SENSE
the Sense pin should be returned to ground.
Constant-Potential Charging (Lead-Acid and Lithium-Ion)
Constant-current charging, which is the technique of choice for NiCd and NiMH batteries, is not recommended for most Lead-Acid or Lithium-Ion applications. Instead, a constant-voltage charging regimen is required, usually with a means of limiting the initial charging current. Such a charging technique is generally referred to as a “Con­stant-Potential” (CP) regimen.
The LTC1325 is at first glance a constant-current part. Such a view of its capabilities, however, is too limited. Its power control section is more completely described as a constant-average-current PWM with both hardware and software feedback. The hardware loop used for current sensing is the Sense input; the software loop, which can be used to control the effective output voltage of an LTC1325 charger circuit, is the microprocessor control routine in conjunction with the ADC and the DAC. Given a suitable output filter (the output inductor and the battery itself), current from the PWM section can be made to produce a current-limited constant voltage at the battery’s terminals. A circuit intended for such CP operation is shown in Figure 10.
AN64-11
Application Note 64
MPU
(e.g.,80C51)
+
C
4.7µF
NOTE 1: PANASONIC TYPE ERT-D2FHL103S NTC THERMISTOR OR EQUIVALENT
REG
R
R
P1.4
P1.3
P1.2
P1.5
MCV1
MCV2
4
DATA 
3
CHIP SELECT
2
CLOCK
5
AUX SHDN
1
REG
2
D
OUT
3
LTC1325
D
R
TF1
R
TF2
R
TF3
IN
4
CS
5
CLK
6
LTF
7
MCV
8
HTF
9
GND
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V SENSE FILTER
IN
1µF
18 17 16 15
14
13
12
11 10
CF
Figure 10. Constant Potential Battery Management System
+
R1
7.5k 1%
THERM 2 NOTE 1
+ +
C
S
500pF
R5 470k
R3
R4
Q1 2N7002
RIN
2k
R
100
CIN 47µF
VDC IN
P1 IRF9Z30
R
R2
7.5k 1%
THERM 1 NOTE 1
S
R
SENSE
62µH
L1
Y
TRK
D1 1N5818
R
DIS
IRF510
+
N1
AN64 F10
C
SPLY
10µF
Batteries that require a CP charging algorithm generally need a rather accurate charging voltage, especially in fast­charge applications. For this reason the LTC1325’s inter­nal battery divider often cannot be used to control the charging voltage, due to its tolerance of ±2% at division ratios other than 1:1. It does, however, remain useful for MCV and/or FEDV detection. For measuring battery volt­age an external resistive divider feeding VIN is recom­mended. The external divider resistors should be chosen such that the voltage at the VIN pin will come as close as possible to the ADC’c full-scale input voltage without exceeding that value; 3.000V maximum is a good choice. Using a near-full-scale input to the ADC improves mea­surement accuracy. To further improve charging voltage accuracy, it’s a good idea to use ±0.1% or ±0.25% tolerance resistors in the battery voltage divider. Under such conditions, the voltage loop error is ideally only the reference error (±0.8%), plus that of the ADC (4 bits out of 1024, or ±0.4%) and of the battery divider (±0.1% or ±0.25%), for a total ±1.3% or ±1.5% error.
“Auxiliary Shutdown” is a static line from the micropro­cessor to a small-signal MOSFET, which prevents the
battery from discharging through the voltage divider string when it is not charging. With the external divider in place, the BATP flag will always be high except when Auxiliary Shutdown is at a logic low and the battery is not installed in the circuit (see “Charging ‘Tall’ Batteries” above). Bat­tery voltage fail-safes will remain operational (assuming that they use the V
input) although it may not be
BAT
possible to make simultaneous use of the MCV and EDV fail-safes with all CP battery types. R
, if needed, main-
TRK
tains the battery in a fully charged condition. A suitable software algorithm to implement a quasi-CP
charger is this:
1. Establish a regular repetition interval for the voltage servo loop. t
values of 10ms to 20ms give good
LOOP
results.
2. Set V
to 160mV at the highest charge rates for best
DAC
resolution. Using a 95% maximum PWM duty cycle [tON/(tON + t I
), where I
MAX
)], R
OFF
is the nominal maximum current to
MAX
chosen as 160mV/(0.95 ×
SENSE
be allowed through the battery. A suitable minimum duty cycle is 10%; beyond such a low duty cycle it is
AN64-12
Application Note 64
usually better to reduce the peak current through the battery (by programming V
) than to reduce the duty
DAC
cycle further.
3. Perform each of the following tasks once each servo loop interval (t
LOOP
): a) Enter Idle mode of operation. b) Read V
CELL
.
c) Adjust the value entered into a timer register (or
a software timer) up or down according to actual V
vs target V
CELL
value is increased. If V
CELL
. If V
is too low, the timer
CELL
is too high, the timer
CELL
value is decreased.
d) The maximum Charge time of the LTC1325 has
been set at 95% of t
; the minimum at 10%.
LOOP
Within that range, the duty cycle at which the loop will operate is set by the timer of 3(c). If the timer’s interval is increased (V each t
during which the LTC1325 is put into
LOOP
too low), the portion of
CELL
Charge mode is increased. If the timer’s interval is decreased (V
is too high), the LTC1325 is com-
CELL
manded into Idle mode for a greater portion of each t
.
LOOP
e) If tON < (0.1 × t
value (note that the V
), switch V
LOOP
to the next lower
DAC
value of 34mV is not used).
DAC
f) Repeat (a) through (e) until the average current into
the battery, or the net duty cycle, drops below a chosen limit. A timer-based secondary cutoff is often recommended for CP chargers.
g) Terminate the software loop with MOSFET P1 in the
“off” state, using R
(if required) to maintain the
TRK
battery’s charge.
A flow chart showing the principals of this voltage servo loop is given in Appendix B, Figures B3a and B3b. Figure B3a shows the “ramp-up” from the point where the charger is first turned on to the maximum charging current required and Figure B3b shows the “taper-down” which simulates the necessary CP charging algorithm. (This algorithm is undergoing refinement at press time. For the latest information on its implementation and optimization, please contact LTC.)
RIN and CIN have greater values in Figure 10 than in most of the circuits in this Application Note. This is because
batteries requiring a CP charge tend to have a significant positive V during the interval in which charging current is flowing through them. The time constant of (RIN × CIN) filters the resulting 10ms to 20ms ripple before it is presented to the V
and VIN pins. If only VIN input will be
BAT
used, RIN may be omitted, CIN may be placed from VIN to ground, and its value can be decreased.
The circuit of Figure 10 has deliberately been generalized to provide flexibility across all common battery types. For applications requiring the support of only specific battery types, or which do not need extensive thermal or other protection mechanisms, various components can be modified or removed to minimize cost and board space.
Overcurrent Protection
Three common scenarios in which battery current can exceed acceptable levels are: accidental shorting of the battery terminals, excessive loads and inserting the bat­tery into the charger in reverse. Battery or charger damage in all three cases can be prevented through the use of a thermal or overcurrent device to limit fault currents. Usually, it is desirable that this device reset itself when the fault goes away. Possible choices are bimetallic (thermo­static) switches and polymer PTC thermistors. The high series resistance of traditional ceramic PTC thermistors, even in the unexcited state, make them unsuitable for this application.
Bimetallic switches operate by sensing battery tempera­ture. By the nature of their operation, these switches cycle on and off as long as the fault remains, causing the battery and all associated components (mechanical as well as electrical) to heat up and cool down repeatedly. Polymer based PTC thermistors such as the Raychem PolySwitch
®
also offer very low series resistance until “tripped,” and have the advantages of a faster response and freedom from thermal cycling.
Polymer PTCs should be chosen such that under normal operation, the average charging current (V
DAC/RSENSE
) is less than the Hold Current rating of the PTC to keep it in the low resistance state. Under fault conditions, the Fuse Current should exceed the Trip Current rating of the fuse. This will cause the fuse’s resistance to increase dramati­cally and reduce the fault current to about V
PolySwitch is a registered trademark of Raychem Corporation.
BAT/RFUSE
(Trip).
AN64-13
Application Note 64
The PolySwitch should ideally be placed between cells in the battery, in close physical contact with one of the cells. In this way the trip point of the device will be reduced as the battery’s temperature increases. Such a configuration provides substantial protection for the battery against shorts across its terminals and from excessive load cur­rents. It will also protect the battery if it is accidentally inserted into the charger in reverse.
Figure 11 shows the fault current path when a battery is inserted into a charger in reverse. Potentially damaging currents may flow through this path since the Sense resistor is usually in the region of 1 or less. A PolySwitch inside the battery pack (as described above), or in series with the Schottky diode, limits fault currents to safe levels. The following points should be noted in choosing the diode and R
SENSE
.
• Normal charging currents should be equal to or less than the holding current rating of the PolySwitch.
• Temperature affects PolySwitch performance. The manufacturer’s data should be consulted for derating factors.
• Initial fault currents will be approximately V
BAT/RSENSE
if the battery is inserted in reverse. This should exceed the trip current rating of the PolySwitch.
• The surge current rating of D1 should exceed the initial fault current of V
BAT/RSENSE
. It may be necessary to confirm the selected diode’s applicability with the manu­facturer of the part.
In addition to the above scenarios, the battery current may exceed acceptable levels when a battery is inserted into a charger which has the charging supply (VDC) turned off. If the VDC supply exhibits a low impedance path to ground when it is turned off, the diode that is intrinsic to the P-channel MOSFET may turn on to form a battery dis­charge path which flows from the battery’s positive termi­nal through the inductor, the MOSFET internal diode, the ground lead and the sense resistor before returning to the negative terminal of the battery. This can be prevented by connecting a Schottky diode between VDC (diode anode) and the source of the P-channel. See the section on “Current Sinking VDC Sources” for more details.
Current-Sinking VDC Sources
In some applications, it may be necessary to add a Schottky rectifier between the VDC supply and the source of MOSFET P1. This rectifier prevents the battery from discharging backwards through MOSFET P1, which could damage P1, L1, or R
. It is required if the following
SENSE
conditions are met:
• The wattage of R
should be high enough to
SENSE
withstand the initial fault currents of V
MPU
(e.g., 8051)
p1.4
p1.3 p1.2
C
REG
4.7µF
R1
R2
R3
+
REG D D CS CLK LTF MCV HTF GND
.
R4
   
+
CF 1µF
THERM 2
+
+
500pF
OUT
IN
LTC1325
BAT/RSENSE
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V
IN
SENSE FILTER
Figure 11. Reversed Battery Protection
3.3µF
IRF9531
R5
100
THERM 1
100
V
DC
12V
P1
D1
R
TRK
L1
+
R
SENSE
FUSE
AN64 F11
C
SPLY
10µF
AN64-14
Application Note 64
• The voltage of the battery being charged can exceed that of the supply.
• The VDC supply can sink current when it is at a lower voltage than the battery being charged.
Most switching power supplies, such as those used for AC adapter and battery charger supplies in portable comput­ers, have a very small reverse leakage current––several milliamperes at most. These would not generally need the additional Schottky rectifier. Two examples of situations where the rectifier is necessary are:
• Charging a 7.2V or greater battery from a 12V car battery using the cigarette lighter socket. Under cold­cranking conditions the 12V nominal battery drops to 6V to 7V and an automobile’s wiring will allow the starter motor to pull current back out of the lighter socket.
• Bench-top testing. Many power supplies have internal protection circuitry which will sink current from the load rather than allow a sourcing load, such as a charged battery, to force current indiscriminately into the supply’s output. Also, any supply with a crowbar represents a possible current-sinking power supply.
Figure 12 depicts a basic charger circuit and shows the proper placement of the Schottky rectifier DIN.
CONCLUSION
MPU
(e.g., 8051)
p1.4
p1.3 p1.2
V
DC
D
(20V SCHOTTKY)
IN
P1
IRF9531
LTC1325
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V
SENSE
FILTER
   
IN
+ +
C 1µF
F
R5
THERM 2
500pF
R6
100
+
THERM 1
3.3µF
100
DC
REG D
OUT
R1
C
REG
4.7µF
R2
R3
R4
+
D
IN
CS CLK LTF MCV HTF GND
Figure 12. Protection Against Discharging Through V
L1
R
D1
SENSE
FUSE
R
TRK
AN64 F012
+
C
SPLY
10µF
AN64-15
Application Note 64
APPENDIX A An Overview of Battery Types, Terminology, and
Techniques
Table A1. Battery Type Characteristics
BATTERY SEALED LITHIUM­CHARACTERISTICS LEAD-ACID NiCd NiMH ION
Energy Density 30 40 60 90 W-h/kg
Energy Density 60 100 140 210 W-h/liter
Cell Voltage (V) 2.0 1.2 1.2 4.20 Max
3.60 Avg
2.50 Min
Charging Method Constant Constant Constant Constant
Potential Current Current Potential
Dicharge Profile Mildly Flat Flat Sloping
Sloping
#Charge/Discharge 300 >500 >500 500 to Cycles* 1000
Self-Discharge 3%/MO 15%/MO 20%/MO 6%/MO Internal Resistance Low Lowest Moderate Highest Discharge Rate** > 4C > 10C 3C < 2C
* Until 80% of rated capacity is available upon discharge.
** C is the capacity rating of the battery in Ampere-Hours.
Battery recharge times generally break down into several groups. The most common of these are the “standard­charge,” suitable for overnight applications (typically re­quiring 16 hours) and the “fast-charge” (typically two hours or less). Between the two is the “quick-charge,” which is in many respects akin to a standard-charge but requires a useably shorter interval (about five hours). Examples of standard-charge applications are cordless telephones and UPS systems for small computers. Quick­charge batteries are commonly found in devices which will see brief but significant power drain several times daily, such as cellular phones. Laptop computers and cordless tools are excellent locations for fast-charge systems. In these and other fast-charge uses there is a high average drain on the battery, and the product’s value is determined in large part by the availability of battery power upon demand. The LTC1325 forms a comprehensive core for battery management systems operating at any of these charge rates; all that need be changed are a few external components and the microprocessor algorithm used to control the charge cycle. Only batteries designed and
rated for fast-charge should be subjected to a fast-
AN64-16
Application Note 64
charge regimen. Similarly, only batteries rated for quick­charge should be subjected to quick-charging conditions.
Using Nickel-Cadmium Batteries
Nickel-Cadmium batteries, in various forms, have been in use for over 50 years. During that time they have evolved from expensive, special purpose devices to the battery of choice for most portable equipment. The availability of inexpensive sealed cells, with ongoing improvements in energy density and cycle life, have been the driving forces for this acceptance. The LTC1325 adds to this the ability to easily implement fast-charge routines, gas gauge algo­rithms and/or switch mode constant current sources, all using very little system overhead and printed circuit board space.
• Special purpose batteries are available with extended operating temperature ranges.
The “cons”:
• Cadmium is commonly considered an environmentally hazardous material. Nickel is also coming under envi­ronmental scrutiny.
• NiCd cells have a significant self-discharge rate (0.5%/ day at room temperature).
Nickel-Cadmium Standard-Charge
• Simplest charging algorithm.
• Least expensive charge termination techniques.
• Small power supply required to provide the charging current.
• Small charging circuit power components.
• Low overall charging system power dissipation.
A standard-charge is relatively straightforward to imple­ment. In “cookbook” form, such a charge requires:
A quick run-down of the pros and cons of Nickel-Cadmium batteries:
The “pros”:
• Good energy density, both by weight and by volume, relative to competing technologies.
• Acceptable charging rates range from 0.1C to 2C and beyond.
• Most NiCd cells can accept a continuous overcharge current of 0.1C.
• A very flat discharge profile.
• The lowest cell impedance of the major battery tech­nologies.
• Well understood and documented electrical behavior and electrochemistry.
• Cells and batteries are available in a variety of sizes from a number of vendors.
• Charging Current: 0.1C.
• Required Charging Voltage: 1.60V/cell or greater, plus charger overhead.
• Charging Temperature Range: 0°C to 45°C.
• Charging Time: 16 hours.
• Charge Termination Method: None required.
• Secondary Charge Termination Methods: None required.
• Special issues which may require further consideration are: wide temperature range charging, wide tempera­ture range discharging and accurate gas gauging at temperature extremes.
A charging current of 0.1C, fed to the battery for 16 hours, will deliver (16 hours × 0.1C) = 160% of standard capacity to the battery. At temperatures between 0°C and 25°C, the resulting 60% overcharge is adequate to ensure that the battery is returned to 100% of its standard capacity. Once
AN64-17
Application Note 64
the cells in the battery reach their actual capacity for the operating temperature, mild gassing will occur, but not enough to cause venting or other cell damage. Since most NiCd batteries will accept a continuous 0.1C charge at any case temperature between 0°C and 50°C, charge termina­tion per se is usually not required. For specialized applica­tions, extended temperature range batteries are available which can be charged at 70°C. Charging at temperatures below 0°C is also possible if the charge current is “throttled back” as the battery temperature decreases. The charging current under such conditions should linearly decrease from 0.1C at 0°C to zero current at –15°C to –25°C. In wide temperature range applications, the use of a battery (or ambient) temperature sensor in conjunction with the LTC1325 is an excellent way to provide positive control of battery charging current versus temperature, thereby ex­tending battery life.
The charge acceptance of NiCd batteries is reduced signifi­cantly at temperatures above 40°C. This effect is only marginally mitigated by longer charge times, and should be taken into account if gas gauging is to be done over extended temperature ranges. By way of example, a bat­tery that can be fully recharged at 25°C in 16 hours will reach only about 75% of standard capacity at 45°C after 48 hours. Again, no damage will be done to the battery, but its available capacity during subsequent discharge will be less than one would otherwise expect. If correction pa­rameters for the gas gauging function of the LTC1325 will be employed, it is recommended that the manufac­turer of the specific battery in question be consulted.
In the same way that charge acceptance is reduced for temperatures above 25°C, actual capacity is reduced when discharging a cell at temperatures much removed from 25°C. The battery temperatures at which actual capacity is 85% of standard capacity are approximately 0°C and 50°C. Again, for more specific data, the manufac­turer of the battery to be used should be contacted.
the charger’s output current to a 0.05C trickle-charge after the five-hour recharge interval. Checking the cell manufacturer’s data will provide further information on this, as well as the specified charge rate, permissible continuous overcharge rate, and information on the allow­able temperature range.
Under some conditions, it may be desirable to use a lower charging rate than 0.1C (for instance, to reduce charger power requirements). This is feasible only within a narrow range: NiCd cells have a reduced charge acceptance at lower charge rates, lengthening the required charge time. This, and their self-discharge characteristic (approximately
0.5%/day at 23°C), combine to make anything under
0.05C a very slow and potentially unreliable charge rate for
most cell types.
Nickel-Cadmium Fast-Charge
In recent years a class of applications has arisen for which 5 hours to 16 hours may constitute an excessive recharge time. Portable computer equipment is an excellent ex­ample of this — even if the battery pack in a laptop can be “swapped out” for external recharge, it is often needed again within several hours, fully charged and ready for use. In this case, the fast-charge techniques which the LTC1325 makes practical are the way to go. A fast-charge regimen implies:
• 90% recharge within one hour; 100% recharge within two to three hours.
• A method for determining the optimum charge termina­tion point(s).
• Backup charge termination method(s) to ensure best battery life.
• Highly efficient use of available charging energy.
• Increased product value through better battery utiliza­tion and greater customer satisfaction.
Specially rated NiCd cells can support a higher rate of relatively uncontrolled overcharge than the ubiquitous
0.1C. This allows the quick-charge regimen, which is typically 0.33C for 5 hours. Charging current and interval aside, most other details for performing a quick-charge are the same as for a standard-charge. It is often desirable in quick-charge regimens to use a timed charge, reducing
AN64-18
Unlike the standard-charge and quick-charge regimens, there is no one best way to fast-charge a Nickel-Cadmium battery. Variables introduced by the allowable cost and size of the end application, the continuing evolution of Ni-Cd cells to accomodate faster charge rates, and the specific battery vendor(s) chosen will all influence the final choice of charging technique. There are several areas of
Application Note 64
industry consensus, however, regarding the suitable fast­charging of NiCd batteries:
• Charging Current: 1.0C to 2.0C.
• Required Charging Voltage: 1.80V/cell or greater, plus charger overhead.
• Charging Temperature Range: 10°C to 40°C.
• Charging Time: Three hours (90% of charge is typically returned within the first hour).
• Suitable Charge Termination Methods: See Table A2.
• Suitable Secondary Charge Termination Methods: See Table A2.
• Special issues which may require further consideration are: accurate gas gauging at temperatures over 25° C, and appropriate mechanical integration of the battery pack into the end equipment.
The objective of fast-charging a NiCd battery is, crudely stated, to cram as much energy as it takes to bring the battery back to a fully charged state into that battery in as short a time as possible. Since current is proportional to
energy divided by time, the charging current should be as high as the battery system will reasonably allow. Gener­ally, NiCd batteries rated for fast-charge use are designed around a 1C to 2C maximum charging rate. At the 1C rate, more than 90% of the usable discharge capacity of the battery is typically returned within the first hour. Higher rate cells (up to 5C) do exist, but they are more oriented to special applications and will not be discussed here, except to note that the LTC1325 is capable of handling the charging routines required for such cells, should that be required.
Fast-charging has compelling benefits, but places certain demands upon the battery system. A properly performed fast-charge can yield a cell life of as many as 500 charge/ discharge cycles. The high charging rates involved, how­ever, do engender correspondingly more rapid electro­chemical reactions within the cell. Once the cell goes into overcharge, these reactions cause a rapid increase in internal cell pressure, and in the cell’s temperature. Figure A1 shows the Voltage, Pressure and Temperature charac­teristics of a Nickel-Cadmium cell being charged at the 1C rate. It can be seen that, as the cell approaches 100% of
Table A2. Fast-Charge Termination Techniques for Nickel-Cadmium Batteries
Voltage Cutoff (VCO) Uses absolute cell voltage to determine the cell’s state of charge. Not generally recommended for use
in NiCd charging regimens.
Negative V (–V) Looks for the relatively pronounced downward slope in cell voltage which a NiCd exhibits (30mV to
50mV) upon entering overcharge. Very common in NiCd applications due to its simplicity and reliability.
Zero V Waits for the time when the voltage of cell under charge stops rising, and is “at the top of the curve”
prior to the downslope seen in overcharge. Sometimes preferred over –V, as it causes less overcharging.
Voltage Slope (dV/dt) Looks for an increasing slope in cell voltage (positive dV/dt) which occurs somewhat before the cell
reaches 100% returned charge (prior to the Zero V point). No longer widely used.
Inflection Point Cutoff (d2V/dt2, IPCO) As a NiCd cell approaches full charge, the rate of its voltage rise begins to level off. This method looks
for a zero or, more commonly, slightly negative value of the second derivative of cell voltage with respect to time.
Absolute Temperature Cutoff (TCO) Uses the cell’s case temperature (which will undergo a rapid rise as the cell enters high-rate overcharge)
to determine when to terminate high-rate charging. A good backup method, but too susceptible to variations in ambient temperature conditions to make a good primary cutoff technique.
Incremental Temperature Cutoff (TCO) Uses a specified increase of a NiCd cell’s case temperature, relative to the ambient temperature, to
determine when to terminate high-rate charging. A popular, relatively inexpensive and reliable cutoff method.
Delta Temperature/Delta Time (T/t) Uses the rate of increase of a NiCd cell’s case temperature to determine the point at which to terminate
the high-rate charge. This technique is inexpensive and relatively reliable as long as the cell and its housing have been properly characterized.
AN64-19
Application Note 64
1.75
1.50
1.25
1.00
0.75
CELL VOLTAGE (V)
0.50
0.25
0
Reproduced with permission by Butterworth-Heinemann,
Batteries Applications Handbook
Figure A1. NiCd Voltage, Pressure, and Temperature Characteristics During Charge at 1C (23°C Ambient)
120
100
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40
20
INTERNAL PRESSURE (PSIG)
0
–20
90
80
70
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50
40
CELL TEMPERATURE (°C)
30
20
0
, copyright 1992
CHARGE INPUT (% OF CAPACITY)
CELL VOLTAGE
PRESSURE
50 100
TEMPERATURE
Rechargeable
150
AN64 FA01
capacity, the charging current must be reduced or termi­nated. Left unchecked, overcharge at the C rate will ulti­mately cause the cell’s safety vent to open. This results in a loss of gaseous electrolyte to the ambient, and a perma­nent diminution of cell capacity. Similarly, allowing the temperature of the cell to rise excessively will cause a degradation of the internal materials, again reducing cell life. The science of fast-charging is largely that of deter­mining when the battery has achieved between 90% and 100% of its dischargeable capacity. At that point the charging circuit must switch from the fast-charge current level to a level appropriate to finish the charging of, and/ or maintain the charge on, the battery. Some of the common methods for doing this are outlined in Table A2.
As Table A2 shows, there are a number of techniques which have been been successfully employed for the purpose of determining when to terminate the high-rate interval of a fast-charge regimen. Individual application requirements, and manufacturer’s recommendations, must of course be considered carefully before making a final design decision. Nonetheless, two techniques for detect­ing the point at which to make the transition from high-rate charging to top-charging have become especially popular over the years, and are used here as examples. These are the –V and the TCO methods. The –V approach looks for a point at which the cell or battery voltage reaches its peak during charging, and holds this maximum value. The high-rate charge is then terminated when the voltage per cell has declined by a value of 15mV to 30mV. TCO
sensing uses two thermistors to measure the case tem­perature of the cell, or of one of the cells in a battery, while also measuring the ambient temperature. A 10°C differen­tial between cell and ambient is the typical high-rate termination criterion. (A single-thermistor variant on the “classic” TCO approach is made possible through the combined power of the LTC1325 and a microprocessor: cell temperature is measured just before commencing charge, and assumed to be the ambient temperature. This baseline value then becomes the reference against which all further temperature measurements are compared.)
For illustration of the fast-charging of NiCd batteries, this document will use a 1C charge rate, in a three-stage algorithm. The three stages are:
• Fast-Charge at the 1C rate, until it is determined by the charging system that the high-rate portion of the charge regimen must be terminated. At this point, a 1C charge will typically have returned between 90% and 95% of the battery’s actual capacity.
• Top-Charge at 0.1C for two hours, to add an additional
0.2C to the battery. This will bring the battery back to 100% of usable capacity.
• Trickle-Charge at between 0.02C and 0.1C to counter the NiCd’s self-discharge value of about 0.5%/day.
Unless the battery is being used in an unusual application, there is little advantage in using a trickle-charge rate different from the 0.1C top-charge rate, which most NiCd cells can tolerate indefinitely. If the trickle-charge is the same as the top-charge rate, the charge regimen illus­trated effectively has only two stages. This is not uncom­mon for NiCd batteries.
It cannot be overstated that the high-rate portion of a fast­charge regimen must be terminated once the battery being charged has reached the appropriate cutoff point. Murphy has taught us to prepare for the unexpected. So for each method consider: “How can this method fail?” To give just one example of each case: contact resistance in the charging path could mask the downslope of the battery’s terminal voltage, causing the microprocessor to miss the –V termination point. For TCO termination, the ambient temperature might not be indicative of the battery’s tem­perature at the start of charge (e.g., recharging of a battery just removed from a cooler environment to a warmer one),
AN64-20
Application Note 64
As mentioned above, fast-charge current levels can cause rapid gas evolution within a NiCd cell. Since gas recombi­nation inside the cell is slower at reduced temperatures, the pressure inside the cell will rise as the cell temperature decreases. This places a lower limit on the permissible fast-charge temperature range. Similarly, the cell’s charge acceptance decreases at elevated temperatures. Hence, although gas recombination occurs much more rapidly, there is the danger of more gas being generated than the cell mechanisms can handle. This places an upper bound­ary on the fast-charge temperature range. Putting num­bers to these limits, 10°C to 15°C are common minimum figures with the high end at 40°C to 45°C. Using the LTC1325 in conjunction with the microprocessor to en­sure that the indicated operations occur within the manufacturer’s rated temperature limits will significantly extend the life of the cell or battery.
For the most accurate gas gauging it may be desirable to take into account the battery’s actual temperature during charge and its temperature during discharge. Both of these have an effect upon the ratio of actual capacity to standard capacity. This effect may be especially pro­nounced if the battery is charged at an ambient tempera­ture above 25°C and/or discharged at 0°C or below. For specific data with which to calibrate the gas gauge func-
tion against charge and discharge temperatures, the manu­facturer of the cells or batteries being used should be contacted.
During fast-charge the battery will get warm and may vent in the unlikely case of overstress or failure. It is prudent engineering to allow for these contingencies in the mechanical design stage of the equipment in which the battery will reside. Again, the manufacturer of the cells or battery to be used should be consulted for specific guidance.
Using Nickel-Metal Hydride Batteries
The Nickel-Hydrogen couple has been known for at least 20 years, but until recently it has been too costly for all but the most specialized of applications. Recent develop­ments in the manufacture of the NiMH cell, specifically of the hydrogen-bearing negative electrode, has brought NiMH technology into the realm of commercial viability. At present NiMH batteries remain somewhat more expensive than either Nickel-Cadmium or SLA units. However, for applications requiring the energy densities which NiMH provides, it can readily justify its higher price. It should also be noted that NiMH is a mature enough technology to be useful and reliable, yet young enough that prices should continue to decline and performance to improve. The LTC1325’s features and flexibility make it an excellent choice for Nickel-Metal Hydride applications, providing the ability to easily implement and modify fast-charge routines, gas gauge algorithms and/or switch-mode con­stant current sources, all using very little system overhead and printed circuit board space.
A quick rundown of the pros and cons of Nickel-Metal Hydride batteries:
The “pros”:
• Excellent energy density, both by weight and by vol­ume, relative to competing technologies.
• Acceptable charging rates range from 0.1C to 1C and beyond (fast-charge capability is virtually a given for NiMH).
• A flat discharge profile.
• Well understood and documented electrical behavior and electrochemistry.
AN64-21
Application Note 64
• Cells and batteries are available in a variety of sizes from a number of vendors.
• It is anticipated that new cell formulations will eliminate all cadmium from the NiMH product.
The “cons”:
• Nickel is coming under scrutiny as a potential ecologi­cal hazard.
• NiMH cells have a significant self-discharge rate (0.5%/ day to 1%/day at room temperature).
• Careful attention to overcharge of NiMH cells is re­quired, even at standard-charge rates.
• NiMH cells command a price premium relative to NiCd cells at the present time.
• MiMH cells do not presently cover the same tempera­ture ranges as either NiCd or SLA units.
Nickel-Metal Hydride Standard-Charge
• Simplest charging algorithm.
• Least expensive charge termination techniques.
• Small power supply required to provide the charging current.
• Small charging circuit power components.
• Low overall charging system power dissipation.
A standard-charge is relatively straightforward to imple­ment. In “cookbook” form, such a charge requires:
• Charging Current: 0.1C, switching to 0.025C trickle­charge.
• Required Charging Voltage: 1.60V/cell or greater, plus charger overhead.
• Charging Temperature Range: 0°C to 50°C.
• Charging Time: 16 hours.
• Charge Termination Method: Timer.
• Secondary Charge Termination Methods: None re­quired.
• Special issues which may require further consideration are: wide temperature range discharging and accurate gas gauging at temperature extremes.
A charging current of 0.1C, fed to the battery for 16 hours, will deliver (16 hours × 0.1C) = 160% of standard capacity to the battery. At temperatures between 0°C and 25°C, the resulting 60% overcharge is adequate to ensure that the battery is returned to 100% of its standard capacity. Once this has occurred the charging rate must be reduced sufficiently that cell venting does not occur. At the same time the 1%/day self-discharge of the NiMH cell needs to be countered with a suitable trickle-charge rate. The resulting two-level constant-current charger usually switches in a 0.025C rate after the 0.1C main charge. A NiMH battery will show a modest temperature increase (typically 8°C to 9°C) after 16 hours of standard-rate charging. However, this value is not tightly defined and the rate of temperature rise is quite gradual at the end of the charging cycle. This rules out thermal charge termination for the standard-charge regimen. A better approach is a timed-charge technique which applies the standard-rate charging current for 16 hours and then drops back to a
0.025C trickle-charge. A refinement to this is to break the
main charging interval into numerous shorter intervals under the control of the timer internal to the LTC1325. In this way, even if the microprocessor controlling the bat­tery system should “lock up,” permanent damage to the battery will be prevented. Charging at temperatures below 0°C or above 45°C is not recommended. In addition, NiMH batteries should not be discharged beyond the range of –20°C to 50°C. If a wide temperature excursion of the ambient is anticipated, the use of a thermal sensor in conjunction with the LTC1325 is an excellent way to ensure that battery operations occur only within their permissible temperature boundaries, which will signifi­cantly extend battery life.
The charge acceptance of NiMH batteries is reduced significantly at temperatures above 40°C. This effect should be taken into account if gas gauging is to be done over extended temperature ranges. In this regard, the perfor­mance of NiMH and Nickel-Cadmium batteries is quite similar. A NiMH battery that will recover 100% of standard capacity after 16 hours at 25°C will attain only about 85% of standard capacity at 45°C. Hence the battery’s available capacity during subsequent discharge will be less than
AN64-22
Application Note 64
one would otherwise expect. If correction parameters for the gas gauging function of the LTC1325 will be employed, it is recommended that the manufacturer of the specific battery in question be consulted.
In the same way that charge acceptance is reduced for temperatures above 25°C, actual capacity is reduced when discharging a cell at temperatures much below 25°C. Typical figures for actual capacity are 85% of standard capacity at 0°C, and 50% at –20°C. Again, for more specific data the manufacturer of the battery to be used should be contacted.
Generally speaking, it’s not a good idea to use a lower charging rate than 0.1C. This is due in part to the fact that NiMH cells have a reduced charge acceptance at lower charge rates, lengthening the required charge time, and in part to the fact that their self-discharge rate of approxi­mately 1%/day at 23°C increases quickly with temperature.
Nickel-Metal Hydride Fast-Charge
In recent years a class of applications has arisen for which 5 hours to 16 hours may constitute an excessive recharge time. NiMH batteries, with their relatively high energy densities, were perfected largely for the mobile portion of this market. Portable computer equipment is an excellent example of a NiMH fast-charge application — even if the battery pack in a laptop can be “swapped out” for external recharge, it is often needed again within several hours, fully charged and ready for use. In this case the techniques which the LTC1325 makes practical are the way to go. Such a fast-charge implies:
• 90% recharge within one hour; 100% recharge within two to four hours.
• A method for determining the optimum charge termina­tion point(s).
• Backup charge termination method(s) to ensure best battery life.
• Highly efficient use of available charging energy.
• Increased product value through better battery utiliza­tion and greater customer satisfaction.
A fast-charge battery system involves:
• Charging Current: 1.0C.
• Charging Time: Three hours (90% of charge is typically returned within the first hour).
• Required Charging Voltage: 1.80V/cell or greater, plus charger overhead.
• Charging Temperature Range: 15°C to 30°C optimal (consult manufacturer for permissible range).
• Charge Termination Method: See Table A3.
• Secondary Charge Termination Methods: See Table A3.
• Special issues which may require further consideration are: accurate gas gauging at temperatures other than 25°C and appropriate mechanical integration of the battery pack into the end equipment.
The objective of fast-charging a NiMH battery is, crudely stated, to cram as much energy as it takes to bring the battery back to a fully charged state into that battery in as short a time as possible. Since current is proportional to energy divided by time, the charging current should be as high as the battery system will reasonably allow. Gener­ally, NiMH batteries are rated for a 1C maximum charging rate. At that rate, more than 90% of the useable discharge capacity of the battery is typically returned within the first hour. Of course, the LTC1325 will also support the charg­ing of higher rate cells as they become available.
Fast-charging has compelling benefits, but places certain demands upon the battery system. A properly performed fast-charge can yield a cell life of as many as 500 charge/ discharge cycles. The high charging rates involved, how­ever, do engender correspondingly more rapid electro­chemical reactions within the cell. Once the cell goes into overcharge, these reactions cause a rapid increase in internal cell pressure and in the cell’s temperature. Figure A2 shows the Voltage and Temperature characteristics of a Nickel-Metal Hydride cell being charged at the 1C rate. It can be seen that, as the cell approaches 100% of capacity, the charging current must be reduced or terminated. Left unchecked, overcharge at the C rate will ultimately cause the cell’s safety vent to open. This results in a loss of gaseous electrolyte to the ambient and a permanent dimi­nution of cell capacity. Similarly, allowing the temperature of the cell to rise excessively will cause a degradation of the internal materials, again reducing cell life. The science of fast-charging is largely that of determining when the battery has achieved between 90% and 100% of its
AN64-23
Application Note 64
Table A3. Fast-Charge Termination Techniques for Nickel-Metal Hydride Batteries
Voltage Cutoff (VCO) Uses absolute cell voltage to determine the cell’s state of charge. Not generally recommended for use
in NiMH charging regimens.
Negative V (–V) Looks for the downward slope in cell voltage which a NiMH exhibits ( 5mV to 15mV) upon entering
overcharge. Common in NiMH applications due to its simplicity and reliability.
Zero V Waits for the time when the voltage of cell under charge stops rising, and is “at the top of the curve”
prior to the downslope seen in overcharge. Sometimes preferred over –V, as it causes less overcharging, and may be easier to detect reliably (due to the small –V of a NiMH cell). Common in NiMH applications.
Voltage Slope (dV/dt) Looks for an increasing slope in cell voltage (positive dV/dt) which occurs somewhat before the cell
reaches 100% returned charge (prior to the Zero V point). Not widely used.
Inflection Point Cutoff (d
Absolute Temperature Cutoff (TCO) Uses the cell’s case temperature (which will undergo a rapid rise as the cell enters high-rate overcharge)
Incremental Temperature Cutoff (TCO) Uses a specified increase of a NiMH cell’s case temperature, relative to the ambient temperature, to
Delta Temperature/Delta Time (T/t) Uses the rate of increase of a NiMH cell’s case temperature to determine the point at which to terminate
2
V/dt2, IPCO) As a NiMH cell approaches full charge, the rate of its voltage rise begins to level off. This method looks
for a zero or, more commonly, slightly negative value of the second derivative of cell voltage with respect to time.
to determine when to terminate high-rate charging. A good backup method, but too susceptible to variations in ambient temperature conditions to make a good primary cutoff technique.
determine when to terminate high-rate charging. A popular, relatively inexpensive and reliable cutoff method.
the high-rate charge. This technique is inexpensive and relatively reliable as long as the cell and its housing have been properly characterized.
70
60
50
40
30
20
BATTERY TEMPERATURE (°C)
10
Data used courtesy of Duracell, Inc.
1.60
1.55
1.50
1.45
1.40
1.35
BATTERY VOLTAGE (V.p.c.)
1.30
1.25
0
VOLTAGE
TEMPERATURE
40
0
CHARGE INPUT (% OF TYPICAL CAPACITY)
60 80
20
100
120 160
140
AN64 FA02
180
Figure A2. NiMH Voltage and Temperature Characteristics During Charge at 1C (20°C Ambient)
dischargeable capacity. At that point the charging circuit must switch from the fast-charge current level to a level appropriate to finish the charging of, and/or maintain the charge on the battery. Some of the common methods for doing this are outlined in Table A3.
As Table A3 shows there are a number of techniques which have been been successfully employed for the purpose of determining when to terminate the high-rate interval of a fast-charge regimen. Individual application requirements, and manufacturer’s recommendations, must of course be considered carefully before making a final design deci­sion. Several techniques for detecting the point at which to make the transition from high-rate charging to top-charg­ing have gained especially wide acceptance in the NiMH community. Among these are the T/t, the TCO, the –V, and the the d2V/dt2 methods. T/t sensing mea­sures the rate of change of the case temperature of the cell, or of a cell in the battery with respect to time. When this rate of rise reaches 1°C/minute, almost all of the dis­chargeable capacity has been returned to the cell and the high-rate charge should be terminated. TCO sensing measures the difference between the case temperature of the cell, or of one of the cells in a battery, while also measuring the ambient temperature. A 15°C differential between cell and ambient is the typical high-rate termina­tion criterion. The –V approach looks for a point at which
AN64-24
Application Note 64
the cell or battery voltage peaks during charging, and holds this maximum value. The high-rate charge is then terminated when the voltage per cell has declined by a value of 5mV to 10mV. The d2V/dt2 technique looks for a slowing rate of rise in the the battery’s terminal voltage. This trend, properly filtered and processed by the system’s software, will yield a negative second derivative of battery voltage when the battery approaches a complete recharge.
For illustration of the fast-charging of NiMH batteries, this document will use the regimen recommended by Duracell, Inc. The three stages of this regimen are:
• Fast-charge at the 1C rate, until it is determined by the charging system that the high-rate portion of the charg­ing cycle must be terminated. At this point, a 1C charge will typically have returned between 90% and 95% of the battery’s actual capacity.
• Top-charge at 0.1C for one hour to add an additional
0.1C to the battery. This will bring the battery back to 100% of usable capacity.
• Trickle-charge at 0.0033C to counter the self-discharge characteristic of Nickel-Metal Hydride, while not expos­ing the battery to excessive overcharge.
Nickel-Metal Hydride batteries suffer quickly and severely from protracted overcharge. To prevent damage to the battery all manufacturer’s algorithms recommend a low trickle-charge value. As shown, Duracell recommends
0.0033C while many other vendors specify 0.025C. The
exact value of this trickle-charge, as well as the specific overall charging regimen, is application and vendor de­pendent, so the literature of the selected battery supplier should be consulted.
It cannot be overstated that the high-rate portion of a fast­charge regimen must be terminated once the battery being charged has reached the appropriate cutoff point. Murphy has taught us to prepare for the unexpected. So for each method consider: “How can the this method fail?” To
illustrate by example: contact resistance in the charging path could mask the downslope of the battery’s terminal voltage, causing the microprocessor to miss the –V termination point. For the case of T/t termination, the ambient temperature might artificially prevent a rapid enough change in temperature from occuring (e.g., re­charging of a battery while it sits in the airstream of an air conditioner). Failure of the charger system to recognize the cutoff point, for whatever reason, can quickly and irretrievably damage the battery. To avoid such damage, inexpensive redundancy is the solution. With the capabili­ties of the LTC1325 already at hand, the best plan is to simply employ two or more methods. It is then reasonable to expect that one of the techniques will result in a successful high-rate charge termination. In Duracell’s suggested regimen the primary technique for terminating the high-rate charge is T/t sensing, with –V serving as a backup. To give Murphy’s gremlins a harder time of it, there are maximum and minimum operating temperatures and cell voltages which the LTC1325 can be set to recog­nize. For example, Duracell recommends using a third, TCO-based “safety” to shut the high-rate charge down if the battery temperature ever exceeds 60°C absolute. The LTC1325 also has a timer feature which will turn off the charge current to the battery unless the timer is reset within a certain interval. Not only does this provide an extra margin of safety, it can simplify charging as well: Duracell’s regimen calls for one hour of timer-controlled 0.1C over­charge. The LTC1325 can offload this timing job from the system processor. Hence, the battery charging task is simplified and the battery is protected from severe over­charge even if the system’s microprocessor should fail altogether.
As mentioned above, fast-charge current levels can cause rapid gas evolution within a NiMH cell. Since gas recom­bination inside the cell is slower at reduced temperatures, the pressure inside the cell will rise as the cell temperature decreases. This places a lower limit on the permissible fast-charge temperature range. Similarly, the cell’s charge acceptance decreases at elevated temperatures. Hence, although gas recombination occurs much more rapidly, there is the danger of more gas being generated than the cell mechanisms can handle. This places an upper bound­ary on the fast-charge temperature range. Putting num­bers to these limits, 10°C to 15°C are common minimum
AN64-25
Application Note 64
figures with the high end at 40°C to 45°C. This tempera­ture span constitutes the limit for fast-charging of NiMH batteries; they will give longer life and better performance if charged between 15°C and 30°C. Using the LTC1325’s measurement capabilities to ensure that the indicated operations occur within the manufacturer’s rated tem­perature limits will significantly extend the life of the cell or battery.
For the most accurate gas gauging, it may be desirable to take into account the battery’s actual temperature during charge and its temperature during discharge. Both of these have an effect upon the ratio of actual capacity to standard capacity. This effect may be especially pro­nounced if the battery is charged at an ambient tempera­ture above 25°C and/or discharged at 0°C or below. For specific data with which to calibrate the gas gauge func­tion against charge and discharge temperatures, the manu­facturer of the cells or batteries being used should be contacted.
During fast-charge the battery will get warm and may vent in the unlikely case of overstress or failure. It is prudent engineering to allow for these contingencies in the mechanical design stage of the equipment in which the battery will reside. Again, the manufacturer of the cells or battery to be used should be consulted for specific guidance.
Using Sealed Lead-Acid Batteries
Lead-Acid batteries are the “venerable elders” among rechargeable power sources. They have been known in various forms for substantially over a century. But age does not imply weakness––many of the most significant developments in Lead-Acid cells, including those which have made the portable Sealed Lead-Acid (SLA) construc­tion practical, have taken place in the last 30 years or less. Concerns about the safety and stability of the sulfuric-acid electrolyte system have been addressed, first by the well­known “Gel Cell,” and thereafter by modern “starved­electrolyte” technologies. Improvements in the purity of materials, and the optimization of the internal cell struc­ture for portable battery applications (as opposed to the traditional automotive market which imposes its own unique demands) have made the SLA battery a serious contender for many applications. In the smaller ratings
SLA batteries compare favorably in cost per Watt-Hour with NiCd batteries and are superior to NiMH devices; in higher Watt-Hour ratings SLA technology is usually the clear choice. With a minimum of board space and system overhead, the LTC1325 provides a programmable switch­mode charging controller. It also carries on-chip all nec­essary battery monitoring and safeguard circuitry, and the means to readily implement gas gauge algorithms.
A quick rundown of the pros and cons of Sealed Lead-Acid batteries:
The “pros”:
• The electrochemistry and electrical behavior of SLA batteries are very well understood and documented for moderate charge rates and for a broad range of dis­charge rates.
• SLA technology lends itself to prismatic batteries as well as cylindrical cells.
• SLA batteries are available with wider operating tem­perature ranges than either NiCd or NiMH batteries.
• Excellent cost/Watt-Hour, especially in larger size cells and batteries.
• Very low self-discharge rates: 0.2%/day at 25°C
• Low cell impedance with a good capability to handle high pulse currents.
• SLA cells are available in a variety of sizes from a number of vendors.
The “cons”:
• The SLA cell has the lowest energy density, by weight and by volume, of all three technologies.
• SLA batteries deliver their best performance under a constant voltage (or pseudo-constant voltage) charge regime.
• Lead is commonly considered to be an environmentally hazardous material.
• SLA cells are susceptible to damage from overcharge, repeated deep discharge, and/or cell reversal.
• The discharge profile of a SLA cell is not as flat as that of a NiCd cell, nor as that of an NiMH cell in most applications.
AN64-26
Application Note 64
Sealed Lead-Acid Standard-Charge
For applications which can allow a recharge period of 24 hours or more –– any period from an extended “overnight” charge to a “float charge”–– the standard-charge is the regimen of choice. The reasons for this include:
• No charge termination required.
• Frequently requires no temperature compensation.
• Small power supply required to provide the charging current.
• Small charging circuit power components.
• Low overall charging system power dissipation.
• Excellent battery life due to low charging stress.
An SLA standard-charge is relatively straightforward to implement. In “cookbook” form, such a charge requires:
• Charging Current: Limited to 0.25C or less.
• Charging Voltage: 2.25V/cell to 2.30V/cell, plus charger overhead.
• Charging Temperature Range: 0°C to 40°C.
• Charging Time: 24 hours or longer.
• Charge Termination Method: None required.
• Secondary Charge Termination Methods: None required.
• Special issues which may require further consideration are: wide temperature range charging, wide tempera­ture range discharging, and accurate gas gauging un­der varying conditions of use.
Sealed Lead-Acid (SLA) batteries are generally charged using a constant voltage source with a deliberately im­posed current limit (essentially a current-limited voltage regulator), or a charger which will, in terms of the electro­chemical effects seen by the battery, act as if it were such a source. The charging regimen which this gives rise to is known as “Constant Voltage,” or more commonly, “Con­stant Potential.” For the purposes of this document the term “Constant Potential” (CP) will be used.
The reasons for using a CP charge regimen are various, but the three principal ones are these:
• Charge acceptance (the efficiency of conversion of previously removed electrical energy back into chemi-
cal potential) is reduced as the charging current through an SLA cell is increased.
• Once full charge is achieved, continued charging cur­rent through an SLA cell will have an irreversible oxidiz­ing effect upon the positive plate of the battery, ulti­mately reducing battery capacity.
• Most importantly from the standpoint of designing a practical charger, there is no reliable way to know an SLA cell’s state of charge based upon its terminal voltage or its temperature.
A significantly discharged cell undergoing CP charging will initially attempt to draw very high currents, as SLA cells are low impedance devices. The function of the current-limiting in the CP regimen is to keep the peak current flowing into the cell within the cell’s (and the charger’s) ratings. Following the current-limited phase of the charging profile, the CP charging technique in combi­nation with the characteristics of SLA devices cause the cell under charge to in essence regulate its own charging current. If the cell vendor’s recommendation as to charg­ing voltage (typically 2.25V/cell to 2.30V/cell at 20°C) are followed, the cell’s charging current will naturally taper off with time as the cell goes slightly into overcharge. Under these conditions a fully discharged cell will essentially cease charging once it has achieved a 110% returned charge which results in a 100% dischargeable capacity. The remaining 10% is lost to heating and other parasitic reactions. This simple charging concept, sometimes combined with compensation for ambient temperature (– 2mV/°C to –3mV/°C, depending upon the manufac­turer), will provide highly satisfactory results over a good temperature range. A range of 0°C to 40°C is typical, with some vendors specifying their products for operation at temperatures of 50°C or more. Figure A3 shows the way in which SLA charge current tapers off and the returned capacity rises under such a CP charging regimen. Figure A4, a reproduction of Figure 10 from the body of this Application Note, shows how the LTC1325 can be used to provide all the necessary functions for SLA battery man­agement. As in the body of this Application Note, Figures B3a and B3b in Appendix B are also relevant here.
The charge acceptance of SLA batteries is reduced at temperatures below about 0°C, and actual capacity is reduced when discharging a cell at temperatures much
AN64-27
Application Note 64
CURRENT
LIMIT
CHARGE
CURRENT
CHARGING CURRENT
0
Reproduced with permission by Butterworth-Heinemann,
Batteries Applications Handbook
CAPACITY RETURNED
TIME
, copyright 1992
100
STATE OF CHARGE
AN64 FA03
Rechargeable
Figure A3. Typical Charging Current and Capacity Returned vs Charge Time for CP Charging
lower than 25°C. The battery temperature at which actual capacity is 85% of standard capacity is approximately 0°C. Similarly, adjustment to the indicated capacity may be desired if the continuous discharge current will be at a rate significantly greater than 0.1C. It may be desirable to take these effects into account if gas gauging is to be done over extended temperature ranges. If correction parameters for
the gas gauging function of the LTC1325 will be employed, it is recommended that the manufacturer of the specific battery in question be consulted.
Under some conditions, it may be desirable to use a lower charging rate than 0.1C (for instance, to reduce charger power requirements). This is quite feasible with SLA batteries due to their low self-discharge rates. SLA batter­ies have excellent charge acceptance characteristics at lower charge rates. Ultimately, the limiting issue is usually the maximum practical time allowable for a recharge.
During charging, the battery may get warm and/or vent. It is prudent engineering to allow for these contingencies in the mechanical design stage of the equipment in which the battery will reside. The manufacturer of the SLA battery to be used should be consulted for specific guidance.
Sealed Lead-Acid Fast-Charge
In many cases, 24 hours or more will constitute an excessive recharge time. Portable instrumentation is an excellent example––even if the battery pack in an instru­ment can be “swapped out” for external recharge, it is often needed again before the day is out, fully charged and
MPU
(e.g.,80C51)
+
C
4.7µF
NOTE 1: PANASONIC TYPE ERT-D2FHL103S NTC THERMISTOR OR EQUIVALENT
REG
R
R
P1.4
P1.3
P1.2
P1.5
MCV1
MCV2
4
DATA 
3
CHIP SELECT
2
CLOCK
5
AUX SHDN
1
REG
2
D
OUT
3
LTC1325
D
R
TF1
R
TF2
R
TF3
IN
4
CS
5
CLK
6
LTF
7
MCV
8
HTF
9
GND
VDD
PGATE
DIS
V
BAT
T
BAT
T
AMB
V SENSE FILTER
IN
1µF
18 17 16 15
14
13
12
11 10
CF
Figure A4. LTC1325 Constant Potential Battery Management System
+
R1
7.5k 1%
THERM 2 NOTE 1
+ +
C
S
500pF
R5 470k
R3
R4
Q1 2N7002
RIN
2k
R
100
CIN 47µF
VDC IN
P1 IRF9Z30
R
R2
7.5k 1%
THERM 1 NOTE 1
S
R
SENSE
62µH
L1
Y
TRK
D1 1N5818
R
DIS
IRF510
+
N1
AN64 FA04
C
SPLY
10µF
AN64-28
Application Note 64
ready for use. In this case the sophisticated fast-charge techniques which the LTC1325 makes practical are the way to go. A fast-charge regimen implies:
• Significant recharge within one hour; 100% recharge within three hours.
• Suitable means to determine charge termination point.
• A backup charge termination method to ensure best battery life.
• Highly efficient use of available charging energy.
• Increased product value through better battery utiliza­tion and greater customer satisfaction.
An SLA fast-charge is very similar to an SLA standard­charge. It is recommended that the section on standard­charging of Sealed Lead-Acid batteries be read before reading this section. There are only three significant differences between the two sections:
a) The charging voltage is increased (to increase the
charging current).
b) Temperature compensation is definitely required at
a rate of –5mV/°C, preferably from a sensor mounted near or on the battery case.
c) Fast-charge termination is required.
• Charging Current: Vendor-dependent. The vendor used as a reference suggests 1.5C.
• Charging Voltage: 2.45V/cell to 2.50V/cell, plus charger overhead.
current of about 0.002C. The backup method should be a 180-minute time-out, according to the recommendations of the vendor suggesting 1.5C as a high-rate current.
During fast-charge the battery will get warm and some venting may occur. It is prudent engineering to allow for these contingencies in the mechanical design stage of the equipment in which the battery will reside. The manufac­turer of the SLA battery to be used should be consulted for specific guidance.
Using Lithium-Ion Batteries
Of the four battery types discussed in this Appendix, Lithium-Ion (Li-Ion) is the newest. Li-Ion cells offer excel­lent service life, are considered environmentally sound, are easily manufactured in true prismatic (rectangular) format, and most importantly, they have the highest energy density, both in terms of Watt-Hours/kg and Watt­Hours/Liter, of any of the cells discussed.
By merely telling the associated microcontroller whether a NiMH or a Li-Ion battery is present in the system, the LTC1325 using the same hardware can accommodate either type of cell technology.
• Charging Temperature Range: 0°C to 30°C.
• Charge Termination Method: Current Cutoff.
• Charging Time: Three hours; 60% of charge is typically returned within the first hour.
• Secondary Charge Termination Methods: Timer.
• Special issues which may require further consideration are: wide temperature range charging, wide tempera­ture range discharging, and accurate gas gauging un­der varying conditions of use.
The primary termination method, “Current Cutoff” (CCO), looks at the absolute value of the average charging current flowing into the battery. When that current drops below
0.01C the battery is charged and needs only a trickle
Li-Ion batteries are charged using a constant voltage source with a deliberately imposed current limit (essen­tially a current-limited voltage regulator), or a charger which will, in terms of the electrochemical effects seen by the battery, act as if it were such a source. The charging regimen which this gives rise to is known as “Constant Voltage,” or more commonly, “Constant Potential.” For the purpose of this document, the term “Constant Poten­tial” (CP) will be used.
A quick run-down of the pros and cons of Lithium-Ion batteries:
The “pros”:
• Superb energy densities, both by Watt-Hours/Liter and Watt-Hours/kg, relative to competing technologies.
AN64-29
Application Note 64
• High average cell voltage during discharge (3.6V).
• Excellent cycle life characteristics.
• Very low self-discharge rates ( 0.3%/day at 25°C).
• Environmentally sound (not a heavy-metal technol­ogy).
• Li-Ion cells are available in prismatic (rectangular) form factors.
The “cons”:
• Susceptible to irreversible damage if taken into deep discharge.
• Susceptible to loss of capacity or catastrophic failure if overcharged.
• Efficient use of cell capacity requires extremely tight control of charging voltage.
Lithium-Ion Fast-Charging
An Li-Ion fast-charge is conceptually quite simple:
• Charging Current: 1C.
• Charging Voltage: 4.20V ± 0.05V (some cells require slightly different voltages)
• Charging Temperature Range: 0°C to 40°C.
• Charging Time: 2.5 Hours to 5 Hours.
• Charge Termination Method: A timer is typical (consult cell manufacturer).
• Secondary Charge Termination Methods: None required.
• Special issues which require further consideration are: wide temperature range charging, wide temperature range discharging, and accurate gas gauging under varying conditions of use.
A significantly discharged cell undergoing CP charging will initially attempt to draw very high currents, as Li-Ion cells are relatively low impedance devices. The function of the current-limiting in the CP regimen is to keep the peak current flowing into the cell within the cell’s (and the charger’s) ratings. Following the current-limited phase of the charging profile, the CP charging technique in combi­nation with the characteristics of the Li-Ion cell cause the cell under charge to in essence regulate its own charging
The LTC1325 can readily charge either a single cell, or a manufacturer’s finished battery pack. The LTC1325 is, at first glance, a constant-current part. Such a view of its capabilities, however, is too limited. Its power control section is more completely described as a constant­average-current PWM, with the capability for “software” feedback. Given a suitable output filter (probably only the output inductor and the battery itself), the current from the PWM section can be turned into a suitably constant voltage at the battery’s terminals and this voltage used to charge Li-Ion cells or batteries.
The software feedback loop mentioned previously allows the controlling processor to handle all aspects of charg­ing, rather than demanding that important variables be hardwired. The necessary CP servo loop is created as follows:
• Establish a regular repetition interval for the voltage servo loop. 10ms to 20ms gives good results for sealed lead-acid and Li-Ion cells and batteries.
• Set V chosen as 150mV/(0.9 • I
to 150mV for best resolution. R
DAC
), where I
MAX
SENSE
is the maxi-
MAX
is then
mum current to be allowed through the battery.
• Perform each of the following tasks once each servo loop interval:
a) Enter Idle mode of operation. b) Each V
CELL
.
c) Adjust the value entered into a timer register (or a
software timer) up or down according to actual V vs target V increased. If V
CELL
. If V
CELL
is too high the timer value is
CELL
is too low the timer value is
CELL
decreased.
AN64-30
Application Note 64
d) Assume that the maximum tON of the charger will be
90% of each servo loop interval.
e) Enter Charge mode of operation, for a period of
between 90% and 20% of the servo loop interval [as determined by (d)]. In essence, the timer’s period is being subtracted from the charging time available during each servo loop interval, to perform a duty
cycle modulation via the processor. f) If tON < 2ms, switch V g) Repeat (a) through (f) until the current into the
battery drops below 0.002C, or until three hours of
charging have elapsed. h) Terminate the software loop with the MOSFET P1
(Figure A4) in the “off” state. No trick-charging
resistor is used.
Lithium-Ion System Issues
Lithium-Ion cells and batteries require tight control over the voltages to which they are exposed. This makes it virtually mandatory that precision external resistive di­vider be used to scale the battery voltage and present it to the auxiliary ADC input VIN . The highest input voltage possible consistent with not overloading the LTC1325’s ADC should be used; 3.000V full-scale is a good choice.
to the next lower value.
DAC
This gives the best ADC resolution and helps preserve the accuracy of the part when measuring battery voltage. If the LTC1325’s internal battery divider is used, account must be taken of its tolerance (±2%), as well as the reference tolerance (± 0.8%) and the ADC tolerances (4 bits/1024 bits = 0.4%). The system tolerance then is ±3.2%. Adding in a ±1% resistor division ratio would bring this tolerance to ±4.2%.
Using a ±0.1% external divider feeding into the VIN pin, the resulting tolerance is the ±0.8% of the reference, plus the ±0.5% represented by the ADC and the divider resistors. The design center charging voltage is 4.19V. Overcharg­ing (an effective voltage at the battery’s terminals of greater than 4.250V absolute maximum) is strongly dis­couraged by Li-Ion cell manufacturers. Any overcharging will shorten the cell’s life and may result in catastrophic failure. With the undivided battery voltage connected to the LTC1325’s V be used to check for V of Discharge Voltage) point.
There is also a need to ensure that the cell voltage rarely, if ever, dips below 2.5V to 2.7V (contact the specific cell manufacturer for details), and that it
1.0V. This is a spot where the fail-safe capabilities of the LTC1325 can serve the Li-Ion user well.
input, the on-chip battery divider can
BAT
reaching the FEDV (Fault: End
CELL
never
goes below
AN64-31
Application Note 64
APPENDIX B
Flow Charts
START
NO
CONDITIONING?
YES
START
DISCHARGE
LONG WAIT
START
TOP-OFF CHARGE
RESUME
FAST CHARGE
NO
NO
READ STATUS
EDV = 1?
YES
START
FAST CHARGE
LONG WAIT
IDLE MODE AND
SHORT WAIT
READ ADC
AND STATUS
TERMINATE?
YES
RESUME
TOP-OFF CHARGE
NO
LONG WAIT
IDLE MODE AND
SHORT WAIT
READ ADC
AND STATUS
TERMINATE?
YES
IDLE MODE AND
SHORT WAIT
MORE
CONDITIONING?
NO
END
YES
AN64 FB01
AN64-32
Figure B1. Simplified Battery Management Flow Chart
START
RESET 1 MINUTE
COUNTER N = 0
IDLE MODE
MODE = 0, FSCLR = 1
FAST-CHARGE RATE
TIME-OUT = 5 MIN.
DISPLAY STATUS
AND MODE
Application Note 64
YES
CHARGE
STARTED?
DISCHARGE MODE
MODE = 1
STOP?
NO
BATTERY
PRESENT?
YES
BATTERY
REVERSED?
NO
HOT OR
COLD?
NO
END OF
DISCHARGE?
NO
SET FAIL-SAFE
TIME-OUT
YES
YES
YES
YES
NO
CHARGE MODE
MODE = 2
NO
SET CHARGE
RATE TO TOP-OFF
DISABLE
CONDITIONING
CHARGE MODE
MODE = 2
NO
YES
TERMINATE?
YES
CHARGE RATE
= FAST?
NO
MORE
CONDITIONING?
NO
END
CONDITIONING
YES
ENABLE
YES
CONDITIONING
ENABLED?
NO
MCV = 1?
NO
TIME-OUT?
NO
YES
YES
TIME-OUT?
NO
N = 3?
YES
INDICATE
DEFECTIVE BATTERY
IDLE MODE
MODE = 0
YES
NO
Figure B2a. Comprehensive Battery Management Flow Chart
AN64 FB02a
AN64-33
Application Note 64
START
SAVE CURRENT
MODE
READ AND SAVE USER SWITCHES
INCREMENT
1 MIN COUNTER N
YES
IDLE MODE
MODE = 0, FSCLR = 0
N = 59?
RESET 1 MINUTE
COUNTER N = 0
READ V
CELL
VOLTAGE
READ T
READ T
VOLTAGE AND
CALCULATE
TERMINATION
CURRENT MODE
VOLTAGE
STATUS
CRITERIA
RESTORE
BAT
AMB
NO
YES
N = 60?
NO
AN64-34
RE-ENABLE
INTERRUPTS
END
AN64 FB02b
Figure B2b. Timer Interrupt Service Routine for Comprehensive Battery Management
START CHARGING
READ V
CELL
Application Note 64
YES
YES
V
> =
CELL
V
CELL(MAX)
NO
SET IPK = 0.105C
SET d = 10%
CHARGE FOR 
(d × t) ms
IDLE FOR 
[(1 – d) × t] ms
READ V
CELL
V
> =
CELL
V
CELL(MAX)
SET IPK = 0.315C SET IPK = 1.05C
SET d = 32%
INCREASE d BY 1%
d = 96%
YES
IPK = 0.105C
NO
YES
NO
IPK = 0.315C
NO “CONTINUE”
YES
“DONE”
V
CELL
(V
CELL(MAX)
– 50mV)
NO
NO
<
YES
Figure B3a. Constant-Potential Charging Algorithm for Lead-Acid and Li-Ion (1 of 2)
AN64 FB03a
AN64-35
Application Note 64
DECREASE d BY 1%
CONTINUE
IPK = 1.05C
AND
d = 31%
NO
IPK = 0.315C
AND
d = 31%
NO
CHARGE FOR 
(d × t) ms
IDLE FOR 
[(1 – d) × t] ms
READ V
CELL
V
> =
CELL
V
CELL(MAX)
NO
YES
YES
YES
SET IPK = 0.315C
SET d = 95%
DONE
(FROM P.1)
MODE = GAS GAUGE
(OR IDLE)
MONITOR BATTERY
SET IPK = 0.105C
AN64-36
V
>
NO
CELL
(V
CELL(MAX)
– 50mV)
YES
AN64 FB03b
Figure B3b. Constant-Potential Charging Algorithm for Lead-Acid and Li-Ion (2 of 2)
APPENDIX C
Application Note 64
A Brief Glossary
As with any other field, rechargeable battery technique has its own terminology. Here are a few definitions which are useful to know. Also included are terms used to describe the LTC1325, its operation and the application circuits.
Actual Capacity: The capacity for electrical energy storage of a cell which is in good condition, under test circum­stances which differ from those established for the mea­surement of the cell’s standard capacity.
Battery: A grouping of cells, to increase the voltage (series), the Ampere-Hour capability (parallel), or both (series-parallel). In this document, “battery” may be used interchangeably with “cell.” Where the two differ, the battery is assumed to be a series assembly of cells unless otherwise specified.
Battery Divider: A programmable voltage divider (divide by 1,2,..,16) connected between the V of the LTC1325. For battery types with per cell voltages of greater than 2.9V, it is necessary to program the divider to keep the divider output within the 2.9V minimum range of the LTC1325 10-bit ADC (Analog-to-Digital Converter).
BATP: Battery Present Status Bit. One of the status bits that the LTC1325 provides. This bit is set when the V pin is pulled below VDD by at least 1.8V.
BATR: Battery Reversed or Battery Shorted Status Bit. One of the status bits that the LTC1325 provides. When the cell voltage, V discharging or charging is terminated.
C: Current expressed in terms of the C rate of a battery, e.g., 1.2C, 0.1C, 2C, etc.
C Rate: A normalization concept widely used in the battery community. A C rate of unity is equal to the capacity of a cell in ampere-hours, divided by one hour. Hence a 2.4 Ampere-Hour cell has a C rate of (2.4 Ampere-Hours)/ (1 Hour) = 2.4 Amperes. By extension, the 0.1C rate for the same cell equates to (0.1) (2.4 Ampere-Hours)/ (1 Hour) = 0.24 Amperes, and the 2C rate is 4.8 Amperes. The value of this term lies in the fact that, for a given cell type, the behavior of cells of varying actual capacity will nonethe­less be very similar at the same C rates.
is less than 100mV, the BATR bit is set and
CELL
and Sense pins
BAT
BAT
Cell: A single electrochemical energy storage element. Cells come in various technologies (e.g., Nickel-Cadmium and Nickel-Metal Hydride) and in various Ampere-Hour ratings.
Cell Reversal: A situation involving the lowest capacity cell in a battery stack, which can manifest itself as the battery stack approaches a deeply discharged state. If a given cell reaches the condition of zero charge before the current draw from the battery stack as a whole is termi­nated, then current from other cells in the battery stack will force a net reverse charge onto the cell in question. This reverse charge, if allowed to continue for a significant length of time, can cause irreversible deterioration of the cell undergoing reversal.
Charge Acceptance: The ability of a battery to transform charging energy (in the form of electrical current) into available energy (in the form of useful chemical reactions). Essentially, a measure of the efficiency of the battery as a storage device for electrical energy. This efficiency varies with battery temperature, state of charge, charging rate, age and electrochemistry.
Charge Mode: The LTC1325 can be programmed into this functional mode to charge batteries. Charging will not commence or is terminated if the battery is absent (see BATP) or the battery temperature is outside permissible limits (see LTF and HTF) or the battery is reversed or shorted (see BATR) or if a time-out condition exists.
Charge Termination Method: The means employed by a given charging algorithm to determine the appropriate point in the charging cycle at which to terminate (a phase of) that charging cycle.
Current Cutoff (CCO): A charge termination technique which monitors the current level flowing into a cell or battery, and indicates to the charging circuit that the charging current should be reduced or cut off when the level falls below a given limit.
Cycle Life: The number of charge/discharge cycles which a battery can sustain before its capacity declines to a specified percentage of its standard capacity, or its initial actual capacity in a given application. The permissible percentage of loss of battery capacity is not a fixed term
AN64-37
Application Note 64
within the battery industry, as most applications have their own unique criteria.
dT
/dt: See Delta Temperature/Delta Time.
BAT
Delta Temperature/Delta Time (∆T/∆t or dT
BAT
/dt): A
Charge Termination Method (or Secondary Charge Termi­nation Method) used to terminate the high-rate portion of a NiCd or NiMH fast-charge regimen. This technique makes use of the fact that the case temperature of a cell undergoing high-rate charge will experience a relatively rapid temperature rise as it goes into high-rate over­charge. When this rate of rise reaches a predetermined value (typically about 1°C/minute), almost all of the dis­chargeable capacity has been returned to the cell, and the high-rate charge should be terminated.
d2V
/dt2: See Inflection Point Cutoff.
BAT
Discharge Mode: The LTC1325 can be programmed into
this functional mode to discharge batteries through an external limiting resistor R
and N-channel MOSFET.
DIS
The gate of the N-channel MOSFET is driven by the DIS pin. Discharge Profile : The voltage-vs-remaining charge char-
acteristic of a cell or battery; the degree of voltage change shown by the battery as its goes from being fully charged to being fully discharged.
Duty Cycle: The LTC1325 can be programmed to modu­late the “on” time of the charge loop with duty cycles of 1/ 16, 1/8, 1/4, 1/2 and 1. The period of this modulation is 42s.
EDV: End of Discharge Voltage. Refers either to the EDV status bit or to the internal end of discharge voltage of
0.9V. Discharge is automatically terminated by the LTC1325 when the cell voltage (V
) falls below 0.9V.
CELL
Energy Density (W-H/kg): A “figure-of-merit” term for comparing differing battery technologies in terms of en­ergy storage capacity vs mass (Watt-Hours/kg).
Energy Density (W-H/L): A “figure-of-merit” term for comparing differing battery technologies in terms of en­ergy storage capacity vs. volume (Watt-Hours/Liter).
Fail-Safes: Various protective measures (voltage, tem­perature and time limits) built into the LTC1325 to protect the battery against potentially damaging voltage and tem­perature conditions when in charge or discharge modes. Also referred to as “Fault Protection.”
Fast-Charge: Generally, any of several charging regimens which is capable of completely recharging a battery within three hours or less. More importantly, such regimens can typically return at least 90% of the battery’s useable capacity within one hour or less. Only batteries specifically designed and rated for the requirements imposed by fast­charge applications should be employed in such applica­tions.
Gas Gauging: Computation of the amount of energy remaining in a battery. This is typically done by coulomet­ric means, that is, the net current with which the battery is charged is metered and integrated. Any currents drawn out of the battery are then metered and subtracted from the integrated total. More sophisticated versions of this same concept use look-up tables and/or algorithmic means to allow for the effects of such variables as charging rate, discharge rate, and temperature during charge and dis­charge phases of battery use. These corrections compen­sate for measurement discrepancies which the battery’s variable charge acceptance and actual capacity might otherwise cause.
Gas Gauge: To perform the gas gauging function. Also, a device or display used somewhere within the system employing the gas gauging function, to indicate the status of the battery to the user and/or to system software routines.
Gas Gauge Mode: The LTC1325 can be programmed into this functional mode to measure load currents sensed by R
. The voltage across R
SENSE
is multipled by – 4, RC
SENSE
filtered before being converted by the ADC. The RC filter consists of an internal 1k resistor and an external non­polarised capacitor C
connected at the Filter pin of
FILTER
the LTC1325. Gassing: The generation of gas(ses) within a cell as it
approaches and enters the overcharge regime. Gassing is an anticipated part of the cell’s operation, and is not harmful unless the rate of gassing exceeds the rate at which the cell can recombine the gas(ses) generated. Under such circumstances, the excess gas(ses) will es­cape to the outside of the cell through a pressure relief valve, causing the permanent loss to the cell of some of the electrolyte from which the gas(ses) were evolved.
High-Rate Charge: The first stage of the two or more stage fast-charge regimen, during which current is flowing
AN64-38
Application Note 64
through the battery under charge at a greater rate than the battery can allow on a continuous basis. This portion of the fast-charge requires specific external termination.
HTF: High Temperature Fault. Refers either to the HTF status bit or to the highest battery temperature at which charging or discharging is permitted by the LTC1325. Charging is automatically terminated by the LTC1325 when the voltage at the T
pin is less than the voltage at
BAT
the HTF pin.
I
: Average Charging Current. This should be within
CHG
recommended limits for the battery.
I
: Average Discharge Current. This should be within
DIS
recommended limits for the battery. Idle Mode: The LTC1325 can be programmed into this
mode when none of the other modes are needed or to make ADC measurements without the presence of switch­ing noise.
Inflection Point Cutoff (d2V
/dt2): A charge termination
BAT
technique used with Nickel-Cadmium and Nickel Metal Hydride batteries. During charge at a constant rate (e.g., the high-current portion of a fast-charge regimen), the terminal voltage of such batteries increases until the battery is slightly into overcharge. The rate of this in­crease, however, is not linear with respect to time. Shortly before the battery reaches full charge, the rate of change of terminal voltage becomes constant; at the time the battery becomes fully charged this rate of change be­comes either zero or negative. The second derivative of the battery’s voltage with respect to time can therefore be used to indicate that point at which the battery is near full charge, by looking for either a zero, or more commonly a negative, value of d2V
BAT
/dt.
Incremental Temperature Cutoff (∆TCO): A Charge Ter­mination Method (or Secondary Charge Termination Method) frequently used to terminate the high-rate por­tion of a fast-charge regimen. TCO makes use of the fact that the case of a fully charged cell will experience a relatively rapid temperature rise as it goes into high-rate overcharge (typically 0.5°C/minute to 1°C/minute).
LTF: Low Temperature Fault. Refers either to the LTF status bit or to the lowest battery temperature at which charging or discharging is permitted by the LTC1325.
Charging is automatically terminated when the voltage at the T
pin of the LTC1325 is greater than the voltage at
BAT
the LTF pin. MCV: Maximum Cell Voltage. Refers either to the MCV
status bit or the highest permissible V
. Charging is
CELL
automatically terminated by the LTC1325 when the cell voltage (V
) is greater than the voltage at the MCV pin.
CELL
Negative ∆ Voltage (–∆V): A Charge Termination Method (or Secondary Charge Termination Method) frequently used to terminate the high rate portion of a fast-charge regimen. This method makes use of the fact that the voltage across a Nickel-Cadmium cell, and to a lesser degree, a Nickel-Metal Hydride cell, will experience a maximum voltage and a subsequent voltage decrease (the “– V”) once it goes into high-rate overcharge (typically between –20mV and –50mV for a Nickel-Cadmium cell). This technique is most commonly employed with NiCd batteries.
NiCd: Nickel-Cadmium NiMH: Nickel-Metal Hydride NTC: Negative Temperature Coefficient. Also used in this
Application Note to refer to thermistors with negative temperature coefficients.
Overcharge: The situation which arises when a cell has been returned to its state of full charge, but the charging current to the cell is not removed. Of necessity, cells are designed to handle a certain amount of overcharge, hence, this is not necessarily either a harmful or an undesirable condition. During overcharge, the excess electrical energy applied to the cell which does not go towards preventing self-discharge is dissipated as heat, through the formation and recombination of gas(ses) within the cell.
PTC: Positive Temperature Coefficient. Also used in this Application Note to refer to thermistors with positive temperature coefficients.
Quick-Charge: A charging regimen for Nickel-Cadmium and Nickel-Metal Hydride batteries which can return 100% of usable capacity to the battery in five hours. Batteries to be charged in this manner must be rated for such charg­ing. The charging current for this regimen is usually stipulated by the manufacturer to be 0.33C.
AN64-39
Application Note 64
R
: External resistor in LTC1325-based circuits to limit
DIS
battery discharge currents to within recommended limits for the battery.
R Required Charging Voltage: The minimum voltage which
should be available with which to charge a given type of battery, in a given charge regimen. Essentially, the compli­ance voltage capability of the charger, as dictated by the voltage which the battery can be expected to achieve during the charging cycle.
R
based circuits which is connected between the Sense pin and ground. This resistor is used to sense battery current in charge and gas gauge modes.
R
Secondary Charge Termination Methods: Certain charg­ing algorithms, especially fast-charge algorithms, have the potential to damage the batteries which they are charging if charge termination does not occur properly. For this reason, such algorithms generally employ more than one termination method. Secondary Charge Termi­nation Methods are those which provide redundancy for the chosen Charge Termination Method.
Self-Discharge: The characteristic of electrochemical stor­age cells to bring themselves to the discharged state, even when their terminals are open-circuited.
Self-Discharge Rate: The rate at which an electrochemi­cal storage cell brings itself towards the discharged state, with its terminals open-circuited. This rate is, for example, approximately 0.5%/day to 1%/day for Nickel-Cadmium and Nickel-Metal Hydride cells at room temperature.
Shutdown Mode: The LTC1325 is programmed into this functional mode to reduce current drain on VDD supply to 30mA typical.
: Drain to source on-resistance of a MOSFET.
DS(ON)
: Sense Resistor. An external resistor in LTC1325-
SENSE
: Trickle Resistor. An external resistor in LTC1325-
TRK
pin high
BAT
Standard Capacity: The capacity for electrical energy storage of a cell which is in good condition. The necessary tests to ascertain this capacity is carried out under the cell manufacturer’s specified standard conditions, which are generally those at which the cell can be expected to deliver its best performance.
Standard-Charge: An “overnight” charge method. This regimen typically involves charging at the 0.1C rate, re­quiring 14 to 16 hours to perform a complete charge on a battery.
T
: Refers to ambient temperature or to the T
AMB
AMB
pin of the LTC1325. This pin is connected to an undedicated channel of the 10-bit ADC and may be used to monitor ambient temperature.
T
: Refers to either battery temperature or the voltage at
BAT
the T
pin of the LTC1325.
BAT
Temperature Cutoff (TCO): A technique for determining at what point to terminate the charging of a cell or battery. The absolute temperature of the cell (or one cell of a battery) is monitored by a temperature-sensitive element which, upon detecting a preset temperature, will either reduce or terminate the charging current to the cell or battery. TCO is frequently used as a backup termination method in fast-charge systems.
Time-Out: A time limit on charge and discharge time. May be one of eight values: 5, 10, 20, 40, 80, 160, 320 minutes or no time-out.
Top-Off Charge: The second portion of the three-stage fast-charge regimen, during which the rate of current flow through the battery under charge is cut back significantly from the high-rate value. This portion of the charge serves to put the battery barely into overcharge.
Trickle-Charge: The third stage of the three-stage fast­charge regimen, during which the rate of current flow through the battery under charge is kept at a sufficient level to prevent the battery from self-discharging, but which contributes little to the charging of the battery per se. The current level required for trickle-charge may or may not be lower than that used for the topoff-charge.
V
: Cell Voltage. The battery voltage divided by the
CELL
programmed setting of the LTC1325 battery divider.
AN64-40
V
: A programmable reference voltage in the LTC1325
DAC
which determines the average voltage at the Sense pin when the LTC1325 is programmed into charge mode. V
may be set to one of four values.
DAC
VDC: Positive charging supply in the LTC1325 circuits described in this Application Note.
VDD: Positive supply pin of the LTC1325. Same as VDC for voltages between 4.5V to 16V.
VEC: End of Charge Voltage. The maximum voltage across each cell of the battery when fully charged. The voltage at the MCV pin should be set above VEC to prevent false fail­safes from occurring.
Venting: The loss of gas(ses) from the inside of a nomi­nally “sealed” cell to the ambient, through the cell’s pressure relief valve. Venting is indicative of a harmful level of overcharge, and will cause eventual irreparable damage to the cell.
Application Note 64
V
: Battery Voltage
BAT
VIN: Refers to the VIN pin of the LTC1325 or its voltage.
Zero Voltage (Zero V): A Charge Termination Method (or Secondary Charge Termination Method) frequently used to terminate the high-rate portion of a fast-charge regi­men. This method makes use of the fact that the voltage across a Nickel-Metal Hydride or Nickel-Cadmium cell will experience a voltage maximum, and subsequent voltage decrease or plateau once it goes into high-rate over­charge. The point at which voltage stops increasing during charging is the point of Zero V. This technique is most commonly employed with NiMH batteries.
APPENDIX D External Component Sources List
Batteries
Duracell USA (HQ) Berkshire Corporate Park Bethel, CT 06801 (203) 796-4000 (800) 243-9540 FAX: (203) 730-8958
Energizer Power Systems Div. of Eveready Battery Co., Inc. Highway 441 North P.O. Box 147114 Gainesville, FL 32614-7114 (904) 462-3911 FAX: (904) 462-6210
GP Batteries (U.S.A.) Inc, 2772 Loker Avenue West Carlsbad, CA 92008 (619) 438-2202 FAX: (619) 438-0694
GS Battery (USA) Inc. 17253 Chestnut Street City of Industry, CA 91748 (818) 964-8348 FAX: (818) 810-9438
Hawker Energy Products, Inc. 617 N. Ridgeview Drive Warrensburg, MO 64093-9301 (816) 429-2165 FAX: (816) 429-2253
Panasonic Industrial Company Headquarters: P. O. Box 1511 Secaucus, NJ 07096 (201) 348-5272 FAX: (201) 392-4728
SAFT America, Inc. Otay Commerce Center 2155 Paseo de las Americas, #31 San Diego, CA 92173 (619) 661-7992 FAX: (619) 661-5096
SANYO Energy (U.S.A.) Corporation 2001 Sanyo Avenue San Diego, CA 92173 (619) 661-6620 FAX: (619) 661-6743
Tadiran Electronic Industries, Inc. 2 Seaview Boulevard Port Washington, NY 11050 (800) 786-9887 (516) 621-4980 FAX: (516) 621-4517
AN64-41
Application Note 64
Varta Batteries Inc. (USA) 300 Executive Boulevard Elmsford, NY 10523-1202 (914) 592-2500 FAX: (914) 592-2667
Inductors
Coiltronics, Inc. 6000 Park of Commerce Boulevard Boca Raton, FL 33487 (407) 241-7876 FAX: (407) 241-9339
Dale Electronics, Inc. East Highway 50 P.O. Box 180 Yankton, SD 57078-0180 (605) 665-9301 FAX: (605) 665-1627
Hurricane Electronics Lab P.O. Box 1280 331 North 2260 West Hurricane, UT 84737 (801) 635-2003 FAX: (801) 635-2495
Sumida Electric (USA) Corp., Ltd. 5999 New Wilkie Road Suite 110 Rolling Meadows, IL 60008 (847) 956-0666 FAX: (847) 956-0702
Thermistors
Alpha Thermistor and Assembly Inc. 7181 Construction Court San Diego, CA 92121 (619) 549-4660 FAX: (619) 549-4791
Panasonic Industrial Company Two Panasonic Way, 7H-3 Secaucus, NJ 07094 (201) 348-5232 FAX: (201) 392-4441
Phillips Components Discrete Products Division 2001 W. Blue Heron Blvd. P.O. Box 10330 Riviera Beach, FL 33404 (407) 881-3200
Thermometrics Inc. 808 U.S. Highway 1 Edison, NJ 08817 (908) 287-2870 FAX: (908) 287-8847
MOSFETs
International Rectifier U.S. World Headquarters 233 Kansas Street El Segundo, CA 90245 (310) 322-3331 FAX: (310) 322-3332
Motorola Semiconductor, Inc. 3102 North 56th Street MS56-126 Phoenix, AZ 85018 (800) 521-6274
Siliconix Inc. 2201 Laurelwood Road P.O. Box 54951 Santa Clara, CA 95056 (408) 988-8000 FAX: (408) 970-3950
Schottky Diodes
General Instrument Power Semiconductor Division 10 Melville Park Road Melville, NY 11747 (516) 847-3000
International Rectifier U.S. World Headquarters 233 Kansas Street El Segundo, CA 90245 (310) 322-3331 FAX: (310) 322-3332
Motorola Semiconductor, Inc. 3102 North 56th Street MS56-126 Phoenix, AZ 85018 (800) 521-6274
Polymer PTCs
Raychem Corporation PolySwitch Division 300 Constitution Drive Menlo Park, CA 94025-1164 (800) 272-9243, x6900 FAX: (800) 227-4866
Bimetallic Thermostats
Phillips Technologies Airpax Protector Group 550 Highland Avenue Frederick, MD 21701 (301) 663-5141 FAX: (301) 698-0624
Fenwal Electronics Inc. 450 Fortune Boulevard Milford, MA 01757 (508) 478-6000 FAX: (508) 473-6035
AN64-42
OFF
ON
AMPS
AN64 FC01
TO LOAD
SELENIUM INDUSTRIES, INC
VOLTS
H
Y D R O
LEAD-ACID
BATTERY
Early Battery Management
Application Note 64
SYSTEM
POWER
MANAGEMENT
µC
SEMI-REGULATED DC IN
INTERNAL
POWER
SUPPLY
µP
INTERFACE
CONTROL
LOGIC
PRECISION
REFERENCE
ANALOG
TO
DIGITAL
CONVERTER
DIGITAL
TO
ANALOG
CONVERTER
GAS
GAUGE
CIRCUITRY
SWITCHING
CHARGER CONTROL
BATTERY
AND 
SENSOR
SIGNAL
CONDITIONING
"HARD 
WIRED"
FAIL-SAFES
V
BAT
T
BAT
T
AMB
SPARE
V TOO HIGH V TOO LOW T TOO HIGH T TOO LOW t TOO LONG
LTC1325
TO DC/DC CONVERTER(S)
POWER
SWITCHING
CIRCUITRY
BATTERY
POWER SUPPLY ENABLES
SYSTEM LOAD ENABLES
Modern Battery Management
Information furnished by Linear Technology Corporation is believed to be accurate and reliable. However, no responsibility is assumed for its use. Linear Technology Corporation makes no represen­tation that the interconnection of its circuits as described herein will not infringe on existing patent rights.
AN64 FC02
AN64-43
Application Note 64
U.S. Area Sales Offices
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International Sales Offices
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Linear Technology Corporation
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TAIWAN Linear Technology Corporation
Rm. 602, No. 46, Sec. 2 Chung Shan N. Rd. Taipei, Taiwan, R.O.C. Phone: 886-2-521-7575 FAX: 886-2-562-2285
UNITED KINGDOM Linear Technology (UK) Ltd.
The Coliseum, Riverside Way Camberley, Surrey GU15 3YL United Kingdom Phone: 44-1276-677676 FAX: 44-1276-64851
AN64-44
World Headquarters
Linear Technology Corporation
1630 McCarthy Blvd. Milpitas, CA 95035-7417 Phone: (408) 432-1900 FAX: (408) 434-0507
Linear Technology Corporation
1630 McCarthy Blvd., Milpitas, CA 95035-7417
(408) 432-1900
FAX
: (408) 434-0507
TELEX
: 499-3977
0896
LT/GP 0896 5K REV A • PRINTED IN USA
LINEAR TECHNOLOGY CORPORATION 1994
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