Lexmark 12015SA User Manual

Section 1. Identification

SAFETY DATA SHEET

755 Toner

Solid.

GHS product identifier

Product type

Emergency telephone number (with hours of operation)

Supplier's details

Description :

Part number :

Toner ASM 755 SS Toner ASM 755 DR

15B0755 15B0756

For actual printer/cartridge compatibility please reference www.lexmark.com

Application

Laser Printer T430, E120

Lexmark International, Inc. 740 West New Circle Road Lexington, Ky 40550

e-mail address of person responsible for this SDS

rcassidy@lexmark.com

ChemTel: US/Canada/Puerto Rico 1-800-255-3924 International 1-813-248-0585 (Collect calls accepted)

24/7

Emergency :1-859-232-3333 Informations :1-859-232-2000

Conforms to US OSHA Hazard Communication 29CFR1910.1200

Section 2. Hazards identification

COMBUSTIBLE DUSTS

Classification of the substance or mixture

Signal word

Warning

Hazard statements

May form combustible dust concentrations in air.

Precautionary statements

Prevention

Not applicable.

Response

Not applicable.

Storage

Not applicable.

Disposal

Not applicable.

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 80.6%

General

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Supplemental label elements

Keep container tightly closed. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Prevent dust accumulation.

Hazards not otherwise classified

None known.

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

1/11

755 Toner

Section 3. Composition/information on ingredients

carbon black

≥5 - <10

1333-86-4

titanium dioxide

≥0.1 - <0.3

13463-67-7

Ingredient name

CAS number %

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:::

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

No known significant effects or critical hazards.

Ingestion

Skin contact

No known significant effects or critical hazards.

Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

No specific data.

::Eye contact

No specific data.

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

2/11

755 Toner

Section 4. First aid measures

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

No specific treatment.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides

Fine dust clouds may form explosive mixtures with air.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical powder.

Extinguishing media

:::

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

3/11

755 Toner

Section 6. Accidental release measures

Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or other ignition sources. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

carbon black

ACGIH TLV (United States, 4/2014).

TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction

NIOSH REL (United States, 10/2013).

TWA: 3.5 mg/m³ 10 hours.

TWA: 0.1 mg of PAHs/cm³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 3.5 mg/m³ 8 hours.

OSHA PEL 1989 (United States, 3/1989).

TWA: 3.5 mg/m³ 8 hours.

titanium dioxide

ACGIH TLV (United States, 4/2014).

TWA: 10 mg/m³ 8 hours.

OSHA PEL 1989 (United States, 3/1989).

TWA: 10 mg/m³ 8 hours. Form: Total dust

OSHA PEL (United States, 2/2013).

TWA: 15 mg/m³ 8 hours. Form: Total dust

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

4/11

+ 7 hidden pages