Lexmark 12015SA User Manual

Download

Page 1

Section 1. Identification

SAFETY DATA SHEET

755 Toner

Solid.

GHS product identifier

Product type

Emergency telephone number (with hours of operation)

Supplier's details

Description :

Part number :

Toner ASM 755 SS Toner ASM 755 DR

15B0755 15B0756

For actual printer/cartridge compatibility please reference www.lexmark.com

Application

Laser Printer T430, E120

Lexmark International, Inc. 740 West New Circle Road Lexington, Ky 40550

e-mail address of person responsible for this SDS

rcassidy@lexmark.com

ChemTel: US/Canada/Puerto Rico 1-800-255-3924 International 1-813-248-0585 (Collect calls accepted)

24/7

Emergency :1-859-232-3333 Informations :1-859-232-2000

Conforms to US OSHA Hazard Communication 29CFR1910.1200

Section 2. Hazards identification

COMBUSTIBLE DUSTS

Classification of the substance or mixture

Signal word

Warning

Hazard statements

May form combustible dust concentrations in air.

Precautionary statements

Prevention

Not applicable.

Response

Not applicable.

Storage

Not applicable.

Disposal

Not applicable.

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 80.6%

General

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Supplemental label elements

Keep container tightly closed. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Prevent dust accumulation.

Hazards not otherwise classified

None known.

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

1/11

Page 2

755 Toner

Section 3. Composition/information on ingredients

carbon black

≥5 - <10

1333-86-4

titanium dioxide

≥0.1 - <0.3

13463-67-7

Ingredient name

CAS number %

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:::

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

No known significant effects or critical hazards.

Ingestion

Skin contact

No known significant effects or critical hazards.

Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

No specific data.

::Eye contact

No specific data.

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

2/11

Page 3

755 Toner

Section 4. First aid measures

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician

In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

No specific treatment.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides

Fine dust clouds may form explosive mixtures with air.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Use dry chemical powder.

Extinguishing media

:::

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

3/11

Page 4

755 Toner

Section 6. Accidental release measures

Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Protective measures

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Prevent dust accumulation. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Electrical equipment and lighting should be protected to appropriate standards to prevent dust coming into contact with hot surfaces, sparks or other ignition sources. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.

Precautions for safe handling

carbon black

ACGIH TLV (United States, 4/2014).

TWA: 3 mg/m³ 8 hours. Form: Inhalable fraction

NIOSH REL (United States, 10/2013).

TWA: 3.5 mg/m³ 10 hours.

TWA: 0.1 mg of PAHs/cm³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 3.5 mg/m³ 8 hours.

OSHA PEL 1989 (United States, 3/1989).

TWA: 3.5 mg/m³ 8 hours.

titanium dioxide

ACGIH TLV (United States, 4/2014).

TWA: 10 mg/m³ 8 hours.

OSHA PEL 1989 (United States, 3/1989).

TWA: 10 mg/m³ 8 hours. Form: Total dust

OSHA PEL (United States, 2/2013).

TWA: 15 mg/m³ 8 hours. Form: Total dust

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

4/11

Page 5

755 Toner

Section 8. Exposure controls/personal protection

Hand protection

Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with sideshields.

Eye/face protection Respiratory protection

Body protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Other skin protection

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Solid. [Finely divided solid.]

Not available.

Faint odor.( Plastic.)

Odor

Black.

Color

Evaporation rate

Not applicable.

Flash point

Closed cup: Not applicable.

Not applicable.

Not available.

Odor threshold

:::

::::Appearance

Boiling point

Not available.

Burning rate

Not available.

Burning time

Not available.

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

5/11

Page 6

755 Toner

Section 9. Physical and chemical properties

Vapor pressure

Relative density

Vapor density

Solubility

Not available.

Insoluble in the following materials: cold water and hot water.

Auto-ignition temperature

Not available.

Viscosity

Not available.

Partition coefficient: noctanol/water

:::::

Flammability (solid, gas)

Not available.

Lower and upper explosive (flammable) limits

Not available.

SADT

Not available.

Decomposition temperature

Not available.

Solubility in water

Not available.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Avoid the creation of dust when handling and avoid all possible sources of ignition (spark or flame). Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Prevent dust accumulation.

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.

Chemical stability

Reactive or incompatible with the following materials: oxidizing materials

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

carbon black

LD50 Oral

Rat

>15400 mg/kg

755 Toner

LC50 Inhalation Vapor

Rat

>5000 mg/l

4 hours

LD50 Oral

Rat

>5000 mg/kg

Product/ingredient name

Result

Species

Dose

Exposure

Irritation/Corrosion

titanium dioxide

Skin - Mild irritant

Human

72 hours 300 Micrograms Intermittent

Product/ingredient name

Result

Score

Exposure

Observation

Species

Information on toxicological effects

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

6/11

Page 7

755 Toner

Section 11. Toxicological information

Carcinogenicity

Not available.

Conclusion/Summary

Low acute inhalation toxicity. As with exposure to high concentrations of any dust, minimal irritation of the respiratory tract may occur. Pure carbon black and titanium dioxide, minor components of this product, has been listed by IARC as a group 2B (possible carcinogen). This classification is based on rat "lung particulate overload" studies performed with airborne particulate. Toner is not listed by IARC, NTP, or OSHA.

Mutagenicity

Not available.

Conclusion/Summary

Not mutagenic in Ames test.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Sensitization

Not available.

Information on the likely routes of exposure

Inhalation

No known significant effects or critical hazards.

Ingestion

Skin contact

No known significant effects or critical hazards.

Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation

No specific data.

:::

Eye contact

No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Not available.

Name

Category

carbon black

Category 1

Not determined

lungs

Aspiration hazard

Not available.

Route of exposure

Target organs

Routes of entry anticipated: Dermal, Inhalation.

Potential acute health effects

Classification

carbon black

-2B-

titanium dioxide

-2B-

Product/ingredient name

NTP

IARC

OSHA

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

7/11

Page 8

755 Toner

Section 11. Toxicological information

Not available.

No known significant effects or critical hazards.

General

No known significant effects or critical hazards.

Carcinogenicity

No known significant effects or critical hazards. Toner is negative (nonmutagenic) in the Ames assay.

Mutagenicity

No known significant effects or critical hazards.

Teratogenicity

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Not available.

Acute toxicity estimates

Potential immediate effects

Not available.

Short term exposure

Potential delayed effects

Not available.

Potential immediate effects

Not available.

Long term exposure

Potential delayed effects

Not available.

Section 12. Ecological information

LogP

BCF

Potential

Bioaccumulative potential

Product/ingredient name

titanium dioxide

352

low

Toxicity

carbon black

Acute EC50 37.563 mg/l Fresh water

Daphnia - Daphnia magna Neonate

48 hours

titanium dioxide

Acute LC50 3 mg/l Fresh water

Crustaceans - Ceriodaphnia dubia - Neonate

48 hours

Acute LC50 6.5 mg/l Fresh water

Daphnia - Daphnia pulex Neonate

48 hours

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

755 Toner

Acute EC50 >1000 mg/l

Daphnia

48 hours

Product/ingredient name

Species

Result

Exposure

Persistence and degradability

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

Not available.

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

8/11

Page 9

755 Toner

Section 12. Ecological information

Other adverse effects

No known significant effects or critical hazards.

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

Section 14. Transport information

Not regulated.

---

DOT

Classification

IMDG

IATA

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No.

Transport within user’s premises:

always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Not available.

TDG

Classification

Not regulated.

No.-ADR/RID

Not regulated.

No.-Mexico

Classification

Not regulated.

No.

Section 15. Regulatory information

United States

TSCA (USA)

All ingredients are listed on the Toxic Substances Control Act (TSCA) inventory, have been registered, or are exempt.

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

9/11

Page 10

755 Toner

Section 15. Regulatory information

Canada

WHMIS (Canada)

Not controlled under WHMIS (Canada).

SARA / EPCRA (USA)

None of the ingredients in this product has a final reportable quantity (RQ) under Emergency Planning and Community Right-to Know Act (EPCRA)- Section 302: Extremely Hazardous Substances (EHS) or notification requirements for EHS under Section 304.

California Prop. 65

This product contains no known materials at levels which the State of California has found to cause cancer, birth defects or other reproductive harm - California Proposition

65.

EINECS (Europe)

All ingredients are listed on the European Inventory of Existing Commercial Substances (EINECS) list, have been registered on the European List of New Chemical Substances (ELINCS), or are exempt.

ENCS (Japan)

All ingredients are listed on the Japanese Existing and New Chemical Substances (ENCS) list, have been registered, or are exempt.

AICS (Australia)

All ingredients are listed in Australian Inventory of Chemical Substances (AICS), have been registered, or are exempt.

International regulations lists

DSL/NDSL

All ingredients are listed on the Canadian Domestic Substances List (DSL), have been registered on the Non-Domestic Substances List (NDSL), or are exempt.

Mexico Classification

Health: 1 Flammability: 1 Reactivity: 0

Philippines inventory (PICCS)

All ingredients are listed on the Philippines Inventory (PICCS) or are exempt.

Korea inventory (KECI)

All ingredients are listed on the Korean Existing Chemicals List (ECL), have been registered, or are exempt.

China inventory (IECSC)

All ingredients are listed on the Chinese inventory (IECSC) or are exempt.

REACH Status

EU (REACH): All components of the toner formulation are registered, pre-registered or exempt under REACH. Pre-registered chemicals will be registered between 2011 and

2018.

Section 16. Other information

History

Date of issue/Date of revision

Version

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

References

HCS (U.S.A.)- Hazard Communication Standard International transport regulations IATA Dangerous Goods Regulation (DGR) 55th Edition 2014

Key to abbreviations

ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

6/15/2015.

2/6/2015.

1.01

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

10/11

Page 11

755 Toner

Section 16. Other information

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Date of issue/Date of revision

6/15/2015.

Date of previous issue

2/6/2015.

Version

1.01

11/11