Lenox® Band Ade®
CHEMTREC (U.S. and Canada) 1800-424-9300
CHEMTREC (Outside the U.S.) 1-703-527-0585
SAFETY DATA SHEET
Product name
Emergency telephone
number (with hours of
operation)
Section 1. Identification
:
:
Manufacturer
:
Lenox Tools
301 Chestnut Street
East Longmeadow, MA 01028
Material uses
:
Metalworking fluid
Section 2. Hazards identification
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
SKIN SENSITIZATION - Category 1
Classification of the
substance or mixture
:
Signal word
:
Warning
Hazard statements
:
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Hazard pictograms
:
Precautionary statements
Prevention
:
Wear protective gloves. Wear eye or face protection. Avoid breathing vapor. Wash
hands thoroughly after handling. Contaminated work clothing should not be allowed out
of the workplace.
Response
:
IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing.
Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage
:
Not applicable.
Disposal
:
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 17.8%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Hazards not otherwise
classified
:
None known.
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:31/10
Lenox® Band Ade®
Section 3. Composition/information on ingredients
Propane-1,2-diol, propoxylated
10 - 20
25322-69-4
Distillates (petroleum), hydrotreated light
2 - 5
64742-47-8
2,2',2''-nitrilotriethanol
2 - 5
102-71-6
2-butylaminoethanol
0.1 - 2
111-75-1
2-aminoethanol
0.1 - 2
141-43-5
2,2',2"-(hexahydro-1,3,5-triazine-1,3,5-triyl)triethanol
0.1 - 2
4719-04-4
Ingredient name
CAS number
%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Substance/mixture
:
Mixture
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention if adverse health
effects persist or are severe. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects
persist or are severe. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:32/10
Lenox® Band Ade®
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
:
No specific treatment.
Skin contact
Ingestion
Inhalation
No specific data.
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
CO₂,
water, water spray, Foam
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialised clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:33/10
Lenox® Band Ade®
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.
Large spill
:
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Small spill
:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
(see Section 10) and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully resealed and kept
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate
containment to avoid environmental contamination.
:
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Do not get in eyes or on skin or clothing. Do not ingest. Avoid
breathing vapor or mist. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Empty containers retain
product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Propane-1,2-diol, propoxylated
AIHA WEEL (United States, 10/2011).
TWA: 10 mg/m³ 8 hours. Form: Aerosol
Distillates (petroleum), hydrotreated light
ACGIH TLV (United States, 6/2013).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.
2,2',2''-nitrilotriethanol
ACGIH TLV (United States, 6/2013).
TWA: 5 mg/m³ 8 hours.
2-aminoethanol
ACGIH TLV (United States, 6/2013).
TWA: 3 ppm 8 hours.
TWA: 7.5 mg/m³ 8 hours.
STEL: 6 ppm 15 minutes.
STEL: 15 mg/m³ 15 minutes.
OSHA PEL 1989 (United States, 3/1989).
TWA: 3 ppm 8 hours.
TWA: 8 mg/m³ 8 hours.
STEL: 6 ppm 15 minutes.
STEL: 15 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 3 ppm 10 hours.
TWA: 8 mg/m³ 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:34/10
Lenox® Band Ade®
Section 8. Exposure controls/personal protection
STEL: 6 ppm 15 minutes.
STEL: 15 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 3 ppm 8 hours.
TWA: 6 mg/m³ 8 hours.
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
:
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
Good general ventilation should be sufficient to control worker exposure to airborne
contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Individual protection measures
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Liquid.
Not available.
Characteristic.
Odor
pH
Yellow.
Color
Evaporation rate
Not available.
Flash point
Not available.
9.65
Not available.
Odor threshold
:
:
:::
:::
Appearance
Boiling point
:
100°C (212°F)
Burning rate
Not applicable.
:
Burning time
:
Not applicable.
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:35/10
Lenox® Band Ade®
Section 9. Physical and chemical properties
Vapor pressure
Relative density
Vapor density
Solubility
1.0104
Not available.
Not available.
Easily soluble in the following materials: cold water and hot water.
Auto-ignition temperature
Not available.
Not available.
Viscosity
Not available.
Partition coefficient: noctanol/water
:::
:
:::
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Not available.
SADT
Not available.
:
Decomposition temperature
:
Not available.
Solubility in water
:
Not available.
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
No specific data.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.
Chemical stability
strong acids, oxidizing substances, nitrates, nitrites
:
:
:
Incompatible materials
:
Possibility of hazardous
reactions
:
No specific data.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
2,2',2''-nitrilotriethanol
LD50 Oral
Rat
7.39 g/kg
-
2-butylaminoethanol
LD50 Oral
Rat
1150 mg/kg
-
2-aminoethanol
LD50 Oral
Rat
1720 mg/kg
-
2,2',2"-(hexahydro-1,3,
5-triazine-1,3,5-triyl)triethanol
LD50 Oral
Rat
763 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Irritation/Corrosion
Propane-1,2-diol,
propoxylated
Eyes - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
Eyes - Mild irritant
Rabbit
-
500
milligrams
-
Skin - Mild irritant
Rabbit
-
500
milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
2,2',2''-nitrilotriethanol
Eyes - Mild irritant
Rabbit
-
10 milligrams
-
Eyes - Severe irritant
Rabbit
-
20 milligrams
-
Skin - Mild irritant
Human
-
72 hours 15
milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Species
Information on toxicological effects
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:36/10
Lenox® Band Ade®
Section 11. Toxicological information
Carcinogenicity
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
Intermittent
Skin - Severe irritant
Mouse
-
50 Percent
-
Skin - Mild irritant
Rabbit
-
24 hours 560
milligrams
-
2-aminoethanol
Eyes - Severe irritant
Rabbit
-
250
Micrograms
-
Skin - Moderate irritant
Rabbit
-
505
milligrams
-
Sensitization
No known significant effects or critical hazards.
Information on the likely
routes of exposure
Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
2-aminoethanol
Category 3
Not applicable.
Respiratory tract
irritation
Name
Category
No known significant effects or critical hazards.
Aspiration hazard
Name
Result
Distillates (petroleum), hydrotreated light
ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
:
Not available.
Potential immediate
effects
:
Causes serious eye irritation. Causes skin irritation.
Short term exposure
Potential delayed effects
:
May cause an allergic skin reaction.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Classification
2,2',2''-nitrilotriethanol
-3-
Product/ingredient name
NTP
IARC
OSHA
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:37/10
Lenox® Band Ade®
Section 11. Toxicological information
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Numerical measures of toxicity
No known significant effects or critical hazards.
Acute toxicity estimates
Section 12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
Propane-1,2-diol,
propoxylated
-0.68 to 0.01
-
low
2,2',2''-nitrilotriethanol
-1
<3.9
low
2-butylaminoethanol
-
3.16
low
2-aminoethanol
-1.31
-
low
2,2',2"-(hexahydro-1,3,
5-triazine-1,3,5-triyl)triethanol
-2-low
Toxicity
Propane-1,2-diol,
propoxylated
Acute LC50 650000 µg/l Marine water
Fish - Menidia beryllina
96 hours
Distillates (petroleum),
hydrotreated light
Acute LC50 2200 µg/l Fresh water
Fish - Lepomis macrochirus
4 days
2,2',2''-nitrilotriethanol
Acute LC50 100000 µg/l Marine water
Crustaceans - Crangon crangon Adult
48 hours
Acute LC50 11800000 µg/l Fresh water
Fish - Pimephales promelas
96 hours
Chronic NOEC 16000 µg/l Fresh water
Daphnia - Daphnia magna
21 days
2-aminoethanol
Acute EC50 8.42 mg/l Fresh water
Algae - Desmodesmus
subspicatus
72 hours
Acute LC50 100000 µg/l Marine water
Crustaceans - Crangon crangon Adult
48 hours
Acute LC50 170000 µg/l Fresh water
Fish - Carassius auratus
96 hours
2,2',2"-(hexahydro-1,3,
5-triazine-1,3,5-triyl)triethanol
Acute EC50 26.1 ppm Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 39 ppm Fresh water
Fish - Lepomis macrochirus
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
No known significant effects or critical hazards.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
:
Disposal methods
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:38/10
Lenox® Band Ade®
Section 13. Disposal considerations
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Section 14. Transport information
-
-
-
-
-
-
-
Not regulated.
-
-
Not regulated.
Not regulated.
---
DOT
Classification
IMDG
IATA
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
No.
No.
No.
Transport within user’s premises:
always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
:
TDG
Classification
Not regulated.
-
-
-
No.
-
Mexico
Classification
Not regulated.
-
-
-
No.
-
Section 15. Regulatory information
U.S. Federal regulations
:
United States inventory (TSCA 8b)
: All components are listed or exempted.
SARA 311/312
Classification
:
Immediate (acute) health hazard
Delayed (chronic) health hazard
Propane-1,2-diol, propoxylated
10 - 20
No.
No.
No.
Yes.
No.
Distillates (petroleum), hydrotreated
light
2 - 5
Yes.
No.
No.
No.
No.
2,2',2''-nitrilotriethanol
2 - 5
No.
No.
No.
Yes.
No.
2-butylaminoethanol
0.1 - 2
No.
No.
No.
Yes.
No.
2-aminoethanol
0.1 - 2
Yes.
No.
No.
Yes.
No.
2,2',2"-(hexahydro-1,3,5-triazine-1,3,
5-triyl)triethanol
0.1 - 2
No.
No.
No.
Yes.
No.
Name
%
Fire
hazard
Sudden
release of
pressure
Reactive
Immediate
(acute)
health
hazard
Delayed
(chronic)
health
hazard
Composition/information on ingredients
WARNING:
This product contains less than 0.1% of a chemical known to the State of California to cause cancer.
WARNING:
This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.
California Prop. 65
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:39/10
Lenox® Band Ade®
Section 15. Regulatory information
The following components are listed: Hydrotreated light distillate
Class D-2B: Material causing other toxic effects (Toxic).
None of the components are listed.
Canada
WHMIS (Canada)
Canadian lists
Canadian NPRI
CEPA Toxic substances
:
:
:
Canada inventory
:
At least one component is not listed in DSL but all such components are listed in NDSL.
ethylene oxide
Yes.
Yes.
Yes.
Yes.
1,4-dioxane
Yes.
No.
Yes.
No.
ethyl acrylate
Yes.
No.
No.
No.
Ingredient name
Cancer
Reproductive
No significant risk
level
Maximum
acceptable dosage
level
Section 16. Other information
History
Date of issue/Date of
revision
Version
Prepared by
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is
based on our current level of knowledge and on national and community regulations. The mixture must not be
used for other uses than those specified in section 1 without having first obtained written handling instructions. It
is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and
local regulations. The information in this safety data sheet must be regarded as a description of the safety
requirements relating to the mixture and not as a guarantee of the properties thereof.
Date of previous issue
:
:::
Indicates information that has changed from previously issued version.
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
UN = United Nations
3/12/2015.
1/23/2015.
3
Product Safety.
Date of issue/Date of revision
:
3/12/2015.
Date of previous issue
:
1/23/2015.
Version
:310/10
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