SP™030 Blue RTV Silicone Sealant
Not available.
Spray
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer
:
Sprayon Products
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
S00030000
S00030000
Product code
:
Product Information
Telephone Number
:
(800)247-3266
Regulatory Information
Telephone Number
:
(216)566-2902
Transportation Emergency
Telephone Number
:
(800)424-9300
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
TOXIC TO REPRODUCTION (Fertility) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard pictograms
:
Precautionary statements
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear eye
or face protection. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after
use. Do not spray on an open flame or other ignition source. Do not breathe vapor.
Wash hands thoroughly after handling.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 56.3%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes eye irritation.
Suspected of damaging fertility.
May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:11/10
Section 2. Hazards identification
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:
None known.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. FOR
INDUSTRIAL USE ONLY.
Section 3. Composition/information on ingredients
Octamethylcyclotetrasiloxane
30.3
556-67-2
1,1-Difluoroethane
4.0
75-37-6
Middle Petroleum Distillates
2.9
64742-46-7
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Get medical attention.
Get medical attention following exposure or if feeling unwell.
Continue to rinse for at least 10 minutes. Get medical attention.
It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
Exposure to decomposition products may cause a health hazard. Serious effects may
be delayed following exposure.
May be irritating to mouth, throat and stomach.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Potential acute health effects
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:12/10
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
:
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments
:
No specific treatment.
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:::
Eye contact
:
Adverse symptoms may include the following:
irritation
watering
redness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds
carbonyl halides
metal oxide/oxides
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Special protective
equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:13/10
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
:
:
In the case of aerosols being ruptured, care should be taken due to the rapid escape of
the pressurized contents and propellant. If a large number of containers are ruptured,
treat as a bulk material spillage according to the instructions in the clean-up section.
Shut off all ignition sources. No flares, smoking or flames in hazard area.
No specific hazard.
Large spill
:
Use spark-proof tools and explosion-proof equipment.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Protect from sunlight. Store locked up.
Eliminate all ignition sources.
:
:
Protective measures
Pressurized container: protect from sunlight and do not expose to temperatures
exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special
instructions before use. Avoid exposure during pregnancy. Do not handle until all
safety precautions have been read and understood. Do not get in eyes or on skin or
clothing. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools.
:
Precautions for safe handling
1,1-Difluoroethane
AIHA WEEL (United States, 10/2011).
TWA: 1000 ppm 8 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Environmental exposure
controls
:
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
If user operations generate dust, fumes, gas, vapor or mist, use process enclosures,
local exhaust ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapor or dust concentrations below any lower explosive
limits. Use explosion-proof ventilation equipment.
Control parameters
Individual protection measures
Occupational exposure limits
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:14/10
Section 8. Exposure controls/personal protection
Hand protection
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
1.02
2.4 [Air = 1]
13.5 kPa (101 mm Hg) [at 20°C]
Not available.
Not available.
Odor
pH
Not available.
Color
Evaporation rate
Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Not available.
Not available.
Viscosity
Kinematic (room temperature): >0.205 cm2/s (>20.5 cSt)
Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.
Odor threshold
Partition coefficient: noctanol/water
:
:::
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Lower: 3.9%
Upper: 16.9%
Decomposition temperature
:
Not available.
Type of aerosol
:
Spray
Heat of combustion
:
3.823 kJ/g
Aerosol product
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:15/10
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
Avoid all possible sources of ignition (spark or flame).
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.
Chemical stability
No specific data.
:
::Incompatible materials
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Octamethylcyclotetrasiloxane
LC50 Inhalation Vapor
Rat
36 g/m³
4 hours
LD50 Dermal
Rat
1770 mg/kg
-
LD50 Oral
Rat
1540 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Irritation/Corrosion
Octamethylcyclotetrasiloxane
Eyes - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
Skin - Mild irritant
Rabbit
-
24 hours 500
milligrams
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
1,1-Difluoroethane
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
Middle Petroleum Distillates
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
Name
Category
Route of
exposure
Target organs
Information on toxicological effects
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:16/10
Section 11. Toxicological information
Name
Category
1,1-Difluoroethane
Category 2
Not determined
Not determined
Middle Petroleum Distillates
Category 2
Not determined
Not determined
Aspiration hazard
Name
Result
Middle Petroleum Distillates
ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Not available.
Information on the likely
routes of exposure
Inhalation
:
Exposure to decomposition products may cause a health hazard. Serious effects may
be delayed following exposure.
May be irritating to mouth, throat and stomach.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes eye irritation.
:
Eye contact
May cause damage to organs through prolonged or repeated exposure.
General
:
No known significant effects or critical hazards.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact
:
Adverse symptoms may include the following:
irritation
watering
redness
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
:
Not available.
Potential acute health effects
Potential immediate
effects
:
Not available.
Short term exposure
Potential delayed effects
:
Not available.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:17/10
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
Suspected of damaging fertility.
Numerical measures of toxicity
Oral
2073.1 mg/kg
Dermal
2551.9 mg/kg
Route
ATE value
Acute toxicity estimates
Section 12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
Octamethylcyclotetrasiloxane
-
13400
high
Toxicity
Octamethylcyclotetrasiloxane
Chronic NOEC 1.7 to 15 µg/l Fresh water
Daphnia - Daphnia magna
21 days
Chronic NOEC 4.4 µg/l Fresh water
Fish - Oncorhynchus mykiss Egg
93 days
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:
Not available.
Mobility in soil
Not available.
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues.
:
Disposal methods
Section 14. Transport information
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:18/10
Section 14. Transport information
AEROSOLS
2.2
-
AEROSOLS
2.2
-
UN1950
UN1950
Special
provisions
LIMITED
QUANTITY
Emergency
schedules (EmS)
LIMITED
QUANTITY, F-D,
S-U
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code
No.
No.
:
Not available.
:
TDG
Classification
UN1950
AEROSOLS
2.2
-
No.
Special
provisions
LIMITED
QUANTITY
Mexico
Classification
UN1950
AEROSOLS
2.2
-
No.
Special
provisions
(ERG#126)
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.
IATA
UN1950
Aerosols, nonflammable
2.2
-
No.
Special
provisions
LIMITED
QUANTITY
Section 15. Regulatory information
U.S. Federal regulations
:
State regulations
Section 16. Other information
Hazardous Material Information System (U.S.A.)
2
2
0
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:19/10
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.
Notice to reader
Date of issue/Date of revision
:
6/1/2015.
Date of previous issue
:
No previous validation.
Version
:110/10
Loading...