Krylon S00020000 User Manual

SP™020 White RTV Silicone Sealant

Not available.
Spray

[phone]

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

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:
:

:

Manufacturer

:

Sprayon Products
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

S00020000

S00020000

Product code

:

Product Information
Telephone Number

:

[phone]

Regulatory Information
Telephone Number

:

[phone]

Transportation Emergency
Telephone Number

:

[phone]

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2B
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Fertility) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Classification of the
substance or mixture

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Signal word

:

Danger

Hazard pictograms

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Precautionary statements

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 56.3%

OSHA/HCS status

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This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes eye irritation.
Suspected of damaging fertility.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

No previous validation.

Version

:11/11

Section 2. Hazards identification

Prevention

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Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear eye
or face protection. Keep away from heat, hot surfaces, sparks, open flames and other
ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after
use. Do not spray on an open flame or other ignition source. Do not breathe vapor.
Wash hands thoroughly after handling.

Response

:

Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.

Storage

:

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

None known.

Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.

Supplemental label
elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains a chemical known to the State of California to cause cancer.
FOR INDUSTRIAL USE ONLY.

Section 3. Composition/information on ingredients

Octamethylcyclotetrasiloxane

30.3

556-67-2

1,1-Difluoroethane

4.0

75-37-6

Middle Petroleum Distillates

2.9

64742-46-7

Titanium Dioxide

1.1

13463-67-7

Ingredient name

CAS number
% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Get medical attention.

Get medical attention.

Continue to rinse for at least 10 minutes. Get medical attention.

It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

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:

:

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Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Potential acute health effects

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

No previous validation.

Version

:12/11

Section 4. First aid measures

Protection of first-aiders

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No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician

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In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.

Specific treatments

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No specific treatment.

Inhalation

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Exposure to decomposition products may cause a health hazard. Serious effects may
be delayed following exposure.

May be irritating to mouth, throat and stomach.

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Ingestion

Skin contact

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No known significant effects or critical hazards.

Causes eye irritation.

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Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
reduced fetal weight
increase in fetal deaths
skeletal malformations

:::

Eye contact

:

Adverse symptoms may include the following:
irritation
watering
redness

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
halogenated compounds
carbonyl halides
metal oxide/oxides

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

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:

None known.

Suitable extinguishing
media

:

Unsuitable extinguishing
media

:

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

No previous validation.

Version

:13/11

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Special protective
equipment for fire-fighters

:

Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

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:

In the case of aerosols being ruptured, care should be taken due to the rapid escape of
the pressurized contents and propellant. If a large number of containers are ruptured,
treat as a bulk material spillage according to the instructions in the clean-up section.
Shut off all ignition sources. No flares, smoking or flames in hazard area.

No specific hazard.

Large spill

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Use spark-proof tools and explosion-proof equipment.

Small spill

:

Methods and materials for containment and cleaning up

For non-emergency
personnel

For emergency responders

:

If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any
incompatibilities

Workers should wash hands and face before eating, drinking and smoking. Remove
contaminated clothing and protective equipment before entering eating areas. See also
Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Protect from sunlight. Store locked up.
Eliminate all ignition sources.

:

:

Protective measures

Pressurized container: protect from sunlight and do not expose to temperatures
exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special
instructions before use. Avoid exposure during pregnancy. Do not handle until all
safety precautions have been read and understood. Do not get in eyes or on skin or
clothing. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools.

:

Precautions for safe handling

1,1-Difluoroethane

AIHA WEEL (United States, 10/2011).

TWA: 1000 ppm 8 hours.

Titanium Dioxide

ACGIH TLV (United States, 4/2014).

TWA: 10 mg/m³ 8 hours.

OSHA PEL (United States, 2/2013).

TWA: 15 mg/m³ 8 hours. Form: Total dust

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

No previous validation.

Version

:14/11