Krylon K42130404-20 User Manual
KRYLON® LINE-UP® Solvent-Based Pavement Striping Paint
Parking Lot White
Not available.
Liquid.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:::
Manufacturer
:
THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
K42130404
K42130404
Product code
:
Product Information
Telephone Number
:
(800) 247-3266
Regulatory Information
Telephone Number
:
(216) 566-2902
Transportation Emergency
Telephone Number
:
(800) 424-9300
Section 2. Hazards identification
FLAMMABLE LIQUIDS - Category 2
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard pictograms
:
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 33.9%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Highly flammable liquid and vapor.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:11/14
Section 2. Hazards identification
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Use explosion-proof
electrical, ventilating, lighting and all material-handling equipment. Use only nonsparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor.
Wash hands thoroughly after handling.
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing. If skin irritation occurs: Get medical attention. IF IN EYES:
Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage
:
Store locked up. Store in a well-ventilated place. Keep cool.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:
None known.
Please refer to the SDS for additional information. Do not transfer contents to other
containers for storage.
Supplemental label
elements
Adequate ventilation required when sanding or abrading the dried film. If Adequate
ventilation cannot be provided wear an approved particulate respirator (NIOSH
approved). Follow respirator manufacturer's directions for respirator use. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film
may release crystalline silica which has been shown to cause lung damage and cancer
under long term exposure. DELAYED EFFECTS FROM LONG TERM
OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous
system damage. Intentional misuse by deliberately concentrating and inhaling the
contents can be harmful or fatal. WARNING: This product contains chemicals known
to the State of California to cause cancer and birth defects or other reproductive harm.
FOR INDUSTRIAL USE ONLY.
Section 3. Composition/information on ingredients
Calcium Carbonate
34.4
471-34-1
Acetone
26.9
67-64-1
Titanium Dioxide
6.2
13463-67-7
Chlorinated Paraffin
2.6
63449-39-8
Xylene
2.4
1330-20-7
Ethylbenzene
0.4
100-41-4
Quartz
0.2
14808-60-7
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Other means of
identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:12/14
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. Irritating to mouth, throat and
stomach.
:
Ingestion
Skin contact
:
Causes skin irritation.
Causes serious eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
No specific data.
Adverse symptoms may include the following:
irritation
redness
:
:
:
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:13/14
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
See toxicological information (Section 11)
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
and the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
Use dry chemical,
CO₂,
water spray (fog) or foam.
Extinguishing media
:
:
:
Do not use water jet.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:14/14
Section 6. Accidental release measures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Large spill
:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well-ventilated
area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.
:
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Avoid exposure obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
:
Precautions for safe handling
Calcium Carbonate
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³ 8 hours. Form: Respirable
fraction
TWA: 15 mg/m³ 8 hours. Form: Total dust
Acetone
ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:15/14
Loading...