Page 1
KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
Not available.
Aerosol.
US/Canada: (216) 566-2917
Mexico: CHEMTREC Mexico 01-800-681-9531. Available 24 hours and 365 days per
year
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:
:
:
Manufacturer
:
Krylon Products Group
101 Prospect Avenue NW
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Paint or paint related material.
K07908000
K07908000
Product code
:
Product Information
Telephone Number
:
US/Canada: (800) 247-3266
Mexico: Not Available
Regulatory Information
Telephone Number
:
US/Canada: (216) 566-2902
Mexico: Not Available
Transportation Emergency
Telephone Number
:
US/Canada: (800) 424-9300
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard pictograms
:
Precautionary statements
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 34.9%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 34.9%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 5%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Suspected of causing cancer.
May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:111/13
K07908000
KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
Page 2
Section 2. Hazards identification
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Do not breathe dust or mist. Wash hands thoroughly after handling.
Pressurized container: Do not pierce or burn, even after use.
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise
classified
:
None known.
Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.
Supplemental label
elements
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
:
Section 3. Composition/information on ingredients
Dimethyl Ether
≥25 - ≤50
115-10-6
2-Butoxyethanol
<10
111-76-2
2-Propanol
≤5
67-63-0
Carbon Black
≤1
1333-86-4
Heavy Aromatic Naphtha
<1
64742-94-5
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.
Other means of
identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Occupational exposure limits, if available, are listed in Section 8.
Mixture
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
:
:
:
Description of necessary first aid measures
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:112/13
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KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
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Section 4. First aid measures
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight clothing
such as a collar, tie, belt or waistband.
Ingestion
:
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes serious eye irritation.
:
Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
No specific data.
:::
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Hazardous thermal
decomposition products
Specific hazards arising
from the chemical
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In
a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel
a considerable distance to a source of ignition and flash back, causing fire or explosion.
Bursting aerosol containers may be propelled from a fire at high speed.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:113/13
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KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
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Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
:
Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Advice on general
occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
:
Protective measures
Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
:
Precautions for safe handling
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:114/13
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KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
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Section 7. Handling and storage
Conditions for safe storage,
including any
incompatibilities
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.
:
Dimethyl Ether
AIHA WEEL (United States, 7/2018).
TWA: 1000 ppm 8 hours.
2-Butoxyethanol
ACGIH TLV (United States, 3/2018).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2016).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.
OSHA PEL (United States, 5/2018).
Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 240 mg/m³ 8 hours.
2-Propanol
ACGIH TLV (United States, 3/2018).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
NIOSH REL (United States, 10/2016).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 5/2018).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Carbon Black
NIOSH REL (United States, 10/2016).
TWA: 3.5 mg/m³ 10 hours.
TWA: 0.1 mg of PAHs/cm³ 10 hours.
ACGIH TLV (United States, 3/2018).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction
OSHA PEL (United States, 5/2018).
TWA: 3.5 mg/m³ 8 hours.
Heavy Aromatic Naphtha
None.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits (OSHA United States)
Ethylene glycol monobutyl ether
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 97 mg/m³ 8 hours.
8 hrs OEL: 20 ppm 8 hours.
CA British Columbia Provincial (Canada,
7/2018).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 1/2018).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 20 ppm 8 hours.
TWAEV: 97 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
Ingredient name
Exposure limits
Occupational exposure limits (Canada)
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:115/13
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KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
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Section 8. Exposure controls/personal protection
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Appropriate engineering
controls
:
Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits. The engineering controls also need to keep gas, vapor or dust concentrations
below any lower explosive limits. Use explosion-proof ventilation equipment.
Individual protection measures
STEL: 30 ppm 15 minutes.
TWA: 20 ppm 8 hours.
Isopropyl alcohol
CA Alberta Provincial (Canada, 6/2018).
15 min OEL: 984 mg/m³ 15 minutes.
8 hrs OEL: 200 ppm 8 hours.
15 min OEL: 400 ppm 15 minutes.
8 hrs OEL: 492 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
7/2018).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
CA Ontario Provincial (Canada, 1/2018).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 400 ppm 8 hours.
TWAEV: 983 mg/m³ 8 hours.
STEV: 500 ppm 15 minutes.
STEV: 1230 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 400 ppm 15 minutes.
TWA: 200 ppm 8 hours.
Carbon black
CA British Columbia Provincial (Canada,
7/2018).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
CA Ontario Provincial (Canada, 1/2018).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction.
CA Alberta Provincial (Canada, 6/2018).
8 hrs OEL: 3.5 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 3.5 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 7 mg/m³ 15 minutes.
TWA: 3.5 mg/m³ 8 hours.
Environmental exposure
controls
:
2-Butoxyethanol
NOM-010-STPS-2014 (Mexico, 4/2016).
Absorbed through skin.
TWA: 20 ppm 8 hours.
2-Propanol
NOM-010-STPS-2014 (Mexico, 4/2016).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
Ingredient name
Exposure limits
Occupational exposure limits (Mexico)
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:116/13
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KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
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Section 8. Exposure controls/personal protection
Hand protection
Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/face protection
Respiratory protection
:
:
:
Body protection
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
:
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Hygiene measures
:
Skin protection
Other skin protection
:
Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point/freezing point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
0.84
1 [Air = 1]
101.3 kPa (760 mm Hg) [at 20°C]
Not available.
Not available.
Odor
pH
Not available.
Color
Evaporation rate
1.44 (butyl acetate = 1)
Auto-ignition temperature
Flash point
Not available.
Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Not available.
9
Viscosity
Kinematic (40°C (104°F)): >0.205 cm2/s (>20.5 cSt)
Not available.
Odor threshold
Partition coefficient: noctanol/water
:::
:::::
:::
:::
:
Appearance
Boiling point/boiling range
:
Not available.
Flammability (solid, gas)
:
Not available.
Lower and upper explosive
(flammable) limits
:
Lower: 1.1%
Upper: 27%
Decomposition temperature
:
Not available.
Molecular weight
:
Not applicable.
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:117/13
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KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
Page 8
Section 9. Physical and chemical properties
Type of aerosol
:
Spray
Heat of combustion
:
13.23 kJ/g
Aerosol product
Section 10. Stability and reactivity
Hazardous decomposition
products
Conditions to avoid
Avoid all possible sources of ignition (spark or flame).
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
The product is stable.
Chemical stability
No specific data.
:
:
:
Incompatible materials
:
Possibility of hazardous
reactions
:
Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity
:
No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
Dimethyl Ether
LC50 Inhalation Gas.
Rat
164000 ppm
4 hours
LC50 Inhalation Vapor
Rat
309 g/m³
4 hours
2-Butoxyethanol
LCLo Inhalation Vapor
Guinea pig
>3.1 mg/l
1 hours
LD50 Dermal
Guinea pig
>2000 mg/kg
-
LD50 Oral
Rat
1300 mg/kg
-
2-Propanol
LD50 Dermal
Rabbit
12800 mg/kg
-
LD50 Oral
Rat
5000 mg/kg
-
Carbon Black
LD50 Oral
Rat
>15400 mg/kg
-
Product/ingredient name
Result
Species
Dose
Exposure
Carcinogenicity
Mutagenicity
Not available.
Irritation/Corrosion
2-Butoxyethanol
Eyes - Moderate irritant
Rabbit
-
24 hours 100
milligrams
-
Eyes - Severe irritant
Rabbit
-
100
milligrams
-
Skin - Mild irritant
Rabbit
-
500
milligrams
-
2-Propanol
Eyes - Moderate irritant
Rabbit
-
24 hours 100
milligrams
-
Eyes - Moderate irritant
Rabbit
-
10 milligrams
-
Eyes - Severe irritant
Rabbit
-
100
milligrams
-
Skin - Mild irritant
Rabbit
-
500
milligrams
-
Heavy Aromatic Naphtha
Skin - Mild irritant
Rabbit
-
24 hours 500
microliters
-
Product/ingredient name
Result
Score
Exposure
Observation
Sensitization
Not available.
Species
Information on toxicological effects
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
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SHW-85-NA-GHS-US
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Section 11. Toxicological information
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
2-Butoxyethanol
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
2-Propanol
Category 3
Not applicable.
Respiratory tract
irritation and
Narcotic effects
Heavy Aromatic Naphtha
Category 3
Not applicable.
Narcotic effects
Name
Category
Name
Category
2-Butoxyethanol
Category 2
Not determined
Not determined
2-Propanol
Category 2
Not determined
Not determined
Aspiration hazard
Name
Result
Heavy Aromatic Naphtha
ASPIRATION HAZARD - Category 1
Route of
exposure
Target organs
Route of
exposure
Target organs
Classification
2-Butoxyethanol
-3-
2-Propanol
-3-
Carbon Black
-2B-
Product/ingredient name
NTP
IARC
OSHA
Information on the likely
routes of exposure
Inhalation
:
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
Ingestion
Skin contact
:
No known significant effects or critical hazards.
Causes serious eye irritation.
:
Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
No specific data.
No specific data.
:::
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
Delayed and immediate effects and also chronic effects from short and long term exposure
:
Not available.
Potential acute health effects
Short term exposure
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:119/13
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Gloss Black
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Section 11. Toxicological information
Not available.
May cause damage to organs through prolonged or repeated exposure.
General
:
Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Carcinogenicity
:
No known significant effects or critical hazards.
Mutagenicity
:
No known significant effects or critical hazards.
Teratogenicity
:
Developmental effects
:
No known significant effects or critical hazards.
Fertility effects
:
No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Oral
11925.7 mg/kg
Dermal
12352.2 mg/kg
Inhalation (vapors)
189.9 mg/l
Route
ATE value
Acute toxicity estimates
Potential immediate
effects
:
Not available.
Potential delayed effects
:
Not available.
Potential immediate
effects
:
Not available.
Long term exposure
Potential delayed effects
:
Not available.
Section 12. Ecological information
LogP
ow
BCF
Potential
Bioaccumulative potential
Other adverse effects
:
No known significant effects or critical hazards.
Product/ingredient name
Heavy Aromatic Naphtha
-
99 to 5780
high
Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
2-Butoxyethanol
--Readily
2-Propanol
--Readily
Toxicity
2-Butoxyethanol
Acute EC50 >1000 mg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 800000 µg/l Marine water
Crustaceans - Crangon crangon
48 hours
Acute LC50 1250000 µg/l Marine water
Fish - Menidia beryllina
96 hours
2-Propanol
Acute EC50 10100 mg/l Fresh water
Daphnia - Daphnia magna
48 hours
Acute LC50 1400000 µg/l Marine water
Crustaceans - Crangon crangon
48 hours
Acute LC50 4200 mg/l Fresh water
Fish - Rasbora heteromorpha
96 hours
Product/ingredient name
Species
Result
Exposure
Persistence and degradability
Soil/water partition
coefficient (KOC)
:
Not available.
Mobility in soil
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:1110/13
K07908000
KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
Page 11
Section 13. Disposal considerations
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.
:
Disposal methods
Section 14. Transport information
AEROSOLS
2.1
-
AEROSOLS
2.1
-
UN1950
UN1950
-
Emergency
schedules
F-D, S-
U
DOT
Classification
IMDG
UN number
UN proper
shipping name
Transport
hazard class(es)
Packing group
Additional
information
Environmental
hazards
Special precautions for user
Transport in bulk according
to Annex II of MARPOL and
the IBC Code
No.
No.
Not available.
:
Proper shipping name
:
Ship type
:
Not available.
Pollution category
:
Not available.
Not available.
:
TDG
Classification
UN1950
AEROSOLS
2.1
-
No.
Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations: 2.
13-2.17 (Class 2).
Mexico
Classification
UN1950
AEROSOLS
2.1
-
No.
-
Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.
IATA
UN1950
AEROSOLS,
flammable
2.1
-
No.
-
126
ERG No.
126
126
ERG No.
ERG No.
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:1111/13
K07908000
KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
Page 12
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
California Prop. 65
Australia inventory (AICS)
: Not determined.
China inventory (IECSC)
: Not determined.
Japan inventory (ENCS)
: Not determined.
Japan inventory (ISHL)
: Not determined.
Korea inventory (KECI)
: Not determined.
Malaysia Inventory (EHS Register)
: Not determined.
New Zealand Inventory of Chemicals (NZIoC)
: Not determined.
Philippines inventory (PICCS)
: Not determined.
Taiwan Chemical Substances Inventory (TCSI)
: Not determined.
Thailand inventory
: Not determined.
Turkey inventory
: Not determined.
Vietnam inventory
: Not determined.
International regulations
International lists
:
Section 16. Other information
5/22/2019
History
Date of printing
Date of issue/Date of
revision
Version
Date of previous issue
:::
:
Key to abbreviations
:
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
5/22/2019
4/5/2019
11
Hazardous Material Information System (U.S.A.)
2
2
3
*
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
FLAMMABLE AEROSOLS - Category 1
On basis of test data
GASES UNDER PRESSURE - Compressed gas
Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
Calculation method
CARCINOGENICITY - Category 2
Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Calculation method
Procedure used to derive the classification
Classification
Justification
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:1112/13
K07908000
KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
Page 13
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.
Indicates information that has changed from previously issued version.
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
Date of issue/Date of revision
:
5/22/2019
Date of previous issue
:
4/5/2019
Version
:1113/13
K07908000
KRYLON® Industrial IRON GUARD® Latex Enamel
Gloss Black
SHW-85-NA-GHS-US
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