Krylon K01403007 User Manual

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KRYLON® Metallics Dull Aluminum

Not available. Aerosol.

(216) 566-2917

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Emergency telephone number of the company

Section 1. Identification

:::

Manufacturer

Krylon Products Group Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

1403

Product code

Product Information Telephone Number

(800) 457-9566

Regulatory Information Telephone Number

(216) 566-2902

Transportation Emergency Telephone Number

(800) 424-9300

CAS #

Not applicable.

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word

Danger

Hazard pictograms

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 38.5%

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:31/17

Section 2. Hazards identification

Precautionary statements

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn, even after use.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

General

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Hazards not otherwise classified

None known.

Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Suspected of damaging the unborn child. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure.

Hazard statements

Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.

Supplemental label elements

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue may spontaneously catch fire if improperly discarded. Immediately place rags, steel wool, other waste soaked with this product, and sanding residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire regulations. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

Section 3. Composition/information on ingredients

Other means of identification

Not available.

Substance/mixture

CAS number/other identifiers

Mixture

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:32/17

Section 3. Composition/information on ingredients

Acetone

46.2

67-64-1

Propane

18.1

74-98-6

Lt. Aliphatic Hydrocarbon Solvent

14.78

64742-89-8

Xylene

4.57

1330-20-7

Toluene

3.27

108-88-3

Medium Aromatic Hydrocarbons

2.09

64742-94-5

Ethylbenzene

0.8

100-41-4

Naphthalene

0.32

91-20-3

Ingredient name

CAS number

% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.

Ingestion Skin contact

No known significant effects or critical hazards.

Causes serious eye irritation.

Eye contact

Over-exposure signs/symptoms

Potential acute health effects

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:33/17

Section 4. First aid measures

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments

No specific treatment.

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

: :

None known.

Suitable extinguishing media

Unsuitable extinguishing media

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:34/17

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders

If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Section 7. Handling and storage

Protective measures

Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

Precautions for safe handling

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:35/17

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.

: :

Acetone

ACGIH TLV (United States, 3/2016).

TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes.

NIOSH REL (United States, 10/2013).

TWA: 250 ppm 10 hours. TWA: 590 mg/m³ 10 hours.

OSHA PEL (United States, 6/2016).

TWA: 1000 ppm 8 hours. TWA: 2400 mg/m³ 8 hours.

Propane

NIOSH REL (United States, 10/2013).

TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours.

OSHA PEL (United States, 6/2016).

TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours.

Lt. Aliphatic Hydrocarbon Solvent

None.

Xylene

ACGIH TLV (United States, 3/2016).

TWA: 100 ppm 8 hours. TWA: 434 mg/m³ 8 hours. STEL: 150 ppm 15 minutes. STEL: 651 mg/m³ 15 minutes.

OSHA PEL (United States, 6/2016).

TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.

Toluene

OSHA PEL Z2 (United States, 2/2013).

TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes.

NIOSH REL (United States, 10/2013).

TWA: 100 ppm 10 hours. TWA: 375 mg/m³ 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m³ 15 minutes.

ACGIH TLV (United States, 3/2016).

TWA: 20 ppm 8 hours. Medium Aromatic Hydrocarbons

None.

Ethylbenzene

ACGIH TLV (United States, 3/2016).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2013).

TWA: 100 ppm 10 hours. TWA: 435 mg/m³ 10 hours. STEL: 125 ppm 15 minutes.

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:36/17

Section 8. Exposure controls/personal protection

STEL: 545 mg/m³ 15 minutes.

OSHA PEL (United States, 6/2016).

TWA: 100 ppm 8 hours. TWA: 435 mg/m³ 8 hours.

Naphthalene

ACGIH TLV (United States, 3/2016). Absorbed through skin.

TWA: 10 ppm 8 hours. TWA: 52 mg/m³ 8 hours.

NIOSH REL (United States, 10/2013).

TWA: 10 ppm 10 hours. TWA: 50 mg/m³ 10 hours. STEL: 15 ppm 15 minutes. STEL: 75 mg/m³ 15 minutes.

OSHA PEL (United States, 6/2016).

TWA: 10 ppm 8 hours. TWA: 50 mg/m³ 8 hours.

Acetone

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 1200 mg/m³ 8 hours. 15 min OEL: 1800 mg/m³ 15 minutes. 8 hrs OEL: 500 ppm 8 hours. 15 min OEL: 750 ppm 15 minutes.

CA British Columbia Provincial (Canada, 5/2015).

TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes.

CA Ontario Provincial (Canada, 7/2015).

TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 500 ppm 8 hours. TWAEV: 1190 mg/m³ 8 hours. STEV: 1000 ppm 15 minutes. STEV: 2380 mg/m³ 15 minutes.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 750 ppm 15 minutes. TWA: 500 ppm 8 hours.

Propane

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 1000 ppm 8 hours.

CA British Columbia Provincial (Canada, 5/2015).

TWA: 1000 ppm 8 hours.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 1000 ppm 8 hours. TWAEV: 1800 mg/m³ 8 hours.

CA Ontario Provincial (Canada, 7/2015).

TWA: 1000 ppm 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013).

STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours.

Toluene

CA Alberta Provincial (Canada, 4/2009). Absorbed through skin.

8 hrs OEL: 50 ppm 8 hours.

Ingredient name

Exposure limits

Occupational exposure limits (Canada)

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:37/17

Section 8. Exposure controls/personal protection

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

8 hrs OEL: 188 mg/m³ 8 hours.

CA British Columbia Provincial (Canada, 5/2015).

TWA: 20 ppm 8 hours.

CA Ontario Provincial (Canada, 7/2015).

TWA: 20 ppm 8 hours.

CA Quebec Provincial (Canada, 1/2014). Absorbed through skin.

TWAEV: 50 ppm 8 hours. TWAEV: 188 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin.

STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours.

Naphthalene

CA Alberta Provincial (Canada, 4/2009). Absorbed through skin.

15 min OEL: 15 ppm 15 minutes. 8 hrs OEL: 10 ppm 8 hours. 8 hrs OEL: 52 mg/m³ 8 hours. 15 min OEL: 79 mg/m³ 15 minutes.

CA British Columbia Provincial (Canada, 5/2015). Absorbed through skin.

TWA: 10 ppm 8 hours. STEL: 15 ppm 15 minutes.

CA Ontario Provincial (Canada, 7/2015). Absorbed through skin.

TWA: 10 ppm 8 hours. STEL: 15 ppm 15 minutes.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 10 ppm 8 hours. TWAEV: 52 mg/m³ 8 hours. STEV: 15 ppm 15 minutes. STEV: 79 mg/m³ 15 minutes.

CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin.

STEL: 15 ppm 15 minutes. TWA: 10 ppm 8 hours.

Environmental exposure controls

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:38/17

Section 8. Exposure controls/personal protection

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection

:::

Body protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Skin protection

Other skin protection

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

0.74

1.55 [Air = 1]

13.5 kPa (101.325 mm Hg) [at 20°C]

Not available.

Odor

Not available.

Color

Evaporation rate

5.6 (butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

Not available. 7

Viscosity

Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)

Not available.

Odor threshold

Partition coefficient: noctanol/water

:::

: :

:::

Appearance

Boiling point

Not available.

Flammability (solid, gas)

Not available.

Lower and upper explosive (flammable) limits

Lower: 0.8% Upper: 12.8%

Decomposition temperature

Not available.

Type of aerosol

Spray

Aerosol product

Molecular weight

Not applicable.

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:39/17

Section 9. Physical and chemical properties

Heat of combustion

31.2 kJ/g

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.

Chemical stability

No specific data.

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Acetone

LD50 Oral

Rat

5800 mg/kg

Xylene

LC50 Inhalation Gas.

Rat

5000 ppm

4 hours

LD50 Oral

Rat

4300 mg/kg

Toluene

LC50 Inhalation Vapor

Rat

49 g/m³

4 hours

LD50 Oral

Rat

636 mg/kg

Ethylbenzene

LD50 Dermal

Rabbit

>5000 mg/kg

LD50 Oral

Rat

3500 mg/kg

Naphthalene

LD50 Dermal

Rabbit

>20 g/kg

LD50 Oral

Rat

490 mg/kg

Product/ingredient name

Result

Species

Dose

Exposure

Irritation/Corrosion

Acetone

Eyes - Mild irritant

Human

186300 parts per million

Eyes - Mild irritant

Rabbit

10 microliters

Eyes - Moderate irritant

Rabbit

24 hours 20 milligrams

Eyes - Severe irritant

Rabbit

20 milligrams

Skin - Mild irritant

Rabbit

24 hours 500 milligrams

Skin - Mild irritant

Rabbit

395 milligrams

Xylene

Eyes - Mild irritant

Rabbit

87 milligrams

Eyes - Severe irritant

Rabbit

24 hours 5 milligrams

Skin - Mild irritant

Rat

8 hours 60 microliters

Skin - Moderate irritant

Rabbit

24 hours 500 milligrams

Skin - Moderate irritant

Rabbit

100 Percent

Toluene

Eyes - Mild irritant

Rabbit

0.5 minutes 100 milligrams

Eyes - Mild irritant

Rabbit

870

Product/ingredient name

Result

Score

Exposure

Observation

Species

Information on toxicological effects

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:310/17

Section 11. Toxicological information

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Micrograms

Eyes - Severe irritant

Rabbit

24 hours 2 milligrams

Skin - Mild irritant

Pig

24 hours 250 microliters

Skin - Mild irritant

Rabbit

435 milligrams

Skin - Moderate irritant

Rabbit

24 hours 20 milligrams

Skin - Moderate irritant

Rabbit

500 milligrams

Medium Aromatic Hydrocarbons

Skin - Mild irritant

Rabbit

24 hours 500 microliters

Ethylbenzene

Eyes - Severe irritant

Rabbit

500 milligrams

Skin - Mild irritant

Rabbit

24 hours 15 milligrams

Naphthalene

Skin - Mild irritant

Rabbit

495 milligrams

Skin - Severe irritant

Rabbit

24 hours 0.05 Mililiters

Sensitization

Not available.

Specific target organ toxicity (single exposure)

Acetone

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Lt. Aliphatic Hydrocarbon Solvent

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Xylene

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Toluene

Category 3

Not applicable.

Respiratory tract

Name

Category

Acetone

Category 2

Not determined

Propane

Category 2

Not determined

Lt. Aliphatic Hydrocarbon Solvent

Category 2

Not determined

Xylene

Category 2

Not determined

Toluene

Category 2

Not determined

Ethylbenzene

Category 2

Not determined

Naphthalene

Category 2

Not determined

Aspiration hazard

Name

Result

Propane

ASPIRATION HAZARD - Category 1

Lt. Aliphatic Hydrocarbon Solvent

ASPIRATION HAZARD - Category 1

Xylene

ASPIRATION HAZARD - Category 1

Toluene

ASPIRATION HAZARD - Category 1

Medium Aromatic Hydrocarbons

ASPIRATION HAZARD - Category 1

Ethylbenzene

ASPIRATION HAZARD - Category 1

Naphthalene

ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Information on the likely routes of exposure

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways.

Ingestion

Skin contact

No known significant effects or critical hazards.

Causes serious eye irritation.

Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation

Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Not available.

Potential acute health effects

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:312/17

Not available.

May cause damage to organs through prolonged or repeated exposure.

General

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Carcinogenicity

No known significant effects or critical hazards.

Mutagenicity

Suspected of damaging the unborn child.

Teratogenicity

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Skin contact

Ingestion

increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Oral

9908.5 mg/kg

Inhalation (gases)

67362.9 ppm

Route

ATE value

Acute toxicity estimates

Potential immediate effects

Not available.

Short term exposure

Potential delayed effects

Not available.

Potential immediate effects

Not available.

Long term exposure

Potential delayed effects

Not available.

Section 12. Ecological information

Toxicity

Acetone

Acute EC50 7200000 µg/l Fresh water

Algae - Selenastrum sp.

96 hours

Acute LC50 6000000 µg/l Fresh water

Crustaceans - Gammarus pulex

48 hours

Acute LC50 6900 mg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna Neonate

21 days

Lt. Aliphatic Hydrocarbon Solvent

Acute LC50 >100000 ppm Fresh water

Fish - Oncorhynchus mykiss

96 hours

Xylene

Acute LC50 8500 µg/l Marine water

Crustaceans - Palaemonetes 48 hours

Product/ingredient name

Species

Result

Exposure

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:313/17

Section 12. Ecological information

LogP

BCF

Potential

Bioaccumulative potential

Other adverse effects

No known significant effects or critical hazards.

Product/ingredient name

Lt. Aliphatic Hydrocarbon Solvent

10 to 2500

high

Xylene

8.1 to 25.9

low

Toluene

-90low

Medium Aromatic Hydrocarbons

99 to 5780

high

Naphthalene

36.5 to 168

low

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetone

--Readily

Xylene

--Readily

Toluene

--Readily

Ethylbenzene

--Readily

pugio

Acute LC50 13400 µg/l Fresh water

Fish - Pimephales promelas

96 hours

Toluene

Acute EC50 12500 µg/l Fresh water

Algae - Pseudokirchneriella subcapitata

72 hours

Acute EC50 11600 µg/l Fresh water

Crustaceans - Gammarus pseudolimnaeus - Adult

48 hours

Acute EC50 6000 µg/l Fresh water

Daphnia - Daphnia magna Juvenile (Fledgling, Hatchling, Weanling)

48 hours

Acute LC50 5500 µg/l Fresh water

Fish - Oncorhynchus kisutch - Fry

96 hours

Chronic NOEC 1000 µg/l Fresh water

Daphnia - Daphnia magna

21 days

Ethylbenzene

Acute EC50 4600 µg/l Fresh water

Algae - Pseudokirchneriella subcapitata

72 hours

Acute EC50 3600 µg/l Fresh water

Algae - Pseudokirchneriella subcapitata

96 hours

Acute EC50 6530 µg/l Fresh water

Crustaceans - Artemia sp. Nauplii

48 hours

Acute EC50 2930 µg/l Fresh water

Daphnia - Daphnia magna Neonate

48 hours

Acute LC50 4200 µg/l Fresh water

Fish - Oncorhynchus mykiss

96 hours

Naphthalene

Acute EC50 1600 µg/l Fresh water

Daphnia - Daphnia magna Neonate

48 hours

Acute LC50 2350 µg/l Marine water

Crustaceans - Palaemonetes pugio

48 hours

Acute LC50 213 µg/l Fresh water

Fish - Melanotaenia fluviatilis Larvae

96 hours

Chronic NOEC 0.5 mg/l Marine water

Crustaceans - Uca pugnax - Adult

3 weeks

Chronic NOEC 1.5 mg/l Fresh water

Fish - Oreochromis mossambicus

60 days

Persistence and degradability

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:314/17

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

Disposal methods

Section 14. Transport information

AEROSOLS

2.1

AEROSOLS

2.1

UN1950

Emergency schedules (EmS)

F-D, S-U

DOT

Classification

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of MARPOL and the IBC Code

No.

No. Not available.

Proper shipping name

Ship type

Not available.

Pollution category

Not available.

TDG

Classification

UN1950

AEROSOLS

2.1

No.

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2. 13-2.17 (Class 2).

Mexico

Classification

UN1950

AEROSOLS

2.1

No.

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

IATA

UN1950

AEROSOLS, flammable

2.1

No.

126

ERG No.

126

ERG No.

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:315/17

Section 15. Regulatory information

SARA 313

SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

California Prop. 65

Section 16. Other information

12/30/2016

History

Date of printing

Date of issue/Date of revision

Version

Notice to reader

Date of previous issue

:::

Key to abbreviations

ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

12/30/2016

7/15/2016

Hazardous Material Information System (U.S.A.)

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Procedure used to derive the classification

Classification

Justification

FLAMMABLE AEROSOLS - Category 1

On basis of test data

GASES UNDER PRESSURE - Compressed gas

Calculation method

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

Calculation method

CARCINOGENICITY - Category 2

Calculation method

TOXIC TO REPRODUCTION (Unborn child) - Category 2

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Calculation method

ASPIRATION HAZARD - Category 1

Calculation method

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:316/17

Section 16. Other information

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision

12/30/2016

Date of previous issue

7/15/2016

Version

:317/17

Krylon K01403007 User Manual

Specifications and Main Features

Frequently Asked Questions

User Manual