Krylon K00779007 User Manual
RUST TOUGH® Rust Preventive Enamel (Aerosol)
Semi-Gloss Black
Not available.
Aerosol.
(216) 566-2917
SAFETY DATA SHEET
Product name
Other means of
identification
Product type
Emergency telephone
number of the company
Section 1. Identification
:
:::
Manufacturer
:
THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
Cleveland, OH 44115
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
R00779
R00779
Product code
:
Product Information
Telephone Number
:
(800) 247-3266
Regulatory Information
Telephone Number
:
(216) 566-2902
Transportation Emergency
Telephone Number
:
(800) 424-9300
Section 2. Hazards identification
FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Classification of the
substance or mixture
:
Signal word
:
Danger
Hazard pictograms
:
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 38.6%
OSHA/HCS status
:
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:11/17
Section 2. Hazards identification
Precautionary statements
Prevention
:
Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Contaminated work clothing should not be
allowed out of the workplace.
Response
:
Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated
clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs:
Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage
:
Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
General
:
Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Hazards not otherwise
classified
:
None known.
Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Suspected of damaging the unborn child.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
:
Hazard statements
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Supplemental label
elements
DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Section 3. Composition/information on ingredients
Other means of
identification
:
Not available.
Substance/mixture
CAS number/other identifiers
:
Mixture
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:12/17
Section 3. Composition/information on ingredients
Acetone
27.0
67-64-1
Propane
13.6
74-98-6
Toluene
12.8
108-88-3
Lt. Aliphatic Hydrocarbon Solvent
8.6
64742-89-8
Methyl n-Propyl Ketone
6.6
107-87-9
Butane
6.4
106-97-8
Xylene
1.1
1330-20-7
Carbon Black
0.9
1333-86-4
Methyl Isobutyl Ketone
0.4
108-10-1
Methyl Ethyl Ketoxime
0.2
96-29-7
Ethylbenzene
0.2
100-41-4
Cumene
0.1
98-82-8
Ingredient name
CAS number
% by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.
Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Description of necessary first aid measures
Most important symptoms/effects, acute and delayed
Inhalation
:
Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
:
Ingestion
Skin contact
:
Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.
:
Eye contact
Potential acute health effects
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:13/17
Section 4. First aid measures
Protection of first-aiders
:
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician
:
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments
:
No specific treatment.
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations
Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
:
:
:
Eye contact
:
Adverse symptoms may include the following:
pain or irritation
watering
redness
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Specific hazards arising
from the chemical
Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
None known.
Suitable extinguishing
media
:
Unsuitable extinguishing
media
:
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:14/17
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Hazardous thermal
decomposition products
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective
equipment for fire-fighters
::Special protective actions
for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
:
:
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
Large spill
:
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Small spill
:
Methods and materials for containment and cleaning up
For non-emergency
personnel
For emergency responders
:
If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 7. Handling and storage
Protective measures
Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing
gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is
:
Precautions for safe handling
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:15/17
Section 7. Handling and storage
Advice on general
occupational hygiene
Conditions for safe storage,
including any
incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.
:
:
inadequate. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Empty containers retain product residue and
can be hazardous.
Acetone
ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Propane
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Toluene
OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
Methyl n-Propyl Ketone
NIOSH REL (United States, 10/2013).
TWA: 150 ppm 10 hours.
TWA: 530 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 200 ppm 8 hours.
TWA: 700 mg/m³ 8 hours.
ACGIH TLV (United States, 4/2014).
STEL: 150 ppm 15 minutes.
Butane
NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
Section 8. Exposure controls/personal protection
Ingredient name
Exposure limits
Control parameters
Occupational exposure limits
Date of issue/Date of revision
:
3/13/2015.
Date of previous issue
:
No previous validation.
Version
:16/17
Loading...