Krylon K00020103-16 User Manual

KRYLON® Weld-Thru Primer
Black

Not available.
Liquid.

[phone]

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

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:::

Manufacturer

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THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

K00020103

K00020103

Product code

:

Product Information
Telephone Number

:

[phone]

Regulatory Information
Telephone Number

:

[phone]

Transportation Emergency
Telephone Number

:

[phone]

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1

Classification of the
substance or mixture

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Signal word

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Danger

Hazard pictograms

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Precautionary statements

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 36.9%

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Flammable liquid and vapor.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
May cause cancer.
May be fatal if swallowed and enters airways.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Date of issue/Date of revision

:

5/20/2015.

Date of previous issue

:

3/27/2015.

Version

:

1.02

1/13

Section 2. Hazards identification

Prevention

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Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Use explosion-proof
electrical, ventilating, lighting and all material-handling equipment. Use only non­sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Do not breathe vapor. Wash hands thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace.

Response

:

Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do
NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and
water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical attention.

Storage

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Store locked up. Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

None known.

Please refer to the SDS for additional information. Do not transfer contents to other
containers for storage.

Supplemental label
elements

Adequate ventilation required when sanding or abrading the dried film. If Adequate
ventilation cannot be provided wear an approved particulate respirator (NIOSH
approved). Follow respirator manufacturer's directions for respirator use. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading or sanding of the dry film
may release crystalline silica which has been shown to cause lung damage and cancer
under long term exposure. DANGER: Rags, steel wool, other waste soaked with this
product, and sanding residue may spontaneously catch fire if improperly discarded.
Immediately place rags, steel wool, other waste soaked with this product, and sanding
residue in a sealed, water-filled, metal container. Dispose of in accordance with local fire
regulations. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains
solvents which can cause permanent brain and nervous system damage. Intentional
misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.
WARNING: This product contains chemicals known to the State of California to cause
cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

Section 3. Composition/information on ingredients

Calcium Carbonate

54.9

471-34-1

Med. Aliphatic Hydrocarbon Solvent

13.8

64742-88-7

zinc oxide

8.1

1314-13-2

Acetone

2.9

67-64-1

Carbon Black

1.5

1333-86-4

Quartz

0.3

14808-60-7

Methyl Ethyl Ketoxime

0.1

96-29-7

Ingredient name

CAS number
% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Mixture

Date of issue/Date of revision

:

5/20/2015.

Date of previous issue

:

3/27/2015.

Version

:

1.02

2/13

Section 3. Composition/information on ingredients

Occupational exposure limits, if available, are listed in Section 8.

Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person providing
aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place
in recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

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Notes to physician

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Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.

Description of necessary first aid measures

Specific treatments

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No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation

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No known significant effects or critical hazards.

May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

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Ingestion

Skin contact

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Causes skin irritation. May cause an allergic skin reaction.

Causes serious eye irritation.

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Eye contact

Over-exposure signs/symptoms

Skin contact
Ingestion
Inhalation

No specific data.

Adverse symptoms may include the following:
nausea or vomiting

Adverse symptoms may include the following:
irritation
redness

:
:

:

Eye contact

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Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision

:

5/20/2015.

Date of previous issue

:

3/27/2015.

Version

:

1.02

3/13

Section 4. First aid measures

Protection of first-aiders

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No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides

Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

Use dry chemical,

CO₂,

water spray (fog) or foam.

Extinguishing media

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:

:

Do not use water jet.

Suitable extinguishing
media

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Unsuitable extinguishing
media

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Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

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:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

:

Methods and materials for containment and cleaning up

For non-emergency
personnel

For emergency responders

:

If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Date of issue/Date of revision

:

5/20/2015.

Date of previous issue

:

3/27/2015.

Version

:

1.02

4/13