Krylon K00020002-16 User Manual

KRYLON® Industrial Primer
Gray

Not available.
Liquid.

[phone]

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

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:::

Manufacturer

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THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

K00020002

K00020002

Product code

:

Product Information
Telephone Number

:

[phone]

Regulatory Information
Telephone Number

:

[phone]

Transportation Emergency
Telephone Number

:

[phone]

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1

Classification of the
substance or mixture

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Signal word

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Danger

Hazard pictograms

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GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 98.7%

OSHA/HCS status

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This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Flammable liquid and vapor.
May cause an allergic skin reaction.
Suspected of damaging the unborn child.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.

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Hazard statements

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

4/8/2015.

Version

:

1.03

1/13

Section 2. Hazards identification

Precautionary statements

Prevention

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Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Use explosion-proof
electrical, ventilating, lighting and all material-handling equipment. Use only non­sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor.
Contaminated work clothing should not be allowed out of the workplace.

Response

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Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. If skin
irritation or rash occurs: Get medical attention.

Storage

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Store locked up. Store in a well-ventilated place. Keep cool.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

None known.

Please refer to the SDS for additional information. Do not transfer contents to other
containers for storage.

Supplemental label
elements

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

Section 3. Composition/information on ingredients

Med. Aliphatic Hydrocarbon Solvent

8.2

64742-88-7

Lt. Aliphatic Hydrocarbon Solvent

7.7

64742-89-8

Mineral Spirits 140-Flash

6.1

64742-88-7

Titanium Dioxide

2.4

13463-67-7

Methyl Ethyl Ketoxime

0.2

96-29-7

2-(2-Methoxyethoxy)-ethanol

0.1

111-77-3

Ingredient name

CAS number
% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

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Occupational exposure limits, if available, are listed in Section 8.

Mixture

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

4/8/2015.

Version

:

1.03

2/13

Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

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Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

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Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

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Ingestion
Skin contact

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May cause an allergic skin reaction.

No known significant effects or critical hazards.

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Eye contact

Over-exposure signs/symptoms

Skin contact

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations

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:

Eye contact

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No specific data.

Potential acute health effects

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

4/8/2015.

Version

:

1.03

3/13

Section 4. First aid measures

Protection of first-aiders

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No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

Notes to physician

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Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.

Specific treatments

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No specific treatment.

Ingestion

Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

:

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides

Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. The vapor/gas is
heavier than air and will spread along the ground. Vapors may accumulate in low or
confined areas or travel a considerable distance to a source of ignition and flash back.
Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

Use dry chemical,

CO₂,

water spray (fog) or foam.

Extinguishing media

:
:

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Do not use water jet.

Suitable extinguishing
media

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Unsuitable extinguishing
media

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Special protective actions
for fire-fighters

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Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

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No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.

For non-emergency
personnel

For emergency responders

:

If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Date of issue/Date of revision

:

6/1/2015.

Date of previous issue

:

4/8/2015.

Version

:

1.03

4/13