Krylon A04420007 User Manual

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

Not available.
Aerosol.

US/Canada: [phone]
Mexico: CHEMTREC Mexico 01-800-681-9531. Available 24 hours and 365 days per
year

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

:

:
:

:

Manufacturer

:

Krylon Products Group
101 Prospect Avenue NW
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Paint or paint related material.

A04420007

A04420007

Product code

:

Product Information
Telephone Number

:

US/Canada: [phone]
Mexico: Not Available

Regulatory Information
Telephone Number

:

US/Canada: [phone]
Mexico: Not Available

Transportation Emergency
Telephone Number

:

US/Canada: [phone]
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1

Classification of the
substance or mixture

:

Signal word

:

Danger

Hazard pictograms

:

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 32.3%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 82.6%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 68.
1%

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:111/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 2. Hazards identification

Precautionary statements

Prevention

:

Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn,
even after use.

Response

:

Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it
before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

:

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations.

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
Suspected of damaging the unborn child.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.

Supplemental label
elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

:

Section 3. Composition/information on ingredients

Acetone

≥25 - ≤50

67-64-1

Propane

≥10 - ≤25

74-98-6

Butane

≥10 - ≤25

106-97-8

Isobutyl Acetate

≤10

110-19-0

Toluene

≤10

108-88-3

Ethyl 3-Ethoxypropionate

≤5

763-69-9

Titanium Dioxide

≤3

13463-67-7

Carbon Black

≤0.3

1333-86-4

Xylene mixed isomers

≤0.3

1330-20-7

Ingredient name

CAS number

% by weight

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:112/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 3. Composition/information on ingredients

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:::

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

:

Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

:

Ingestion
Skin contact

:

Causes skin irritation.

Causes serious eye irritation.

:

Eye contact

Over-exposure signs/symptoms

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

:

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential acute health effects

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:113/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 4. First aid measures

Protection of first-aiders

:

No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

Notes to physician

:

Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.

Specific treatments

:

No specific treatment.

Skin contact
Ingestion

Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations

:

:

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides

Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In
a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel
a considerable distance to a source of ignition and flash back, causing fire or explosion.
Bursting aerosol containers may be propelled from a fire at high speed.

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:
:

:

None known.

Suitable extinguishing
media

:

Unsuitable extinguishing
media

:

Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put

For non-emergency
personnel

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:114/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 6. Accidental release measures

Environmental precautions

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

:

on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Large spill

:

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

:

Methods and materials for containment and cleaning up

For emergency responders

:

If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any
incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.

:

:

Protective measures

Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.

:

Precautions for safe handling

Section 8. Exposure controls/personal protection

Control parameters

Occupational exposure limits (OSHA United States)

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:115/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protection

Acetone

ACGIH TLV (United States, 3/2018).

TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.

NIOSH REL (United States, 10/2016).

TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.

OSHA PEL (United States, 5/2018).

TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.

Propane

NIOSH REL (United States, 10/2016).

TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.

OSHA PEL (United States, 5/2018).

TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.

ACGIH TLV (United States, 3/2018). Oxygen
Depletion [Asphyxiant].

Butane

NIOSH REL (United States, 10/2016).

TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.

ACGIH TLV (United States, 3/2018).

STEL: 1000 ppm 15 minutes.

Isobutyl Acetate

NIOSH REL (United States, 10/2016).

TWA: 150 ppm 10 hours.
TWA: 700 mg/m³ 10 hours.

OSHA PEL (United States, 5/2018).

TWA: 150 ppm 8 hours.
TWA: 700 mg/m³ 8 hours.

ACGIH TLV (United States, 3/2018).

STEL: 150 ppm 15 minutes.
TWA: 50 ppm 8 hours.

Toluene

OSHA PEL Z2 (United States, 2/2013).

TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.

NIOSH REL (United States, 10/2016).

TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.

ACGIH TLV (United States, 3/2018).

TWA: 20 ppm 8 hours.
Ethyl 3-Ethoxypropionate

None.

Titanium Dioxide

ACGIH TLV (United States, 3/2018).

TWA: 10 mg/m³ 8 hours.

OSHA PEL (United States, 5/2018).

TWA: 15 mg/m³ 8 hours. Form: Total dust

Carbon Black

NIOSH REL (United States, 10/2016).

TWA: 3.5 mg/m³ 10 hours.
TWA: 0.1 mg of PAHs/cm³ 10 hours.

ACGIH TLV (United States, 3/2018).

TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction

OSHA PEL (United States, 5/2018).

TWA: 3.5 mg/m³ 8 hours.

Xylene mixed isomers

ACGIH TLV (United States, 3/2018).

TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.

Ingredient name

Exposure limits

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:116/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protection

STEL: 651 mg/m³ 15 minutes.

OSHA PEL (United States, 5/2018).

TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

Acetone

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 1200 mg/m³ 8 hours.
15 min OEL: 1800 mg/m³ 15 minutes.
8 hrs OEL: 500 ppm 8 hours.
15 min OEL: 750 ppm 15 minutes.

CA British Columbia Provincial (Canada,
6/2017).

TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.

CA Ontario Provincial (Canada, 1/2018).

TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 500 ppm 8 hours.
TWAEV: 1190 mg/m³ 8 hours.
STEV: 1000 ppm 15 minutes.
STEV: 2380 mg/m³ 15 minutes.

CA Saskatchewan Provincial (Canada,
7/2013).

STEL: 750 ppm 15 minutes.
TWA: 500 ppm 8 hours.

Normal propane

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 1000 ppm 8 hours.

CA British Columbia Provincial (Canada,
6/2017).

TWA: 1000 ppm 8 hours.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 1000 ppm 8 hours.
TWAEV: 1800 mg/m³ 8 hours.

CA Ontario Provincial (Canada, 1/2018).

TWA: 1000 ppm 8 hours.

CA Saskatchewan Provincial (Canada,
7/2013).

STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.

Butane

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 1000 ppm 8 hours.

CA British Columbia Provincial (Canada,
6/2017).

TWA: 600 ppm 8 hours.
STEL: 750 ppm 15 minutes.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 800 ppm 8 hours.
TWAEV: 1900 mg/m³ 8 hours.

CA Ontario Provincial (Canada, 1/2018).

TWA: 800 ppm 8 hours.

CA Saskatchewan Provincial (Canada,
7/2013).

STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.

Isobutyl acetate

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 150 ppm 8 hours.
8 hrs OEL: 713 mg/m³ 8 hours.

Ingredient name

Exposure limits

Occupational exposure limits (Canada)

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:117/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protection

CA British Columbia Provincial (Canada,
6/2017).

TWA: 150 ppm 8 hours.

CA Ontario Provincial (Canada, 1/2018).

TWA: 150 ppm 8 hours.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 150 ppm 8 hours.
TWAEV: 713 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada,
7/2013).

STEL: 188 ppm 15 minutes.
TWA: 150 ppm 8 hours.

Toluene

CA Alberta Provincial (Canada, 4/2009).
Absorbed through skin.

8 hrs OEL: 50 ppm 8 hours.
8 hrs OEL: 188 mg/m³ 8 hours.

CA British Columbia Provincial (Canada,
6/2017).

TWA: 20 ppm 8 hours.

CA Ontario Provincial (Canada, 1/2018).

TWA: 20 ppm 8 hours.

CA Quebec Provincial (Canada, 1/2014).
Absorbed through skin.

TWAEV: 50 ppm 8 hours.
TWAEV: 188 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada,
7/2013). Absorbed through skin.

STEL: 60 ppm 15 minutes.
TWA: 50 ppm 8 hours.

Titanium dioxide

CA British Columbia Provincial (Canada,
6/2017).

TWA: 3 mg/m³ 8 hours. Form: Respirable
dust
TWA: 10 mg/m³ 8 hours. Form: Total dust

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 10 mg/m³ 8 hours. Form: Total dust.

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 10 mg/m³ 8 hours.

CA Ontario Provincial (Canada, 1/2018).

TWA: 10 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada,
7/2013).

STEL: 20 mg/m³ 15 minutes.
TWA: 10 mg/m³ 8 hours.

Carbon black

CA British Columbia Provincial (Canada,
6/2017).

TWA: 3 mg/m³ 8 hours. Form: Inhalable

CA Ontario Provincial (Canada, 1/2018).

TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction.

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 3.5 mg/m³ 8 hours.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 3.5 mg/m³ 8 hours.

CA Saskatchewan Provincial (Canada,
7/2013).

STEL: 7 mg/m³ 15 minutes.
TWA: 3.5 mg/m³ 8 hours.

Xylene

CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 100 ppm 8 hours.
15 min OEL: 651 mg/m³ 15 minutes.

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:118/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protection

Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

:

Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Appropriate engineering
controls

:

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

Hygiene measures

:

Individual protection measures

Skin protection

15 min OEL: 150 ppm 15 minutes.
8 hrs OEL: 434 mg/m³ 8 hours.

CA British Columbia Provincial (Canada,
6/2017).

TWA: 100 ppm 8 hours.
STEL: 150 ppm 15 minutes.

CA Quebec Provincial (Canada, 1/2014).

TWAEV: 100 ppm 8 hours.
TWAEV: 434 mg/m³ 8 hours.
STEV: 150 ppm 15 minutes.
STEV: 651 mg/m³ 15 minutes.

CA Ontario Provincial (Canada, 1/2018).

STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.

CA Saskatchewan Provincial (Canada,
7/2013).

STEL: 150 ppm 15 minutes.
TWA: 100 ppm 8 hours.

Environmental exposure
controls

:

Acetone

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 500 ppm 8 hours.
STEL: 750 ppm 15 minutes.

Propane

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 1000 ppm 8 hours.

Butane

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 1000 ppm 8 hours.

Isobutyl Acetate

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 150 ppm 8 hours.

Toluene

NOM-010-STPS-2014 (Mexico, 4/2016).

TWA: 20 ppm 8 hours.

Ingredient name

Exposure limits

Occupational exposure limits (Mexico)

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:119/17

A04420007

Industrial WORK DAY™ Enamel Spray Paint
Dark Gray

SHW-85-NA-GHS-US

Section 8. Exposure controls/personal protection

Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

Respiratory protection

:

:

Body protection

Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti­static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.

:

Other skin protection

:

Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point/freezing point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

0.73

1.55 [Air = 1]

101.3 kPa (760 mm Hg) [at 20°C]

Not available.

Not available.

Odor

pH

Not available.

Color

Evaporation rate

5.6 (butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

Not available.
Not available.

Viscosity

Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)

Not available.

Odor threshold

Partition coefficient: n­octanol/water

:

:::

:

:::

:

:
:

:

:

:

:

Appearance

Boiling point/boiling range

:

Not available.

Flammability (solid, gas)

:

Not available.

Lower and upper explosive
(flammable) limits

:

Lower: 1%
Upper: 12.8%

Decomposition temperature

:

Not available.

Type of aerosol

:

Spray

Heat of combustion

:

29.665 kJ/g

Aerosol product

Molecular weight

:

Not applicable.

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:1110/17

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SHW-85-NA-GHS-US

Section 10. Stability and reactivity

Hazardous decomposition
products

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

The product is stable.

Chemical stability

No specific data.

:

::Incompatible materials

:

Possibility of hazardous
reactions

:

Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity

:

No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Acetone

LD50 Oral

Rat

5800 mg/kg

-

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

Isobutyl Acetate

LD50 Dermal

Rabbit

>17400 mg/kg

-

LD50 Oral

Rat

13400 mg/kg

-

Toluene

LC50 Inhalation Vapor

Rat

49 g/m³

4 hours

LD50 Oral

Rat

636 mg/kg

-

Ethyl 3-Ethoxypropionate

LD50 Oral

Rat

3200 mg/kg

-

Carbon Black

LD50 Oral

Rat

>15400 mg/kg

-

Xylene mixed isomers

LC50 Inhalation Gas.

Rat

5000 ppm

4 hours

LD50 Oral

Rat

4300 mg/kg

-

Product/ingredient name

Result

Species

Dose

Exposure

Irritation/Corrosion

Acetone

Eyes - Mild irritant

Human

-

186300 parts
per million

-

Eyes - Mild irritant

Rabbit

-

10 microliters

-

Eyes - Moderate irritant

Rabbit

-

24 hours 20
milligrams

-

Eyes - Severe irritant

Rabbit

-

20 milligrams

-

Skin - Mild irritant

Rabbit

-

24 hours 500
milligrams

-

Skin - Mild irritant

Rabbit

-

395
milligrams

-

Isobutyl Acetate

Eyes - Moderate irritant

Rabbit

-

24 hours 500
milligrams

-

Skin - Mild irritant

Rabbit

-

500
milligrams

-

Skin - Moderate irritant

Rabbit

-

24 hours 500
milligrams

-

Toluene

Eyes - Mild irritant

Rabbit

-

0.5 minutes
100
milligrams

-

Eyes - Mild irritant

Rabbit

-

870
Micrograms

-

Eyes - Severe irritant

Rabbit

-

24 hours 2
milligrams

-

Skin - Mild irritant

Pig

-

24 hours 250
microliters

-

Skin - Mild irritant

Rabbit

-

435

-

Product/ingredient name

Result

Score

Exposure

Observation

Species

Information on toxicological effects

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:

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Date of previous issue

:

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:1111/17

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Section 11. Toxicological information

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

milligrams

Skin - Moderate irritant

Rabbit

-

24 hours 20
milligrams

-

Skin - Moderate irritant

Rabbit

-

500
milligrams

-

Ethyl 3-Ethoxypropionate

Skin - Mild irritant

Rabbit

-

24 hours 500
milligrams

-

Titanium Dioxide

Skin - Mild irritant

Human

-

72 hours 300
Micrograms
Intermittent

-

Xylene mixed isomers

Eyes - Mild irritant

Rabbit

-

87 milligrams

-

Eyes - Severe irritant

Rabbit

-

24 hours 5
milligrams

-

Skin - Mild irritant

Rat

-

8 hours 60
microliters

-

Skin - Moderate irritant

Rabbit

-

24 hours 500
milligrams

-

Skin - Moderate irritant

Rabbit

-

100 Percent

-

Sensitization

Not available.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Acetone

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Butane

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Isobutyl Acetate

Category 3

Not applicable.

Narcotic effects

Toluene

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Xylene mixed isomers

Category 3

Not applicable.

Respiratory tract
irritation

Name

Category

Route of
exposure

Target organs
Classification

Toluene

-3-

Titanium Dioxide

-2B-

Carbon Black

-2B-

Xylene mixed isomers

-3-

Product/ingredient name

NTP

IARC

OSHA

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:1112/17

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Section 11. Toxicological information

Name

Category

Acetone

Category 2

Not determined

Not determined

Propane

Category 2

Not determined

Not determined

Butane

Category 2

Not determined

Not determined

Toluene

Category 2

Not determined

Not determined

Xylene mixed isomers

Category 2

Not determined

Not determined

Aspiration hazard

Name

Result

Propane

ASPIRATION HAZARD - Category 1

Butane

ASPIRATION HAZARD - Category 1

Toluene

ASPIRATION HAZARD - Category 1

Xylene mixed isomers

ASPIRATION HAZARD - Category 1

Route of
exposure

Target organs

Information on the likely
routes of exposure

Inhalation

:

Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

:

Ingestion

Skin contact

:

Causes skin irritation.

Causes serious eye irritation.

:

Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations

:

:

:

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Delayed and immediate effects and also chronic effects from short and long term exposure

:

Not available.

Potential acute health effects

Short term exposure

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:

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:

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Not available.

May cause damage to organs through prolonged or repeated exposure.

General

:

Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.

Carcinogenicity

:

No known significant effects or critical hazards.

Mutagenicity

:

Suspected of damaging the unborn child.

Teratogenicity

:

Developmental effects

:

No known significant effects or critical hazards.

Fertility effects

:

No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Oral

4847.6 mg/kg

Route

ATE value

Acute toxicity estimates

Potential immediate
effects

:

Not available.

Potential delayed effects

:

Not available.

Potential immediate
effects

:

Not available.

Long term exposure

Potential delayed effects

:

Not available.

Section 12. Ecological information

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetone

--Readily

Toluene

--Readily

Xylene mixed isomers

--Readily

Toxicity

Acetone

Acute EC50 7200000 µg/l Fresh water

Algae - Selenastrum sp.

96 hours

Acute LC50 6000000 µg/l Fresh water

Crustaceans - Gammarus pulex

48 hours

Acute LC50 6900 mg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna ­Neonate

21 days

Chronic NOEC 0.1 mg/l Fresh water

Fish - Fundulus heteroclitus

4 weeks

Toluene

Acute EC50 12500 µg/l Fresh water

Algae - Pseudokirchneriella
subcapitata

72 hours

Acute EC50 11600 µg/l Fresh water

Crustaceans - Gammarus
pseudolimnaeus - Adult

48 hours

Acute EC50 5.56 mg/l Fresh water

Daphnia - Daphnia magna ­Neonate

48 hours

Acute LC50 5500 µg/l Fresh water

Fish - Oncorhynchus kisutch - Fry

96 hours

Chronic NOEC 1000 µg/l Fresh water

Daphnia - Daphnia magna

21 days

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

Xylene mixed isomers

Acute LC50 8500 µg/l Marine water

Crustaceans - Palaemonetes
pugio

48 hours

Acute LC50 13400 µg/l Fresh water

Fish - Pimephales promelas

96 hours

Product/ingredient name

Species

Result

Exposure

Persistence and degradability

Date of issue/Date of revision

:

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:

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Section 12. Ecological information

LogP

ow

BCF

Potential

Bioaccumulative potential

Other adverse effects

:

No known significant effects or critical hazards.

Product/ingredient name

Toluene

-90low

Xylene mixed isomers

-

8.1 to 25.9

low

Soil/water partition
coefficient (KOC)

:

Not available.

Mobility in soil

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

:

Disposal methods

Section 14. Transport information

AEROSOLS

2.1

-

AEROSOLS

2.1

-

UN1950

UN1950

-

Emergency
schedules

F-D, S-

U

DOT

Classification

IMDG

UN number

UN proper
shipping name

Transport
hazard class(es)

Packing group

Additional
information

Environmental
hazards

No.

No.

TDG

Classification

UN1950

AEROSOLS

2.1

-

No.

Product classified
as per the
following sections
of the
Transportation of
Dangerous Goods
Regulations: 2.
13-2.17 (Class 2).

Mexico

Classification

UN1950

AEROSOLS

2.1

-

No.

-

IATA

UN1950

AEROSOLS,
flammable

2.1

-

No.

-

126

ERG No.

126

126

ERG No.

ERG No.

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:1115/17

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Section 14. Transport information

Special precautions for user

Transport in bulk according
to Annex II of MARPOL and
the IBC Code

Not available.

:

Proper shipping name

:

Ship type

:

Not available.

Pollution category

:

Not available.

Not available.

:

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.

Section 15. Regulatory information

SARA 313

SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

California Prop. 65

Australia inventory (AICS)

: Not determined.

China inventory (IECSC)

: Not determined.

Japan inventory (ENCS)

: Not determined.

Japan inventory (ISHL)

: Not determined.

Korea inventory (KECI)

: Not determined.

Malaysia Inventory (EHS Register)

: Not determined.

New Zealand Inventory of Chemicals (NZIoC)

: Not determined.

Philippines inventory (PICCS)

: Not determined.

Taiwan Chemical Substances Inventory (TCSI)

: Not determined.

Thailand inventory

: Not determined.

Turkey inventory

: Not determined.

Vietnam inventory

: Not determined.

International regulations

International lists

:

Section 16. Other information

Hazardous Material Information System (U.S.A.)

3

4

3

*

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.

The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

Procedure used to derive the classification

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:1116/17

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Section 16. Other information

1/21/2019

History

Date of printing

Date of issue/Date of
revision

Version

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer,
or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements
are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is
responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The
conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is
responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user
should not use the product for any purpose other than the purpose shown in the applicable section of this SDS
without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of
sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs
obtained from any other source.

Date of previous issue

:::

:

Key to abbreviations

:

ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations

1/21/2019

11/6/2018

11

FLAMMABLE AEROSOLS - Category 1

On basis of test data

GASES UNDER PRESSURE - Compressed gas

Calculation method

SKIN CORROSION/IRRITATION - Category 2

Calculation method

SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A

Calculation method

CARCINOGENICITY - Category 2

Calculation method

TOXIC TO REPRODUCTION (Unborn child) - Category 2

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3

Calculation method

SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2

Calculation method

ASPIRATION HAZARD - Category 1

Calculation method

Classification

Justification

Notice to reader

Date of issue/Date of revision

:

1/21/2019

Date of previous issue

:

11/6/2018

Version

:1117/17

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