Krylon A03731007 User Manual

KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Paint (APWA)
Bright Orange

Not available.
Aerosol.

[phone]

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

:

:::

Manufacturer

:

THE SHERWIN-WILLIAMS COMPANY
KRYLON PRODUCTS GROUP
Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

03731

03731

Product code

:

Product Information
Telephone Number

:

[phone]

Regulatory Information
Telephone Number

:

[phone]

Transportation Emergency
Telephone Number

:

[phone]

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1
GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1

Classification of the
substance or mixture

:

Signal word

:

Danger

Hazard pictograms

:

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 19.7%

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

1/14

Section 2. Hazards identification

Precautionary statements

Prevention

:

Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling.

Response

:

Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated
clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.

Storage

:

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

General

:

Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.

Hazards not otherwise
classified

:

None known.

Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May damage the unborn child.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.

Supplemental label
elements

DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm.

Section 3. Composition/information on ingredients

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Mixture

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

2/14

Section 3. Composition/information on ingredients

Toluene

20.7

108-88-3

Propane

12.2

74-98-6

Butane

5.8

106-97-8

Lt. Aliphatic Hydrocarbon Solvent

2.0

64742-89-8

Titanium Dioxide

0.6

13463-67-7

1-Methyl-2-Pyrrolidone

0.1

872-50-4

Ingredient name

CAS number
% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

Occupational exposure limits, if available, are listed in Section 8.

Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

:

:

:

:

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

:

Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

:

Ingestion
Skin contact

:

Causes skin irritation.

Causes serious eye irritation.

:

Eye contact

Over-exposure signs/symptoms

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential acute health effects

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

3/14

Section 4. First aid measures

Protection of first-aiders

:

No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

Notes to physician

:

Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.

Specific treatments

:

No specific treatment.

Skin contact
Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations

:

:

:

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
metal oxide/oxides

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:
:

None known.

Suitable extinguishing
media

:

Unsuitable extinguishing
media

:

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

4/14

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

:

Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

:

:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Large spill

:

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

:

Methods and materials for containment and cleaning up

For non-emergency
personnel

For emergency responders

:

If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Section 7. Handling and storage

Protective measures

Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.

:

Precautions for safe handling

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

5/14

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any
incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

:
:

Toluene

OSHA PEL Z2 (United States, 2/2013).

TWA: 200 ppm 8 hours.

CEIL: 300 ppm

AMP: 500 ppm 10 minutes.

NIOSH REL (United States, 10/2013).

TWA: 100 ppm 10 hours.

TWA: 375 mg/m³ 10 hours.

STEL: 150 ppm 15 minutes.

STEL: 560 mg/m³ 15 minutes.

ACGIH TLV (United States, 4/2014).

TWA: 20 ppm 8 hours.

Propane

NIOSH REL (United States, 10/2013).

TWA: 1000 ppm 10 hours.

TWA: 1800 mg/m³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.

TWA: 1800 mg/m³ 8 hours.

Butane

NIOSH REL (United States, 10/2013).

TWA: 800 ppm 10 hours.

TWA: 1900 mg/m³ 10 hours.

ACGIH TLV (United States, 4/2014).

STEL: 1000 ppm 15 minutes.

Titanium Dioxide

ACGIH TLV (United States, 4/2014).

TWA: 10 mg/m³ 8 hours.

OSHA PEL (United States, 2/2013).

TWA: 15 mg/m³ 8 hours. Form: Total dust

1-Methyl-2-Pyrrolidone

AIHA WEEL (United States, 10/2011).
Absorbed through skin.

TWA: 10 ppm 8 hours.

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Environmental exposure
controls

:

Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Appropriate engineering
controls

:

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Control parameters

Individual protection measures

Occupational exposure limits

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

6/14

Section 8. Exposure controls/personal protection

Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection

:

:

:

Body protection

Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti­static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.

:

Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.

Hygiene measures

:

Skin protection

Other skin protection

:

Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Solubility

Liquid.

Not available.

0.86

1 [Air = 1]

13.5 kPa (101.325 mm Hg) [at 20°C]

Not available.

Not available.

Odor

pH

Not available.

Color

Evaporation rate

3.22 (butyl acetate = 1)

Auto-ignition temperature

Flash point

Not available.

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

Not available.
7

Not available.

Odor threshold

Partition coefficient: n­octanol/water

:::

:::

:

:

:::::

:

Appearance

Boiling point

:

Not available.

Flammability (solid, gas)

:

Not available.

Lower and upper explosive
(flammable) limits

:

Lower: 0.9%
Upper: 12.8%

Decomposition temperature

:

Not available.

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

7/14

Section 9. Physical and chemical properties

Viscosity

Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)

:

Type of aerosol

:

Spray

Heat of combustion

:

0.00002217 kJ/g

Aerosol product

Section 10. Stability and reactivity

Hazardous decomposition
products

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products should
not be produced.

The product is stable.

Chemical stability

No specific data.

:

:

:

Incompatible materials

:

Possibility of hazardous
reactions

:

Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity

:

No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Toluene

LC50 Inhalation Vapor

Rat

49 g/m³

4 hours

LD50 Oral

Rat

636 mg/kg

-

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

1-Methyl-2-Pyrrolidone

LD50 Dermal

Rabbit

8 g/kg

-

LD50 Oral

Rat

3914 mg/kg

-

Product/ingredient name

Result

Species

Dose

Exposure

Irritation/Corrosion

Toluene

Eyes - Mild irritant

Rabbit

-

0.5 minutes
100
milligrams

-

Eyes - Mild irritant

Rabbit

-

870
Micrograms

-

Eyes - Severe irritant

Rabbit

-

24 hours 2
milligrams

-

Skin - Mild irritant

Pig

-

24 hours 250
microliters

-

Skin - Mild irritant

Rabbit

-

435
milligrams

-

Skin - Moderate irritant

Rabbit

-

24 hours 20
milligrams

-

Skin - Moderate irritant

Rabbit

-

500
milligrams

-

Titanium Dioxide

Skin - Mild irritant

Human

-

72 hours 300
Micrograms
Intermittent

-

1-Methyl-2-Pyrrolidone

Eyes - Moderate irritant

Rabbit

-

100
milligrams

-

Product/ingredient name

Result

Score

Exposure

Observation

Species

Information on toxicological effects

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

8/14

Section 11. Toxicological information

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Sensitization

Not available.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Toluene

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Butane

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Lt. Aliphatic Hydrocarbon Solvent

Category 3

Not applicable.

Respiratory tract
irritation and
Narcotic effects

Name

Category

Name

Category

Toluene

Category 2

Not determined

Not determined

Propane

Category 2

Not determined

Not determined

Butane

Category 2

Not determined

Not determined

Lt. Aliphatic Hydrocarbon Solvent

Category 2

Not determined

Not determined

Aspiration hazard

Name

Result

Toluene

ASPIRATION HAZARD - Category 1

Propane

ASPIRATION HAZARD - Category 1

Butane

ASPIRATION HAZARD - Category 1

Lt. Aliphatic Hydrocarbon Solvent

ASPIRATION HAZARD - Category 1

Route of
exposure

Target organs

Route of
exposure

Target organs
Classification

Toluene

-3-

Titanium Dioxide

-2B-

Product/ingredient name

NTP

IARC

OSHA

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

9/14

Not available.

Information on the likely
routes of exposure

Inhalation

:

Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

:

Ingestion

Skin contact

:

Causes skin irritation.

Causes serious eye irritation.

:

Eye contact

May cause damage to organs through prolonged or repeated exposure.

General

:

Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.

Carcinogenicity

:

No known significant effects or critical hazards.

Mutagenicity

:

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations

:

::Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

:

Not available.

Potential acute health effects

Potential immediate
effects

:

Not available.

Short term exposure

Potential delayed effects

:

Not available.

Potential immediate
effects

:

Not available.

Long term exposure

Potential delayed effects

:

Not available.

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

10/14

May damage the unborn child.

Teratogenicity

:

Developmental effects

:

No known significant effects or critical hazards.

Fertility effects

:

No known significant effects or critical hazards.

Numerical measures of toxicity

Oral

2467.2 mg/kg

Route

ATE value

Acute toxicity estimates

Section 12. Ecological information

LogP

ow

BCF

Potential

Bioaccumulative potential

Other adverse effects

:

No known significant effects or critical hazards.

Product/ingredient name

Toluene

-90low

Lt. Aliphatic Hydrocarbon
Solvent

-

10 to 2500

high

Titanium Dioxide

-

352

low

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Toluene

--Readily

Toxicity

Toluene

Acute EC50 12500 µg/l Fresh water

Algae - Pseudokirchneriella
subcapitata

72 hours

Acute EC50 11600 µg/l Fresh water

Crustaceans - Gammarus
pseudolimnaeus - Adult

48 hours

Acute EC50 6000 µg/l Fresh water

Daphnia - Daphnia magna ­Juvenile (Fledgling, Hatchling,
Weanling)

48 hours

Acute LC50 5500 µg/l Fresh water

Fish - Oncorhynchus kisutch - Fry

96 hours

Chronic NOEC 1000 µg/l Fresh water

Daphnia - Daphnia magna

21 days

Lt. Aliphatic Hydrocarbon
Solvent

Acute LC50 >100000 ppm Fresh water

Fish - Oncorhynchus mykiss

96 hours

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

1-Methyl-2-Pyrrolidone

Acute LC50 1.23 ppm Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 832 ppm Fresh water

Fish - Lepomis macrochirus

96 hours

Product/ingredient name

Species

Result

Exposure

Persistence and degradability

Soil/water partition
coefficient (KOC)

:

Not available.

Mobility in soil

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

11/14

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

:

Disposal methods

Section 14. Transport information

AEROSOLS

2.1

-

AEROSOLS

2.1

-

UN1950

UN1950

Special
provisions

LIMITED
QUANTITY

Emergency
schedules (EmS)

LIMITED
QUANTITY, F-D,
S-U

DOT

Classification

IMDG

UN number

UN proper
shipping name

Transport
hazard class(es)

Packing group

Additional
information

Environmental
hazards

Special precautions for user

Transport in bulk according
to Annex II of MARPOL
73/78 and the IBC Code

No.

No.

:

Not available.

:

TDG

Classification

UN1950

AEROSOLS

2.1

-

No.

Special
provisions

LIMITED
QUANTITY

Mexico

Classification

UN1950

AEROSOLS

2.1

-

No.

Special
provisions

(ERG#126)

Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

IATA

UN1950

AEROSOLS,
flammable

2.1

-

No.

Special
provisions

LIMITED
QUANTITY

Section 15. Regulatory information

U.S. Federal regulations

:

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

12/14

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

California Prop. 65

State regulations

Section 16. Other information

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Notice to reader

Hazardous Material Information System (U.S.A.)

2

3

0

*

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller [phone].

The customer is responsible for determining the PPE code for this material.

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

13/14

Date of issue/Date of revision

:

5/5/2015.

Date of previous issue

:

4/7/2015.

Version

:

1.02

14/14