Krylon A01470007 User Manual

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KRYLON® Industrial TOUGH COAT™ Acrylic Enamel OSHA Safety Green

Not available. Aerosol.

(216) 566-2917

SAFETY DATA SHEET

Product name

Other means of identification

Product type

Emergency telephone number of the company

Section 1. Identification

:::

Manufacturer

THE SHERWIN-WILLIAMS COMPANY KRYLON PRODUCTS GROUP Cleveland, OH 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

1470

Product code

Product Information Telephone Number

(800) 247-3266

Regulatory Information Telephone Number

(216) 566-2902

Transportation Emergency Telephone Number

(800) 424-9300

Section 2. Hazards identification

FLAMMABLE AEROSOLS - Category 1 GASES UNDER PRESSURE - Compressed gas SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION (Unborn child) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation and Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word

Danger

Hazard pictograms

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 17.7%

OSHA/HCS status

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

1/14

Section 2. Hazards identification

Precautionary statements

Prevention

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.

Response

Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.

Storage

Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and international regulations.

General

Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand.

Hazards not otherwise classified

None known.

Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. Suspected of damaging the unborn child. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause respiratory irritation. May cause drowsiness and dizziness. May cause damage to organs through prolonged or repeated exposure.

Hazard statements

Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do not discard empty can in trash compactor.

Supplemental label elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

Section 3. Composition/information on ingredients

Other means of identification

Not available.

Substance/mixture

CAS number/other identifiers

Mixture

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

2/14

Section 3. Composition/information on ingredients

Acetone

29.4

67-64-1

Toluene

22.5

108-88-3

Propane

13.9

74-98-6

Butane

13.4

106-97-8

Titanium Dioxide

3.8

13463-67-7

Methyl Ethyl Ketoxime

0.2

96-29-7

Ingredient name

CAS number % by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Section 4. First aid measures

Eye contact

Skin contact

Inhalation

Ingestion

Description of necessary first aid measures

Most important symptoms/effects, acute and delayed

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Ingestion Skin contact

Causes skin irritation. May cause an allergic skin reaction.

Causes serious eye irritation.

Eye contact

Over-exposure signs/symptoms

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Potential acute health effects

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

3/14

Section 4. First aid measures

Protection of first-aiders

No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

Notes to physician

Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments

No specific treatment.

Skin contact Ingestion

Inhalation

Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations

See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Section 5. Fire-fighting measures

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard.

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

: :

None known.

Suitable extinguishing media

Unsuitable extinguishing media

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

4/14

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective equipment for fire-fighters

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Large spill

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.

Small spill

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders

If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".

Section 7. Handling and storage

Protective measures

Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

Precautions for safe handling

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

5/14

Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.

: :

Acetone

ACGIH TLV (United States, 4/2014).

TWA: 500 ppm 8 hours.

TWA: 1188 mg/m³ 8 hours.

STEL: 750 ppm 15 minutes.

STEL: 1782 mg/m³ 15 minutes.

NIOSH REL (United States, 10/2013).

TWA: 250 ppm 10 hours.

TWA: 590 mg/m³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.

TWA: 2400 mg/m³ 8 hours.

Toluene

OSHA PEL Z2 (United States, 2/2013).

TWA: 200 ppm 8 hours.

CEIL: 300 ppm

AMP: 500 ppm 10 minutes.

NIOSH REL (United States, 10/2013).

TWA: 100 ppm 10 hours.

TWA: 375 mg/m³ 10 hours.

STEL: 150 ppm 15 minutes.

STEL: 560 mg/m³ 15 minutes.

ACGIH TLV (United States, 4/2014).

TWA: 20 ppm 8 hours.

Propane

NIOSH REL (United States, 10/2013).

TWA: 1000 ppm 10 hours.

TWA: 1800 mg/m³ 10 hours.

OSHA PEL (United States, 2/2013).

TWA: 1000 ppm 8 hours.

TWA: 1800 mg/m³ 8 hours.

Butane

NIOSH REL (United States, 10/2013).

TWA: 800 ppm 10 hours.

TWA: 1900 mg/m³ 10 hours.

ACGIH TLV (United States, 4/2014).

STEL: 1000 ppm 15 minutes.

Titanium Dioxide

ACGIH TLV (United States, 4/2014).

TWA: 10 mg/m³ 8 hours.

OSHA PEL (United States, 2/2013).

TWA: 15 mg/m³ 8 hours. Form: Total dust

Methyl Ethyl Ketoxime

AIHA WEEL (United States, 10/2011). Skin sensitizer.

TWA: 10 ppm 8 hours.

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

6/14

Section 8. Exposure controls/personal protection

Hand protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Eye/face protection

Respiratory protection

Body protection

Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear antistatic protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Other skin protection

Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Liquid.

Not available.

Odor

Not available.

Color

Evaporation rate

5.6 (butyl acetate = 1)

Flash point

Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]

Not available.

Odor threshold

:::

::Appearance

Boiling point

Not available.

Flammability (solid, gas)

Not available.

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

7/14

Section 9. Physical and chemical properties

Vapor pressure

Relative density

Vapor density

Solubility

0.76

1.55 [Air = 1]

13.5 kPa (101.325 mm Hg) [at 20°C]

Not available.

Auto-ignition temperature

Not available.

Viscosity

Kinematic (room temperature): <0.07 cm2/s (<7 cSt) Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)

Partition coefficient: noctanol/water

:::

: :

Lower and upper explosive (flammable) limits

Lower: 1% Upper: 12.8%

Decomposition temperature

Not available.

Type of aerosol

Spray

Heat of combustion

0.00002725 kJ/g

Aerosol product

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.

Chemical stability

No specific data.

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity

No specific test data related to reactivity available for this product or its ingredients.

Section 11. Toxicological information

Acute toxicity

Acetone

LD50 Oral

Rat

5800 mg/kg

Toluene

LC50 Inhalation Vapor

Rat

49 g/m³

4 hours

LD50 Oral

Rat

636 mg/kg

Butane

LC50 Inhalation Vapor

Rat

658000 mg/m³

4 hours

Methyl Ethyl Ketoxime

LD50 Oral

Rat

930 mg/kg

Product/ingredient name

Result

Species

Dose

Exposure

Irritation/Corrosion

Acetone

Eyes - Mild irritant

Human

186300 parts per million

Eyes - Mild irritant

Rabbit

10 microliters

Eyes - Moderate irritant

Rabbit

24 hours 20 milligrams

Eyes - Severe irritant

Rabbit

20 milligrams

Skin - Mild irritant

Rabbit

24 hours 500 milligrams

Product/ingredient name

Result

Score

Exposure

Observation

Species

Information on toxicological effects

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

8/14

Section 11. Toxicological information

Carcinogenicity

Not available.

Mutagenicity

Not available.

Teratogenicity

Not available.

Reproductive toxicity

Not available.

Skin - Mild irritant

Rabbit

395 milligrams

Toluene

Eyes - Mild irritant

Rabbit

0.5 minutes 100 milligrams

Eyes - Mild irritant

Rabbit

870 Micrograms

Eyes - Severe irritant

Rabbit

24 hours 2 milligrams

Skin - Mild irritant

Pig

24 hours 250 microliters

Skin - Mild irritant

Rabbit

435 milligrams

Skin - Moderate irritant

Rabbit

24 hours 20 milligrams

Skin - Moderate irritant

Rabbit

500 milligrams

Titanium Dioxide

Skin - Mild irritant

Human

72 hours 300 Micrograms Intermittent

Methyl Ethyl Ketoxime

Eyes - Severe irritant

Rabbit

100 microliters

Sensitization

Not available.

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Acetone

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Toluene

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Propane

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Butane

Category 3

Not applicable.

Respiratory tract irritation and Narcotic effects

Name

Category

Acetone

Category 2

Not determined

Toluene

Category 2

Not determined

Propane

Category 2

Not determined

Butane

Category 2

Not determined

Aspiration hazard

Name

Result

Toluene

ASPIRATION HAZARD - Category 1

Propane

ASPIRATION HAZARD - Category 1

Butane

ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Information on the likely routes of exposure

Inhalation

Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Irritating to mouth, throat and stomach.

Ingestion

Skin contact

Causes skin irritation. May cause an allergic skin reaction.

Causes serious eye irritation.

Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation

Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations

Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations

Eye contact

Adverse symptoms may include the following: pain or irritation watering redness

Delayed and immediate effects and also chronic effects from short and long term exposure

Not available.

Potential acute health effects

Short term exposure

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

10/14

Not available.

May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.

General

Suspected of causing cancer. Risk of cancer depends on duration and level of exposure.

Carcinogenicity

No known significant effects or critical hazards.

Mutagenicity

Suspected of damaging the unborn child.

Teratogenicity

Developmental effects

No known significant effects or critical hazards.

Fertility effects

No known significant effects or critical hazards.

Potential chronic health effects

Numerical measures of toxicity

Oral

2296.6 mg/kg

Route

ATE value

Acute toxicity estimates

Potential immediate effects

Not available.

Potential delayed effects

Not available.

Potential immediate effects

Not available.

Long term exposure

Potential delayed effects

Not available.

Section 12. Ecological information

Toxicity

Acetone

Acute EC50 20.565 mg/l Marine water

Algae - Ulva pertusa

96 hours

Acute LC50 6000000 µg/l Fresh water

Crustaceans - Gammarus pulex

48 hours

Acute LC50 10000 µg/l Fresh water

Daphnia - Daphnia magna

48 hours

Acute LC50 5600 ppm Fresh water

Fish - Poecilia reticulata

96 hours

Chronic NOEC 4.95 mg/l Marine water

Algae - Ulva pertusa

96 hours

Chronic NOEC 0.016 ml/L Fresh water

Crustaceans - Daphniidae

21 days

Chronic NOEC 0.1 ml/L Fresh water

Daphnia - Daphnia magna Neonate

21 days

Chronic NOEC 5 µg/l Marine water

Fish - Gasterosteus aculeatus Larvae

42 days

Toluene

Acute EC50 12500 µg/l Fresh water

Algae - Pseudokirchneriella subcapitata

72 hours

Acute EC50 11600 µg/l Fresh water

Crustaceans - Gammarus pseudolimnaeus - Adult

48 hours

Acute EC50 6000 µg/l Fresh water

Daphnia - Daphnia magna Juvenile (Fledgling, Hatchling, Weanling)

48 hours

Acute LC50 5500 µg/l Fresh water

Fish - Oncorhynchus kisutch - Fry

96 hours

Chronic NOEC 1000 µg/l Fresh water

Daphnia - Daphnia magna

21 days

Titanium Dioxide

Acute LC50 >1000000 µg/l Marine water

Fish - Fundulus heteroclitus

96 hours

Methyl Ethyl Ketoxime

Acute LC50 843000 µg/l Fresh water

Fish - Pimephales promelas

96 hours

Product/ingredient name

Species

Result

Exposure

Persistence and degradability

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

11/14

Section 12. Ecological information

LogP

BCF

Potential

Bioaccumulative potential

Other adverse effects

No known significant effects or critical hazards.

Product/ingredient name

Toluene

-90low

Titanium Dioxide

352

low

Methyl Ethyl Ketoxime

2.5 to 5.8

low

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Acetone

--Readily

Toluene

--Readily

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

Section 13. Disposal considerations

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

Disposal methods

Section 14. Transport information

AEROSOLS

2.1

AEROSOLS

2.1

UN1950

Special provisions

LIMITED QUANTITY

Emergency schedules (EmS)

LIMITED QUANTITY, F-D, S-U

DOT

Classification

IMDG

UN number

UN proper shipping name

Transport hazard class(es)

Packing group

Additional information

Environmental hazards

No.

TDG

Classification

UN1950

AEROSOLS

2.1

No.

Special provisions

LIMITED QUANTITY

Mexico

Classification

UN1950

AEROSOLS

2.1

No.

Special provisions

(ERG#126)

IATA

UN1950

AEROSOLS, flammable

2.1

No.

Special provisions

LIMITED QUANTITY

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

12/14

Section 14. Transport information

Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not available.

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations.

Section 15. Regulatory information

U.S. Federal regulations

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.

California Prop. 65

State regulations

Section 16. Other information

Notice to reader

Hazardous Material Information System (U.S.A.)

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

The customer is responsible for determining the PPE code for this material.

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

13/14

Section 16. Other information

It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision

3/26/2015.

Date of previous issue

3/13/2015.

Version

1.01

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Krylon A01470007 User Manual

Specifications and Main Features

Frequently Asked Questions

User Manual