Krud Kutter GR326 User Manual

Date Printed: 4/17/2020
Safety Data Sheet
www.rustoleum.com
1. Identification
Product Name: KRDKUT QT 6PK TRG GRAFFITI REMOVER Revision Date: 4/17/2020
Product Identifier: GR326 Supercedes Date: 10/9/2015
Recommended Use: Graffiti Remover/ Emulsion
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Supplier:
Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
24 Hour Hotline: 847-367-7700
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
23% of the mixture consists of ingredient(s) of unknown acute toxicity.
Manufacturer:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
GHS HAZARD STATEMENTS
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
Serious Eye Damage, category 1 H318 Causes serious eye damage.
GHS LABEL PRECAUTIONARY STATEMENTS
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P271 Use only outdoors or in a well-ventilated area.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
P310 If exposed immediately call a POISON CENTER or doctor/physician.
and easy to do. Continue rinsing.
3. Composition / Information On Ingredients
Date Printed: 4/17/2020
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Benzyl Alcohol 100-51-6 10-25 GHS07 H302-312-320-332
GHS Symbols
GHS Statements
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Fatty alcohol ethoxylate
Dipropylene Glycol Monomethyl Ether 34590-94-8 2.5-10 Not Available Not Available
Alcohols, C10-16, Ethoxylated, Sulfates, Sodium Salts
Sodium Xylene Sulfonate 1300-72-7 2.5-10 GHS07 H302
Ethanol 64-17-5 0.1-1.0 GHS02 H225
160875-66-
1
68585-34-2 2.5-10 Not Available Not Available
10-25 GHS05 H318
4. First-Aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed. Remove contact lenses, if present and easy to do. Continue rinsing.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, rinse mouth with water. If feeling unwell, get medical attention. If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively.
5. Fire-Fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Keep containers tightly closed. FLASH
POINT IS TESTED TO BE GREATER THAN 200 DEGREES F.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. If water is used, fog nozzles are preferred.
Special Fire and Explosion Hazard (Combustible Dust): No Information
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. Do not incinerate closed containers
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Advice on Safe Handling of Combustible Dust: No Information
Date Printed: 4/17/2020
8. Exposure Controls / Personal Protection
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Chemical Name CAS-No.
Benzyl Alcohol 100-51-6 25.0 N.E. N.E. N.E. N.E. Fatty alcohol ethoxylate 160875-66-1 15.0 N.E. N.E. N.E. N.E. Dipropylene Glycol Monomethyl Ether Alcohols, C10-16, Ethoxylated, Sulfates, Sodium Salts Sodium Xylene Sulfonate 1300-72-7 5.0 N.E. N.E. N.E. N.E. Ethanol 64-17-5 1.0 N.E. 1000 ppm 1000 ppm N.E.
34590-94-8 5.0 100 ppm 150 ppm 100 ppm N.E.
68585-34-2 5.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Engineering Measures for Combustible Dust: No Information
9. Physical and Chemical Properties
Appearance: Odor: Specific Gravity: Freeze Point, °C: Solubility in Water: Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
Liquid Mild N.E.
1.020 N.D. Slight N.D. 212 - 537 Does not Support Combustion 94 Slower than Ether N.D. Heavier than Air
(See "Other information" Section for abbreviation legend)
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid excess heat. Keep from freezing.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
Liquid
8.0-9.0 N.D.
N.D.
1.1 - 14.0
N.D.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, and may injure eye tissue if not removed promptly.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Low hazard for usual industrial handling or commercial handling by trained
personnel.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.
Date Printed: 4/17/2020
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: No Information
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
100-51-6 Benzyl Alcohol 1230 mg/kg Rat 2000 mg/kg Rabbit 11 mg/L Rat 34590-94-8 Dipropylene Glycol Monomethyl Ether 5350 mg/kg Rat 9500 mg/kg Rabbit >20 mg/L 1300-72-7 Sodium Xylene Sulfonate 1000 mg/kg Rat N.E. N.E. 64-17-5 Ethanol 7060 mg/kg Rat 15,800 mg/kg Rabbit 30,000 mg/L Rat
N.E. - Not Established
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
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12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. No ecotoxicity data was found for this product.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Acute Toxicity (any route of exposure), Serious eye damage or eye irritation
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
No TSCA 12(b) components exist in this product.
U.S. State Regulations:
California Proposition 65:
Date Printed: 4/17/2020
WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 1 Physical Hazard: 0 Personal Protection: X
NFPA RATINGS
Health: 2 Flammability: 1 Instability 0
Volatile Organic Compounds 255 g/L
SDS REVISION DATE: 4/17/2020
REASON FOR REVISION: Product Composition Changed
Substance and/or Product Properties Changed in Section(s): 02 - Hazard Identification 05 - Fire-fighting Measures 09 - Physical & Chemical Properties 15 - Regulatory Information 16 - Other Information Revision Statement(s) Changed
Legend:
N.A. - Not Applicable, N.D. - Not Determined, N.E. - Not Established
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The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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