Date Printed: 10/9/2015
100-51-6
PROPRIET
ARY
Safety Data Sheet
www.rustoleum.com
1. Identification
Product Name: KRDKUT 1-GLF 2PK GRAFFITI REMOVER Revision Date: 10/9/2015
Product Identifier: GR012 Supercedes Date: 8/17/2015
Product Use/Class: Graffiti Remover/ Emulsion
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Supplier:
Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
22% of the mixture consists of ingredient(s) of unknown acute toxicity.
GHS HAZARD STATEMENTS
Serious Eye Damage, category 1 H318 Causes serious eye damage.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
GHS LABEL PRECAUTIONARY STATEMENTS
P261 Avoid breathing dust, fumes, gases, mists, vapors, or spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Benzyl Alcohol
Ethoxylated Alcohols
10-25
10-25
GHS Symbols
GHS06
GHS05-GHS07
GHS Statements
H302-312-331
H302-318
Date Printed: 10/9/2015
34590-94-8
64-17-5
68002-97-1
Dipropylene glycol monomethyl ether
Alcohols, C10-16, ethoxylated, sulfates, sodium
salts
Ethanol
C10-16 Ethoxylated Alcohols
68585-34-2
2.5-10
2.5-10
0.1-1.0
<0.1
No Information
No Information
GHS02
No Information
No Information
No Information
H225
No Information
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4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, rinse mouth with water. If feeling unwell, get medical attention. Swallowing less than an
ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and
get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. FLASH POINT IS TESTED TO BE GREATER THAN
200 DEGREES F. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. If water is
used, fog nozzles are preferred.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal
regulations. Do not incinerate closed containers
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Benzyl Alcohol 100-51-6 25.0 N.E. N.E. N.E. N.E.
Ethoxylated Alcohols PROPRIETARY 15.0 N.E. N.E. N.E. N.E.
Dipropylene glycol monomethyl
ether
Alcohols, C10-16, ethoxylated,
sulfates, sodium salts
Ethanol 64-17-5 1.0 N.E. 1000 ppm 1000 ppm N.E.
C10-16 Ethoxylated Alcohols 68002-97-1 0.1 N.E. N.E. N.E. N.E.
34590-94-8 5.0 100 ppm 150 ppm 100 ppm N.E.
68585-34-2 5.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.
Date Printed: 10/9/2015
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
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9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid
Mild
1.010
N.D.
Slight
N.D.
78 - 205
Does not Support Combustion
Slower than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
8.0-9.0
No Information
N.D.
1.3 - 13.0
94
N.D.
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, and may injure eye tissue if not removed promptly.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Low hazard for usual industrial handling or commercial handling by trained
personnel.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid
breathing fumes, spray, vapors, or mist.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: No Information
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
100-51-6 Benzyl Alcohol 1230 mg/kg Rat 2000 mg/kg Rabbit 8.8 mg/L Rat
34590-94-8 Dipropylene glycol monomethyl ether N.I. 9500 mg/kg Rabbit N.I.
64-17-5 Ethanol 7060 mg/kg Rat N.I. 124.7 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
Date Printed: 10/9/2015
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
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14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from
the United States:
No TSCA 12(b) components exist in this product.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 1 Physical Hazard: 0 Personal Protection: X
NFPA RATINGS
Health: 2 Flammability: 1 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
SDS REVISION DATE: 10/9/2015
REASON FOR REVISION: Substance and/or Product Properties Changed in Section(s):
02 - Hazard Identification
09 - Physical & Chemical Properties
11 - Toxicological Information
Product Composition Changed
Statement(s) Changed
614
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Date Printed: 10/9/2015
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The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate
and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these
materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the
use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the
data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The
information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is
the responsibility of the user to determine the final suitability of this information and to comply with all applicable international,
federal, state, and local laws and regulations.
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