Krud Kutter AR014 User Manual

Date Printed: 11/3/2015
34590-94-8
PROPRIET
ARY
141-43-5
Safety Data Sheet
www.rustoleum.com
1. Identification
Product Name: KRDKUT 1-GLF ADHESIVE REMOVER Revision Date: 11/3/2015
Product Identifier: AR014 Supercedes Date: 10/9/2015
Product Use/Class: Adhesive Remover/ Water-based
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Supplier:
Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger

GHS HAZARD STATEMENTS

Skin Irritation, category 2 H315 Causes skin irritation. Serious Eye Damage, category 1 H318 Causes serious eye damage.

GHS LABEL PRECAUTIONARY STATEMENTS

P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P362 Take off contaminated clothing.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Dipropylene glycol monomethyl ether Ethoxylated Alcohols
Monoethanolamine
2.5-10
2.5-10
1.0-2.5
GHS Symbols
No Information GHS05-GHS07
GHS05-GHS06
GHS Statements
No Information H302-318
H302-311-314-332-335
Date Printed: 11/3/2015
1300-72-7
1310-58-3
68603-42-9
Sodium Xylene Sulfonate Potassium Hydroxide Coconut Oil Diethanolamide Diethanolamine
111-42-2
1.0-2.5
0.1-1.0
0.1-1.0
0.1-1.0
GHS07 GHS05-GHS06 No Information GHS05-GHS07-
GHS08
H302 H301-314 No Information H302-315-318-373
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4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Containers can rupture and release highly toxic material if exposed to heat. Substance
is non-combustible but reacts with many metals to form explosive hydrogen gas. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid runoff into sewers and waterways. Provide ventilation
and approach spill from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with sodium bicarbonate (NaHCO3). Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Dipropylene glycol monomethyl ether Ethoxylated Alcohols PROPRIETARY 5.0 N.E. N.E. N.E. N.E. Monoethanolamine 141-43-5 5.0 3 ppm 6 ppm 3 ppm N.E. Sodium Xylene Sulfonate 1300-72-7 5.0 N.E. N.E. N.E. N.E. Potassium Hydroxide 1310-58-3 1.0 N.E. N.E. N.E. N.E. Coconut Oil Diethanolamide 68603-42-9 1.0 N.E. N.E. N.E. N.E. Diethanolamine 111-42-2 1.0 1 mg/m3 N.E. N.E. N.E.
34590-94-8 5.0 100 ppm 150 ppm 100 ppm N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
PERSONAL PROTECTION
Date Printed: 11/3/2015
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
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9. Physical and Chemical Properties
Appearance: Odor: Relative Density: Freeze Point, °C: Solubility in Water: Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid Solvent Like
1.013 30 Soluble N.D. 100 - 218 Does not Support Combustion Slower than Ether Heavier than Air
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
Liquid N.E. Alkaline No Information
N.D.
1.7 - 17.0 94 N.D. N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases. Avoid contact with metals.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Product slowly corrodes copper,
aluminum, zinc, and galvanized surfaces.
HAZARDOUS DECOMPOSITION: Decomposition produces hydrogen chloride, chlorine and hydrogen gases.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Substance causes severe eye irritation. Injury may be permanent.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Severely irritating; may cause permanent skin damage.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Corrosive and may cause severe and permanent damage to mouth, throat and stomach. Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated exposure to low concentrations of HCl vapor or mist may cause bleeding of nose and gums.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
34590-94-8 Dipropylene glycol monomethyl ether N.I. 9500 mg/kg Rabbit N.I. 141-43-5 Monoethanolamine 1720 mg/kg Rat 1000 mg/kg Rabbit N.I. 1300-72-7 Sodium Xylene Sulfonate 1000 mg/kg Rat N.I. N.I. 1310-58-3 Potassium Hydroxide 284 mg/kg Rat N.I. N.I. 111-42-2 Diethanolamine 675 mg/kg Rat N.I. N.I.
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
Date Printed: 11/3/2015
N.I. - No Information
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12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Diethanolamine 111-42-2
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
No TSCA 12(b) components exist in this product.
CAS-No.
Date Printed: 11/3/2015
16. Other Information
HMIS RATINGS
Health: 1* Flammability: 1 Physical Hazard: 0 Personal Protection: X
NFPA RATINGS
Health: 1 Flammability: 1 Instability 0
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VOLATILE ORGANIC COMPOUNDS, g/L:
SDS REVISION DATE: 11/3/2015
REASON FOR REVISION: Substance and/or Product Properties Changed in Section(s):
01 - Identification
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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