Krud Kutter 352239 User Manual

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Date Printed: 12/10/2019
Safety Data Sheet
1. Identification
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www.rustoleum.com/krudkutterpro
Product Nam e:
Recomm ended Use: Cleaner Degreaser/Aerosols
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
KK PRO 20OZ 6PK CONC CLNR DEGSR AEROSOL
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
24 Hour Hotline: 847-367-7700
Revision Date: 12/10/2019
Manufacturer:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Warning
Possible Hazards
7% of the mixture consists of ingredient(s) of unknown acute toxicity.
GHS HAZARD STATEMENTS
Compressed Gas H280 Contains gas under pressure; may explode if heated.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2A H319 Causes serious eye irritation.
GHS LABEL PRECAUTIONARY STATEMENTS
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P321 For specific treatment see label
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
P337+P313 If eye irritation persists: Get medical advice/attention.
easy to do. Continue rinsing.
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Date Printed: 12/10/2019
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3. Composition / Information On Ingredients
HAZARDOUS SUBSTANCES
Chem ical Name CAS-No. Wt.%
Range
n-Butane 106-97-8 2.5-10 GHS04 H280
C9-C11 Alcohols Ethoxylated 68439-46-3 1.0-2.5 GHS05-GHS07 H302-315-318
Sodium Metasilicate 6834-92-0 1.0-2.5 GHS05-GHS07 H302-314-335
GHS Symbols
GHS Statem ents
4. First-Aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-Fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam. Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted. Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Special Fire and Explosion Hazard (Combustible Dust): No Information
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of flammable aerosols. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep away from heat, sparks, flame and sources of ignition. Avoid excess heat.
Advice on Safe Handling of Combustible Dust: No Information
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Date Printed: 12/10/2019
8. Exposure Controls / Personal Protection
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Chem ical Name CAS-No.
n-Butane 106-97-8 5.0 N.E. 1000 ppm N.E. N.E. C9-C11 Alcohols Ethoxylated 68439-46-3 5.0 N.E. N.E. N.E. N.E. Sodium Metasilicate 6834-92-0 5.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STE L
OSHA PEL-TWA
OSHA PEL-
CEILING
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in
volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Engineering Measures for Com bustible Dust: No Information
9. Physical and Chemical Properties
Appearance: Odor: Specific Gravity: Freeze Point, °C: Solubility in Water: Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
Aerosolized Mist Mild
0.980 30 Miscible N.D.
-24 - 537 Does not Support Combustion Slower than Ether Heavier than Air
(See "Other information" Section for abbreviation legend)
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-
octanol/water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
Liquid N.E.
12.4 N.D.
N.D.
N.A. - N.A. 94 N.D. N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: No Information
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. High
vapor concentrations are irritating to the eyes, nose, throat and lungs. Harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
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EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e.g., narcosis involving a
loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
106-97-8 n-Butane N.E. N.E. 658 mg/L Rat 68439-46-3 C9-C11 Alcohols Ethoxylated 1400 mg/kg Rat N.E. N.E. 6834-92-0 Sodium Metasilicate 1153 mg/kg Rat N.E. N.E.
N.E. - Not Established
Chem ical Name Oral LD50 Dermal LD50 Vapor LC50
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12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Do not incinerate closed containers. This product as supplied is a USEPA defined ignitable hazardous
waste. Dispose of unusable product as a hazardous waste (D001) in accordance with local, state, and federal regulation.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name:
Hazard Class: N.A. 2.2 2.2 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Lim ited Quantity: Yes Yes Yes Yes
Aerosols non-flammable
in limited quantities
Aerosols
Aerosols non
flammable
Aerosols non-
flammable in limited
quantities
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Gas under pressure, Skin Corrosion or Irritation, Serious eye damage or eye irritation
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
No TSCA 12(b) components exist in this product.
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U.S. State Regulations:
California Proposition 65:
WARNING: No Prop. 65 warning is required.
16. Other Information
HMIS RATINGS
Health: 2 Flammability: 0 Physical Hazard: 1 Personal Protection: X
NFPA RATINGS
Health: 2 Flammability: 1 Instability 0
Volatile Organic Com pounds 5.00%
SDS REVISION DATE: 12/10/2019
REASON FOR REVISION: Substance and/or Product Properties Changed in Section(s):
01 - Identification
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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