Krud Kutter 352236 User Manual

Date Printed: 12/10/2019
Safety Data Sheet
www.rustoleum.com/krudkutterpro
1. Identification
Product Nam e: KK PRO 32OZ 6PK DRAIN OPENER Revision Date: 12/10/2019
Product Identifier: 352236 Supercedes Date: 12/10/2019
Recomm ended Use: Drain Clog Remover
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Supplier:
Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
24 Hour Hotline: 847-367-7700
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
3% of the mixture consists of ingredient(s) of unknown acute toxicity.
Manufacturer:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
GHS HAZARD STATEMENTS
Skin Corrosion, category 1B H314 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
GHS LABEL PRECAUTIONARY STATEMENTS
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
P310 If exposed immediately call a POISON CENTER or doctor/physician.
P321 For specific treatment see label
P405 Store locked up.
P501 Dispose of contents/container in accordance with local, regional and national regulations.
P272 Contaminated work clothing should not be allowed out of the workplace.
easy to do. Continue rinsing.
Date Printed: 12/10/2019
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
GHS SDS PRECAUTIONARY STATEMENTS
P363 Wash contaminated clothing before reuse.
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3. Composition / Information On Ingredients
HAZARDOUS SUBSTANCES
Chem ical Name CAS-No. Wt.%
Range
Sodium Hypochlorite 7681-52-9 2.5-10 GHS05 H314
Sodium Hydroxide 1310-73-2 2.5-10 GHS05-GHS07 H302-312-314
Lauramine Oxide 1643-20-5 0.1-1.0 Not Available Not Available
Lauric acid 143-07-7 0.1-1.0 GHS07 H317
GHS Symbols
GHS Statem ents
4. First-Aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, rinse mouth with water. If feeling unwell, get medical attention. If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.
5. Fire-Fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Keep containers tightly closed.
FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. If water is used, fog nozzles are preferred. Containers can rupture and release highly toxic material if exposed to heat. Substance is non­combustible but reacts with many metals to form explosive hydrogen gas. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Special Fire and Explosion Hazard (Combustible Dust): No Information
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: If spilled, contain spilled material and remove with inert
absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. Do not incinerate closed containersAvoid runoff into sewers and waterways. Provide ventilation and approach spill from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with sodium bicarbonate (NaHCO3). Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust.
Date Printed: 12/10/2019
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7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all SDS and label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Advice on Safe Handling of Combustible Dust: No Information
8. Exposure Controls / Personal Protection
Chem ical Name CAS-No.
Sodium Hypochlorite 7681-52-9 10.0 N.E. N.E. N.E. N.E. Sodium Hydroxide 1310-73-2 5.0 N.E. N.E. 2 mg/m3 N.E. Lauramine Oxide 1643-20-5 1.0 N.E. N.E. N.E. N.E. Lauric acid 143-07-7 1.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STE L
OSHA PEL-TWA
OSHA PEL-
CEILING
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection. Use impervious gloves to prevent skin contact and absorption of this material through the skin.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Engineering Measures for Com bustible Dust: No Information
9. Physical and Chemical Properties
Appearance: Odor: Specific Gravity: Freeze Point, °C: Solubility in Water: Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
Liquid Characteristic
1.102 N.D. Miscible N.D. 100 - 140 Does not Support Combustion Slower than Ether Heavier than Air
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-
octanol/water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
Liquid N.E. 13 N.D.
N.D.
N.A. - N.A. 93 N.D. N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with metals.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Product slowly corrodes copper,
aluminum, zinc, and galvanized surfaces.
HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes. Decomposition produces hydrogen chloride, chlorine and hydrogen gases.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
Date Printed: 12/10/2019
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11. Toxicological Information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, and may injure eye tissue if not removed promptly. Substance
causes severe eye irritation. Injury may be permanent.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Low hazard for usual industrial handling or commercial handling by trained personnel. Severely irritating; may cause permanent skin damage.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Harmful if inhaled. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Corrosive and may cause severe and permanent damage to mouth, throat and stomach.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated exposure to low concentrations of HCl vapor or mist may cause bleeding of nose and gums.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
7681-52-9 Sodium Hypochlorite 8910 mg/kg Rat >10000 mg/kg Rabbit >20 mg/L 1310-73-2 Sodium Hydroxide 325 mg/kg Rat 1350 mg/kg Rabbit N.E. 143-07-7 Lauric acid 12000 mg/kg Rat N.E. N.E.
N.E. - Not Established
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. RCRA
Hazardous Waste: This material, when discarded or disposed of, could be a hazardous waste according to federal regulations (40 CFR 261) due to the characteristic of corrosivity (D002). Check state and local regulations for disposal requirements. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this SDS incomplete, inaccurate, or otherwise inappropriate.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1760 1760 N.A.
Proper Shipping Name:
Hazard Class: N.A. 8 8 N.A.
Packing Group: N.A. II II N.A.
Lim ited Quantity: Yes Yes No Yes
Corrosive Liquids in
Limited Quantities
Corrosive Liquid N.O.S.
(Sodium hypochlorite,
Sodium hydroxide)
Corrosive Liquid
N.O.S. (Sodium
hypochlorite, Sodium
hydroxide)
Corrosive Liquids in
Limited Quantities
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Date Printed: 12/10/2019
Skin Corrosion or Irritation, Respiratory or Skin Sensitization
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
No TSCA 12(b) components exist in this product.
U.S. State Regulations:
California Proposition 65:
WARNING: No Prop. 65 warning is required.
16. Other Information
HMIS RATINGS
Health: 2* Flam mability: 1 Physical Hazard: 0 Personal Protection: X
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NFPA RATINGS
Health: 2 Flamm ability: 1 Instability 0
Volatile Organic Com pounds 0.00%
SDS REVISION DATE: 12/10/2019
REASON FOR REVISION: Substance and/or Product Properties Changed in Section(s):
01 - Identification
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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