Krud Kutter 302815 User Manual

Date Printed: 10/13/2017
Safety Data Sheet
www.rustoleum.com
1. Identification
Product Name: KK 16 OZ ULTRA POWER REMOVER Revision Date: 10/13/2017
Product Identifier: 302815 Supercedes Date: 10/7/2015
Product Use/Class: Adhesive Remover/ Solvent-Based
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Supplier:
Preparer: Regulatory Department
Emergency Telephone:
24 Hour Hotline: 847-367-7700
Manufacturer:
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
10% of the mixture consists of ingredient(s) of unknown acute toxicity.
GHS HAZARD STATEMENTS
Aspiration Hazard, category 1 H304 May be fatal if swallowed and enters airways.
Flammable liquid, category 4 H227 Combustible liquid
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.
GHS LABEL PRECAUTIONARY STATEMENTS
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Date Printed: 10/13/2017
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P321 For specific treatment see label
P331 Do NOT induce vomiting.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
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P370+P378 In case of fire: Use alcohol film forming foam, carbon dioxide, dry chemical, dry sand to
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local, regional and national regulations.
extinguish.
GHS SDS PRECAUTIONARY STATEMENTS
P363 Wash contaminated clothing before reuse.
3. Composition / Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Hydrotreated Light Distillate 64742-47-8 75-100 GHS08 H304
D-Limonene 5989-27-5 2.5-10 GHS02-GHS07 H226-315-317
GHS Symbols
GHS Statements
Dipropylene Glycol Monomethyl Ether 34590-94-8 2.5-10 Not Available Not Available
Dimethyl-2-Methyl Glutarate 14035-94-0 2.5-10 Not Available Not Available
4. First-Aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Do not induce vomiting. Give water or milk. Get immediate medical attention. Careful evacuation of stomach by medical personnel imperative. If swallowed, get medical attention.
Date Printed: 10/13/2017
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5. Fire-Fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Containers can rupture and release highly toxic material if exposed to heat. Use water
spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Ventilate area, isolate spilled material, and remove with inert
absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid prolonged or repeated contact with skin. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use.
8. Exposure Controls / Personal Protection
Chemical Name CAS-No.
Hydrotreated Light Distillate 64742-47-8 90.0 N.E. N.E. N.E. N.E. D-Limonene 5989-27-5 5.0 N.E. N.E. N.E. N.E. Dipropylene Glycol Monomethyl Ether Dimethyl-2-Methyl Glutarate 14035-94-0 5.0 N.E. N.E. N.E. N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
34590-94-8 5.0 100 ppm 150 ppm 100 ppm N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
Date Printed: 10/13/2017
9. Physical and Chemical Properties
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Appearance: Odor: Relative Density: Freeze Point, °C: Solubility in Water: Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid Citrus Like
0.829 N.D. Negligible N.D. 176 - 249 Supports Combustion Slower than Ether Heavier than Air
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
Liquid N.E. N.A. N.D.
N.D.
0.7 - 14.0 78 N.D. N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: No Information
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Can cause severe eye irritation. Substance causes severe eye irritation. Injury
may be permanent. Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Contact causes skin irritation. May cause allergic skin reaction. Causes skin irritation. Allergic reactions are possible. May cause skin sensitization, an allergic reaction, which becomes evident upon re­exposure to this material. Prolonged or repeated contact may cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation. Causes nose and throat irritation. Breathing small amounts during normal handling is not likely to cause harmful effects; breathing large amounts may be harmful. Symptoms of overexposure include nose, throat and respiratory tract irritation. Pre-existing lung disorders, e.g. asthma-like conditions, may be aggravated by exposure to this material.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Contains d-Limonene, which is an IARC Group 3 agent: "probably not
carcinogenic to humans". D-Limonene is NOT classified as a carcinogen by OSHA, NTP nor ACGIH. Prolonged or repeated skin contact may cause dermatitis.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
64742-47-8 Hydrotreated Light Distillate >5000 mg/kg Rat >2000 mg/kg Rabbit >5000 mg/L Rat 5989-27-5 D-Limonene 5200 mg/kg, 4400 mg/
kg Rat
34590-94-8 Dipropylene Glycol Monomethyl Ether N.I. 9500 mg/kg Rabbit N.I.
N.I. - No Information
>5000 mg/kg Rabbit N.I.
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: No Information
Date Printed: 10/13/2017
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14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
No Information
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:
Chemical Name
Dimethyl-2-Methyl Glutarate 14035-94-0
No TSCA 12(b) components exist in this product.
CAS-No.
Date Printed: 10/13/2017
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
NFPA RATINGS
Health: 2 Flammability: 2 Instability 0
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VOLATILE ORGANIC COMPOUNDS, g/L:
SDS REVISION DATE: 10/13/2017
REASON FOR REVISION: Product Composition Changed
Substance and/or Product Properties Changed in Section(s): 02 - Hazard Identification 05 - Fire-fighting Measures 09 - Physical & Chemical Properties 15 - Regulatory Information 16 - Other Information Statement(s) Changed
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The manufacturer believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. The manufacturer makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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