Krazy Glue KG58548R, KG517, KG583, KG925, KG945 User Manual

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Safety Data Sheet:
Material Name: Krazy Glue
All-Purpose Glue Series
SDS ID: SDS-79
Issue Date: 2015-07-12
Revision: .
Other Sections
01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16
Material Name
Krazy Glue All-Purpose Glue Series
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Synonyms
KG517, KG583, KG925, KG945, KG820, KG824, KG825, KG852, KG585, KG582, 10100, 10120, 10582, 10925
Chemical Family
Cyanoacrylate containing adhesive.
Restrictions on Use
None known.
Manufacturer Information
Elmer's Products, Inc 460 Polaris Parkway, Suite 500 Westerville, OH 43082 USA Phone:1-888-435-6377 Fax:1-800-741-6046 Email:comments@elmers.com
Emergency Phone Number: Poison Control Center 1-888-516-2502
For additional product information, access our website at www.elmers.com. To place an order, call 1-800-848-9400.
Section 2 - HAZARDS IDENTIFICATION
Classification in accordance with paragraph (d) of 29 CFR 1910.1200.
Flammable Liquids - Category
4
Serious Eye Damage/Eye Irritation - Category 2A Skin Sensitization - Category 1A Reproductive Toxicity - Category 2 Specific Target Organ Toxicity - Single Exposure - Category 3
GHS Label Elements
Symbol(s)
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Signal Word
Warning
Hazard Statement(s)
Combustible liquid Causes serious eye irritation May cause allergic skin reaction Suspected of damaging fertility or the unborn child May cause respiratory irritation
Precautionary Statement(s)
Prevention
Obtain special instructions before use Do not handle until all safety precautions have been read and understood Keep away from heat/sparks/open flame/hot surfaces - No smoking Use only outdoors or in a well-ventilated area Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapours/spray Wash thoroughly after handling Contaminated work clothing must not be allowed out of the workplace
Response
In case of fire: Use appropriate media to extinguish IF exposed or concerned: Get medical advice/attention IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor if you feel unwell IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention
r
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IF ON SKIN: Wash with plenty of soap and wate If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Specific treatment (see label)
Storage
Store in a well-ventilated place. Keep container tightly closed Keep cool Store locked up
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations
Other Hazards
No additional information is available.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
CAS Component Name Percent
7085-85-0 Ethyl cyanoacrylate >95
119-47-1
2,2'-Methylenebis(4-methyl-6-tert­butylphenol)
0.10
Section 4 - FIRST AID MEASURES
Description of Necessary Measures
IF exposed or concerned: Get medical advice/attention.
Inhalation
Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell.
Skin
Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Peel or roll the surfaces apart using a blunt edge, such as a spatula or spoon handle.
Eyes
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion
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Rinse mouth immediately and drink plenty of water. Do NOT induce vomiting. Immediately call a POISON CENTER.
Most Important Symptoms/Effects
Acute
May cause respiratory irritation, eye irritation. May cause allergic skin reaction.
Delayed
Suspected of damaging fertility or the unborn child.
Section 5 - FIRE FIGHTING MEASURES
Extinguishing Media
Suitable Extinguishing Media
Use carbon dioxide, regular dry chemical, regular foam or water.
Unsuitable Extinguishing Media
Do not use high-pressure water streams.
Special Hazards Arising from the Chemical
Combustible liquid
Hazardous Combustion Products
oxides of carbon
Special Protective Equipment and Precautions for Firefighters
Vapors may form explosive mixtures with air. Vapors can travel considerable distances to a source of ignition where they can ignite, flash back, or explode. Vapors are heavier than air. Prevent entry into waterways, sewers, basements, or confined areas. May explode when heated.
Fire Fighting Measures
Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. Move container from fire area if it can be done without risk. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with water spray until well after the fire is out. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible withdraw from area and let fire burn. Do not scatter spilled material with high-pressure water streams.
Section 6 - ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
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Wear personal protective clothing and equipment, see Section 8. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind and keep out of low areas. Ventilate closed spaces before entering.
Methods and Materials for Containment and Cleaning Up
Eliminate all sources of ignition. Do not touch or walk through spilled material. Stop leak if possible without personal risk. Prevent entry into waterways, sewers, basements, or confined areas. Reduce vapors with water spray. Absorb with earth, sand or other non-combustible material and transfer to container. Use non-sparking tools. Large spills: Dike for later disposal.
Environmental Precautions
Avoid release to the environment.
Section 7 - HANDLING AND STORAGE
Precautions for Safe Handling
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flame/hot surfaces - No smoking. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.
Conditions for Safe Storage, Including any Incompatibilities
Store in a well-ventilated place. Keep container tightly closed Keep cool Store locked up Avoid contact with water or moisture. Keep away from heat and ignition sources. Keep away from incompatible materials. Protect from sunlight.
Incompatible Materials
alcohols, amines, bases
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
Ethyl cyanoacrylate 7085-85-0
ACGIH: 0.2 ppm TWA
Biological limit value
There are no biological limit values for any of this product's components.
Engineering Controls
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Provide local exhaust ventilation system. Ensure adequate ventilation.
Individual Protection Measures, such as Personal Protective Equipment
Eye/face protection
Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Skin Protection
Wear appropriate chemical resistant clothing.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed. A NIOSH approved air-purifying respirator with an appropriate cartridge or canister may be appropriate under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance clear colorless liquid Physical State liquid
Odor irritating odor Color Not available
Odor Threshold Not available pH Not available
Melting Point Not available Boiling Point 62 °C
Freezing point -22 °C Evaporation Rate Not available
Boiling Point Range
Autoignition Not available Flash Point 83 °C
Lower Explosive Limit
Not available Flammability (solid, gas) Not available
Not available Decomposition Not available
Upper Explosive Limit
Vapor Density (air=1)
Water Solubility
Viscosity 40 cps @ 25 °C Solubility (Other) Not available
Density 1.05 g/cm3 VOC
Not available Vapor Pressure
>1
insoluble (causes rapid polymerization)
Specific Gravity (water=1)
Partition coefficient: n-octanol/water
0.13 mmHg (@ 20 ° C)
Not available
Not available
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0 g/L (SCAQMD Method 316B)
Section 10 - STABILITY AND REACTIVITY
Reactivity
May polymerize when heated. Avoid contact with water or moisture. Avoid contact with light.
Chemical Stability
Unstable at elevated temperatures.
Possibility of Hazardous Reactions
May polymerize. Avoid contact with water or moisture.
Conditions to Avoid
Avoid heat, flames, sparks and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers. Avoid contact with water or moisture.
Incompatible Materials
alcohols, amines, bases
Hazardous decomposition products
oxides of carbon
Section 11 - TOXICOLOGICAL INFORMATION
Information on Likely Routes of Exposure
Inhalation
May cause respiratory irritation.
Skin Contact
May cause allergic skin reaction.
Eye Contact
Causes eye irritation.
Ingestion
No information on significant adverse effects.
Acute and Chronic Toxicity
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Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following selected endpoints are published: Ethyl cyanoacrylate (7085-85-0) Oral LD50 Rat> 5 mL/kg 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) (119-47-1) Oral LD50 Rat> 10000 mg/kg Dermal LD50 Rabbit> 10000 mg/kg
Immediate Effects
May cause respiratory irritation, eye irritation. May cause allergic skin reaction.
Delayed Effects
Suspected of damaging fertility or the unborn child.
Irritation/Corrosivity Data
May cause respiratory irritation, eye irritation.
Respiratory Sensitization
No information available for the product.
Dermal Sensitization
May cause allergic skin reaction.
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Germ Cell Mutagenicity
No information available for the product.
Reproductive Toxicity
Suspected of damaging fertility or the unborn child.
Specific Target Organ Toxicity - Single Exposure
Respiratory system
Specific Target Organ Toxicity - Repeated Exposure
No target organs identified.
Aspiration hazard
No information available for the product.
Medical Conditions Aggravated by Exposure
No data available.
Section 12 - ECOLOGICAL INFORMATION
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Methods
Dispose in accordance with all applicable regulations.
Section 14 - TRANSPORT INFORMATION
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US DOT Information: UN/NA #: Not Regulated
IATA Information: UN#: Not Regulated
TDG Information: UN#: Not Regulated
Section 15 - REGULATORY INFORMATION
U.S. Federal Regulations
None of this products components are listed under SARA Sections 302/304 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan.
SARA Section 311/312 (40 CFR 370 Subparts B and C) Acute Health: Yes Chronic Health: Yes Fire: Yes Pressure: No Reactivity: No
U.S. State Regulations
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA
Ethyl cyanoacrylate 7085-85-0 No No No Yes No
Not listed under California Proposition 65
WHMIS Classification
B3, D2A, D2B
Component Analysis - Inventory
Ethyl cyanoacrylate (7085-85-0)
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US CA EU AU PH
Yes DSL EIN Yes Yes Yes No Yes No Yes Yes Yes
2,2'-Methylenebis(4-methyl-6-tert-butylphenol) (119-47-1)
US CA EU AU PH
Yes DSL EIN Yes Yes Yes No Yes No Yes Yes Yes
JP ­ENCS
JP ­ENCS
JP ­ISHL
JP ­ISHL
KR ­KECI/KECL
KR ­KECI/KECL
KR ­TCCA
KR ­TCCA
CN NZ MX
CN NZ MX
Section 16 - OTHER INFORMATION
NFPA Ratings
Health: 2 Fire: 2 Reactivity: 1 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Summary of Changes
New SDS: 3/17/2015
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS ­Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CLP - Classification, Labelling, and Packaging; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD - Dangerous Substance Directive; DSL - Domestic Substances List; EEC ­European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC ­International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO
- International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow ­Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of LIsts™ - ChemADVISOR’s Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA ­Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL ­Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States.
Other Information
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Disclaimer:
Supplier gives no warranty whatsoever, including the warranties of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser shall determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights.
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