Reviewed 08/01/2018
Reviewed 08/01/2018
Page 1/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
*
1 Identification
·
Product identifier
·
Trade name: Kool Mist Formula 77
·
Relevant identified uses of the substance or mixture and uses advised against:
·
Product description
·
Details of the supplier of the safety data sheet:
·
Manufacturer/Supplier:
Kool Mist
9218 Norwalk Blvd.
Santa Fe Springs, CA 90670
Ph: (562) 246-0949
·
Emergency telephone number:
2 Hazard(s) identification
Heavy duty coolant for spray mist systems.
Chemtrec 1-800-424-9300 or outside USA 1-703-527-3887
·
Classification of the substance or mixture:
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2B H320 Causes eye irritation.
·
Label elements:
·
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
·
Hazard pictograms:
GHS07
·
Signal word:
·
Hazard-determining components of labeling:
Warning
Poly(ethylene glycol-ran-propylene glycol) monobutyl ether
·
Hazard statements:
Harmful if swallowed.
Causes skin and eye irritation.
·
Precautionary statements:
Wear protective gloves.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If swallowed: Call a poison center/doctor if you feel unwell.
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Rinse mouth.
If on skin: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
(Contd. on page 2)
41.1.7
Page 2/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
Trade name: Kool Mist Formula 77
Dispose of contents/container in accordance with local/regional/national/international regulations.
·
Classification system:
·
NFPA ratings (scale 0 - 4)
Health = 1
100
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
Fire = 0
Reactivity = 0
1
Health = 1
0
Fire = 0
Reactivity = 0
0
·
Hazard(s) not otherwise classified (HNOC):
*
3 Composition/information on ingredients
·
Chemical characterization: Mixtures
·
Description:
·
Dangerous Components:
Mixture of substances listed below with nonhazardous additions.
None known
102-71-6 Triethanolamine, TEA
Skin Irrit. 2, H315; Eye Irrit. 2B, H320
9038-95-3 Poly(ethylene glycol-ran-propylene glycol) monobutyl ether
Acute Tox. 2, H300
·
Additional information:
Concentration of Dangerous Components when diluted:
Triethanolamine, TEA : <1%
Poly(ethylene glycol-ran-propylene glycol) monobutyl ether: <0.1
4 First-aid measures
·
Description of first aid measures:
·
General information:
Symptoms of poisoning may occur after several hours; therefore medical observation is advised for at least 48
hours after the accident.
·
After inhalation:
·
After skin contact:
Immediately wash with water and soap and rinse thoroughly.
If skin irritation occurs, consult a doctor.
·
After eye contact:
Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
·
Information for doctor:
·
Most important symptoms and effects, both acute and delayed:
·
Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
In case of unconsciousness place patient stably in side position for transportation.
Immediately call a doctor.
No further relevant information available.
20-40%
1-5%
5 Fire-fighting measures
·
Extinguishing media:
·
Suitable extinguishing agents:
·
Special hazards arising from the substance or mixture:
41.1.7
Use fire fighting measures that suit the environment.
No further relevant information available.
(Contd. on page 3)
Page 3/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
Trade name: Kool Mist Formula 77
·
Advice for firefighters:
·
Protective equipment:
As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear to prevent contact with skin and eyes.
6 Accidental release measures
·
Personal precautions, protective equipment and emergency procedures:
·
Environmental precautions:
·
Methods and material for containment and cleaning up:
Do not allow to enter sewers/ surface or ground water.
Not required.
Absorb with liquid-binding material (i.e. sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
Dispose of the collected material according to regulations.
·
Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
*
7 Handling and storage
·
Handling
·
Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
·
Information about protection against explosions and fires:
·
Conditions for safe storage, including any incompatibilities:
·
Storage
·
Requirements to be met by storerooms and receptacles:
·
Information about storage in one common storage facility:
·
Further information about storage conditions:
·
Specific end use(s):
No further relevant information available.
Keep receptacle tightly sealed.
No special measures required.
Store only in the original receptacle.
Not required.
8 Exposure controls/personal protection
·
Additional information about design of technical systems:
·
Control parameters:
·
Components with occupational exposure limits:
No further data; see section 7.
102-71-6 Triethanolamine, TEA
TLV Long-term value: 5 mg/m³
·
Additional information:
·
Exposure controls:
·
Personal protective equipment:
·
General protective and hygienic measures:
The lists that were valid during the creation of this SDS were used as basis.
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing and wash before reuse.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
·
Breathing equipment:
41.1.7
Not required.
(Contd. on page 4)
Page 4/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
Trade name: Kool Mist Formula 77
·
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Select glove material based on penetration times, rates of diffusion and degradation.
·
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the
application.
·
Penetration time of glove material:
The exact break-through time has to be determined and observed by the manufacturer of the protective
gloves.
·
Eye protection:
Tightly sealed goggles
*
9 Physical and chemical properties
·
Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Color:
·
Odor:
·
Odor threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Ignition temperature:
·
Decomposition temperature:
·
Auto igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapor pressure @ 20 °C (68 °F):
Liquid
Green
Vinegar
Not determined.
Acidic
Not determined.
100 °C (212 °F)
180 °C (356 °F)
Not applicable.
305 °C (581 °F)
Not determined.
Product is not self-igniting.
Product does not present an explosion hazard.
0.0 Vol %
0.0 Vol %
23 hPa (17 mm Hg)
(Contd. on page 5)
41.1.7
Page 5/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
Trade name: Kool Mist Formula 77
·
Density:
Relative density:
Vapor density:
Evaporation rate:
·
Solubility in / Miscibility with:
Water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
Solvent content:
Organic solvents:
Water:
VOC content:
·
Other information:
Not determined.
Not determined.
Not determined.
Not miscible or difficult to mix.
Not determined.
Not determined.
Not determined.
20.0 %
20.0 %
0 %
No further relevant information available.
10 Stability and reactivity
·
Reactivity:
·
Chemical stability:
·
Thermal decomposition / conditions to be avoided:
·
Possibility of hazardous reactions:
·
Conditions to avoid:
·
Incompatible materials:
·
Hazardous decomposition products:
No further relevant information available.
Stable under normal conditions.
No decomposition if used according to specifications.
No dangerous reactions known.
No further relevant information available.
No further relevant information available.
No dangerous decomposition products known.
11 Toxicological information
·
Information on toxicological effects:
·
Acute toxicity:
·
LD/LC50 values that are relevant for classification:
102-71-6 Triethanolamine, TEA
Oral LD50 5530 mg/kg (rat)
2200 mg/kg (rabbit)
LD50 Oral 2200 ml/kg (Guinea Pig)
5846 ml/kg (mouse)
Dermal LD50 >22500 mg/kg (rabbit)
9038-95-3 Poly(ethylene glycol-ran-propylene glycol) monobutyl ether
Oral LD50 12.792 mg/kg (rat)
Dermal LD50 >20.800 mg/kg (rabbit)
·
Primary irritant effect:
·
On the skin:
·
On the eye:
Irritating effect.
Causes serious eye irritation.
·
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Irritant to skin and mucous membranes.
(Contd. on page 6)
41.1.7
Page 6/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
Trade name: Kool Mist Formula 77
Harmful
Irritant
·
Carcinogenic categories:
·
IARC (International Agency for Research on Cancer):
102-71-6 Triethanolamine, TEA 3
·
NTP (National Toxicology Program):
None of the ingredients are listed.
·
OSHA-Ca (Occupational Safety & Health Administration):
None of the ingredients are listed.
12 Ecological information
·
Toxicity:
·
Aquatic toxicity:
102-71-6 Triethanolamine, TEA
EC50 609.98 mg/l (daphnia)
·
Persistence and degradability:
·
Behavior in environmental systems:
·
Bioaccumulative potential:
·
Mobility in soil:
·
Additional ecological information:
·
General notes:
·
Results of PBT and vPvB assessment:
·
·
·
Not applicable.
PBT:
vPvB:
Not applicable.
Other adverse effects:
No further relevant information available.
Not known to be hazardous to water.
No further relevant information available.
No further relevant information available.
No further relevant information available.
13 Disposal considerations
·
Waste treatment methods:
·
Recommendation:
·
Uncleaned packagings:
·
Recommendation:
Recycle or dispose with household trash.
Disposal must be made according to official regulations.
14 Transport information
·
UN-Number:
·
DOT, ADR, ADN, IMDG, IATA
·
UN proper shipping name:
·
DOT, ADR, ADN, IMDG, IATA
·
Transport hazard class(es):
·
DOT, ADR, ADN, IMDG, IATA
·
Class:
·
Packing group:
·
DOT, ADR, IMDG, IATA
·
Environmental hazards:
·
Special precautions for user:
·
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code:
Non-Regulated Material
Non-Regulated Material
Non-Regulated Material
Non-Regulated Material
Not applicable.
Not applicable.
Not applicable.
(Contd. on page 7)
41.1.7
Page 7/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
Trade name: Kool Mist Formula 77
·
UN "Model Regulation":
Non-Regulated Material
15 Regulatory information
·
Safety, health and environmental regulations/legislation specific for the substance or mixture:
·
SARA (Superfund Amendments and Reauthorization):
·
Section 355 (extremely hazardous substances):
None of the ingredients are listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients are listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
California Proposition 65:
·
Chemicals known to cause cancer:
None of the ingredients are listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
·
Carcinogenic categories:
·
EPA (Environmental Protection Agency):
None of the ingredients are listed.
·
TLV (Threshold Limit Value established by ACGIH):
None of the ingredients are listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health):
None of the ingredients are listed.
·
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
·
Hazard pictograms:
GHS07
·
Signal word:
·
Hazard-determining components of labeling:
Warning
Poly(ethylene glycol-ran-propylene glycol) monobutyl ether
·
Hazard statements:
Harmful if swallowed.
Causes skin and eye irritation.
·
Precautionary statements:
Wear protective gloves.
Wash thoroughly after handling.
(Contd. on page 8)
41.1.7
Page 8/8
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 08/03/2015 Reviewed on 08/03/2015
Trade name: Kool Mist Formula 77
Do not eat, drink or smoke when using this product.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If swallowed: Call a poison center/doctor if you feel unwell.
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
Rinse mouth.
If on skin: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Dispose of contents/container in accordance with local/regional/national/international regulations.
·
National regulations:
The product is subject to be classified according with the latest version of the regulations on hazardous
substances.
·
State Right to Know:
102-71-6 Triethanolamine, TEA
Skin Irrit. 2, H315; Eye Irrit. 2B, H320
9038-95-3 Poly(ethylene glycol-ran-propylene glycol) monobutyl ether
Acute Tox. 2, H300
All ingredients are listed.
·
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
20-40%
1-5%
16 Other information
The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as
of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall not
establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of
this information and the suitability of the material or product for any particular purpose.
·
Date of preparation / last revision:
·
Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 2: Acute toxicity, Hazard Category 2
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2B: Serious eye damage/eye irritation, Hazard Category 2B
·
* Data compared to the previous version altered.
SDS created by MSDS Authoring Services www.msdsauthoring.com +1-877-204-9106
08/03/2015 / 4
41.1.7
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