Kidde 466112, 466204, 466227 User Manual

SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
1.
IDENTIFICATION
Product Name
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non­pressurized)
Other Names
Multi-Purpose, Ammonium Phosphate, Monoammonium Phosphate
Recommended use of the chemical and restrictions on use
Identified uses
Fire Extinguishing Agent
Restrictions on use
Consult applicable fire protection codes
Company Identification
Kidde Residential & Commercial
1016 Corporate Park Drive Mebane, NC 27302 USA
Customer Information Number
(919) 563-5911 (919) 304-8200
Emergency Telephone Number
CHEMTREC Number
(800) 424-9300 (703) 527-3887 (International)
Issue Date
December 10, 2019
Supersedes Date
May 31, 2019
Safety Data Sheet prepared in accordance with OSHA’s Hazard Communication Standard (29 CFR 1910.1200, the Canadian
Hazardous Products Regulations (HPR) and the Globally Harmonized System of Classification and Labelling of Chemicals (GHS)
2.
HAZARD IDENTIFICATION
This SDS covers the product listed above as sold in pressurized and non-pressurized containers. GHS classifications for both forms are listed below.
GHS Classification – Pressurized
Hazard Classification
Gas under pressure – Compressed gas
Label Elements
Hazard Symbols
Signal Word: Warning
Hazard Statements
Contents under pressure; may explode if heated.
Precautionary Statements
Prevention
None
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
2.
HAZARD IDENTIFICATION
Response
None
Storage
Protect from sunlight. Store in well-ventilated place.
Disposal
None
GHS Classification: Non - pressurized
Hazard Classification
This product is classified as not hazardous in accordance with the Globally Harmonized System of Classification and Labelling (GHS).
Label Elements
Hazard Symbols
None
Signal Word: None
Hazard Statements
None
Precautionary Statements
Prevention
None
Response
None
Storage
None
Disposal
None
Other Hazards
This product may contain small quantities of quartz (crystalline silica) as an impurity. Prolonged exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure limits may increase the risk of developing a disabling lung disease known as silicosis. IARC found limited evidence for pulmonary carcinogenicity of crystalline silica in humans.
Specific Concentration Limits
The values listed below represent the percentages of ingredients of unknown toxicity.
Acute oral toxicity
< 10%
Acute dermal toxicity
< 10%
Acute inhalation toxicity
< 10%
Acute aquatic toxicity
< 10%
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
3.
COMPOSITION/INFORMATION ON INGREDIENTS
This product is a mixture.
Component
CAS Number
Concentration*
Calcium Carbonate
471-34-1
10 – 30%
Mica
12001-26-2
0.5 – 1.5%
Kaolin Clay
1332-58-7
0.5 – 1.5%
Non-hazardous ingredients
Monoammonium Phosphate
7722-76-1
45 – 70%
Ammonium Sulfate
7783-20-2
10 – 30%
Note: Pressurized product uses nitrogen or compressed air as the expellant.
*Exact concentration withheld as trade secret.
4.
FIRST- AID MEASURES
Description of necessary first-aid measures
Eyes
Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention if soreness or redness persists.
Skin
Wash skin thoroughly with soap and water. Obtain medical attention if irritation persists.
Ingestion
Dilute by drinking large quantities of water and obtain medical attention.
Inhalation
Move victim to fresh air. Obtain medical attention immediately for any breathing difficulty.
Most important symptoms/effects, acute and delayed
Aside from the information found under Description of necessary first aid measures (above) and Indication of immediate medical attention and special treatment needed, no additional symptoms and effects are anticipated.
Indication of immediate medical attention and special treatment needed
Notes to Physicians
Treat symptomatically.
5.
FIRE - FIGHTING MEASURES
Suitable Extinguishing Media
This preparation is used as an extinguishing agent and therefore is not a problem when trying to control a fire. Use extinguishing agent appropriate to other materials involved. Keep pressurized containers and surroundings cool with water spray as they may rupture or burst in the heat of a fire.
Specific hazards arising from the chemical
Pressurized containers may explode in heat of fire.
Special Protective Actions for Fire-Fighters
Wear full protective clothing and self-contained breathing apparatus as appropriate for specific fire conditions.
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
6.
ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear appropriate protective clothing. Prevent skin and eye contact. Remove leaking container to a safe place. Ventilate the area.
Environmental Precautions
Prevent large quantities of the material from entering drains or watercourses.
Methods and materials for containment and cleaning up
Sweep up or vacuum and transfer into suitable containers for recovery or disposal.
7.
HANDLING AND STORAGE
Precautions for safe handling
Wear appropriate protective clothing. Prevent skin and eye contact.
Conditions for safe storage
Pressurized containers should be properly stored and secured to prevent falling or being knocked over. Do not drag, slide or roll pressurized containers. Do not drop pressurized containers or permit them to strike against each other. Never apply flame or localized heat directly to any part of the pressurized or plastic container. Store pressurized and plastic containers away from high heat sources. Storage area should be: - cool - dry - well ventilated - under cover - out of direct sunlight
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure limits are listed below, if they exist.
Calcium Carbonate
OSHA PEL: 15 mg/m3 TWA, total dust 5 mg/m3 TWA, respirable fraction
Mica
ACGIH TLV: 3 mg/m3 TWA, measured as respirable fraction of the aerosol. OSHA PEL: 20 mppcf, <1% crystalline silica
Kaolin
ACGIH TLV: 2 mg/m3 TWA, for particulate matter containing no asbestos and <1% Crystalline silica OSHA PEL: 15 mg/m3 TWA, total dust 5 mg/m3 TWA, respirable fraction
Particulates not otherwise classified /regulated
OSHA PEL: 50 mppcf or 15 mg/m3 TWA, total dust 15 mppcf or 5 mg/m3 TWA, respirable fraction
Appropriate engineering controls
Use with adequate ventilation. If this product is used in a pressurized system, there should be local procedures for the selection, training, inspection and maintenance of this equipment. When used in large volumes, use local exhaust ventilation.
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Individual protection measures
Respiratory Protection
Not normally required. Use dust mask where dustiness is prevalent, or TLV is exceeded. In oxygen deficient atmospheres, use a self contained breathing apparatus, as an air purifying respirator will not provide protection.
Skin Protection
Gloves
Eye/Face Protection
Chemical goggles or safety glasses with side shields.
Body Protection
Normal work wear.
9.
PHYSICAL AND CHEMICAL PROPERTIES
Non- Pressurized
Appearance
Physical State
Solid (powder)
Color
Pale Yellow
Odor
Odorless
Odor Threshold
No data available
pH
Not applicable
Specific Gravity
No data available
Boiling Range/Point (°C/F)
Not applicable
Melting Point (°C/F)
No data available
Flash Point (PMCC) (°C/F)
Not flammable
Vapor Pressure
No data available
Evaporation Rate (BuAc=1)
No data available
Solubility in Water
No data available
Vapor Density (Air = 1)
Not applicable
VOC (g/l)
None
VOC (%)
None
Partition coefficient (n­octanol/water)
No data available
Viscosity
No data available
Auto-ignition Temperature
No data available
Decomposition Temperature
No data available
Upper explosive limit
No data available
Lower explosive limit
No data available
Flammability (solid, gas)
No data available
Expellant - Nitrogen
Appearance
Physical State
Compressed gas
Color
Colorless
Odor
None
Odor Threshold
No data available
pH
Not applicable
Specific Gravity
0.075 lb/ft3 @70oF as vapor
Boiling Range/Point (°C/F)
-196oC/-321 oF
Melting Point (°C/F)
-210°C/-346°F
Flash Point (PMCC) (°C/F)
Not flammable
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
9.
PHYSICAL AND CHEMICAL PROPERTIES
Vapor Pressure
No data available
Evaporation Rate (BuAc=1)
Not applicable
Solubility in Water
0.02 g/L
Vapor Density (Air = 1)
0.97
VOC (g/l)
Not applicable
VOC (%)
Not applicable
Partition coefficient (n­octanol/water)
No data available
Viscosity
Not applicable
Auto-ignition Temperature
No data available
Decomposition Temperature
No data available
Upper explosive limit
Not explosive
Lower explosive limit
Not explosive
Flammability (solid, gas)
Not flammable
10.
STABILITY AND REACTIVITY
Reactivity
Pressurized containers may rupture or explode if exposed to heat.
Chemical Stability
Stable under normal conditions.
Possibility of hazardous reactions
Hazardous polymerization will not occur.
Conditions to Avoid
Exposure to direct sunlight - contact with incompatible materials
Incompatible Materials
Strong oxidizing agents - strong acids - sodium hypochlorite
Hazardous Decomposition Products
Oxides of carbon - ammonia - oxides of phosphorus - nitrogen oxides
11.
TOXICOLOGICAL INFORMATION
Acute Toxicity
Mica: Oral LD50 (Rat) >2000 mg/kg Kaolin (clay): Oral LD50 (Rat) >5000 mg/kg Dermal LD50 (Rabbit) >5000mg/kg Nitrogen Simple asphyxiant
Specific Target Organ Toxicity (STOT) – single exposure
Nitrogen: Exposure to nitrogen gas at high concentrations can cause suffocation by reducing oxygen available for breathing. Breathing very high concentrations can cause dizziness, shortness of breath, unconsciousness or asphyxiation.
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
11.
TOXICOLOGICAL INFORMATION
Specific Target Organ Toxicity (STOT) – repeat exposure
No relevant studies identified.
Serious Eye damage/Irritation
Mica: Not irritating (rabbit)
Skin Corrosion/Irritation
Mica: Not irritating (rabbit)
Respiratory or Skin Sensitization
No relevant studies identified.
Carcinogenicity
This product may contain small quantities of quartz (crystalline silica) as an impurity. Prolonged exposure to respirable crystalline silica dust at concentrations exceeding the occupational exposure limits may increase the risk of developing a disabling lung disease known as silicosis. IARC has classified Silica Dust, Crystalline, in the form of quartz or cristobalite as 1 (carcinogenic to humans).
Germ Cell Mutagenicity
No relevant studies identified.
Reproductive Toxicity
No relevant studies identified.
Aspiration Hazard
Not an aspiration hazard.
12.
ECOLOGICAL INFORMATION
Ecotoxicity
No relevant studies identified.
Mobility in soil
No relevant studies identified.
Persistence/Degradability
No relevant studies identified.
Bioaccumulative Potential
No relevant studies identified.
Other adverse effects
No relevant studies identified.
13.
DISPOSAL CONSIDERATIONS
Disposal Methods
Dispose of container in accordance with all applicable local and national regulations.
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
14.
TRANSPORT INFORMATION
Safety Data Sheet information is intended to address a specific material and not various forms or states of containment. Special Precautions for Shipping: Individuals must be certified as Hazardous Material Shipper for all transportation modes. Pressurized Fire Extinguishers are considered a hazardous material by the US Department of Transportation and Transport Canada.
DOT CFR 172.101 Data
Fire extinguishers, 2.2, UN1044
UN Proper Shipping Name
Fire extinguishers
UN Class
(2.2)
UN Number
UN1044
UN Packaging Group
Not applicable
Classification for AIR Transportation (IATA)
Consult current IATA Regulations prior to shipping by air.
Classification for Water Transport IMDG
Consult current IMDG Regulations prior to shipping by water.
When shipping via ground, portable fire extinguishers pressurized to less than 241 psi and of less than 1100 cubic inches in size meet the requirements of “Limited Quantity” as referenced in 49 CFR 173.309 (2010). There is no limited quantity designation for fire extinguishers when shipped by air or water.
This section is believed to be accurate at the time of preparation. It is not intended to be a complete statement or summary of the applicable laws, rules, or hazardous material regulations, and is subject to change. Users have the responsibility to confirm compliance with all laws, rules, and hazardous material regulations in effect at the time of shipping.
15.
REGULATORY INFORMATION
United States TSCA Inventory
This product contains ingredients that are listed on or exempt from listing on the EPA Toxic Substance Control Act Chemical Substance Inventory.
Canada DSL Inventory
All ingredients in this product are listed on the Domestic Substance List (DSL) or the Non-Domestic Substance List (NDSL) or are exempt from listing.
SARA Title III Sect. 311/312 Categorization: Pressurized
Gas under pressure
SARA Title III Sect. 311/312 Categorization: Non-pressurized
None
SARA Title III Sect. 313
This product does not contain any chemicals that are listed in Section 313 at or above de minimis concentrations.
SAFETY DATA SHEET
Commercial ABC Dry Chemical (Fire Extinguishing Agent, Pressurized and Non-pressurized)
16.
OTHER INFORMATION
NFPA Ratings
NFPA Code for Health - 1 NFPA Code for Flammability - 0 NFPA Code for Reactivity - 0 NFPA Code for Special Hazards - None
Legend
ACGIH: American Conference of Governmental Industrial Hygienists CAS#: Chemical Abstracts Service Number EC50: Effect Concentration 50% IARC: International Agency for Research on Cancer LC50: Lethal Concentration 50% LD50: Lethal Dose 50% N/A: Denotes no applicable information found or available OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit STEL: Short Term Exposure Limit TLV: Threshold Limit Value TSCA: Toxic Substance Control Act
Revision Date: December 10, 2019
Replaces: May 31, 2019
Changes made: Update to Sections 3 and 9.
Information Source and References
This SDS is prepared by Hazard Communication Specialists based on information provided by internal company references.
Prepared By:
EnviroNet LLC.
The information and recommendations presented in this SDS are based on sources believed to be accurate. Kidde Residential & Commercial assumes no liability for the accuracy or completeness of this information. It is the user's responsibility to determine the suitability of the material for their particular purposes. In particular, we make NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, with respect to such information, and we assume no liability resulting from its use. Users should ensure that any use or disposal of the material is in accordance with applicable Federal, State, and local laws and regulations.
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