KEMO LEITSILBER Datasheet

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

4.0

Print Date
Page Page 1 of 18

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING

Kemo L100

1.2 Relevant identified uses of the substance or mixture and uses advised against

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Use of the
Substance/Mixture

1.3 Details of the supplier of the safety data sheet

Company

Telephone : [phone]
Telefax : [phone]
E-mail address : [e-mail]
Responsible/issuing person

1.4 Emergency telephone number

In-Country Number :

Metallo-ceramic coating suited for firing, for the decoration of

:

glass and ceramics.

:

Kemo-Electronic GmbH
Leher Landstraße 20
D-27607 Geestland

+(44)-870-8200418

:CHEMTREC Global Number +(1)-703-527-3887(Call Collect)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Flammable liquids, Category 2

H225: Highly flammable liquid and vapour.

Specific target organ toxicity - single
exposure, Category 3. Central nervous
system

Acute aquatic toxicity, Category 1

Chronic aquatic toxicity, Category 1

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

H336: May cause drowsiness or dizziness.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting
effects.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

Hazard pictograms :

Signal word : Danger

4.0

Revision Date
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Hazard statements : H225

H336
H410

Highly flammable liquid and vapour.
May cause drowsin
Very toxic to aquatic life with long lasting
effects.

Precautionary statements :

Prevention:

P210

Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources

smoking.
P233 Keep container tightly closed.
P261

Avoid breathing dust/ fume/ gas/ mist/

vapours/ spray.
P273 Avoid release to the environment.

Response:

P303 + P361 + P353 IF ON SKIN (or hair): Take off

immediately all contaminated clothing.

Rinse skin with water/shower.
P370 + P378

In case of fire: Use dry sand, dry chemical

or alcohol-resistant foam to extinguish.

Hazardous components which must be listed on the label:
1-ethoxypropan-2-ol

acetone

ess or dizziness.

. No

ethyl acetate

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative
and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Chemical nature : precious metal

glycol ether/-acetate
natural polymer, modified
alcohol
aldehyde/ketone
carbonic acid/ester/anhydride

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

Hazardous components

Chemical Name Concentration (%)CAS-No.

silver >= 25 - < 50Aquatic Acute 1;

4.0

EG-No.
Registration number
7440-22-4
231-131-3
01-2119555669-21­0032

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Page Page 3 of 18

Classification
(VERORDNUNG
(EG) Nr. 1272/2008)

H400
Aquatic Chronic 1;
H410

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1-ethoxypropan-2-ol

/

acetone >= 3 - < 10Flam. Liq. 2; H225

67-64-1
200-662-2
01-2119471330-49-

Flam. Liq. 3; H226
STOT SE 3: H336

Eye Irrit. 2; H319
STOT SE 3; H336

xxxx

collodion wool,
dissolved

ethyl acetate >= 1 - < 3

/
141-78-6

205-500-4 /

Flam. Liq. 2; H225
Eye Irrit. 2; H319
STOT SE 3; H336

Substances with a workplace exposure limit :
ethanol Flam. Liq. 2; H22564-17-5

200-578-6 /

For explanation of abbreviations see section 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

General advice :

Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

>= 20 - < 2552125-53-8

< 10Flam. Liq. 2; H2259004-70-0

>= 10 - < 20

If inhaled :

In case of skin contact :

In case of eye contact :

Consult a physician after significant exposure.
If unconscious place in recovery position and seek medical
advice.

Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.

ush eyes with water as a precaution.

Fl
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

4.0

Revision Date
Print Date
Page Page 4 of 18

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10/19/2015

If swallowed :

Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : None known.
Risks : May cause drowsiness or dizziness.

4.3 Indication of any immediate medical attention and speci

al treatment needed

Treatment : The first aid procedure should be established in consultation

with the doctor responsible for industrial medicine.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media :

Unsuitable extinguishing
media

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

: High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during
firefighting

: Do not allow run-off from fire fighting to enter drains or water

courses.

Hazardous combustion

: No hazardous combustion products are known

products

5.3 Advice for firefighters

Special protective equipment

: In the event of fire, wear self-contained breathing apparatus.

for firefighters

Further information : Use water spray to cool unopened containers.

Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residue

s and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation.

6.2 Environmental precautions

Environmental precautions : Prevent product from entering drains.

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Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

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5

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Contain spillage, and then collect with non-combustible

absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place

in container for disposal according to
local / national regulations (see section 13).
Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For personal protection see section 8.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling :: Avoid formation of aerosol.

Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Container may be opened only under exhaust ventilation
hood
Dispose of rinse water in
regulations.
Avoid release to the environment

accordance with local and national

Advice on protection against
fire and explosion

Avoid formation of aerosol. Keep away from sources of
ignition - No smoking. Take measures to prevent the build up
of electrostatic charge.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

4.0

Revision Date
Print Date
Page Page 6 of 18

10/15/2015
10/19/2015

Hygiene measures :

Handle in accordance with good industrial hygiene and safety
practice. Wash hands before breaks and at the end of
workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage
areas and containers

: No smoking. Store in cool place. Keep in a well-ventilated

place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage. Observe label
precautions. Electrical installations / working materials must
comply with the technological safety standards.

Other data : No decomposition if stored and applied as directed.

7.3 Specific end use(s)

Specific use(s) :

Consult the technical guidelines for the use of this
substance/mixture.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure Limits

Components Value type

(Form of
exposure)

silver TWA 0,1 mg/m3 2000/39/EC7440-22-4

IndicativeFurther

information

VLE-MP 0,1 mg/m3 PT OEL

Further
information

Included by specific national legislation or by not transposed communitary
legilation, agyria

TWA 0.01 mg/m3

ethanol 64-17-5 VLE-MP 1,000 ppm PT OEL

Further
information

Substances that are not classified as carcinogenic for humans, irritation of the
upper respiratory tract, eye irritation, damage of central nervous system

Control
parameters

(Silver)

ExpressedasBasisCAS-No.

Silver PT DL

305/2007

acetone TWA 500 ppm

1,210 mg/m3

Further

Indicative

information

VLE-MP 500 ppm PT OEL

Further
information

Included by specific national legislation or by not transposed communitary
legilation, substances that are not classified as carcinogenic for humans,
identification of substances for which bioligical exposure values are available.

2000/39/EC67-64-1