KEMO LEITSILBER Datasheet

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

4.0

Print Date
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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING

Kemo L100

1.2 Relevant identified uses of the substance or mixture and uses advised against

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Use of the
Substance/Mixture

1.3 Details of the supplier of the safety data sheet

Company

Telephone : [phone]
Telefax : [phone]
E-mail address : [e-mail]
Responsible/issuing person

1.4 Emergency telephone number

In-Country Number :

Metallo-ceramic coating suited for firing, for the decoration of

:

glass and ceramics.

:

Kemo-Electronic GmbH
Leher Landstraße 20
D-27607 Geestland

+(44)-870-8200418

:CHEMTREC Global Number +(1)-703-527-3887(Call Collect)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Flammable liquids, Category 2

H225: Highly flammable liquid and vapour.

Specific target organ toxicity - single
exposure, Category 3. Central nervous
system

Acute aquatic toxicity, Category 1

Chronic aquatic toxicity, Category 1

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

H336: May cause drowsiness or dizziness.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting
effects.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

Hazard pictograms :

Signal word : Danger

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Hazard statements : H225

H336
H410

Highly flammable liquid and vapour.
May cause drowsin
Very toxic to aquatic life with long lasting
effects.

Precautionary statements :

Prevention:

P210

Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources

smoking.
P233 Keep container tightly closed.
P261

Avoid breathing dust/ fume/ gas/ mist/

vapours/ spray.
P273 Avoid release to the environment.

Response:

P303 + P361 + P353 IF ON SKIN (or hair): Take off

immediately all contaminated clothing.

Rinse skin with water/shower.
P370 + P378

In case of fire: Use dry sand, dry chemical

or alcohol-resistant foam to extinguish.

Hazardous components which must be listed on the label:
1-ethoxypropan-2-ol

acetone

ess or dizziness.

. No

ethyl acetate

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative
and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Chemical nature : precious metal

glycol ether/-acetate
natural polymer, modified
alcohol
aldehyde/ketone
carbonic acid/ester/anhydride

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

Hazardous components

Chemical Name Concentration (%)CAS-No.

silver >= 25 - < 50Aquatic Acute 1;

4.0

EG-No.
Registration number
7440-22-4
231-131-3
01-2119555669-21­0032

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Classification
(VERORDNUNG
(EG) Nr. 1272/2008)

H400
Aquatic Chronic 1;
H410

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1-ethoxypropan-2-ol

/

acetone >= 3 - < 10Flam. Liq. 2; H225

67-64-1
200-662-2
01-2119471330-49-

Flam. Liq. 3; H226
STOT SE 3: H336

Eye Irrit. 2; H319
STOT SE 3; H336

xxxx

collodion wool,
dissolved

ethyl acetate >= 1 - < 3

/
141-78-6

205-500-4 /

Flam. Liq. 2; H225
Eye Irrit. 2; H319
STOT SE 3; H336

Substances with a workplace exposure limit :
ethanol Flam. Liq. 2; H22564-17-5

200-578-6 /

For explanation of abbreviations see section 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

General advice :

Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

>= 20 - < 2552125-53-8

< 10Flam. Liq. 2; H2259004-70-0

>= 10 - < 20

If inhaled :

In case of skin contact :

In case of eye contact :

Consult a physician after significant exposure.
If unconscious place in recovery position and seek medical
advice.

Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.

ush eyes with water as a precaution.

Fl
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

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If swallowed :

Clean mouth with water and drink afterwards plenty of water.
Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : None known.
Risks : May cause drowsiness or dizziness.

4.3 Indication of any immediate medical attention and speci

al treatment needed

Treatment : The first aid procedure should be established in consultation

with the doctor responsible for industrial medicine.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media :

Unsuitable extinguishing
media

Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

: High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during
firefighting

: Do not allow run-off from fire fighting to enter drains or water

courses.

Hazardous combustion

: No hazardous combustion products are known

products

5.3 Advice for firefighters

Special protective equipment

: In the event of fire, wear self-contained breathing apparatus.

for firefighters

Further information : Use water spray to cool unopened containers.

Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residue

s and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation.

6.2 Environmental precautions

Environmental precautions : Prevent product from entering drains.

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Remove all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

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5

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Contain spillage, and then collect with non-combustible

absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place

in container for disposal according to
local / national regulations (see section 13).
Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

For personal protection see section 8.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling :: Avoid formation of aerosol.

Do not breathe vapours/dust.
Avoid exposure - obtain special instructions before use.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Container may be opened only under exhaust ventilation
hood
Dispose of rinse water in
regulations.
Avoid release to the environment

accordance with local and national

Advice on protection against
fire and explosion

Avoid formation of aerosol. Keep away from sources of
ignition - No smoking. Take measures to prevent the build up
of electrostatic charge.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

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Hygiene measures :

Handle in accordance with good industrial hygiene and safety
practice. Wash hands before breaks and at the end of
workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage
areas and containers

: No smoking. Store in cool place. Keep in a well-ventilated

place. Containers which are opened must be carefully
resealed and kept upright to prevent leakage. Observe label
precautions. Electrical installations / working materials must
comply with the technological safety standards.

Other data : No decomposition if stored and applied as directed.

7.3 Specific end use(s)

Specific use(s) :

Consult the technical guidelines for the use of this
substance/mixture.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

Occupational Exposure Limits

Components Value type

(Form of
exposure)

silver TWA 0,1 mg/m3 2000/39/EC7440-22-4

IndicativeFurther

information

VLE-MP 0,1 mg/m3 PT OEL

Further
information

Included by specific national legislation or by not transposed communitary
legilation, agyria

TWA 0.01 mg/m3

ethanol 64-17-5 VLE-MP 1,000 ppm PT OEL

Further
information

Substances that are not classified as carcinogenic for humans, irritation of the
upper respiratory tract, eye irritation, damage of central nervous system

Control
parameters

(Silver)

ExpressedasBasisCAS-No.

Silver PT DL

305/2007

acetone TWA 500 ppm

1,210 mg/m3

Further

Indicative

information

VLE-MP 500 ppm PT OEL

Further
information

Included by specific national legislation or by not transposed communitary
legilation, substances that are not classified as carcinogenic for humans,
identification of substances for which bioligical exposure values are available.

2000/39/EC67-64-1

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

Further
information

4.0

There are two types: IBE A refers to acetylcholinesterase inhibitors pesticides
and IBE M to metahaemoglobine inductors, hematologic effects, irritation of the
upper respiratory tract, impairment of central nervous system, eye irritation

VLE_CD

Included by specific national legislation or by not transposed communitary
legilation, substances that are not classified as carcinogenic for humans,
Identification of substances for which biological exposure values are available.
There are two types: IBE A refers to acetylcholinesterase inhibitors pesticides
upper respiratory tract, impairment of central nervous system, eye irritation

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750 ppm

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PT OEL

ethyl acetate VLE-MP 400 ppm PT OEL141-78-6

Further
information

irritation of the upper respiratory tract, eye irritation

8.2 Exposure controls

Engineering measures

No data available

Personal protective equipment

Eye protection

Hand protection
Remarks

TWA

Eye wash bottle with pure water

:

500 ppm

1.210 mg/m3

PT DL
305/2007

Tightly fitting safety goggles

Solvent-resistant gloves. The selected protective gloves have

:

to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it. Before removing gloves
clean them with soap and water. The suitability for a specific
workplace should be discussed with the producers of the
protective gloves.

Skin and body protection :

impervious clothing
Choose body protection according to the amount and

gerous substance at the work place.

Respiratory protection :

concentration of the dan

In the case of vapour formation use a respirator with an
approved filter.

Environmental exposure controls

General advice : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Appearance : paste

Colour : silver

Odour : characteristic

Odour Threshold : No data available

pH : No data available

Melting point/range : No data available

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Boiling point/boiling range : No data available

Flash point :

12 °C
Method:DIN 51755 Part 1

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Burning rate : No data available

Auto-ignition temperature

: No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure :

> 1,100 - 1,750 hPa (50 °C)

Relative vapour density No data available

Relative density ::No data available

Density :

1,44 g/cm3 (20 °C)

Bulk density : No data available

Solubility(ies)

Water solubility : soluble

Solubility in other solvents : No data available

Partition coefficient: n-

: No data available

octanol/water

Thermal decomposition : No data available

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

Viscosity

Viscosity, dynamic : No data availab

Viscosity, kinematic :

4.0

> 411 mm2/s (23 °C)

> 473 mm2/s (20 °C)

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le

Flow time :

61 s at 23 °C
Cross section: 6 mm
Method: ISO 2431
write protected

> 100 s at 23 °C
Cross section: 4 mm
Method: ISO 2431
write protected

>= 90 s at 20 °C
Cross section: 4 mm
Method: DIN 53211
write protected

>= 30 s at 23 °C
Cross section: 3 mm
Method: ISO 2431
write protected

Explosive properties : No data available

Oxidizing properties : No data available

9.2 Other information

Refractive index : No data available

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity

Stable under recommended storage conditions.
No decomposition if stored and applied as directed.

10.2 Chemical stability

No decomposition if stored and applied as directed.

10.3 Possibility of hazardous reactions

Hazardous reactions : No decomposition if stored and applied as directed.

Vapours may form explosive mixture with air.

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

10.4 Conditions to avoid

Conditions to avoid : Heat, flames and sparks.

10.5 Incompatible materials

Materials to avoid : No data available

10.6 Hazardous decomposition products

Hazardous decomposition
products

SECTION 11: TOXICOLOGICAL INFORMATION

4.0

: Stable under normal conditions.

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11.1 Information on toxicological effects

Acute toxicity

Not classified based on available information.

Product:

Acute oral toxicity : Remarks: No data available

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

Skin corrosion/irritation

Not classified based on available information.

Product:

Remarks: According to the classification criteria of the European Union, the product is not
considered as being a skin irritant.

Serious eye damage/eye irritation

Not classified based on available information.

Product:

Remarks: According to the classification criteria of the European Union, the product is not
considered as being an eye irritant.

Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available infor

mation.

Respiratory sensitisation: Not classified based on available information.

Product:

Remarks: No data available

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

V

ersion

Germ cell mutagenicity

Not classified based on available information.

Carcinogenicity

Not classified based on available information.

Reproductive toxicity

Not classified based on available information.

STOT - single exposure

May cause drowsiness or dizziness.

STOT - repeated exposure

Not classified based on available information.

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Aspiration toxicity

Not classified based on available information.

Further information

Product:

Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
Concentrations substantially above the TLV value may cause narcotic effects.
Solvents may degrease the skin.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity

Product:

Ecotoxicology Assessment
Acute aquatic toxicity

Chronic aquatic toxicity : No data available

Components:

acetone:

Toxicity to fish :

: No data available

LC50 (Fish): 4.74 mg/l
Exposure time: 96 h

Toxicity to daphnia and other
aquatic invertebrates

ethyl acetate:

Toxicity to fish :

Toxicity to daphnia and other
aquatic invertebrates

:

EC50 (Daphnia (water flea)): 10.294 mg/l
Exposure time: 48 h

LC50 (Fish): 220 mg/l
Exposure time: 96 h

:

EC50 (Daphnia (water flea)): 560 mg/l
Exposure time: 48 h

SAFETY DATA SHEET

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L100

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Toxicity to algae :

ethanol:

Toxicity to fish :

Toxicity to daphnia and other :
aquatic invertebrates

12.2 Persistence and degradability

Product:

Biodegradability :

Components:

1-ethoxypropan-2-ol:

Biodegradability :

acetone:

Biodegradability :

collodion wool, dissolved:

Biodegradability :

EC50 (algae): 3.300 mg/l
Exposure time: 48 h

LC50 (Fish): 12 mg/l
Exposure time: 96 h

LC50 (Daphnia (water flea)): 9.268 mg/l
Exposure time:48 h

Remarks: No data available

Remarks: No data available

Remarks: No data available

Remarks: No data available

ethyl acetate:

Biodegradability :

ethanol:

Biodegradability :

12.3 Bioaccumulative potential

Product:

Bioaccumulation :

Components:

1-ethoxypropan-2-ol:

Bioaccumulation :

acetone:

Bioaccumulation :

collodion wool, dissolved:

Bioaccumulation :

ethyl acetate:

Bioaccumulation :

ethanol:

Bioaccumulation :

Remarks: No data available

Remarks: No data available

Remarks: No data available

Remarks: No data available

Remarks: No data available

Remarks: No data available

Remarks: No data available

Remarks: No data available

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

12.4 Mobility in soil

Product:

Distribution among
environmental compartments

Components:

1-ethoxypropan-2-ol:

Distribution among
environmental compartments

acetone:

Distribution among
environmental compartments

4.0

Remarks: No data available

:

:

Remarks: No data available

Remarks: No data available

:

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collodion wool, dissolved:

Distribution among

:

Remarks: No data available

environmental compartments

ethyl acetate:

Distribution among

Remarks: No data available

:

environmental compartments

ethanol:

Distribution among

Remarks: No data available

:

environmental compartments

12.5 Results of PBT and vPvB assessment

Product:

Assessment :

This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of

0.1% or higher.

12.6 Other adverse effects

Product:

Additional ecological
information

:

Remarks: An environmental hazard cannot be excluded in the
event of unprofessional handling or disposal.
Very toxic to aquatic organisms, ma
effects in the aquatic environment.
Very toxic to aquatic life with long lasting effects.

y cause long-term adverse

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Version

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product :

4.0

The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Offer surplus and non-recyclable solutions to a licensed
disposal company.
Send to a licensed waste management company.

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Contaminated packaging :

Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the em

SECTION 14: TRANSPORT INFORMATION

14.1 UN number

ADN

ADR

RID

IMDG

IATA

14.2 UN proper shipping name

ADN

ADR

RID

IMDG

IATA

14.3 Transport hazard class(es)

: UN 1993

: UN 1993

: UN 1993

UN 1993

:

UN 1993

:

: FLAMMABLE LIQUID, N.O.S.

(ethanol, silver)

: FLAMMABLE LIQUID, N.O.S.

(ethanol, silver)

: FLAMMABLE LIQUID, N.O.S.

(ethanol, silver)

FLAMMABLE LIQUID, N.O.S.

:

(ethanol, silver)
Flammable liquid, n.o.s.

:

(ethanol, silver)

pty drum.

ADN

ADR

RID

IMDG

: 3

: 3

: 3

: 3

SAFETY DATA SHEET

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L100

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IATA

14.4 Packing group

ADN

Packing group : II
Classification Code

Hazard Identification Number
Labels : 3
Special Provisions

ADR

Packing group : II
Classification Code

Hazard Identification Number
Labels : 3
Tunnel restriction code
Special Provisions

RID

Packing group : II
Classification Code

Hazard Identification Number
Labels : 3
Special Provisions

: 3

: F1
: 33

Special Provision 640C

:

: F1
: 33

(D/E)

:

Special Provision 640C

:

: F1
: 33

Special Provision 640C

:

IMDG

Packing group
Labels : 3

EmS Code

IATA

Packing instruction (cargo
aircraft)
Packing instruction
(passenger aircraft)
Packing instruction (LQ) : Y341
Packing group

Labels : 3

14.5 Environmental hazards

ADN

Environmentally hazardous

ADR

Environmentally hazardous

II

:

F-E, S-E

:

: 364

: 353

II

:

yes

:

yes

:

SAFETY DATA SHEET

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L100

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RID

Environmentally hazardous

IMDG

Marine pollutant

14.6 Special precautions for user

Not applicable

4.0

yes

:

yes

:

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14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Ship type : N/A
Pollution category : N/A

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the su

International Chemical Weapons Convention (CWC)
Schedules of Toxic Chemicals and Precursors

REACH - Restrictions on the manufacture, placing on
the market and use of certain dangerous substances,
preparations and articles (Annex XVII)

Regulation (EC) No 649/2012 of the European
Parliament and the Council concerning the export and
import of dangerous chemicals

REACH - Candidate List of Substances of Very High
Concern for Authorisation (Article 59).

REACH - List of substances subject to authorisation
(Annex XIV)

: Neither banned nor restricted

: Neither banned nor restricted

: Neither banned nor restricted

: This product does not contain

substances of very high concern
(Regulation (EC) No
1907/2006 (REACH), Article 57).

: Neither banned nor restricted

bstance or mixture

Regulation (EC) No 1005/2009 on substances that

: Neither banned nor restricted

deplete the ozone layer

Regulation (EC) No 850/2004 on persistent organic

nts

polluta

: Neither banned nor restricted

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.

Quantity 1 Quantity 2

E1 ENVIRONMENTAL

100 t 200 t

HAZARDS

P5c FLAMMABLE LIQUIDS 5,000 t 50,000 t

SAFETY DATA SHEET

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L100

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34 2,500 t 25.000 t

Petroleum products: (a)
gasolines and naphthas,
(b) kerosenes (including jet
fuels), (c) gas oils
(including diesel fuels,
home heating oils and gas
oil blending streams)

The components of this product are reported in the following inventories:

REACH :

This mixture contains only ingredients which have been
subject to a pre-registration according to Regulation (EC) No.
1907/2006 (R

EACH).

CH INV : Not in compliance with the inventory

TSCA : On TSCA Inventory

DSL : All components of this product are on the Canadian DSL.

AICS : On the inventory, or in compliance with the inventory

NZIoC : On the inventory, or in compliance with the inventory

ENCS : Not in compliance with the inventory

ISHL : Not in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : Not in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA), CH INV
(Switzerland), MY INV (Malaysia), TR INV (Turkey), TW INV (Taiwan)

15.2 Chemical Safety Assessment

Not applicable

SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

L100

Revision Date

Version

SECTION 16: OTHER INFORMATION

Full text of H-Statements

H225 : Highly flammable liquid and vapour.
H226 : Flammable liquid and vapour.
H319 : Causes serious eye irritation.
H336 : May cause drowsiness or dizziness.
H400 : Very toxic to aquatic life.
H410 : Very toxic to aquatic life with long lasting effects.

Full text of other abbreviations

Aquatic Acute : Acute aquatic toxicity
Aquatic Chronic : Chronic aquatic toxicity
Eye Irrit. : Eye irritation
Flam. Liq. : Flammable liquids
STOT SE :

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Specific target organ toxicity - single exposure

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he information provided in this Safety Data Sheet is correct to the best of our knowledge,

T
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any

other

materials or in any process, unless specified in the text.