SAFETY DATA SHEET
CARBON DIOXIDE (CO2)
Buckeye Fire Equipment Company
Page 1 of 5
SECTION I. Chemical Product and Company Identi fication
Weight %*
CAS #
Carbon dioxide
Impurities
> 99.90%
< 0.2
124-38-9
N/A
Product Name: Carbon Dioxide
Synonym:
Distributor: Buckeye Fir e Equipment Company
CO
2,
Carbonic Anhydride
110 Kings Road
Kings Mountain, NC 28086
Telephone: 704-739-7415
Manufacturer: Praxair Inc.
39 Old Ridgebury Roa
anbury, CT 06810
D
d
Telephone: 1.800.645.4633
Web Address: www.buckeyefire.com
Email Address: bfec@buckeyef.com
Recommended Use: Fire Suppression.
Emergency: CHEMTREC 1.800.424.9300
Revision Date: 06/2018
ECTION II. Hazard Identification
S
WARNING!!! Liquefied gas under pressure.
Contains gas and liquids under pressure; may explode if heated.
Can cause rapid suffocation.
May cause dizziness and drowsiness.
Can increase respiration and heart rate.
May cause frostbite
.
OSHA Regulatory Status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).
H
azard Classification: Gases Under Pressure – Liquefied Gas
Precautionary Statements: Protect from sunlight. Store in a well-ventilated place.
CTION III. Composition/Information on I ngredients
SE
* % is rounded to the nearest appropriate number. Values are not to be considered product specifications
ECTION IV. First Aid Measures
S
NOTE: Rescuers should not attempt to retrieve a victim of exposure to this product without adequate personal protective
equipment. At a minimum, self-contained breathing apparatus should be worn.
R
emove victim to fresh air as quickly as possible. Trained personnel should administer supplemental oxygen and /or cardio-
pulmonary resuscitati on if necessa ry. Only trained perso nnel should a dminister supplemental oxygen.
SAFETY DATA SHEET
CARBON DIOXIDE (CO2)
Buckeye Fire Equipment Company
Page 2 of 5
n case of frostbite, place the frostbitte n p a rt in warm water. Do Not Use Hot Water. If warm water is not available or is
OSHA PEL
ACGIH TLV
Carbon Dioxide
5000 ppm
5000 ppm
I
impractical to use, wrap the affected part gently in a blanket. If fingers or hands are frostbitten, place the affected part in the
armpit. Have victim gently exercise the affected part while being warmed. Seek immediate medical attention. Take a copy of
this SDS to the attending physicia n or health professional. For more information see supplier website.
SECTION V. Fire fighting Measures
Extinguishing Media: This product is an extinguishing agent. It is nonflammable and noncombustible.
Special Firefighting Procedures: Structural firefighters must wear self-contained breathing apparatus and full protective
equipment. Move fire exposed cylinders if it can be done without risk to firefighters. Otherwise cool containers with hose
stream and protect personnel. Withdraw immediately in case of rising sounds from venting safety device or any discoloration
of tanks due to fire.
Unusual Fire and Explosi on H az ar ds : Containers of carbon dioxide, when involved in fire, may rupture or burst from the
heat of the fire.
Sensitivity to Mechanical Impact or Static Discharge: None
ECTION VI. Accidental Release Measures
S
In case of accidental release, use the appropriate respiratory and personal protection. Evacuate the area and allow the gas,
which is heavier than air, to dissipate. Monitor the surrounding area for carbon dioxide and oxygen levels. The levels of
carbon dioxide must be below those listed in Section II and the atmosphere must have at least 19.5% oxygen before
personnel are allowed back into the area.
SE
CTION VII. Handli ng and Storage
Avoid eye, respiratory, and skin exposure. Use the appropriate personal protective equipment when handling. Be aware of
any signs of dizziness, fatigue, or any exposure symptom described in Section II. Product should be stored in dry, wellventilated areas away from sources of heat. Store in its original container or extinguisher. Containers are under pressure and
present significant safety hazards. Store away from heavily trafficked areas and paths for ingress/egress. Protect containers
from possible damage and falling. Secure cylinders to prevent accidental knock over. Protect from sunlight. For more
information see supplier website.
SECTION VIII. Exposure Controls and Personal Protection
Exposure Guidelines:
U
se adequate ventilation to prevent unacceptable concentration levels noted in Section II.
Respiratory Protection: Use self-contained breathing apparatus
E
ye Protection: Wear chemic al goggles or full-face air-purifying respirator.
Skin Protection: Use low-temperature protective gloves and appropriate body protection.
ECTION IX. Physical and Chemical Properties
S
Appearance and Odor: Carbon dioxide is a colorless gas that is odorless at low concentrations. At high concentrations it will
have a sharp acidic odor.
Gas Density @ 21ºC and 1 atm: 0.1144 lb/ft³
Solubility: 0.90%
Flash Point: N/A
Flammability: N/A
Melting Point/Freezing Point at 1 atm: -78.5ºC
Boiling Point @ 1 atm: -78.5ºC
SAFETY DATA SHEET
CARBON DIOXIDE (CO2)
Buckeye Fire Equipment Company
Page 3 of 5
H: 3.7
Carbon Dioxide
Inhaled
Effects
1%
Breathing rate increases slightly.
2%
Breathing rate increases to 50% above normal level. Prolonged exposure can cause
headache, tiredness.
3%
Breathing increases to twice normal rate and becomes labored. Weak narcotic effect.
Impaired hearing, headache, increased blood pressure and pulse rate.
4-5%
Breathing increases to approximately four times normal rate, symptoms of intoxication
become evident, and slight choking may be felt.
5-10%
Characteristic sharp odor noticeable. Very labored breathing, visual impairment,
loss of consciousness.
10-100%
Unconsciousness occurs more rapidly about 10% level. Prolonged exposure to high
concentrati ons may eventually result in death from asphyxi ation.
p
Vapor Pressure at 20ºC: 838 psig
Vapor Density at 21.1 ºC: Liquid Density 762 kg/m³
Relative Density/Specific Gravity (H₂O = 1) at 21.1 ºC: 1.22
Relative Density/Specific Gravity (Air = 1) at 21.1 ºC and 1 atm: 1.52
Solubility in Water, % by wt: 0.90
SE
CTION X. Stability a nd Reactivity
Stability: Normally stable
Incompatibles: Will ignite and explode when heated with powered aluminum, beryllium, cerium alloy s, chromium,
magnesium-aluminum alloys, manganese, thorium, titanium, and zirconium. In the presence of moisture, will ignite with
cesium oxide. Metal acetylides will also ignite and explode on contact with carbon dioxide.
Decomposition Products: In an electrical discharge, yields carbon monoxide and oxygen. In the presence of moisture, carbon
dioxide will form carbonic acid.
Hazardous Polymerization: Will not occur, however carbon dioxide acts as to catalyze the polymerization of acryladehyde
and aziridine.
SECTION XI. Toxicological Information
Potential Health Effects:
Effects of a Single Acute Overexposure:
Inhalation: Carbon Dioxide gas is an asphyxiate with effects due to lack of oxygen. It is also physiologically active,
affectin g circulation and breathing. Moderate concentrations may cause headache, drowsiness, dizziness, stinging of the nose
and throat, excitation, rapid brea t hing and hear t rate, excess salivati on, vomiting, and unconsciousness. Lack of oxygen can
kill.
Carbon dioxide is an asphyxiant. It initially stimulates respiration and then causes respiratory depre ssion. High
concentrations result in narcos is. Symptoms in humans are as follows:
Concentration
headache, and ringing in ears. Judgement may be impaired, followed within minutes of
Skin Contact: No harm expected from vapor. Cold gas, or liquid or solid carbon dioxide may cause severe frostbite.
Swallowing: An unlikely route of exposure. This product is a gas a normal temperature and pressure.
E
ye Contact: No harm expected from vapor. Cold gas, or liquid or solid carbon dioxide may cause severe frostbite.
ffects of Repeated Overexposure: No harm expected.
E
Other Effects of Over Exposure: Damage to reti nal or ganglion cells and central nervous system may occur .
SAFETY DATA SHEET
CARBON DIOXIDE (CO2)
Buckeye Fire Equipment Company
Page 4 of 5
Medical Conditions Aggravated by Overexposure: The toxicology and the physical and chemical properties of carbon
Country
Agency
U.S.A.
TSCA
Canada
DSL
Europe
EINECS/ELINCS
Australia
AICS
Japan
MITI
South Korea
KECL
dioxide suggest that overexpo sure is unlikely to aggravate exisiting medic a l c onditions.
Acute Dose Effects: LC
= 90,000 ppm, 5 min, human
Lo
Reproductive Effects: A single study has shown an increase in heart defects in rats exposed to 6% carbon dioxide in air for 24
hours at different times during gestation. There is no evidence that carbon dioxide is tetragenic for humans.
Carcinogenicity: None
ECTION XII. Ecological Information
S
Ecotoxicity: Occurs naturally in the enviro nment.
Dissipation: Dissipates rap idly in well-ventilated areas.
A
ny adverse effect on animals would be related to overexposure and oxygen deficient environments. No adverse effect to
plant life except for frost caused by rapidly expanding gases.
SECTION XIII. Disposal Consideration
This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of according to state or local
laws, which may be more restrictive than federal regulations.
ECTION XIV. Transportation Information
S
This product is hazardous as defined by U.S. Department of Transportation 49 CFR 172, and dangerous goods as defined by
Transport Canada “Transportation of Dangerous Goods” regulations.
Proper Shipping Name: Carbon Dio xide
Hazard Class Number and Description: 2.2 (non-flammable gas)
UN Identification Number: UN1013
Packing Group: N/A
DOT Label Required: Non-Flammable Gas
S
ECTION XV. Regulatory Information
International Inventor y St at us : All ingredients are on the following inventories
U.S. Federal Regulatory Information:
This product is not subject to the SARA reporting requirements or has SARA Thresho l d Planning Quantities or
CERCLA Reportable Quantities.
State Regulatory Information:
Chemicals in this product are covered under the specific State regulations noted:
Alaska Designated Toxic and Hazardous Subs ta nc es- Carbon Dioxide
California Permissible Exposure Limits for Chemical Contaminants- Carbon Dioxide
Florida Substance list- Carbon Dioxide
SAFETY DATA SHEET
CARBON DIOXIDE (CO2)
Buckeye Fire Equipment Company
Page 5 of 5
Illinois Toxic Substance List- Carbon Dioxide
Kansas Section 302/303 List- No
Massachusetts Substance list- Carbon Dioxide
Minnesota List of Hazardous Substances- Carbon Dioxide
Missouri Employer Information/Toxic Substance List- Carbon Dioxide
New Jersey Right to Know Hazardous Substance List- Carbon Dioxide
North Dakota List of Hazardous Chemicals, Reportable Quantities- No
Pennsylvania Hazardous Substan ce List- Carbon Dioxide
Rhode Island Hazardous Substance List- Carbon Dioxide
Texas Hazardous Substance List- No
West Virginia Hazardous Substan ce List- Carbon Dioxide
Wisconsin Toxic and Hazardous Substances- Carbon Dioxide
California Prop os i tion 65- Carbon Dioxide is not listed on the California Proposition 65 List
SECTION XVI. Other Informatio n
HMIS RATINGS:
Health 1
Flammability 0
Reactivity 0
Personal Protective Equipment: Appropriate gloves and eye protection. (See Section 8)
WHMIS (Canadian Workplace Hazardous Materials Identification)
Class A: Compressed
The information contained herein is given in good faith as typical values and not as product specifications. No warranty,
either expressed or implied, is hereby made.
Loading...