Page 1
Roadware Incorporated
381 Bridgepoint Way
South Saint Paul MN 55075
10 Minute Concrete Mender – Part B (RES)
Version 2 10/30/2012 Page 1 of 7
Material Safety Data Sheet
1. Product and Company Identification
Product: Roadware 10 Minute Concrete Mender (Component B – RES or Polyol side)
Manufacturer’s Name
Roadware Incorporated
381 Bridgepoint Way
South Saint Paul, MN 55075
651-457-6122
24 HOUR EMERGENCY TELEPHONE NUMBER: CHEM-TEL 800-255-3924. USE ONLY IN THE EVENT OF
CHEMICAL EMERGENCIES INVOLVING A SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT INVOLVING ROADWARE
PRODUCTS.
WHMIS Classification: D2B; TDG Shipping Information: Non-regulated Materials US DOT CA-9501002; Non-regulated by
Road or Rail as per permit No. SU 4625, NON IATA Regulated.
2. Composition / Information on Ingredients
HAZARDOUS COMPONENTS
Components
CAS No.
OSHA TWA (final)
ACGIH Exposure
Limits:
Weight %
Polyether Polyol
Proprietary
None
None
20-40%
Aromatic hydrocarbon
64742-94-5
None
None
40-60%
Naphthalene
91-20-3
10 ppm
50mg/m3
10 ppm
15 ppm STEL
1 – 5%
3. Hazards Identification
Physical State
Liquid
Odor
Slightly Musty
SHA/HCS status
This material is classified as hazardous under OSHA Hazard Communications Standard
(20 CFR 1910.1200)
Emergency Overview
WARNING
This material, when combined with 10 Minute Concrete Mender Side A, will react within
the mixing process in seconds. Any exposure to individual components will be minimal
due to the polymer locking reaction between part A and part B. Material in pre-packaged
a cartridges is self-mixing and is applied directly to the repair area in a semi-reacted
state. Exposure under these conditions is generally below measurable amounts. When
pot-mixing these materials, adequate ventilation should be provided. Do not pot-mix in
enclosed areas. A slight odor is generated within the reaction process. This is caused
by a trace amount of naphthalene within the materials. Ventilate enclosed areas to
dissipate.
WARNING
Inhalation of high concentrations may irritate respiratory tract, dizziness, headache,
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Roadware Incorporated
381 Bridgepoint Way
South Saint Paul MN 55075
10 Minute Concrete Mender – Part B (RES)
Version 2 10/30/2012 Page 2 of 7
Eye Contact
Skin Contact
Inhalation
Ingestion
unconsciousness and other central nervous system effects.
Moderately irritating to the eyes.
Prolonged skin contact may defeat the skin and produce dermatitis. Repeated or
prolonged skin contact may cause allergic reactions with susceptible people.
Avoid breathing vapors or mists. May cause irritation of respiratory tract. Inhalation of
high vapor concentrations may cause symptoms such as headache, dizziness,
tiredness, nausea and vomiting. Prolonged exposure may cause liver and kidney
damage based on animal studies.
Harmful if swallowed. Aspiration hazard.
4. First Aid Measures
Eye Contact
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Consult a physician.
Skin Contact
After contact with skin, wash immediately with plenty of soap and water. Get medical
attention if irritation develops. Remove contaminated clothing. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Inhalation
If inhaled, remove to fresh air. If not breathing, give artificial respiration and get medical
attention immediately. If breathing is labored, oxygen should be administered by
qualified personnel. Consult a physician if necessary.
Ingestion
If victim is conscious, give water. Do not induce vomiting unless directed to do so by
medical personnel. Call a physician immediately. Never give anything by mouth to an
unconscious person.
Notes to Physician
Aspiration may cause pulmonary edema and pneumonitis. Dangerous amounts can be
absorbed through the skin.
Medical Condition aggravated
by exposure
Dermatitis and asthma.
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Roadware Incorporated
381 Bridgepoint Way
South Saint Paul MN 55075
10 Minute Concrete Mender – Part B (RES)
Version 2 10/30/2012 Page 3 of 7
5. Fire Fighting Measures
Flash point
145°F. Flashpoint Method: PMCC
Products of combustion
Extinguishing media
Suitable
Not Suitable
Use an extinguishing agent suitable for the surrounding fire. Dry chemical, CO2, water
spray or ‘alcohol foam’.
None known.
Special exposure hazards
Vapors are heavier than air and may spread along floors. Keep away from opem flames,
hot surfaces and sources of ignition. In a fire or if heated, a pressure increase will occur
and the container may burst.
No specific hazard.
Special protective equipment
for fire-fighters
Fire fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode. PVC
boots, gloves, safety helmet and protective clothing should be worn.
Special remarks on explosion
hazards
Water mist may be used to cool closed containers.
6. Accidental Release Measures
Personal protection
Use suitable protective equipment (see section 8). Ensure adequate ventilation.
Environmental precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up
Contain and adsorb large spillages onto an inert, non-flammable adsorbent carrier (such
as earth or sand). Shovel into open-top drums or suitable container for disposal.
7. Handling and Storage
Handling
Storage
Safe storage temperature
Keep container in a cool, well-ventilated area. Keep container tightly closed. Keep away
from heat and sources of ignition.
60 - 100° F
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Roadware Incorporated
381 Bridgepoint Way
South Saint Paul MN 55075
10 Minute Concrete Mender – Part B (RES)
Version 2 10/30/2012 Page 4 of 7
8. Exposure Controls / Personal Protection
Components
NTP:
IARC
OSHA – Select
Carcinogens
NIOSH – Selected
LD50s and LC50s
Aromatic hydrocarbons
This product does
not contain any
material shown to
be a carcinogen by
the National
Toxicology
Program (NTP).
This product does
not contain any
material shown to
be a carcinogen by
the International
Agency for
Research on
Cancer (IARC).
This product does
not contain any
material shown to
be a carcinogen by
OSHA.
2ml/kg Dermal
LD50 Rabbit
590mg/m3 Inhalation
LC50 Rat
Naphthalene
(PB2001-103699:
male rat – clear)
Monograph 82,
2002
Present
490mg/kg Oral
LD50 Rat
Preventive Measures
Conditions of use, adequacy of engineering or other control measures and actual
exposures will dictate the need for specific protective devices at your workplace.
Engineering Controls
Ensure adequate ventilation.
Personal Protection
Eyes
Chemical safety goggles. If there is a potential for splashing, use a full face shield.
Skin
The following protective materials are recommended: Gloves – neoprene, nitrile rubber,
butyl rubber. Thin latex disposable gloves should be avoided for repeated or long term
use. Protective clothing should be selected and used in accordance with ‘Guidelines for
the Selection of Chemical Protective Clothing’ published by ACGIH.
Respiratory
When the product is sprayed or used without adequate ventilation, an approved
MSHA/NIOSH positive pressure, supplied-air respirator may be required. Air purifying
respirators equipped with organic vapor cartridges and a HEPA (P100) particulate filter
may be used under certain conditions when a cartridge change-out schedule has been
developed in accordance with OSHA respiratory protection standard (29 CFR
1910.134).
Hands
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.
Other Protection
Consult your supervisor or S.O.P. for special handling instructions.
9. Physical and Chemical Properties
General Information
Appearance
Physical state
Liquid
Color
Black
Odor
Hydrocarbon like
Odor Threshold
Not available
Important health, safety and environmental information
pH
Not available
Boiling point
350°-380° F
Melting point
Not available
Flash point
145°F PMCC
Explosive properties
Non-explosive in the presence of the following materials or conditions: Open flames,
sparks and static discharge and shocks and mechanical impacts.
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Roadware Incorporated
381 Bridgepoint Way
South Saint Paul MN 55075
10 Minute Concrete Mender – Part B (RES)
Version 2 10/30/2012 Page 5 of 7
Vapor pressure
Not available
Relative density
0.95
Viscosity
5 – 15 cps
Vapor density
Not available
VOC content
Not Available
10. Stability and Reactivity
Stability and reactivity
Stable under recommended storage conditions.
Conditions of instability
Avoid high temperatures
Incompatibility with various
substances
Strong oxidizing agents, unintended isocyanates.
Hazardous polymerization
Polymerization may occur with incompatible reactants, especially strong oxidizers.
Hazardous decomposition
products
Combustion products may include: carbon oxides (CO, CO2). Thermal decomposition
can lead to the release of irritating gasses and vapors.
11. Toxicological Information
No toxicological information is available on the product.
12. Ecological Information
Persistence and degradability
No data available
Mobility
No data available
Bioaccumulation
No date available
Ecotoxicity effects
No data available
Aquatic toxicity
No data available
Naphthalene:
Ecotoxicity – Fish Species Data
1.24 mg/L LC50 pink salmon (fry) 96h Static
13. Disposal Considerations
Waste disposal
The generation of waste should be avoided or minimized wherever possible. Dispose of
surplus and non-recyclable products via a licensed waste disposal contractor. Disposal
of this product, solutions and any by-product should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers.
Contaminated Packaging
Do not reuse empty containers
Methods for cleaning up
Soak up with oil absorbent material. Shovel into suitable container for disposal.
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Roadware Incorporated
381 Bridgepoint Way
South Saint Paul MN 55075
10 Minute Concrete Mender – Part B (RES)
Version 2 10/30/2012 Page 6 of 7
14. Transport Information
Regulatory Information
UN Number
Proper Shipping Name
Class
PG*
Label
Additional information
DOT Classification
Not regulated
TDG Classification
Not regulated
IMDG Class
Not regulated
IATA-DGR Class
Not regulated
15. Regulatory Information
United States
OSHA HCS Classification
This material is considered to be hazardous.
U.S. Federal regulations
United States Inventory (TSCA 8b): All components are listed or exempted.
CERCLA: Hazardous Substances
Components
Concentration
Section 304 CERCLA
Hazardous Substance
CERCLA Reportable
Quantity
Product Reportable
Quantity
SARA (311, 312)hazard class
This product possesses the following SARA hazard categories:
Immediate Health (acute)
Delayed Health (Chronic)
Flammability
Pressure
Reactivity
Yes
Yes
Yes
No
No
SARA 313 Emission reporting
Listed
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State Regulations
Listed components are present:
Naphthalene 91-20-3
California Prop 65
MARTK
NJRTK
PARTK
Carcinogen, initial date 4/19/02
Present
Sn 1322
Environmental hazard
Canada
WHMIS (Canada)
Product classification data
Component classification data
Aromatic hydrocarbon
CAS 64742-94-5
Naphthalene
CAS 91-20-3
WHMIS Class D-2B: Material causing other toxic effects (Toxic).
WHMIS hazard class B3, D2B
1% (English item 1108. French item 1181)
WHMIS hazard class B4, D2B
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Roadware Incorporated
381 Bridgepoint Way
South Saint Paul MN 55075
10 Minute Concrete Mender – Part B (RES)
Version 2 10/30/2012 Page 7 of 7
CEPA (DSL)
Canada inventory: All components are listed or exempted.
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all the
information required by the CPR.
EC EINECS/ELINCS/NLP List
Compliance has not been determined
16. Other Information
Label requirements
Harmful by inhalation. Irritating to eyes and respiratory system. May cause sensitization by
inhalation and skin contact. This product is a respiratory irritant and potential respiratory
sensitizer. Repeated inhalation of vapor or aerosol at levels above the occupational
exposure limit could cause respiratory sensitization. A hyper-reactive response to even
minimal concentrations of diisocyanates may develop in sensitized persons. The onset of
the respiratory symptoms may be delayed for several hours after exposure.
Hazardous Material
Information System (USA)
2 Health
1 Flammability
0 Reactivity
Protective
Equipment
National Fire Protection
Association (USA)
While the information and recommendations in this publication are to the best of our knowledge, information and
belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS
OR OTHERWISE.
IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERIMINE THE APPLICABILITY OF SUCH
INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN
PARTICULAR PURPOSE.
THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS
ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.
Disclaimer:
The data set forth in this sheet is based on information provided by the suppliers of raw materials and chemicals used in
the manufacture of the aforementioned product. Roadware Incorporated makes no warranty with respect to the accuracy
of the information provided by their suppliers, and disclaims all liability of reliance thereof.
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