• IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion
• None
Fire
• In case of fire: Use CO2, dry chemical, or foam for extinction.
Spills and Leaks
• Collect spillage.
Storage
• Store locked up.
• Store in a well-ventilated place. Keep container tightly closed.
Disposal
• Dispose of contents/container to an approved waste disposal plant.
Hazard Not Otherwise Classified (HNOC)
Not applicable
Other information
Very toxic to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical NameCAS-NoWeight %Trade secret
n-Butyl acetate123-86-460-100*
Titanium dioxide13463-67-740-70*
Copper7440-50-810-30*
Aluminum7429-90-510-30*
Carbon black1333-86-47-13*
Isopropyl alcohol67-63-03 -7*
Silicon dioxide7631-86-93 -7*
Aluminum hydroxide21645-51-23 -7*
1,2,4 Trimethylbenzene95-63-61-5*
Zirconium oxide1314-23-40.1-1*
Quartz14808-60-7< 0.1*
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of necessary first-aid measures
General Advice
Eye Contact
Immediate medical attention is required. Show this safety data sheet to the doctor in
attendance. If symptoms persist, call a physician.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eye wide open while rinsing. If symptoms persist, call a physician.
Skin Contact
Inhalation
Ingestion
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. If skin irritation persists, call a physician.
Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician.
Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Drink plenty of water. Consult a physician if necessary
Methods and materials for containment and cleaning up
Methods for Containment
Methods for Cleaning Up
Evacuate personnel to safe areas. Use personal protective equipment. Ensure adequate
ventilation. Remove all sources of ignition. Stop leak if you can do it without risk.
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do
not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so.
Small spillage: Use a non-combustible material like vermiculite, sand or earth to soak up
the product and place into a container for later disposal. Large spillage: Pump or vacuum
transfer spilled product to clean containers for recovery. Absorb unrecoverable product.
7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Avoid contact with skin, eyes and clothing. Keep away from open flames, hot surfaces and
sources of ignition. Take precautionary measures against static discharges. Use only in an
area containing flame proof equipment. Ensure adequate ventilation. To avoid ignition of
vapors by static electricity discharge, all metal parts of the equipment must be grounded.
Empty containers pose a potential fire and explosion hazard. Do not cut, puncture or weld
containers.
Conditions for safe storage, including any incompatibilities
Keep away from open flames, hot surfaces and sources of ignition. Keep containers tightly
closed in a cool, well-ventilated place. Keep out of the reach of children. Keep container
closed when not in use. Keep away from incompatible materials.
TWA: 1 mg/m3 respirable fractionTWA: 15 mg/m3 total dust
7429-90-5
Carbon black
1333-86-4
Isopropyl alcohol
67-63-0
Silicon dioxide
7631-86-9
Aluminum hydroxide
TWA: 1 mg/m3 respirable fraction--
21645-51-2
1,2,4 Trimethylbenzene
95-63-6
Zirconium oxide
1314-23-4
Quartz
14808-60-7
Stoddard solvent
8052-41-3
Immediately Dangerous to Life or Health. ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold
Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH:
STEL: 200 ppm
TWA: 150 ppm
TWA: 150 ppm
TWA: 710 mg/m
(vacated) TWA: 150 ppm
(vacated) TWA: 710 mg/m
(vacated) STEL: 200 ppm
(vacated) STEL: 950 mg/m
TWA: 10 mg/m
3
TWA: 15 mg/m3 total dust
(vacated) TWA: 10 mg/m3 total
dust
TWA: 0.2 mg/m3 fumeTWA: 0.1 mg/m3 fume
TWA: 1 mg/m3 dust and mist
(vacated) TWA: 0.1 mg/m3 Cu
dust, fume, mist
TWA: 5 mg/m3 respirable fraction
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m
respirable fraction
TWA: 3.5 mg/m
3
TWA: 3.5 mg/m
(vacated) TWA: 3.5 mg/m
STEL: 400 ppm
TWA: 200 ppm
TWA: 400 ppm
TWA: 980 mg/m
(vacated) TWA: 400 ppm
(vacated) TWA: 980 mg/m
(vacated) STEL: 500 ppm
(vacated) STEL: 1225 mg/m
10 mg/m
3
20 mppcf TWA; ((80)/(% SiO2)
mg/m3)
TWA: 25 ppm(vacated) TWA: 25 ppm
(vacated) TWA: 125 mg/m
STEL: 10 mg/m3 Zr
TWA: 5 mg/m3 Zr
TWA: 5 mg/m3 Zr
(vacated) TWA: 5 mg/m3 Zr
(vacated) STEL: 10 mg/m3 Zr
TWA: 0.025 mg/m3 respirable
fraction
30/(%SiO2+2) mg/m3 TWA, Total
Dust;250/%SiO2+5) mppcf TWA,
respirable fraction; 10/(%SiO2+2)
mg/m3 TWA, respirable
TWA: 0.1 mg/m3 (vacated)
TWA: 100 ppmTWA: 500 ppm
TWA: 2900 mg/m
(vacated) TWA: 100 ppm
(vacated) TWA: 525 mg/m
3
3
3
IDLH: 1700 ppm
TWA: 150 ppm
TWA: 710 mg/m
STEL: 200 ppm
STEL: 950 mg/m
IDLH: 5000 mg/m
3
3
3
IDLH: 100 mg/m3 dust, fume and
mist
TWA: 1 mg/m3 dust and mist
TWA: 0.1 mg/m3 fume
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
3
3
3
IDLH: 1750 mg/m
TWA: 3.5 mg/m
3
3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
3
IDLH: 2000 ppm 10% LEL
TWA: 980 mg/m
3
3
TWA: 400 ppm
STEL: 500 ppm
STEL: 1225 mg/m
IDLH: 3000 mg/m
TWA: 6 mg/m
3
TWA: 25 ppm
TWA: 125 mg/m
3
3
3
3
3
IDLH: 25 mg/m3 Zr
TWA: 5 mg/m3 except Zirconium
tetrachloride Zr
STEL: 10 mg/m3 Zr
IDLH: 50 mg/m3 respirable dust
TWA: 0.05 mg/m3 respirable dust
3
3
IDLH: 20000 mg/m
Ceiling: 1800 mg/m3 15 min
TWA: 350 mg/m
3
3
Other Exposure Guidelines
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Individual protection measures, such as personal protective equipment
Eye/Face Protection
Skin and Body Protection
Respiratory Protection
Hygiene Measures
Showers
Eyewash stations
Ventilation systems
Safety glasses with side-shields. If splashes are likely to occur, wear: Chemical splash
goggles.
Chemical resistant gloves. Risk of contact: Boots. Apron.
No special protective equipment required. If exposure limits are exceeded or irritation is
experienced, NIOSH/MSHA approved respiratory protection should be worn.
When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area
and clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State
Odor
Property Values Remarks/ - Method
pH
Melting Point/Range
Boiling Point/Boiling Range
Flash Point
Evaporation rate
Flammability (solid, gas)
Flammability Limits in Air
upper flammability limit
lower flammability limit
Vapor Pressure
Vapor Density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition Temperature
Decomposition Temperature
Viscosity
Liquid.
Sweet.
No data availableNone known
No data availableNone known
122.2 °C / 252 °FNone known
27.2 °C / 81 °FTag closed cup
< 1 (BuAc = 1)None known
No data availableNone known
No data available 7.6
No data available 1.7
No data availableNone known
No data availableNone known
No data availableNone known
Slightly solubleNone known
No data availableNone known
No data availableNone known
No data availableNone known
No data available
No data availableNone known
Appearance
Odor Threshold
None known
Opaque, Varies.
No information available.
Flammable Properties
Explosive Properties
Oxidizing Properties
Other information
VOC Content (%)
Flammable liquid. Flammable; may be ignited by heat, sparks or flames.
No data available
Information on likely routes of exposure
Product Information
Inhalation
Eye Contact
Skin Contact
Ingestion
May cause irritation of respiratory tract. May cause drowsiness and dizziness.
Irritating to eyes. Causes serious eye irritation.
Irritating to skin. Causes skin irritation.
Ingestion may cause nausea and vomiting.
Chemical NameLD50 OralLD50 DermalLC50 Inhalation
Propylene glycol monomethyl ether
acetate
n-Butyl acetate= 10768 mg/kg ( Rat )> 17600 mg/kg ( Rabbit )= 391 ppm ( Rat ) 4 h
Isopropyl alcohol= 4396 mg/kg ( Rat )12800 mg/kg ( Rat )
12870 mg/kg ( Rabbit )
Silicon dioxide> 5000 mg/kg ( Rat )> 2000 mg/kg ( Rabbit )>2.2 mg/L ( Rat ) 4 h
Aluminum hydroxide> 5000 mg/kg ( Rat )--
Petroleum naphtha, light aromatic= 8400 mg/kg ( Rat )> 2000 mg/kg ( Rabbit )= 3400 ppm ( Rat ) 4 h
1,2,4 Trimethylbenzene= 3280 mg/kg ( Rat )> 3160 mg/kg ( Rabbit )= 18 g/m3 ( Rat ) 4 h
Silica= 3160 mg/kg ( Rat )--
Quartz---
Symptoms related to the physical, chemical and toxicological characteristics
72.6 mg/L ( Rat ) 4 h
Symptoms
No information available.
Delayed and immediate effects and also chronic effects from short and long term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
No information available.
May cause genetic defects.
This product contains one or more substances which are classified by IARC as
carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly
carcinogenic to humans (Group 2B).
Chemical NameACGIHIARCNTPOSHA
Titanium dioxideGroup 2B--
Carbon blackA3Group 2B-X
Isopropyl alcoholGroup 3
Silicon dioxideGroup 3
QuartzA2Group 1KnownX
ACGIH: (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC: (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans
Group 3 - Not Classifiable as to its Carcinogenicity to Humans
OSHA: (Occupational Safety & Health Administration)
X - Present
Reproductive Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
Target Organ Effects
No information available.
No information available.
No information available.
Avoid repeated exposure.
Liver. Kidney. Respiratory system. Eyes. Skin. Central nervous system (CNS). Blood.
Lungs. Lymphatic system.
Aspiration Hazard
No information available.
Numerical measures of toxicity - Product
The following values are calculated based on chapter 3.1 of the GHS document:
LD50 Oral
LD50 Dermal
dust/mist
Vapor
2419 mg/kg
5753 mg/kg mg/L
29.7 mg/L
113 mg/L
12. ECOLOGICAL INFORMATION
This product contains a chemical which is listed as a severe marine pollutant according to DOT.
Ecotoxicity
Very toxic to aquatic life with long lasting effects.
Waste Disposal Methods
Contaminated Packaging
US EPA Waste Number
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical NameCalifornia Hazardous Waste
n-Butyl acetateToxic
CopperToxic
AluminumIgnitable powder
Isopropyl alcoholToxic
Dispose of in accordance with federal, state, and local regulations
Do not re-use empty containers.
D001
U239
Ignitable
DOT
UN-Number
Proper shipping name
Hazard Class
Packing Group
Marine Pollutant
Description
Emergency Response Guide
Number
TDG
UN-Number
Proper Shipping Name
Hazard Class
Packing Group
Description
MEX
UN-Number
Proper Shipping Name
Hazard Class
Packing Group
Description
14. TRANSPORT INFORMATION
UN1263
Paint
3
III
This product contains a chemical which is listed as a severe marine pollutant according to
DOT.
UN1263, Paint, 3, III, Marine Pollutant, Limited Quantity
128
UN1263
Paint
3
III
UN1263, Paint, 3, III, Marine Pollutant, Limited Quantity
UN1263
Paint
3
III
UN1263, Paint, 3, III, Limited Quantity
UN-Number
Proper Shipping Name
Hazard Class
Packing Group
ERG Code
Description
IMDG/IMO
UN-Number
Proper Shipping Name
Hazard Class
Packing Group
EmS No.
Marine Pollutant
Description
RID
UN-Number
Proper Shipping Name
Hazard Class
Packing Group
Classification Code
Description
3
III
UN1263, Paint, 3, III
UN1263
Paint
3
III
3L
UN1263, Paint, 3, III
UN1263
Paint
3
III
F-E, S-E
Product is a marine pollutant according to the criteria set by IMDG/IMO
UN1263, Paint, 3, III, (27.2°C c.c.), Marine Pollutant, Limited Quantity
UN1263
Paint
3
III
F1
UN1263, Paint, 3, III, Limited Quantity
ADR
UN-Number
Proper Shipping Name
Hazard Class
Packing Group
Classification Code
Tunnel Restriction Code
Description
UN1263
Paint
3
III
F1
(D/E)
UN1263, Paint, 3, III, (D/E), Limited Quantity
ADN
Proper Shipping Name
Hazard Class
Packing Group
Classification Code
Special Provisions
Description
Limited Quantity
Ventilation
Paint
3
III
F1
163, 640E, 650
UN1263, Paint, 3, III, Limited Quantity
5 L
VE01
15. REGULATORY INFORMATION
International Inventories
TSCA
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
Complies
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical NameHazardous Substances RQsExtremely Hazardous Substances
RQs
n-Butyl acetate5000 lbRQ 5000 lb final RQ
RQ 2270 kg final RQ
Copper5000 lbRQ 5000 lb final RQ
RQ 2270 kg final RQ
RQ
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Chemical NameCAS-NoCalifornia Prop. 65
Titanium dioxide13463-67-7Carcinogen
Carbon black1333-86-4Carcinogen
Quartz14808-60-7Carcinogen
U.S. State Right-to-Know Regulations
Chemical NameNew JerseyMassachusettsPennsylvaniaIllinoisRhode Island
n-Butyl acetateXXXX
Titanium dioxideXX
CopperXXXXX
AluminumXXXX
Carbon blackXXXXX
Isopropyl alcoholXXXX
ZincXXXX
1,2,4 TrimethylbenzeneXXXXX
U.S. EPA Label Information
EPA Pesticide Registration Number
Not applicable
16. OTHER INFORMATION
NFPA Health Hazard 2Flammability 3Instability 0Physical and Chemical
General Disclaimer
The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The
information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be
valid for such material used in combination with any other material or in any process, unless specified in the text.
Product Stewardship
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
15-Aug-2014
09-Jun-2015
Change to composition.