ITW UN1263 User Manual

SAFETY DATA SHEET
Issuing Date 15-Aug-2014 Revision Date 09-Jun-2015 Revision Number 1
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING
GHS product identifier Product Name BRITE-MARK PAINT MARKER Other means of identification Part Number
Formula Code
UN-Number Synonyms
Recommended use of the chemical and restrictions on use Recommended Use Uses advised against
Supplier's details
Supplier Address
ITW PRO BRANDS 805 E. Old 56 Highway Olathe, KS 66061 TEL: 1-800-443-9536
Black (40003, 41003, 84002, 84202), Blue (40001, 41001, 84001, 84201), Brown (40007,
A720M (Black), A788M (Blue), A786M (Brown), A946M (Gold), A789M (Green), A783M (Light Blue), A790M (Orange), A787M (Pink), A791M (Red), A945M (Silver), A785M (Violet), A718M (White), A719M (Yellow)
UN1263 None
Solvent based marker No information available
Emergency telephone number Emergency Telephone
Number
800-535-5053 Infotrac
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200)
Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2
_____________________________________________________________________________________________
Page 1 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Germ Cell Mutagenicity Category 1B Carcinogenicity Category 1B Specific Target Organ Systemic Toxicity (Single Exposure) Category 3 Flammable liquids Category 3
GHS Label elements, including precautionary statements
Emergency Overview
Signal Word Danger Hazard Statements
• Causes skin irritation
• Causes serious eye irritation
• May cause genetic defects
• May cause cancer
• Very toxic to aquatic life with long lasting effects
• May cause respiratory irritation. May cause drowsiness or dizziness
• May cause drowsiness or dizziness
• Flammable liquid and vapor.
Appearance Opaque, Varies
Precautionary Statements
Prevention
• Obtain special instructions before use.
• Do not handle until all safety precautions have been read and understood.
• Keep away from heat/sparks/open flames/hot surfaces - No smoking.
• Keep container tightly closed.
• Keep cool.
• Ground/bond container and receiving equipment.
• Use explosion-proof electrical/ventilating/lighting/equipment.
• Use only non-sparking tools.
• Take precautionary measures against static discharge.
• Avoid breathing dust/fume/gas/mist/vapors/spray.
• Wash face, hands and any exposed skin thoroughly after handling.
• Use only outdoors or in a well-ventilated area.
• Avoid release to the environment.
• Wear protective gloves/protective clothing/eye protection/face protection.
• Use personal protective equipment as required.
General Advice
• If exposed or concerned: Get medical attention/advice
• Specific treatment (see supplemental first aid instructions on this label)
Eyes
• IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
• If eye irritation persists: Get medical advice/attention.
Physical State Liquid. Odor Sweet
Skin
• Wash contaminated clothing before reuse.
• IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
• If skin irritation occurs: Get medical advice/attention.
_____________________________________________________________________________________________
Page 2 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Inhalation
• IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Ingestion
• None
Fire
• In case of fire: Use CO2, dry chemical, or foam for extinction.
Spills and Leaks
• Collect spillage.
Storage
• Store locked up.
• Store in a well-ventilated place. Keep container tightly closed.
Disposal
• Dispose of contents/container to an approved waste disposal plant.
Hazard Not Otherwise Classified (HNOC)
Not applicable
Other information
Very toxic to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight % Trade secret
n-Butyl acetate 123-86-4 60-100 *
Titanium dioxide 13463-67-7 40-70 *
Copper 7440-50-8 10-30 *
Aluminum 7429-90-5 10-30 *
Carbon black 1333-86-4 7-13 *
Isopropyl alcohol 67-63-0 3 -7 *
Silicon dioxide 7631-86-9 3 -7 *
Aluminum hydroxide 21645-51-2 3 -7 *
1,2,4 Trimethylbenzene 95-63-6 1-5 *
Zirconium oxide 1314-23-4 0.1-1 *
Quartz 14808-60-7 < 0.1 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of necessary first-aid measures
General Advice
Eye Contact
Immediate medical attention is required. Show this safety data sheet to the doctor in attendance. If symptoms persist, call a physician.
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician.
Skin Contact
Inhalation Ingestion
Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes. If skin irritation persists, call a physician.
Move to fresh air. If breathing is difficult, give oxygen. If symptoms persist, call a physician. Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Drink plenty of water. Consult a physician if necessary
_____________________________________________________________________________________________
Page 3 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Protection of First-aiders Most important symptoms/effects, acute and delayed
Use personal protective equipment. Remove all sources of ignition.
Most Important Symptoms/Effects Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician
No information available.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Carbon dioxide (CO 2 ). Foam. Dry chemical.
Unsuitable Extinguishing Media
Specific Hazards Arising from the Chemical
Flammable. Keep product and empty container away from heat and sources of ignition. Risk of ignition
Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Water.
None. Yes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal Precautions
Environmental Precautions Environmental Precautions
Methods and materials for containment and cleaning up
Methods for Containment Methods for Cleaning Up
Evacuate personnel to safe areas. Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Stop leak if you can do it without risk.
Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system.
Prevent further leakage or spillage if safe to do so. Small spillage: Use a non-combustible material like vermiculite, sand or earth to soak up
the product and place into a container for later disposal. Large spillage: Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product.
7. HANDLING AND STORAGE
Precautions for safe handling Handling
Avoid contact with skin, eyes and clothing. Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharges. Use only in an area containing flame proof equipment. Ensure adequate ventilation. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Empty containers pose a potential fire and explosion hazard. Do not cut, puncture or weld containers.
Conditions for safe storage, including any incompatibilities
_____________________________________________________________________________________________
Page 4 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Storage
Keep away from open flames, hot surfaces and sources of ignition. Keep containers tightly closed in a cool, well-ventilated place. Keep out of the reach of children. Keep container closed when not in use. Keep away from incompatible materials.
Incompatible Products
Strong oxidizing agents. Strong reducing agents. Strong alkalis. Strong acids.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
n-Butyl acetate
123-86-4
Titanium dioxide
13463-67-7
Copper
7440-50-8
Aluminum
TWA: 1 mg/m3 respirable fraction TWA: 15 mg/m3 total dust
7429-90-5
Carbon black
1333-86-4
Isopropyl alcohol
67-63-0
Silicon dioxide
7631-86-9
Aluminum hydroxide
TWA: 1 mg/m3 respirable fraction - -
21645-51-2
1,2,4 Trimethylbenzene
95-63-6
Zirconium oxide
1314-23-4
Quartz
14808-60-7
Stoddard solvent
8052-41-3
Immediately Dangerous to Life or Health. ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH:
STEL: 200 ppm
TWA: 150 ppm
TWA: 150 ppm
TWA: 710 mg/m
(vacated) TWA: 150 ppm
(vacated) TWA: 710 mg/m
(vacated) STEL: 200 ppm
(vacated) STEL: 950 mg/m
TWA: 10 mg/m
3
TWA: 15 mg/m3 total dust
(vacated) TWA: 10 mg/m3 total
dust
TWA: 0.2 mg/m3 fume TWA: 0.1 mg/m3 fume
TWA: 1 mg/m3 dust and mist
(vacated) TWA: 0.1 mg/m3 Cu
dust, fume, mist
TWA: 5 mg/m3 respirable fraction
(vacated) TWA: 15 mg/m3 total
dust
(vacated) TWA: 5 mg/m
respirable fraction
TWA: 3.5 mg/m
3
TWA: 3.5 mg/m
(vacated) TWA: 3.5 mg/m
STEL: 400 ppm
TWA: 200 ppm
TWA: 400 ppm
TWA: 980 mg/m
(vacated) TWA: 400 ppm
(vacated) TWA: 980 mg/m
(vacated) STEL: 500 ppm
(vacated) STEL: 1225 mg/m
10 mg/m
3
20 mppcf TWA; ((80)/(% SiO2)
mg/m3)
TWA: 25 ppm (vacated) TWA: 25 ppm
(vacated) TWA: 125 mg/m
STEL: 10 mg/m3 Zr
TWA: 5 mg/m3 Zr
TWA: 5 mg/m3 Zr
(vacated) TWA: 5 mg/m3 Zr
(vacated) STEL: 10 mg/m3 Zr
TWA: 0.025 mg/m3 respirable
fraction
30/(%SiO2+2) mg/m3 TWA, Total Dust;250/%SiO2+5) mppcf TWA,
respirable fraction; 10/(%SiO2+2)
mg/m3 TWA, respirable
TWA: 0.1 mg/m3 (vacated)
TWA: 100 ppm TWA: 500 ppm
TWA: 2900 mg/m
(vacated) TWA: 100 ppm
(vacated) TWA: 525 mg/m
3
3
3
IDLH: 1700 ppm
TWA: 150 ppm
TWA: 710 mg/m
STEL: 200 ppm
STEL: 950 mg/m
IDLH: 5000 mg/m
3
3
3
IDLH: 100 mg/m3 dust, fume and
mist
TWA: 1 mg/m3 dust and mist
TWA: 0.1 mg/m3 fume
TWA: 10 mg/m3 total dust
TWA: 5 mg/m3 respirable dust
3
3
3
IDLH: 1750 mg/m
TWA: 3.5 mg/m
3
3
TWA: 0.1 mg/m3 Carbon black in
presence of Polycyclic aromatic
hydrocarbons PAH
3
IDLH: 2000 ppm 10% LEL
TWA: 980 mg/m
3
3
TWA: 400 ppm
STEL: 500 ppm
STEL: 1225 mg/m
IDLH: 3000 mg/m
TWA: 6 mg/m
3
TWA: 25 ppm
TWA: 125 mg/m
3
3
3
3
3
IDLH: 25 mg/m3 Zr
TWA: 5 mg/m3 except Zirconium
tetrachloride Zr
STEL: 10 mg/m3 Zr
IDLH: 50 mg/m3 respirable dust
TWA: 0.05 mg/m3 respirable dust
3
3
IDLH: 20000 mg/m
Ceiling: 1800 mg/m3 15 min
TWA: 350 mg/m
3
3
Other Exposure Guidelines
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).
_____________________________________________________________________________________________
Page 5 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Appropriate engineering controls Engineering Measures
Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection
Respiratory Protection
Hygiene Measures
Showers Eyewash stations Ventilation systems
Safety glasses with side-shields. If splashes are likely to occur, wear: Chemical splash goggles. Chemical resistant gloves. Risk of contact: Boots. Apron. No special protective equipment required. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn.
When using, do not eat, drink or smoke. Provide regular cleaning of equipment, work area and clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties Physical State
Odor Property Values Remarks/ - Method
pH Melting Point/Range Boiling Point/Boiling Range Flash Point Evaporation rate Flammability (solid, gas) Flammability Limits in Air
upper flammability limit
lower flammability limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity
Liquid. Sweet.
No data available None known No data available None known
122.2 °C / 252 °F None known
27.2 °C / 81 °F Tag closed cup < 1 (BuAc = 1) None known No data available None known
No data available 7.6 No data available 1.7 No data available None known No data available None known No data available None known Slightly soluble None known No data available None known No data available None known No data available None known No data available No data available None known
Appearance Odor Threshold
None known
Opaque, Varies. No information available.
Flammable Properties Explosive Properties
Oxidizing Properties Other information VOC Content (%)
Flammable liquid. Flammable; may be ignited by heat, sparks or flames. No data available
No data available
A720M Black: 66.61% A786M Brown: 67.78% A789M Green: 69.77% A787M Pink: 48.62% A945M Silver: 71.68% A718M White: 47.85% A788M Blue: 68.83% A946M Gold: 59.75% A783M Light Blue: 50.34% A790M Orange: 65.48% A791M Red: 66.17% A785M Violet: 76.57% A719M Yellow: 68.20%
_____________________________________________________________________________________________
Page 6 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
VOC (g/l)
A720M Black: 672 g/L A786M Brown: 712 g/L A789M Green: 725 g/L A787M Pink: 637 g/L A945M Silver: 714 g/L A718M White: 627 g/L A788M Blue: 694 g/L A946M Gold: 689 g/L A783M Light Blue: 588 g/L A790M Orange: 647 g/L A791M Red: 671 g/L A791M Red: 671 g/L A785M Violet: 771 g/L A719M Yellow: 716 g/L
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
Heat, flames and sparks. Incompatible products.
Incompatible materials
Strong oxidizing agents. Strong reducing agents. Strong alkalis. Strong acids.
Hazardous decomposition products
Carbon oxides. Smoke Soot.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Product Information
Inhalation Eye Contact Skin Contact Ingestion
May cause irritation of respiratory tract. May cause drowsiness and dizziness. Irritating to eyes. Causes serious eye irritation. Irritating to skin. Causes skin irritation. Ingestion may cause nausea and vomiting.
Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation
Propylene glycol monomethyl ether
acetate
n-Butyl acetate = 10768 mg/kg ( Rat ) > 17600 mg/kg ( Rabbit ) = 391 ppm ( Rat ) 4 h
Titanium dioxide > 10000 mg/kg ( Rat ) - -
Carbon black > 15400 mg/kg ( Rat ) > 3 g/kg ( Rabbit )
= 8532 mg/kg ( Rat ) > 5000 mg/kg ( Rabbit ) 5321 mg/m
3
-
_____________________________________________________________________________________________
Page 7 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Isopropyl alcohol = 4396 mg/kg ( Rat ) 12800 mg/kg ( Rat )
12870 mg/kg ( Rabbit )
Silicon dioxide > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) >2.2 mg/L ( Rat ) 4 h
Aluminum hydroxide > 5000 mg/kg ( Rat ) - -
Petroleum naphtha, light aromatic = 8400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 3400 ppm ( Rat ) 4 h
1,2,4 Trimethylbenzene = 3280 mg/kg ( Rat ) > 3160 mg/kg ( Rabbit ) = 18 g/m3 ( Rat ) 4 h
Silica = 3160 mg/kg ( Rat ) - -
Quartz - - -
Symptoms related to the physical, chemical and toxicological characteristics
72.6 mg/L ( Rat ) 4 h
Symptoms
No information available.
Delayed and immediate effects and also chronic effects from short and long term exposure Sensitization
Mutagenic Effects Carcinogenicity
No information available. May cause genetic defects. This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B).
Chemical Name ACGIH IARC NTP OSHA
Titanium dioxide Group 2B - -
Carbon black A3 Group 2B - X
Isopropyl alcohol Group 3
Silicon dioxide Group 3
Quartz A2 Group 1 Known X
ACGIH: (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC: (International Agency for Research on Cancer)
Group 2B - Possibly Carcinogenic to Humans Group 3 - Not Classifiable as to its Carcinogenicity to Humans
OSHA: (Occupational Safety & Health Administration)
X - Present
Reproductive Toxicity STOT - single exposure STOT - repeated exposure
Chronic Toxicity Target Organ Effects
No information available. No information available. No information available. Avoid repeated exposure. Liver. Kidney. Respiratory system. Eyes. Skin. Central nervous system (CNS). Blood. Lungs. Lymphatic system.
Aspiration Hazard
No information available.
Numerical measures of toxicity - Product
The following values are calculated based on chapter 3.1 of the GHS document:
LD50 Oral LD50 Dermal
dust/mist Vapor
2419 mg/kg 5753 mg/kg mg/L
29.7 mg/L 113 mg/L
12. ECOLOGICAL INFORMATION
This product contains a chemical which is listed as a severe marine pollutant according to DOT.
Ecotoxicity
Very toxic to aquatic life with long lasting effects.
Chemical Name
_____________________________________________________________________________________________
Page 8 / 13
Toxicity to Algae Toxicity to Fish
Toxicity to
Microorganisms
Daphnia Magna (Water
Flea)
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Propylene glycol
monomethyl ether acetate
108-65-6
n-Butyl acetate
123-86-4
Copper
7440-50-8
Carbon black
1333-86-4
Isopropyl alcohol
67-63-0
Silicon dioxide
7631-86-9
Zinc
7440-66-6
Petroleum naphtha, light
aromatic
64742-95-6
EC50 72 h: = 674.7 mg/L
(Desmodesmus
subspicatus)
EC50 96 h: 0.031 - 0.054
mg/L static
(Pseudokirchneriella
subcapitata)
EC50 72 h: 0.0426 - 0.0535
mg/L static
(Pseudokirchneriella
subcapitata)
EC50 96 h: > 1000 mg/L
(Desmodesmus
subspicatus) EC50 72 h: >
1000 mg/L (Desmodesmus
subspicatus)
EC50 72 h: = 440 mg/L
(Pseudokirchneriella
subcapitata)
EC50 72 h: 0.09 - 0.125
mg/L static
(Pseudokirchneriella
subcapitata)
EC50 96 h: 0.11 - 0.271
mg/L static
(Pseudokirchneriella
subcapitata)
LC50 96 h: = 161 mg/L static
(Pimephales promelas)
LC50 96 h: 17 - 19 mg/L
flow-through (Pimephales
promelas) LC50 96 h: = 100
mg/L static (Lepomis
macrochirus) LC50 96 h: =
62 mg/L static (Leuciscus
idus)
LC50 96 h: 0.0068 - 0.0156
mg/L (Pimephales
promelas)
LC50 96 h: < 0.3 mg/L static
(Pimephales promelas)
LC50 96 h: = 0.052 mg/L
flow-through (Oncorhynchus
mykiss)
LC50 96 h: = 0.112 mg/L
flow-through (Poecilia
reticulata)
LC50 96 h: = 0.2 mg/L
flow-through (Pimephales
promelas)
LC50 96 h: = 0.3 mg/L semi-static (Cyprinus carpio) LC50 96 h: = 0.8 mg/L static
(Cyprinus carpio)
LC50 96 h: = 1.25 mg/L
static (Lepomis macrochirus)
LC50 96 h: = 11130 mg/L
static (Pimephales
promelas)
LC50 96 h: = 9640 mg/L
flow-through (Pimephales
promelas)
LC50 96 h: > 1400000 µg/L
(Lepomis macrochirus)
LC50 96 h: = 5000 mg/L
static (Brachydanio rerio)
LC50 96 h: 0.211-0.269
mg/L semi-static
(Pimephales promelas)
LC50 96 h: 2.16-3.05 mg/L
flow-through (Pimephales
promelas)
LC50 96 h: = 0.24 mg/L
flow-through (Oncorhynchus
mykiss)
LC50 96 h: = 0.41 mg/L
static (Oncorhynchus
mykiss)
LC50 96 h: = 0.45 mg/L
semi-static (Cyprinus carpio)
LC50 96 h: = 0.59 mg/L
semi-static (Oncorhynchus
mykiss)
LC50 96 h: = 2.66 mg/L
static (Pimephales
promelas)
LC50 96 h: = 3.5 mg/L static
(Lepomis macrochirus)
LC50 96 h: = 30 mg/L
(Cyprinus carpio)
LC50 96 h: = 7.8 mg/L static
(Cyprinus carpio)
LC50 96 h: = 9.22 mg/L (Oncorhynchus mykiss)
EC50 = 70.0 mg/L 5 min
EC50 = 82.2 mg/L 15 min
EC50 = 959 mg/L 18 h
EC50 = 98.9 mg/L 30 min
- EC50 48 h: = 0.03 mg/L
EC50 48 h: > 500 mg/L
(Daphnia magna)
EC50 24 h: = 72.8 mg/L
(Daphnia magna)
Static (Daphnia magna)
EC50 24 h: > 5600 mg/L
(Daphnia magna)
EC50 48 h: = 13299 mg/L
(Daphnia magna)
EC50 48 h: = 7600 mg/L
(Ceriodaphnia dubia)
EC50 48 h: 0.139 - 0.908
mg/L Static (Daphnia
magna)
EC50 48 h: = 6.14 mg/L
(Daphnia magna)
_____________________________________________________________________________________________
Page 9 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
1,2,4 Trimethylbenzene
95-63-6
LC50 96 h: 7.19 - 8.28 mg/L
flow-through (Pimephales
promelas)
EC50 48 h: = 6.14 mg/L
(Daphnia magna)
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
n-Butyl acetate 1.81
Isopropyl alcohol 0.05
1,2,4 Trimethylbenzene 3.63
Other Adverse Effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Contaminated Packaging US EPA Waste Number
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste
n-Butyl acetate Toxic
Copper Toxic
Aluminum Ignitable powder
Isopropyl alcohol Toxic
Dispose of in accordance with federal, state, and local regulations Do not re-use empty containers. D001
U239
Ignitable
DOT
UN-Number Proper shipping name Hazard Class Packing Group Marine Pollutant
Description Emergency Response Guide Number
TDG
UN-Number Proper Shipping Name Hazard Class Packing Group Description
MEX
UN-Number Proper Shipping Name Hazard Class Packing Group Description
14. TRANSPORT INFORMATION
UN1263 Paint 3 III This product contains a chemical which is listed as a severe marine pollutant according to DOT. UN1263, Paint, 3, III, Marine Pollutant, Limited Quantity 128
UN1263 Paint 3 III UN1263, Paint, 3, III, Marine Pollutant, Limited Quantity
UN1263 Paint 3 III UN1263, Paint, 3, III, Limited Quantity
ICAO
UN-Number Proper shipping name
UN1263 Paint
_____________________________________________________________________________________________
Page 10 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Hazard Class Packing Group Description
IATA
UN-Number Proper Shipping Name Hazard Class Packing Group ERG Code Description
IMDG/IMO
UN-Number Proper Shipping Name Hazard Class Packing Group EmS No. Marine Pollutant Description
RID
UN-Number Proper Shipping Name Hazard Class Packing Group Classification Code Description
3 III UN1263, Paint, 3, III
UN1263 Paint 3 III 3L UN1263, Paint, 3, III
UN1263 Paint 3 III F-E, S-E Product is a marine pollutant according to the criteria set by IMDG/IMO UN1263, Paint, 3, III, (27.2°C c.c.), Marine Pollutant, Limited Quantity
UN1263 Paint 3 III F1 UN1263, Paint, 3, III, Limited Quantity
ADR
UN-Number Proper Shipping Name Hazard Class Packing Group Classification Code
Tunnel Restriction Code
Description
UN1263 Paint 3 III F1 (D/E) UN1263, Paint, 3, III, (D/E), Limited Quantity
ADN
Proper Shipping Name Hazard Class Packing Group Classification Code Special Provisions Description Limited Quantity Ventilation
Paint 3 III F1 163, 640E, 650 UN1263, Paint, 3, III, Limited Quantity 5 L VE01
15. REGULATORY INFORMATION
International Inventories
TSCA
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
U.S. Federal Regulations
Complies
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:
Chemical Name CAS-No Weight % SARA 313 - Threshold
Copper 7440-50-8 10-30 1.0
Aluminum 7429-90-5
10-30 1.0
Values %
_____________________________________________________________________________________________
Page 11 / 13
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Zinc 7440-66-6 3 -7 1.0
1,2,4 Trimethylbenzene 95-63-6 1-5 1.0
SARA 311/312 Hazard Categories
Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard
Clean Water Act
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):
Yes Yes Yes No No
Chemical Name CWA - Reportable
Quantities
n-Butyl acetate 5000 lb X
Copper X X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances
RQs
n-Butyl acetate 5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
Copper 5000 lb RQ 5000 lb final RQ
RQ 2270 kg final RQ
RQ
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Chemical Name CAS-No California Prop. 65
Titanium dioxide 13463-67-7 Carcinogen
Carbon black 1333-86-4 Carcinogen
Quartz 14808-60-7 Carcinogen
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Illinois Rhode Island
n-Butyl acetate X X X X
Titanium dioxide X X
Copper X X X X X
Aluminum X X X X
Carbon black X X X X X
Isopropyl alcohol X X X X
Zinc X X X X
1,2,4 Trimethylbenzene X X X X X
U.S. EPA Label Information EPA Pesticide Registration Number
Not applicable
16. OTHER INFORMATION
NFPA Health Hazard 2 Flammability 3 Instability 0 Physical and Chemical
Hazards -
HMIS
*Indicates a chronic health hazard.
_____________________________________________________________________________________________
Page 12 / 13
Health Hazard 2* Flammability 3
Physical Hazard 0 Personal Protection X
WPS-ITW-042 - BRITE-MARK PAINT MARKER
Revision Date 09-Jun-2015
_____________________________________________________________________________________________
Prepared By
Issuing Date Revision Date Revision Note
General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 15-Aug-2014 09-Jun-2015 Change to composition.
End of Safety Data Sheet
_____________________________________________________________________________________________
Page 13 / 13
Loading...