Howard RF1008 User Manual

Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product Identity / Alternate Names
Restor-A-Finish
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use / Application Method
See Technical Data Sheet.
1.3. Details of the supplier of the safety data sheet
Company Name
Howard Products, Inc. 560 Linne Road Paso Robles, CA 93446
Emergency
CHEMTREC (USA)
(800) 424-9300
Customer Service: Howard Products, Inc.
EMERGENCY PHONE:1-805-227-1000 FAX PHONE: 1-805-227-1007
2. Hazard identification of the product
2.1. Classification of the substance or mixture
Flam. Liq. 2;H225
Highly Flammable liquid and vapor.
Acute Tox. 4;H332
Harmful if inhaled.
Skin Irrit. 3;H316
Causes mild skin irritation. (Not adopted by US OSHA)
Eye Irrit. 2;H319
Causes serious eye irritation.
2.2. Label elements
Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.
Danger
H225 Highly flammable liquid and vapor. H316 Causes mild skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled.
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
[Prevention]:
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P241 Use explosion-proof electrical / ventilating / light / equipment. P261 Avoid breathing dust / fume / gas / mist / vapors / spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves / eye protection / face protection.
[Response]:
P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower. P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell. P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P332+313 If skin irritation occurs: Get medical advice / attention. P337+313 If eye irritation persists: Get medical advice / attention. P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing. P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
3. Composition/information on ingredients
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.
Ingredient/Chemical Designations
Weight %
GHS Classification
Notes
Distillates (petroleum), hydrotreated heavy paraffinic CAS Number: 0064742-54-7
50 - 75
Carc. 1A;H350
[1]
Petroleum distillates, hydrotreated light CAS Number: 0064742-47-8
25 - 50
Asp. Tox. 1;H304
[1]
Isopropyl Alcohol CAS Number: 0000067-63-0
1.0 - 10
Flam. Liq. 2;H225 Eye Irrit. 2;H319 STOT SE 3;H336
[1][2]
Acetone CAS Number: 0000067-64-1
1.0 - 10
Flam. Liq. 2;H225 Eye Irrit. 2;H319 STOT SE 3;H336
[1][2]
Butanone CAS Number: 0000078-93-3
1.0 - 10
Flam. Liq. 2;H225 Eye Irrit. 2;H319 STOT SE 3;H336
[1][2]
Xylene CAS Number: 0001330-20-7
1.0 - 10
Flam. Liq. 3;H226 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315
[1][2] Gilsonite
CAS Number: 0012002-43-6
1.0 - 10
[1]
[1] Substance classified with a health or environmental hazard. [3] PBT-substance or vPvB-substance. [2] Substance with a workplace exposure limit. *The full texts of the phrases are shown in Section 16.
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
4. First aid measures
4.1. Description of first aid measures
General
Move victim to fresh air. Keep victim warm and quiet. Call 911 or emergency medical service if deemed necessary. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water. Wash skin with soap and water. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.
Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.
Eyes
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
Skin
Remove and isolate contaminated clothing and shoes. Clothing frozen to the skin should be thawed before being removed. In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
Ingestion
If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Overview
Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. See section 2 for further details.
Inhalation
Harmful if inhaled.
Eyes
Causes serious eye irritation.
Skin
Causes mild skin irritation. (Not adopted by US OSHA)
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
5. Fire-fighting measures
5.1. Extinguishing media
Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray. Do not use; water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous decomposition: High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide.
Keep away from heat / sparks / open flames / hot surfaces - No smoking.
Use explosion-proof electrical / ventilating / light / equipment.
Avoid breathing dust / fume / gas / mist / vapors / spray.
5.3. Advice for fire-fighters
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection.
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.
ERG Guide No.
127
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Water spray may reduce vapor; but may not prevent ignition in closed spaces.
6.2. Environmental precautions
Do not allow spills to enter drains or watercourses.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
6.3. Methods and material for containment and cleaning up
As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering.
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
7. Handling and storage
7.1. Precautions for safe handling
Store in accordance with the National Fire Protection Association's publication NFPA 30, Flammable and Combustible Liquids Code. 29 CFR 1910.106 applies to the handling, storage, and use of flammable and combustible liquids. See section 2 for further details. - [Prevention]:
7.2. Conditions for safe storage, including any incompatibilities Handle containers carefully to prevent damage and spillage. Incompatible materials: Strong oxidizing agents and acids. See section 2 for further details. - [Storage]:
7.3. Specific end use(s) No data available.
8. Exposure controls and personal protection
8.1. Control parameters
Exposure
CAS No.
Ingredient
Source
Value
0000067-63-0
Isopropyl Alcohol
OSHA
TWA 400 ppm (980 mg/m3)STEL 500 ppm
ACGIH
TWA: 200 ppmSTEL: 400 ppm Revised 2003,
NIOSH
TWA 400 ppm (980 mg/m3) ST 500 ppm (1225 mg/m3)
Supplier
No Established Limit
0000067-64-1
Acetone
OSHA
TWA 1000 ppm (2400 mg/m3)STEL 2400 mg/m3
ACGIH
TWA: 250 ppmSTEL: 500 ppm Skin
NIOSH
250 ppm (590 mg/m3) TWA
Supplier
No Established Limit
0000078-93-3
Butanone
OSHA
TWA 200 ppm (590 mg/m3)
ACGIH
TWA: 50 ppmSTEL: 100 ppm
NIOSH
TWA 200 ppm (590 mg/m3) ST 300 ppm (885 mg/m3)
Supplier
No Established Limit
0001330-20-7
Xylene
OSHA
STEL 150 ppm
ACGIH
TWA: 100 ppmSTEL: 150 ppm
NIOSH
No Established Limit
Supplier
No Established Limit
0064742-47-8
Petroleum distillates, hydrotreated light
OSHA
No Established Limit
ACGIH
No Established Limit
NIOSH
No Established Limit
Supplier
Recommended 300 ppm PEL
0064742-54-7
Distillates (petroleum), hydrotreated heavy paraffinic
OSHA
No Established Limit
ACGIH
No Established Limit
NIOSH
No Established Limit
Supplier
No Established Limit
Contains mineral oil. The exposure limits for oil mist are 5 mg/m3 OSHA PEL and 10 mg/m3 ACGIH.
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
8.2. Exposure controls
Respiratory
If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.
Eyes
Safety glasses with side shields
Skin
Wear overalls to keep skin contact to a minimum. Impervious rubber gloves
Engineering Controls
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.
Other Work Practices
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
See section 2 for further details. - [Prevention]:
9. Physical and chemical properties
Appearance
Clear to dark Liquid
Odor
Aromatic
Odor threshold
Not Available
pH
Not Established
Melting point / freezing point
Not Established
Initial boiling point and boiling range
> 93.33 C ( > 200 F)
Flash Point
3.88 C (39 F)
Evaporation rate (Ether = 1)
Less than Bu Acetate
Flammability (solid, gas)
Not Applicable
Upper/lower flammability or explosive limits
Not Established
Vapor pressure (Pa)
51.2 mmHg @20C
Vapor Density
> 1
Specific Gravity
0.87
Solubility in Water
Insoluble
Partition coefficient n-octanol/water (Log Kow)
Not Measured
Auto-ignition temperature
Not Established
Decomposition temperature
Not Established
Viscosity (cSt)
Not Established
VOC %
Not Established
% Volatile
Not available
9.2. Other information
DMSO extract by IP346: Less than 3.0 wt % (mineral oil component only)
This product contains no known or suspected carcinogens and is not believed to be carcinogenic.
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
10. Stability and reactivity
10.1. Reactivity
Hazardous Polymerization will not occur.
10.2. Chemical stability
Stable under normal circumstances.
10.3. Possibility of hazardous reactions
No data available.
10.4. Conditions to avoid
Excessive heat and open flame.
10.5. Incompatible materials
Strong oxidizing agents and acids.
10.6. Hazardous decomposition products
High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide.
11. Toxicological information
Acute toxicity
Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.
Ingredient
Oral LD50,
mg/kg
Skin LD50,
mg/kg
Inhalation
Vapor LD50,
mg/L/4hr
Inhalation
Dust/Mist LD50,
mg/L/4hr
Inhalation
Gas LD50,
ppm
Distillates (petroleum), hydrotreated heavy paraffinic ­(64742-54-7)
5,000.00, Rat -
Category: 5
No data
available
No data
available
2.18, Rat -
Category: 4
No data
available
Petroleum distillates, hydrotreated light - (64742-47-8)
5,000.00, Rat -
Category: 5
>2,000.00,
Rabbit -
Category: 5
No data
available
No data
available
No data
available
Isopropyl Alcohol - (67-63-0)
4,710.00, Rat -
Category: 5
12,800.00, Rat -
Category: NA
72.60, Rat -
Category: NA
No data
available
No data
available
Acetone - (67-64-1)
2,000.00, Rat -
Category: 4
2,000.00,
Rabbit -
Category: 4
76.00, Rat -
Category: NA
No data
available
No data
available
Butanone - (78-93-3)
2,737.00, Rat -
Category: 5
6,480.00,
Rabbit -
Category: NA
32.00, Mouse ­Category: NA
No data
available
No data
available
Xylene - (1330-20-7)
4,299.00, Rat -
Category: 5
1,548.00,
Rabbit -
Category: 4
No data
available
20.00, Rat -
Category: NA
5,000.00, Rat -
Category: 4
Gilsonite - (12002-43-6)
No data
available
No data
available
No data
available
No data
available
No data
available
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the
product's ATE (Acute Toxicity Estimate).
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
Classification
Category
Hazard Description
Acute toxicity (oral)
---
Not Applicable
Acute toxicity (dermal)
---
Not Applicable
Acute toxicity (inhalation)
4
Harmful if inhaled.
Skin corrosion/irritation
3
Causes mild skin irritation. (Not adopted by US OSHA)
Serious eye damage/irritation
2
Causes serious eye irritation.
Respiratory sensitization
---
Not Applicable
Skin sensitization
---
Not Applicable
Germ cell mutagenicity
---
Not Applicable
Carcinogenicity
---
Not Applicable
Reproductive toxicity
---
Not Applicable
STOT-single exposure
---
Not Applicable
STOT-repeated exposure
---
Not Applicable
Aspiration hazard
---
Not Applicable
12. Ecological information
12.1. Toxicity Aquatic Ecotoxicity
Ingredient
96 hr LC50 fish, mg/l
48 hr EC50 crustacea, mg/l
ErC50 algae, mg/l
Distillates (petroleum), hydrotreated heavy paraffinic ­(64742-54-7)
5,000.00, Oncorhynchus
mykiss
1,000.00, Daphnia magna
Not Available
Petroleum distillates, hydrotreated light - (64742-47-8)
Not Available
Not Available
Not Available
Isopropyl Alcohol - (67-63-0)
1,400.00, Lepomis
macrochirus
100.00, Daphnia magna
100.00 (72 hr), Scenedesmus subspicatus
Acetone - (67-64-1)
100.00, Pimephales promelas
10.00, Daphnia magna
20.565 (72 hr), Ulva pertusa
Butanone - (78-93-3)
400.00, Cyprinodon
variegatus
520.00, Daphnia magna
500.00 (96 hr), Skeletonema costatum
Xylene - (1330-20-7)
3.30, Oncorhynchus mykiss
8.50, Palaemonetes pugio
100.00 (72 hr), Chlorococcales Gilsonite - (12002-43-6)
Not Available
Not Available
Not Available
12.2. Persistence and degradability There is no data available on the preparation itself.
12.3. Bioaccumulative potential Not Measured
12.4. Mobility in soil No data available.
12.5. Results of PBT and vPvB assessment This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects No data available.
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
13. Disposal considerations
13.1. Waste treatment methods
Do not allow into drains or water courses. Wastes and emptied containers should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Using information provided in this data sheet advice should be obtained from the Waste Regulation Authority, whether the special waste regulations apply.
14. Transport information
DOT
IMO / IMDG
ICAO/IATA
14.1. UN number
UN1263
UN1263
UN1263
14.2. UN proper ship. name
UN1263, Paint, 3, III
Paint
Paint
14.3. Transport hazard class(es)
DOT Hazard Class: 3 DOT Label: 3
IMDG: 3 Sub Class: Not Applicable
Air Class: 3
14.4. Packing group
III
III
III
14.5. Environmental hazards
IMDG
Marine Pollutant: No
14.6. Special precautions for user
No further information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not Applicable
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
15. Regulatory information
Regulatory Overview
The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. All ingredients of this product are listed on the TSCA (Toxic Substance Control Act) Inventory or are not required to be listed on the TSCA Inventory.
WHMIS Classification
B2 D2B
US EPA Tier II Hazards
Fire:
Yes
Sudden Release of Pressure:
No
Reactive:
No
Immediate (Acute):
Yes
Delayed (Chronic):
No
Acetone ( 5,000.00)
Butanone ( 5,000.00)
Xylene ( 100.00)
EPCRA 302 Extremely Hazardous : (No Product Ingredients Listed)
EPCRA 313 Toxic Chemicals:
Ethyl Benzene
Isopropyl Alcohol
Xylene
Proposition 65 - Carcinogens (>0.0%):
Ethyl Benzene
Proposition 65 - Developmental Toxins (>0.0%):
Toluene
Proposition 65 - Female Repro Toxins (>0.0%): (No Product Ingredients Listed)
Proposition 65 - Male Repro Toxins (>0.0%): (No Product Ingredients Listed)
N.J. RTK Substances (>1%):
Acetone
Butanone
Isopropyl Alcohol
Xylene
Penn RTK Substances (>1%):
Acetone
Butanone
Isopropyl Alcohol
EPCRA 311/312 Chemicals and RQs (lbs):
Page 10 of 11
Safety Data Sheet
Restor-A-Finish
SDS Revision Date:
08/20/2014
Xylene
16. Other information
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.
The full text of the phrases appearing in section 3 is:
H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness and dizziness.
H350 May cause cancer.
This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.
Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document.
End of Document
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