SAFETY DATA SHEET
MSDS L-106 REVISION 14
SECTION 1: IDENTIFICATION OF THE SUBSTANCE AND PRODUCER
DATE OF ISSUE: October 20, 2014
PRODUCT NAME: Bar Soap
I.D. NUMBERS: 99103368 (Bar Soap Deodorant), 99103369 (Dial Basics Deodorant)
Address:
VVF, LLC. Medical Emergencies: 1-888-689-9082
2000 Aucutt Rd. Chemtrec: 1-800-424-9300 (24 Hours Daily)
Montgomery, Illinois 60538 Other Information: 1-888-468-6673
SECTION 2: COMPOSITION / INFORMATION ON INGREDIENTS
Based on our hazard evaluation, the following chemical substance(s) in this product have been identified as hazardous.
INGREDIENT CAS NUMBER PERCENT (w/w)
Sodium Soap 67701-11-5 & 67701-10-4 60 – 100 %
Glycerin 56-81-5 1 – 5 %
SECTION 3: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: White or light colored soap-based bar
ODOR/ODOR THRESHOLD: Pleasant fragrance PHYSICAL STATE: Solid
pH (@ 25°C): Not available VAPOR DENSITY: Not available
BOILING POINT: Not available VAPOR PRESSURE: Not available
MELTING/FREEZING POINT: Not available FLASH POINT: See Section 6.
FLAMMABLE PROPERTIES: Not flammable SOLUBILITY IN WATER: Nearly complete
DENSITY/SPECIFIC GRAVITY: Not applicable EVAPORATION RATE: Not available
OCTANOL/WATER PARTITION COEFFICIENT (Kow): Not available
VISCOSITY (Dynamic): Not available
SECTION 4: HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION: This product is a white soap-based bar with a pleasant fragrance. Direct contact with eyes may cause
irritation. Repeated or prolonged excessive exposure with skin may cause irritation or dermatitis. No significant
environmental effects. Not a fire hazard. Product is stable.
This product is labeled in accordance with guidelines set forth in the Food, Drug, and Cosmetic Act. The use pattern
and exposure in the workplace are generally not consistent with those experienced by consumers. The requirements of
the Occupational Safety and Health Administration applicable to this Material Safety Data Sheet may differ from the
requirements of the FD&C Act and as a result, this MSDS may contain additional health hazard information not pertinent
to consumer use and not found on the product label.
REGULATORY STATUS
VVF, LLC. 2000 Aucutt Rd. Montgomery, Illinois 60538
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DIAL BAR SOAP MSDS L-105 (Rev. 13) March 9, 2009
While this product is not considered to be hazardous under OSHA’s Hazard Communication Standard (29 CFR
1900.1200), this MSDS includes valuable information that is critical for safe handling and proper use of this product.
This MSDS should be retained and available for employees and other users of this product.
POTENTIAL HEALTH EFFECTS
NOTE: The acute health effects described below are those which could potentially occur for the finished product. They
are based on the toxicology information available for the finished product and/or each hazardous ingredient, and are
consistent with the product type and the likelihood of a specific route of exposure. Known chronic health effects related
to exposure to a specific ingredient are indicated.
EYE CONTACT: This product may cause irritation.
SKIN CONTACT: Repeated or prolonged excessive exposure may cause irritation.
INGESTION: May cause mild gastrointestinal irritation with nausea, vomiting , diarrhea and abdominal pain.
INHALATION: Dust may cause mucous membrane irritation with sore throat, sneezing, coughing and shortness
CHRONIC HEALTH EFFECTS: None known.
of breath.
MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE: Pre-existing skin
conditions.
POTENTIAL ENVIRONMENTAL EFFECTS
See Section 11: Ecological Information.
SECTION 5: FIRST AID MEASURES
EYES: Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until no evidence of product
remains. Get medical attention if pain or irritation persists.
SKIN: Rinse affected area with plenty of water until no evidence of product remains. Get medical attention if irritation
persists.
INGESTION: Treat symptomatically and supportively. Maintain airway and respiration. If vomiting occurs, keep head
below hips to prevent aspiration. Dilution by rinsing the mouth and giving water or milk to drink is generally recommended.
If unconscious, the victim should not be given anything to drink. Contact physician or local poison control center.
INHALATION: Remove from exposure area to fresh air. Keep affected person warm and at rest. Treat symptomatically
and supportively. Contact physician or local poison control center. If breathing has stopped, give artificial respiration, and
get medical attention immediately.
NOTE TO PHYSICIAN: The physician's judgment should be used to control symptoms and clinical condition based on the
individual reactions of the patient.
SECTION 6: FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
OSHA FLAMMABILITY CLASSIFICATION: Not applicable FLASH POINT: None
UPPER FLAMMABILITY LIMIT: Not applicable LOWER FLAMMABILITY LIMIT: Not applicable
AUTO-IGNITION TEMPERATURE: Not applicable
FIRE AND EXPLOSION HAZARD: Negligible fire hazard when exposed to heat or flame. Dust - air mixtures may ignite or
explode.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon.
EXTINGUISHING MEDIA
Dry chemical, carbon dioxide, water spray or regular foam.
VVF, LLC. 2000 Aucutt Rd. Montgomery, Illinois 60538
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DIAL BAR SOAP MSDS L-105 (Rev. 13) March 9, 2009
INGREDIENT
CAS NUMBER
EXPOSURE LIMIT
Soap Dust = Particles
Not Otherwise
Specified:
67701-11-5 & 6770110-4
TLV-TWA: 10 mg/m3 (total dust), TLV-TWA: 3 mg/m3 (respirable
fraction), PEL-TWA: 15 mg/m3 (total dust), PEL-TWA: 5 mg/m3
(respirable fraction),
Glycerin (as mist)
56-81-5
TLV-TWA: 10 mg/m3 (mist), PEL-TWA: 5 mg/m
3
(respirable fraction); 15
mg/m3 (total mist)
PROTECTION OF FIREFIGHTERS
In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Move container
from fire area if you can do it without risk. Do not scatter spilled material with high-pressure water streams. Dike firecontrol water for later disposal. Use agents suitable for type of surrounding fire. Avoid breathing vapors, keep upwind.
SECTION 7: ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear skin, eye and respiratory protection as recommended in Section 8. Stop or reduce any leaks if it is safe to do so.
Spills present a slipping hazard. Keep unnecessary personnel away. Ventilate spill area if possible. Ensure clean-up is
conducted by trained personnel only. Make sure area is slip-free before re-opening to traffic.
ENVIRONMENTAL PRECAUTIONS
Small or household quantities may be disposed in regular domestic trash. For larger quantities check with your local
disposal authorities.
METHODS FOR CONTAINMENT AND CLEAN UP
SMALL SPILLS: Sweep or scoop up and place into suitable clean, dry containers for reclamation or later disposal. Wash
site of spillage thoroughly with water. LARGE SPILLS: Sweep or scoop up. Dispose in suitable waste container. Keep
unnecessary people away from spill.
SECTION 8: HANDLING AND STORAGE
HANDLING:
Do not get in eyes. Do not take internally. Use with adequate ventilation. Keep the containers closed when not in use.
STORAGE:
Store in original containers in a cool dry area. Store away from excessive heat and incompatible substances. Storage
areas for large quantities (warehouse) should be well ventilated. Keep the containers tightly closed when not in use.
SECTION 9: EXPOSURE CONTROLS / PERSONAL PROTECTION
This product is a personal care or cosmetic product. The use of this product by consumers is safe under normal and
reasonable foreseen use. The information provided below refers to the occupational settings.
WORKER EXPOSURE LIMITS
The following exposure limits exist for the ingredients listed below. The TLV-TWA is the ACGIH Threshold Limit Value –
Time Weighted Average. TLV-Ceiling Limit is the ACGIH Threshold Limit Value – Ceiling Limit. PEL-TWA is the OSHA
Permissible Exposure Limit.
ENGINEERING CONTROLS: Provide local exhaust or general dilution ventilation to keep exposure to airborne
contaminants below the permissible exposure limits where mists or vapors may be generated.
RESPIRATOR: Air contamination monitoring should be carried out where mists or vapors are likely to be generated, to
assure that the employees are not exposed to airborne contaminants above the permissible exposure limits. If respiratory
protection is required, it must be based on the contamination levels found in the workplace, must not exceed the working
limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine
Safety and Health Administration (NIOSH-MSHA).
FOR FIRE FIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: Any self-
contained breathing apparatus that has a full-face piece and is operated in a pressure-demand or other positive-pressure
mode. Any supplied-air respirator that has a full-face piece and is operated in a pressure-demand or other positive-
VVF, LLC. 2000 Aucutt Rd. Montgomery, Illinois 60538
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DIAL BAR SOAP MSDS L-105 (Rev. 13) March 9, 2009
PRODUCT / INGREDIENT
LC50/EC50 (ANIMAL SPECIE)
TOXICITY RATING
VERTEBRATES
Glycerin
96-hr LC50: 50 mg/L (Oncorhynchus mykiss)
Harmful
INVERTEBRATES
Glycerin
24-hr EC50: > 500 mg/L (Daphnia magna)
Practically Non-Hazardous
INGREDIENT
LD50 / DRAIZE SCORE
TOXICITY / IRRITATION RATING
ACUTE ORAL TOXICITY
Glycerin
12,600 mg/kg (rat)
Non-hazardous
ACUTE DERMAL TOXICITY
Glycerin
> 10,000 mg/kg (rabbit)
Non-hazardous
ACUTE INHALATION TOXICITY
Glycerin
> 570 mg/m3 (rat)
Toxic
pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure demand or other
positive-pressure mode.
CLOTHING: Protective clothing is required where repeated or prolonged skin contact may occur.
GLOVES: Protective gloves are required where repeated or prolonged skin contact may occur.
EYE/FACE PROTECTION: Safety glasses are required to prevent eye contact where dusty conditions may occur.
SECTION 10: STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm).
CONDITIONS TO AVOID: Avoid contact with incompatible substances and excessive heat.
INCOMPATIBLE MATERIALS: Strong oxidizers, acids and bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may release toxic and/or hazardous gases
including oxides of carbon and sodium.
POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.
SECTION 11: ECOLOGICAL INFORMATION
This product is anticipated to be safe for the environment at concentrations predicted in household settings under normal
use conditions.
ENVIRONMENTAL FATE: No environmental fate data exists for the product. The product is anticipated to be rapidly
biodegradable.
PERSISTENCE AND DEGRADABILITY: The persistence and degradability of this product has not been determined.
BIOACCUMULATION POTENTIAL: The bioaccumulation potential of this product has not been determined.
MOBILITY: The mobility of this product (in soil and water) has not been determined.
SECTION 12: TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION SUMMARY: This product is a personal care or cosmetic product. The use of this product by
consumers is safe under normal and reasonable foreseen use. Direct contact with eyes may cause eye irritation.
Repeated or prolonged excessive exposure with skin may cause irritation.
COMPONENT ANALYSIS: The following toxicity information is for the hazardous ingredient(s) when used as technical
grade and is provided as reference for the occupational settings.
VVF, LLC. 2000 Aucutt Rd. Montgomery, Illinois 60538
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DIAL BAR SOAP MSDS L-105 (Rev. 13) March 9, 2009
SENSITIZATION: This product is not considered a skin or respiratory sensitizer.
CARCINOGENICITY: None of the ingredients in this product are listed as carcinogens by the International Agency for
Research on Cancer (IARC), the National Toxicology Program (NTP) or the Occupational Safety and Health
Administration (OSHA).
MUTAGENICITY: None of the ingredients in this product are known to cause mutagenicity.
REPRODUCTIVE/FETAL/DEVELOPMENTAL TOXICITY: None of the ingredients in this product are known as
reproductive, fetal, or developmental hazards.
TARGET ORGAN TOXICITY: None of the ingredients in this product are known to have target organ toxicity.
EPIDEMIOLOGICAL INFORMATION: None of the ingredients in this product are known to have health-related information
in working populations.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE NUMBER AND DESCRIPTION: Not applicable, not regulated.
DISPOSAL CONSIDERATIONS: This product is not a RCRA hazardous waste and can be disposed of in accordance with
federal, state and local regulations.
SECTION 14: TRANSPORT INFORMATION
GROUND TRANSPORT
DOT Hazard Class: Not regulated Packing Group: Not applicable
DOT Proper Shipping Name: Not applicable Shipping Label Information: Not applicable
UN/NA Number: Not applicable
AIR TRANSPORT (ICAO/IATA) MARINE TRANSPORT (IMDG/IMO)
ICAO/IATA Hazard Class: Not regulated IMDG/IMO Hazard Class: Not regulated
ICAO/IATA Proper Shipping Name: Not applicable IMDG/IMO Proper Shipping Name: Not applicable
SECTION 15: REGULATORY INFORMATION
UNITED STATES:
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:
The Occupational Safety and Health Administration requires Material Safety Data Sheets to provide any hazards that may
be associated with the product, and make this information available in the workplace. Since the use pattern and exposure
in the workplace are generally not consistent with those experienced by consumers, this MSDS may contain additional
health hazard information not pertinent to consumer use.
FOOD AND DRUG ADMINISTRATION:
This product is regulated as a cosmetic under the Food and Drug Administration.
EPA - SARA TITLE III SECTION 313: Not applicable - Consumer product.
EPA CERCLA/SARA TITLE III SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:
This product contains no CERCLA/SARA Title III materials. This product contains no hazardous chemicals reportable
under Sections 311/312. This product contains no hazardous chemicals reportable under Section 304.
TSCA: All components of this product are either listed on or exempt from the U.S. Toxic Substances Control Act (TSCA)
chemical substance inventory.
STATE REGULATIONS
CALIFORNIA PROPOSITION 65: This product does not contain substances listed under California Proposition 65.
CANADA:
CANADIAN ENVIRONMENTAL PROTECTION ACT:
INVENTORY STATUS: Some components of this product are not listed on the Canadian Domestic Substances List (DSL)
nor the NDSL.
VVF, LLC. 2000 Aucutt Rd. Montgomery, Illinois 60538
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DIAL BAR SOAP MSDS L-105 (Rev. 13) March 9, 2009
HEALTH CANADA:
This product is regulated as a cosmetic product under the Cosmetics Programme.
WORKER HAZARDOUS MATERIALS INFORMATION SYSTEM:
WHMIS CLASSIFICATION: Not subject to classification.
SECTION 16: OTHER INFORMATION
DISCLAIMER: The information contained herein is provided in good faith and is believed to be correct as of the date
hereof. However, VVF, LLC. makes no representation as to the comprehensiveness or accuracy of the information. It is
expected that individuals receiving the information will exercise their independent judgment in determining its
appropriateness for a particular purpose. Accordingly, VVF, LLC. will not be responsible for damages of any kind resulting
from the use of or reliance upon such information. No representations, or warranties, either expressed or implied of
merchantability, fitness for a particular purpose or of any other nature is made hereunder with respect to the information
set forth herein or to the product to which the information refers.
NFPA RATINGS (Scale 0-4, where 4=high degree of hazard): HEALTH=1 FLAMMABILITY=0 REACTIVITY=0
HMIS RATINGS (Scale 0-4, where 4=severe hazard): HEALTH=0 FLAMMABILITY=0 REACTIVITY=0
SDS CREATION DATE: 04/21/93
SUPERCEDES: 01/7/2013, Rev. 13
REVISION DATE: 10/20/14
REVISION: Converted to SDS format
VVF, LLC. 2000 Aucutt Rd. Montgomery, Illinois 60538
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