Hoover CH27260 User Manual

SAMSUNG SDI Co., Ltd.

Date: January 1, 2018 Reference no.: SDI-TTi-30Q-I-1
MODEL: INR18650-30Q Revision no.: 00

Safety Data Sheet

1. Product and Company Identification

Important Note: As a solid, manufactured article, exposure to hazardous ingredients is not expected with
normal use. This battery is an article pursuant to 29 CFR 1910.1200 and, as such, is not subject to the
OSHA Hazard Communication Standard requirement. The information contained in this Safety Data Sheet
contains valuable information critical to the safe handling and proper use of the product. This SDS should
be retained and available for employees and other users of this product.

Commercial product name

INR18650-30Q

Use of the substance/preparation

Lithium-ion batteries

Synonyms

Lithium-ion Cell, Lithium-ion Battery, Li-Ion Cell, Li-Ion Battery

Manufacturer

SAMSUNG SDI Co., Ltd.
Address

HQ: 150-20, Gongse-ro, Giheung-gu, Yongin-si, Gyeonggi-do, Korea

Company/undertaking identification

Emergency Contact(Chemtrec)
1-800-424-9300: US and Canada / 1-703-527-3887: International

Further Information

Battery-System: Lithium-ion (Li-ion)

Nominal Voltage: 3.6 V
Rated Capacity: 3.000 Ah
Wh rating: 10.80 Wh

Anode (negative electrode): based on intercalation graphite
Cathode (positive electrode): based on lithiated metal oxide (Cobalt, Nickel, Aluminium)

Remark:

The information and recommendations set forth are made in good faith and believed to be accurate as of
the date of preparation. SAMSUNG SDI Co., Ltd. makes no warranty, expressed or implied, with respect
to this information and disclaims all liabilities from reliance on it.

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SAMSUNG SDI Co., Ltd.

Date: January 1, 2018 Reference no.: SDI-TTi-30Q-I-1
MODEL: INR18650-30Q Revision no.: 00

2. Hazards Identification

Classification of the substance or mixture.

Preparation Hazards and Classification: The product is a Lithium ion cell or battery and is therefore classified

as an article and is not hazardous when used according to the recommendations of the manufacturer. The hazard
is associated with the contents of the cell or battery. Under recommended use conditions, the electrode materials
and liquid electrolyte are non-reactive provided that the cell or battery integrity remains and the seals remain intact.
The potential for exposure should not exist unless the cell or battery leaks, is exposed to high temperatures or is
mechanically, electrically or physically abused/damaged. If the cell or battery is compromised and starts to leak,
based upon the battery ingredients, the contents are classified as Hazardous.

Hazard Summary
Physical hazards: Not classified for physical hazards.
Health hazards: Not classified for health hazards.
Environmental hazards: Not classified for hazards to the environment.
Specific hazards: Exposure to contents of an open or damaged cell or battery: contact with this material will

cause burns to the skin, eyes and mucous membranes. May cause sensitization by skin contact.

Main Symptoms: Symptoms include itching, burning, redness and tearing.

Hazardous Materials Information Label (HMIS)

Health: 0
Flammability: 1
Physical Hazard: 0

NFPA Hazard Ratings

Health: 0
Flammability: 1
Reactivity: 0
Unique Hazard:

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SAMSUNG SDI Co., Ltd.

Precautionary
Statement(s)
Prevention

P102: Keep out of reach of children.
P103: Read label prior to use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P234: Keep only in original container.
P254: Wash hands thoroughly after handling.

Response
(If cell/battery
leaks)

P260: Do not breathe vapor or spray.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301/330/331: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting.
P303/361/353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304/340: If INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305/351/338: IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P363: Wash contaminated clothing before reuse.
P370: In case of fire: Use carbon dioxide, dry chemical or water extinguisher.

Storage
(Store as indicated
in Section 7)

P402: Store in a dry place.
P405: Store locked up.
P410: Protect from sunlight.

Disposal

P406: Store any spilled/leaking electrolyte material in a corrosive resistant container with a resistant inner liner.
P501: Dispose of batteries in accordance with applicable hazardous waste regulations.

Date: January 1, 2018 Reference no.: SDI-TTi-30Q-I-1
MODEL: INR18650-30Q Revision no.: 00

Labelling

If the cell or battery is compromised and starts to leak, based upon the battery ingredients, the contents are
classified as Hazardous

Symbol:

Signal word: Danger

GHS precautionary statements

Other Hazards.

Appearance, Color and Odor: Solid object with no odor.
Primary Routes(s) of Exposure: These chemicals are contained in a sealed enclosure. Risk of exposure occurs

only if the cell or pack is mechanically, thermally, electrically or physically abused to the point of compromising the
enclosure.
If this occurs, exposure to the electrolyte solution contained within can occur by inhalation, ingestion, eye contact
and skin contact.

Potential Health Effect(s):

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SAMSUNG SDI Co., Ltd.

Chemical Name

CAS No.

*Mass range in cell (g/g %)

Electrolyte

Contains Electrolyte salt and solvents.

5-20

Electrolyte salt

Lithium hexafluorophosphate

21324-40-3

0.05-5

Electrolyte
solvent

Includes one or more of the following;
Ethelyne Carbonate
Propylene Carbonate
Diethyl Carbonate

Ethyl propionate

96-49-1
108-32-7
105-58-8
105-37-3

5-20
PVDF

Polyvinylidenfluoride

24937-79-9

<1

Copper

Cu

7440-50-8

3-15

Aluminium

Al

7429-90-5

2-10

Cathode

Lithium cobalt oxide

12190-79-3

20-50

Anode

Graphite

7782-42-5

10-30

Steel, Nickel, and
inert components

Various

Balance

Date: January 1, 2018 Reference no.: SDI-TTi-30Q-I-1
MODEL: INR18650-30Q Revision no.: 00

Acute (short term): see Section 8 for exposure controls.
In the event that this cell or pack has been ruptured, the electrolyte solution contained within the cell would
be corrosive and can cause burns to skin and eyes.
Inhalation: Inhalation of materials from a sealed cell is not an expected route of exposure. Vapors or mists
from a ruptured cell may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed cell is not an expected route of exposure. Swallowing the
contents of an open cell can cause serious chemical burns to mouth, esophagus, and gastrointestinal tract.
Skin: Contact between the cell and skin will not cause any harm. Skin contact with the contents of an open
cell can cause severe irritation or burns to the skin.
Eye: Contact between the cell and the eye will not cause any harm. Eye contact with the contents of an open
cell can cause severe irritation or burns to the eye.

CHRONIC (long term): see Section 11 for additional toxicological data.

Interactions with other chemicals: Immersion in high conductivity liquids may cause corrosion and breaching of

the cell or battery enclosure. The electrolyte solution inside of the cells may react with alkaline (basic) materials
and present a flammability hazard.

Potential Environmental Effects: Not Available.

3. Composition/information on ingredients
Hazardous components

Because of the cell structure the dangerous ingredients will not be available if used properly.
During charge process a lithium graphite intercalation phase is formed.

4. First Aid Measures

Description of first aid measures

The hazardous components of this cell or battery are contained within a sealed unit. The following measures are only
applicable if exposure has occurred to components when a cell or battery leaks, is exposed to high temperatures or is

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