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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: Green Stuff
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503 USA
Phone: (228) 896-9220
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
59128
Basic cleaner
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
corrosion
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
C; Corrosive
R35: Causes severe burns.
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
·
Hazard pictograms
GHS05
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 1)
·
Signal word
·
Hazard-determining components of labelling:
sodium hydroxide
·
Hazard statements
H314 Causes severe skin burns and eye damage.
·
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash thoroughly after handling.
P260 Do not breathe vapours.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
·
Hazard description:
·
WHMIS-symbols:
D2B - Toxic material causing other toxic effects
E - Corrosive material
Danger
skin with water/shower.
present and easy to do. Continue rinsing.
·
NFPA ratings (scale 0 - 4)
Health = 3
300
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
HMIS Long Term Health Hazard Substances
Fire = 0
Reactivity = 0
3
Health = 3
0
Fire = 0
0
Reactivity = 0
None of the ingredients is listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 2)
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 1310-73-2
EINECS: 215-185-5
Index number: 011-002-00-6
·
Additional information:
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
·
After inhalation:
·
After skin contact:
Rinse with 3% acetic acid and plenty of water.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn, if possible.
Rinse opened eye for several minutes under running water. Then consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
Medical supervision for at least 48 hours.
Mixture of substances listed below with nonhazardous additions.
sodium hydroxide
C R35
Skin Corr. 1A, H314
For the wording of the listed risk phrases refer to section 16.
Immediately remove any clothing soiled by the product.
Supply fresh air; consult doctor in case of complaints.
Danger of gastric perforation.
10-25%
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
38.0.16
No further relevant information available.
None.
No further relevant information available.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 3)
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Particular danger of slipping on leaked/spilled product.
·
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Clean the affected area carefully; suitable cleaners are:
Warm water
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
No special measures required.
7 Handling and storage
·
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
No special measures required.
Unsuitable material for receptacle: glass or ceramic.
Unsuitable material for receptacle: aluminium.
Unsuitable material for receptacle: steel.
Protect from humidity and water.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Do not store together with acids.
·
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Protect from frost.
·
7.3 Specific end use(s)
No further relevant information available.
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
No further data; see item 7.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 4)
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
1310-73-2 sodium hydroxide
PEL (USA) Long-term value: 2 mg/m³
REL (USA) Short-term value: C 2 mg/m³
TLV (USA) Short-term value: C 2 mg/m³
EL (Canada) Short-term value: C 2 mg/m³
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
·
Respiratory protection:
Not required under normal conditions of use.
Use suitable respiratory protective device in case of insufficient ventilation.
Use suitable respiratory protective device when aerosol or mist is formed.
·
Protection of hands:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the produc t/ the
preparation/ the chemical mixture.
Selection of the glove m aterial on consideration of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Nitrile rubber, NBR
Neoprene gloves
PVC gloves
Fluorocarbon rubber (Viton)
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 5)
·
Eye protection:
Contact lenses should not be worn.
Safety glasses
·
Body protection:
·
Limitation and supervision of exposure into the environment
No further relevant information available.
·
Risk management measures
See Section 7 for additional information.
No further relevant information available.
9 Physical and chemical properties
Alkaline resistant protective clothing
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value at 20 °C:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure at 20 °C:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
Liquid
Green
Characteristic
Not determined.
>13
Not Determined.
212 °F / 100 °C
Not applicable.
Not applicable.
Not determined.
Not determined.
Product is not self-igniting.
Product does not present an explosion hazard.
Not determined.
Not determined.
23 hPa
1,08 g/cm³
Not determined.
Not determined.
Not determined.
(Contd. on page 7)
38.0.16
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 6)
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
9.2 Other information
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Reacts with strong acids and oxidizing agents.
Reacts with various metals.
Corrosive action on metals.
Reacts with fats and oils.
Reacts with carbon dioxide.
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Store away from oxidizing agents.
No further relevant information available.
Fully miscible.
Not determined.
Not determined.
Not determined.
No further relevant information available.
Possible in traces.
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
1310-73-2 sodium hydroxide
Oral LD50 2000 mg/kg (rat)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
The product shows the following dangers according to the calculation m ethod of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Corrosive
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus and stomach.
Strong caustic effect on skin and mucous membranes.
Strong caustic effect.
No sensitizing effects known.
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 7)
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Additional ecological information:
·
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Rinse off of bigger amounts into drains or the aquatic environment may lead to increased pH-values. A
high pH-value harms aquatic organisms. In the dilution of the use-level the pH-value is considerably
reduced, so that after the use of the product the aqueous waste, emptied into drains, is only low waterdangerous.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in
accordance with Local Authority requirements.
Can be disposed of with household garbage with prior chemical-physical or biological treatment following
consultation with the waste disposal facility operator and the pertinent authorities and adhering to the
necessary technical regulations.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
Disposal must be made according to official regulations.
Water, if necessary together with cleansing agents.
14 Transport information
·
14.1 UN-Number
·
DOT, ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT
·
ADR
UN3266
Corrosive liq uid, b asic, i norga nic, n.o.s. (Sodium
Hydroxide)
3266 C ORROSIVE LIQ UID, BASIC , INOR GANIC,
N.O.S. (Sodium Hydroxide)
(Contd. on page 9)
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Page 9
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III
5L
2
E
UN3266, CORROSIVE LIQUID, BASIC, INORGANIC,
N.O.S. (SODIUM HYDROXIDE), 8, III
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 8)
·
IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT
·
Class
·
Label
·
ADR
CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.
(Sodium Hydroxide)
8 Corrosive substances.
8
·
Class
·
Label
·
IMDG, IATA
·
Class
·
Label
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
Segregation groups
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
·
Transport category
·
Tunnel restriction code
·
UN "Model Regulation":
8 (C5) Corrosive substances.
8
8 Corrosive substances.
8
II
No
Warning: Corrosive substances.
80
F-A,S-B
Alkalis
Not applicable.
1L
2
E
UN3266, CORROSIVE LIQUID, BASIC, INORGANIC,
N.O.S.(Sodium Hydroxide), 8, II
38.0.16
(Contd. on page 10)
Page 10
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 9)
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients is listed.
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
1310-73-2 sodium hydroxide
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
1310-73-2 sodium hydroxide
(Contd. on page 11)
38.0.16
Page 11
Page 11/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 26.02.2014 Revision: 26.02.2014
Trade name: Green Stuff
(Contd. of page 10)
·
15.2 Chemical safety assessment:
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H314 Causes severe skin burns and eye damage.
R35 Causes severe burns.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
A Chemical Safety Assessment has not been carried out.
38.0.16
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