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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: SUPER FLUSH
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the preparation
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503 USA
Phone: (228) 896-9220
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
55032, 55128, 55550
Chemical intermediate
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
The following Hazard Statements are applicable only to the general GHS regulations and not the specific
CLP regulation: H227.
H227: Combustible Liquid. (General GHS and USA only)
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xi; Irritant
R36/38: Irritating to eyes and skin.
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international substances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
H227: Combustible Liquid. (General GHS and USA only)
The product is classified and labelled according to the CLP regulation.
(Contd. on page 2)
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Page 2
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 1)
·
Hazard pictograms
GHS07
·
Signal word
·
Hazard statements
H227: Combustible Liquid. (General GHS and USA only)
H315 Causes skin irritation.
H319 Causes serious eye irritation.
·
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P280 Wear protective gloves / eye protection.
P264 Wash thoroughly after handling.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
P370+P378 In case of fire: Use foam, powder, or carbon dioxide for extinction.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P403+P235 Store in a well-ventilated place. Keep cool.
·
Hazard description:
·
WHMIS-symbols:
B3 - Combustible liquid
D2B - Toxic material causing other toxic effects
Warning
present and easy to do. Continue rinsing.
·
NFPA ratings (scale 0 - 4)
Health = 1
120
·
HMIS-ratings (scale 0 - 4)
HEALTH
FIRE
REACTIVITY
·
HMIS Long Term Health Hazard Substances
Fire = 2
Reactivity = 0
1
Health = 1
2
Fire = 2
0
Reactivity = 0
None of the ingredients is listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
(Contd. on page 3)
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Page 3
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 2)
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 34590-94-8
EINECS: 252-104-2
CAS: 5131-66-8
EINECS: 225-878-4
Index number: 603-052-00-8
·
Additional information:
4 First aid measures
Mixture of substances listed below with nonhazardous additions.
(2-methoxymethylethoxy)propanol
substance with a Community workplace exposure limit
3-butoxypropan-2-ol
Xi R36/38
Skin Irrit. 2, H315; Eye Irrit. 2, H319
For the wording of the listed risk phrases refer to section 16.
25-50%
25-50%
·
4.1 Description of first aid measures
·
General information:
Take affected persons out into the fresh air.
Immediately remove any clothing soiled by the product.
In case of irregular breathing or respiratory arrest provide artificial respiration.
·
After inhalation:
·
After skin contact:
Supply fresh air; consult doctor in case of complaints.
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
·
After eye contact:
Remove contact lenses if worn.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Cramp
Nausea
Dizziness
Breathing difficulty
·
Hazards
·
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Medical supervision for at least 48 hours.
If necessary oxygen respiration treatment.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
·
For safety reasons unsuitable extinguishing agents:
37.0
None.
(Contd. on page 4)
Page 4
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 3)
·
5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
Eliminate all ignition sources if safe to do so.
Use large quantities of foam as it is partially destroyed by the product.
Cool endangered receptacles with water spray.
6 Accidental release measures
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6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources.
·
6.2 Environmental precautions:
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Send for recovery or disposal in suitable receptacles.
Ensure adequate ventilation.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Do not allow to enter sewers/ surface or ground water.
7 Handling and storage
·
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
·
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
When heated the product forms flammable fumes.
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Store in a cool location.
Avoid storage near extreme heat, ignition sources or open flame.
Provide ventilation for receptacles.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Do not store together with oxidizing and acidic materials.
·
Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
(Contd. on page 5)
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Page 5
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 4)
·
7.3 Specific end use(s)
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
34590-94-8 (2-methoxymethylethoxy)propanol
IOELV (EU) Long-term value: 308 mg/m³, 50 ppm
Skin
PEL (USA) Long-term value: 600 mg/m³, 100 ppm
Skin
REL (USA) Short-term value: 900 mg/m³, 150 ppm
Long-term value: 600 mg/m³, 100 ppm
Skin
TLV (USA) Short-term value: 909 mg/m³, 150 ppm
Long-term value: 606 mg/m³, 100 ppm
Skin
EL (Canada) Short-term value: 150 ppm
Long-term value: 100 ppm
Skin
EV (Canada) Short-term value: 910 mg/m³, 150 ppm
Long-term value: 605 mg/m³, 100 ppm
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
·
Respiratory protection:
Not required under normal conditions of use.
Use suitable respiratory protective device when aerosol or mist is formed.
Use suitable respiratory protective device in case of insufficient ventilation.
·
Protection of hands:
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further data; see item 7.
The lists valid during the making were used as basis.
Protective gloves
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 5)
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove m aterial on consideration of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to
be observed.
·
For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Neoprene gloves
·
Eye protection:
Safety glasses
·
Body protection:
·
Limitation and supervision of exposure into the environment
Light weight protective clothing
No further relevant information available.
·
Risk management measures
See Section 7 for additional information.
No further relevant information available.
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Ignition temperature:
·
Decomposition temperature:
Liquid
Clear
Characteristic
Not determined.
Not determined.
Undetermined.
340⁰F / 171⁰C
160⁰F / 71 °C (ASTM D-93)
Not applicable.
Not determined.
Not determined.
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 6)
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure at 20 °C:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
Solvent content:
Organic solvents:
VOC (California)
·
9.2 Other information
Product is not self-igniting.
Product does not present an explosion hazard.
1,1 Vol %
14,0 Vol %
1,3 hPa
0,91 g/cm³
Not determined.
Not determined.
Not determined.
Fully miscible.
Not determined.
Not determined.
Not determined.
Not determined.
>99 %
No further relevant information available.
10 Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Reacts with strong acids.
Reacts with strong oxidizing agents.
Used empty containers may contain product gases which form explosive mixtures with air.
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised.
Toxic fumes may be released if heated above the decomposition point.
·
10.4 Conditions to avoid
Keep ignition sources away - Do not smoke.
Store away from oxidizing agents.
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Hydrocarbons
Irritant gases/vapours
No further relevant information available.
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 7)
Carbon monoxide and carbon dioxide
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Subacute to chronic toxicity:
·
Additional toxicological information:
The product shows the following dangers according to the calculation m ethod of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
Irritant to skin and mucous membranes.
Irritating effect.
No sensitizing effects known.
Vapours have narcotic effect.
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Ecotoxical effects:
·
Remark:
The product is oxygen-consuming. The declared action may be partly caused by lack of oxygen.
Due to mechanical actions of the product (e.g. agglutinations) damages may occur.
·
Additional ecological information:
·
General notes:
This statement was deduced from the properties of the single components.
Due to available data on eliminability/decomposition and bioaccumulation potential a prolonged damage of
the environment is unlikely.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
12.6 Other adverse effects
Not applicable.
No further relevant information available.
Moderately /partly biodegradable
Does not accumulate in organisms.
No further relevant information available.
No further relevant information available.
(Contd. on page 9)
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Page 9
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 8)
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
·
Uncleaned packaging:
·
Recommendation:
·
Recommended cleansing agents:
14 Transport information
Disposal must be made according to official regulations.
Water, if necessary together with cleansing agents.
·
14.1 UN-Number
·
DOT, ADR, ADN, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT, ADR, ADN, IMDG, IATA
·
14.3 Transport hazard class(es)
·
DOT, ADR, ADN, IMDG, IATA
·
Class
·
14.4 Packing group
·
DOT, ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
14.6 Special precautions for user
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
UN "Model Regulation":
N/A
N/A
N/A
N/A
No
Not applicable.
Not applicable.
-
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
(Contd. on page 10)
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Page 10
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 9)
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
None of the ingredients is listed.
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
34590-94-8 (2-methoxymethylethoxy)propanol
·
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H315 Causes skin irritation.
H319 Causes serious eye irritation.
R36/38 Irritating to eyes and skin.
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(Contd. on page 11)
Page 11
Page 11/11
Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 20.06.2013 Revision: 19.06.2013
Trade name: SUPER FLUSH
(Contd. of page 10)
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
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