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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
1 Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: SOLDERLENE
·
Article number:
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the Safety Data Sheet
·
Manufacturer/Supplier:
Highside Chemicals, Inc.
11114 Reichold Road
Gulfport, MS 39503 USA
Phone: (228) 896-9220
·
1.4 Emergency telephone number:
ChemTel Inc.
(800)255-3924, +1 (813)248-0585
30004, 30016
Soldering flux
2 Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
The following Hazard Statements are applicable only to the EU regulations and not the US GHS
regulation: H411.
health hazard
Carc. 1B H350 May cause cancer.
corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
·
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
C; Corrosive
R34: Causes burns.
Xi; Irritant
R37: Irritating to respiratory system.
N; Dangerous for the environment
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 1)
·
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
·
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and
literature data.
The classification is in accordance with the latest editions of international su bstances lists, and is
supplemented by information from technical literature and by information provided by the company.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
·
Hazard pictograms
This pictogram only applicable for EU regulations. Not for use in the United States (OSHA GHS).
GHS05 GHS08 GHS09
·
Signal word
·
Hazard-determining components of labelling:
Danger
Petrolatum
zinc chloride
·
Hazard statements
The following Hazard Statements are applicable only to the EU regulations and not the US GHS
regulation: H411.
H314 Causes severe skin burns and eye damage.
H350 May cause cancer.
H411 Toxic to aquatic life with long lasting effects.
·
Precautionary statements
P281 Use personal protective equipment as required.
P273 Avoid release to the environment.
P264 Wash thoroughly after handling.
P202 Do not handle until all safety precautions have been read and understood.
P303+P361+P353 IF ON SKIN (or ha ir) : Re mo ve/T ake off imm edi ate ly al l c ont amin ate d c loth ing . R ins e
skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
·
Additional information:
Restricted to professional users.
·
Hazard description:
·
WHMIS-symbols:
D2B - Toxic material causing other toxic effects
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 2)
E - Corrosive material
·
NFPA ratings (scale 0 - 4)
Health = 3
310
·
HMIS-ratings (scale 0 - 4)
Fire = 1
Reactivity = 0
HEALTH
FIRE
REACTIVITY
*3
Health = *3
1
Fire = 1
0
Reactivity = 0
* - Indicates a long term health hazard from repeated or prolonged exposures.
·
HMIS Long Term Health Hazard Substances
None of the ingredients is listed.
·
2.3 Other hazards
·
Results of PBT and vPvB assessment
·
·
Not applicable.
PBT:
vPvB:
Not applicable.
3 Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 7646-85-7
EINECS: 231-592-0
Index number: 030-003-00-2
CAS: 12125-02-9
EINECS: 235-186-4
Index number: 017-014-00-8
·
Additional information:
Mixture of substances listed below with nonhazardous additions.
zinc chloride
C R34; Xn R22; N R50/53
Skin Corr. 1B, H314
Aquatic Acute 1, H400; Aquatic Chronic 1, H410
Acute Tox. 4, H302
ammonium chloride
Xn R22; Xi R36
Acute Tox. 4, H302; Eye Irrit. 2, H319
For the wording of the listed risk phrases refer to section 16.
10-25%
< 5,0%
4 First aid measures
·
4.1 Description of first aid measures
·
General information:
Immediately remove any clothing soiled by the product.
Take affected persons out into the fresh air.
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(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 3)
·
After inhalation:
·
After skin contact:
Immediately rinse with water.
If skin irritation continues, consult a doctor.
Seek immediate medical help for blistering or open wounds.
·
After eye contact:
Remove contact lenses if worn, if possible.
Rinse opened eye for several minutes under running water. Then consult a doctor.
·
After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; call for medical help immediately.
·
4.2 Most important symptoms and effects, both acute and delayed
Strong caustic effect on skin and mucous membranes.
Breathing difficulty
Coughing
Nausea
Cramp
Gastric or intestinal disorders.
·
Hazards
Danger of gastric perforation.
Danger of severe eye injury.
·
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Supply fresh air; consult doctor in case of complaints.
5 Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
·
For safety reasons unsuitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
CO2, sand, extinguishing powder. Do not use water.
Water
Formation of toxic gases is possible during heating or in case of fire.
·
5.3 Advice for firefighters
·
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
·
Additional information
No further relevant information available.
6 Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Use respiratory protective device against the effects of fumes/dust/aerosol.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Particular danger of slipping on leaked/spilled product.
·
6.2 Environmental precautions:
Do not allow to enter sewers/ surface or ground water.
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 4)
Inform respective authorities in case of seepage into water course or sewage system.
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
·
7.1 Precautions for safe handling
Prevent formation of aerosols.
Avoid splashes or spray in enclosed areas.
Use only in well ventilated areas.
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
Unsuitable material for receptacle: aluminium.
Avoid storage near extreme heat, ignition sources or open flame.
·
Information about storage in one common storage facility:
Store away from foodstuffs.
Store away from oxidizing agents.
·
Further information about storage conditions:
·
7.3 Specific end use(s)
No further relevant information available.
No special measures required.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
7646-85-7 zinc chloride
PEL (USA) Long-term value: 1 mg/m³
Fume
REL (USA) Short-term value: 2 mg/m³
Long-term value: 1 mg/m³
TLV (USA) Short-term value: 2 mg/m³
Long-term value: 1 mg/m³
fume
38.0.16
No further data; see item 7.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 5)
EL (Canada) Short-term value: 2 mg/m³
Long-term value: 1 mg/m³
EV (Canada) Short-term value: 2 mg/m³
Long-term value: 1 mg/m³
fume
12125-02-9 ammonium chloride
REL (USA) Short-term value: 20 mg/m³
Long-term value: 10 mg/m³
TLV (USA) Short-term value: 20 mg/m³
Long-term value: 10 mg/m³
EL (Canada) Short-term value: 20 mg/m³
Long-term value: 10 mg/m³
fume
EV (Canada) Short-term value: 20 mg/m³
Long-term value: 10 mg/m³
fume
·
DNELs
·
PNECs
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
·
Respiratory protection:
Not required under normal conditions of use.
Use suitable respiratory protective device when aerosol or mist is formed.
Use suitable respiratory protective device when high concentrations are present.
For spills, respiratory protection may be advisable.
·
Protection of hands:
No further relevant information available.
No further relevant information available.
The lists valid during the making were used as basis.
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideratio n of the penetration times, rates of diffusion and the
degradation.
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has there fore to be
checked prior to the application.
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 6)
·
Penetration time of glove material
The exact break through time has to be found out by the manufactur er of the pr otective gloves and has to
be observed.
·
For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Neoprene gloves
·
Eye protection:
Contact lenses should not be worn.
Safety glasses
·
Body protection:
·
Limitation and supervision of exposure into the environment
Protective work clothing
No further relevant information available.
·
Risk management measures
See Section 7 for additional information.
No further relevant information available.
9 Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
·
Flash point:
·
Flammability (solid, gaseous):
·
Auto/Self-ignition temperature:
·
Decomposition temperature:
·
Self-igniting:
·
Danger of explosion:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure at 20 °C:
Liquid
Yellowish
Petroleum-like
Not determined.
Not determined.
Not Determined.
1330 ° F / 721 °C
390 ° F / 199 °C
Not applicable.
Not determined.
Not determined.
Product is not self-igniting.
Product does not present an explosion hazard.
Not determined.
Not determined.
1 hPa
(Contd. on page 8)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 7)
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
water:
·
Partition coefficient (n-octanol/water):
·
Viscosity:
Dynamic:
Kinematic:
·
9.2 Other information
10 Stability and reactivity
0,815 - 0,880 g/cm³
Not determined.
Not determined.
Not determined.
Not miscible or difficult to mix.
Not determined.
Not determined.
Not determined.
No further relevant information available.
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
·
10.3 Possibility of hazardous reactions
Toxic fumes may be released if heated above the decomposition point.
Reacts with strong oxidizing agents.
Reacts with strong alkali.
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
Store away from oxidizing agents.
No further relevant information available.
Carbon monoxide and carbon dioxide
Chlorine compounds
Toxic metal oxide smoke
11 Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity:
·
LD/LC50 values relevant for classification:
7646-85-7 zinc chloride
Oral LD50 350 mg/kg (rat)
·
Primary irritant effect:
·
on the skin:
·
on the eye:
·
Sensitization:
·
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Caustic effect on skin and mucous membranes.
Strong caustic effect.
No sensitizing effects known.
(Contd. on page 9)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 8)
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus and stomach.
·
Repeated dose toxicity:
·
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
Carc. 1B
12 Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Ecotoxical effects:
·
Remark:
Toxic for fish
The product is oxygen-consuming. The declared action may be partly caused by lack of oxygen.
Due to mechanical actions of the product (e.g. agglutinations) damages may occur.
·
Additional ecological information:
·
General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
Due to available data on eliminability/decomposition and bioaccumulation potential prolonged term
damage of the environment can not be excluded.
·
12.5 Results of PBT and vPvB assessment
·
·
·
Not applicable.
PBT:
vPvB:
Not applicable.
12.6 Other adverse effects
Toxic for aquatic organisms
May cause damage to organs through prolonged or repeated exposure.
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
13 Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Can be burned with household garbage after consulting with the waste disposal facility operator and the
pertinent authorities and adhering to the necessary technical regulations.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all releva nt local, state and fed eral laws and regulations regard ing treatment, storage
and disposal for hazardous and nonhazardous wastes. Residual materials should be treated as
hazardous.
38.0.16
(Contd. on page 10)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 9)
·
Uncleaned packaging:
·
Recommendation:
14 Transport information
·
14.1 UN-Number
·
DOT
·
ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
DOT
·
ADR
·
IMDG
·
IATA
·
14.3 Transport hazard class(es)
·
DOT
·
Class
·
ADR
Disposal must be made according to official regulations.
Not Regulated
UN3082
Not Regulated
3082 ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (ZINC CHLORIDE)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (ZINC CHLORIDE), MARINE
POLLUTANT
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (ZINC CHLORIDE)
Not Regulated
·
Class
·
Label
·
IMDG
·
Class
·
Label
·
IATA
·
Class
·
Label
·
14.4 Packing group
·
DOT
·
ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
Special marking (ADR):
9 (M6) Miscellaneous dangerous substances and
articles.
9
9 Miscellaneous dangerous substances and articles.
9
9 Miscellaneous dangerous substances and articles.
9
Not Regulated
III
Yes
Symbol (fish and tree)
(Contd. on page 11)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 10)
·
Special marking (IATA):
·
14.6 Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
Segregation groups
·
14.7 Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
·
Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
·
Transport category
·
Tunnel restriction code
·
UN "Model Regulation":
Symbol (fish and tree)
Warning: Miscellaneous dangerous substances and
articles.
90
F-A,S-F
Acids
Not applicable.
5L
3
E
UN3082, ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (ZINC CHLORIDE), 9,
III
15 Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
United States (USA)
·
SARA
·
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
·
Section 313 (Specific toxic chemical listings):
Substance / component not listed individually, but listed under family group as Zinc salts.
7646-85-7 zinc chloride
·
TSCA (Toxic Substances Control Act):
All ingredients are listed.
·
Proposition 65 (California):
·
Chemicals known to cause cancer:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
·
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
·
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
·
Carcinogenic Categories
·
EPA (Environmental Protection Agency)
7646-85-7 zinc chloride D, I, II
(Contd. on page 12)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
(Contd. of page 11)
·
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
·
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
·
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
·
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
·
Canada
·
Canadian Domestic Substances List (DSL)
All ingredients are listed.
·
Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
·
Canadian Ingredient Disclosure list (limit 1%)
7646-85-7 zinc chloride
12125-02-9 ammonium chloride
·
Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products
Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
·
15.2 Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
·
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuse s par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
ACGIH: American Conference of Governmental Industrial Hygienists
(Contd. on page 13)
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Safety Data Sheet
according to 1907/2006/EC (REACH), 1272/2008/EC (CLP), and
GHS
Printing date 12.03.2014 Revision: 12.03.2014
Trade name: SOLDERLENE
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Carc. 1B: Carcinogenicity, Hazard Category 1B
Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
·
Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com
(Contd. of page 12)
38.0.16
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